BR112022021915A2 - Produtos de interpolímero de etileno tendo viscosidade intrínseca de fluxo de fusão (mfivi) única e alta insaturação - Google Patents

Produtos de interpolímero de etileno tendo viscosidade intrínseca de fluxo de fusão (mfivi) única e alta insaturação

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Publication number
BR112022021915A2
BR112022021915A2 BR112022021915A BR112022021915A BR112022021915A2 BR 112022021915 A2 BR112022021915 A2 BR 112022021915A2 BR 112022021915 A BR112022021915 A BR 112022021915A BR 112022021915 A BR112022021915 A BR 112022021915A BR 112022021915 A2 BR112022021915 A2 BR 112022021915A2
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Brazil
Prior art keywords
ethylene interpolymer
interpolymer products
mfivi
melts
ethylene
Prior art date
Application number
BR112022021915A
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English (en)
Inventor
Zhang Zengrong
Sibtain Fazle
Brown Stephen
Kleczek Monika
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Nova Chem Int Sa
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Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of BR112022021915A2 publication Critical patent/BR112022021915A2/pt

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/055 or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

PRODUTOS DE INTERPOLÍMERO DE ETILENO TENDO VISCOSIDADE INTRÍNSECA DE FLUXO DE FUSÃO (MFIVI) ÚNICA E ALTA INSATURAÇÃO. A presente invenção refere-se a produtos de interpolímero de etileno compreendendo um valor de Índice de Viscosidade Intrínseca de Fluxo de Fusão, MFIVI, de = 0,05 a = 0,80; uma primeira derivada de uma função de distribuição de fluxo de fusão, (dLog(1/I_n))/(dLog(loading)) em uma carga de 4000 g, de = -1,85 a = -1,51, uma soma de insaturação, SUMU, de = 0,047 a = 0,100 insaturações por 100 átomos de carbono; e um metal catalítico residual de = 0,03 a = 5 ppm de háfnio. Produtos de interpolímero de etileno compreendem pelo menos dois interpolímeros de etileno. Produtos de interpolímero de etileno são caracterizados por um índice de fusão (I2) de 0,3 a 500 dg/minuto, uma densidade de 0,855 a 0,975 g/cc e de 0 a 25 moles por cento de uma ou mais alfa-olefinas. Produtos de interpolímero de etileno têm polidispersividade, Mw/Mn, de 1,7 a 25; e valores de CDBI50 de 1% a 98%. Esses produtos de interpolímero de etileno têm utilidade em aplicações flexíveis e rígidas.
BR112022021915A 2020-05-08 2021-05-06 Produtos de interpolímero de etileno tendo viscosidade intrínseca de fluxo de fusão (mfivi) única e alta insaturação BR112022021915A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202063021896P 2020-05-08 2020-05-08
PCT/IB2021/053844 WO2021224846A1 (en) 2020-05-08 2021-05-06 Ethylene interpolymer products having unique melt flow-intrinsic viscosity (mfivi) and high unsaturation

Publications (1)

Publication Number Publication Date
BR112022021915A2 true BR112022021915A2 (pt) 2022-12-13

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ID=75904976

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BR112022021915A BR112022021915A2 (pt) 2020-05-08 2021-05-06 Produtos de interpolímero de etileno tendo viscosidade intrínseca de fluxo de fusão (mfivi) única e alta insaturação

Country Status (6)

Country Link
US (1) US20230174756A1 (pt)
EP (1) EP4146711A1 (pt)
BR (1) BR112022021915A2 (pt)
CA (1) CA3179879A1 (pt)
MX (1) MX2022013802A (pt)
WO (1) WO2021224846A1 (pt)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2302305A1 (fr) 1975-02-28 1976-09-24 Charbonnages Ste Chimique Procede perfectionne de polymerisation et de copolyme
JPS5783538A (en) 1980-11-12 1982-05-25 Kyowa Chem Ind Co Ltd Polyolefin composition and agent thereof
GB8610126D0 (en) 1986-04-25 1986-05-29 Du Pont Canada Isopropanolamines
US4731438A (en) 1986-12-30 1988-03-15 Union Carbide Corporation Water treatment method for resin in a purge vessel
US5206075A (en) 1991-12-19 1993-04-27 Exxon Chemical Patents Inc. Sealable polyolefin films containing very low density ethylene copolymers
DE69308153T3 (de) 1992-09-16 2012-04-05 Exxonmobil Chemical Patents, Inc. (N.D.Ges.D. Staates Delaware) Weiche filme mit verbesserten physikalischen eigenschaften
CA2227674C (en) 1998-01-21 2007-04-24 Stephen John Brown Catalyst deactivation
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
EP2344551B1 (en) * 2008-09-25 2014-05-28 Basell Polyolefine GmbH Impact resistant lldpe composition and films made thereof
US10995166B2 (en) * 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films

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Publication number Publication date
EP4146711A1 (en) 2023-03-15
MX2022013802A (es) 2022-11-30
WO2021224846A1 (en) 2021-11-11
US20230174756A1 (en) 2023-06-08
CA3179879A1 (en) 2021-11-11

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