BR112021016858B1

BR112021016858B1 - Composição para tratamento dos cabelos e métodos para tratamento dos cabelos e para preservar a atividade ou minimizar a degradação de compostos à base de tiol

Composição para tratamento dos cabelos e métodos para tratamento dos cabelos e para preservar a atividade ou minimizar a degradação de compostos à base de tiol Download PDF

Info

Publication number: BR112021016858B1
Authority: BR; Brazil
Prior art keywords: hair; weight; acid; composition; mixtures
Prior art date: 2019-04-30

Application number

BR112021016858-3A

Other languages

English (en)

Portuguese (pt)

Other versions

BR112021016858A2 (pt

Inventor

Pedro Henrique Pereira De Carvalho

Bruno SATO

Original Assignee

L'oreal

Priority date

2019-04-30

Filing date

2019-04-30

Publication date

2023-09-26

2019-04-30 Application filed by L'oreal filed Critical L'oreal

2022-01-18 Publication of BR112021016858A2 publication Critical patent/BR112021016858A2/pt

2023-09-26 Publication of BR112021016858B1 publication Critical patent/BR112021016858B1/pt

Links

239000000203 mixture Substances 0.000 title claims abstract description 419
210000004209 hair Anatomy 0.000 title claims abstract description 409
238000011282 treatment Methods 0.000 title claims abstract description 123
150000001875 compounds Chemical class 0.000 title claims abstract description 73
238000000034 method Methods 0.000 title claims abstract description 43
230000000694 effects Effects 0.000 title claims abstract description 30
230000015556 catabolic process Effects 0.000 title claims abstract description 9
238000006731 degradation reaction Methods 0.000 title claims abstract description 9
150000003839 salts Chemical class 0.000 claims abstract description 88
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 73
239000003795 chemical substances by application Substances 0.000 claims abstract description 39
239000002562 thickening agent Substances 0.000 claims abstract description 37
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 36
239000002738 chelating agent Substances 0.000 claims abstract description 33
239000003638 chemical reducing agent Substances 0.000 claims abstract description 29
150000003573 thiols Chemical class 0.000 claims abstract description 28
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 26
239000002736 nonionic surfactant Substances 0.000 claims abstract description 25
239000004322 Butylated hydroxytoluene Substances 0.000 claims abstract description 23
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 23
235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 23
229940095259 butylated hydroxytoluene Drugs 0.000 claims abstract description 23
239000003093 cationic surfactant Substances 0.000 claims abstract description 19
IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims abstract description 13
IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims abstract description 13
235000002949 phytic acid Nutrition 0.000 claims abstract description 13
239000000467 phytic acid Substances 0.000 claims abstract description 13
229940068041 phytic acid Drugs 0.000 claims abstract description 13
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 13
235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 13
KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 claims abstract description 13
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims abstract description 12
-1 MEA-thiolactate Chemical compound 0.000 claims description 121
PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 claims description 58
150000002191 fatty alcohols Chemical class 0.000 claims description 39
229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 39
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125000000217 alkyl group Chemical group 0.000 claims description 32
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235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 27
150000001412 amines Chemical class 0.000 claims description 26
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239000000194 fatty acid Substances 0.000 claims description 25
229930195729 fatty acid Natural products 0.000 claims description 25
150000004665 fatty acids Chemical class 0.000 claims description 24
229910019142 PO4 Inorganic materials 0.000 claims description 23
230000003472 neutralizing effect Effects 0.000 claims description 23
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 22
235000021317 phosphate Nutrition 0.000 claims description 22
230000009471 action Effects 0.000 claims description 21
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 19
239000002453 shampoo Substances 0.000 claims description 18
229920002125 Sokalan® Polymers 0.000 claims description 16
238000001035 drying Methods 0.000 claims description 15
241001558929 Sclerotium <basidiomycota> Species 0.000 claims description 14
239000002253 acid Substances 0.000 claims description 14
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 14
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235000001014 amino acid Nutrition 0.000 claims description 13
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235000019698 starch Nutrition 0.000 claims description 11
235000018417 cysteine Nutrition 0.000 claims description 10
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 10
RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 10
DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 10
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 9
XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 8
DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims description 7
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
150000003863 ammonium salts Chemical class 0.000 claims description 7
UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 claims description 7
229960003151 mercaptamine Drugs 0.000 claims description 7
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 6
125000005250 alkyl acrylate group Chemical group 0.000 claims description 6
DKIDEFUBRARXTE-UHFFFAOYSA-M 3-mercaptopropionate Chemical compound [O-]C(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-M 0.000 claims description 5
108010024636 Glutathione Proteins 0.000 claims description 5
PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 claims description 5
229960004308 acetylcysteine Drugs 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 5
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 5
229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 5
VHJLVAABSRFDPM-QWWZWVQMSA-N dithiothreitol Chemical compound SC[C@@H](O)[C@H](O)CS VHJLVAABSRFDPM-QWWZWVQMSA-N 0.000 claims description 5
229960003180 glutathione Drugs 0.000 claims description 5
235000019136 lipoic acid Nutrition 0.000 claims description 5
PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 claims description 5
KOODSCBKXPPKHE-UHFFFAOYSA-N propanethioic s-acid Chemical compound CCC(S)=O KOODSCBKXPPKHE-UHFFFAOYSA-N 0.000 claims description 5
229960002663 thioctic acid Drugs 0.000 claims description 5
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 claims description 5
229950006389 thiodiglycol Drugs 0.000 claims description 5
229940035024 thioglycerol Drugs 0.000 claims description 5
NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 claims description 5
NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 claims description 5
229940103494 thiosalicylic acid Drugs 0.000 claims description 5
150000007513 acids Chemical class 0.000 claims description 4
150000008041 alkali metal carbonates Chemical class 0.000 claims description 4
150000001342 alkaline earth metals Chemical class 0.000 claims description 4
239000004584 polyacrylic acid Substances 0.000 claims description 4
GADGMZDHLQLZRI-UHFFFAOYSA-N 2-[(4-Aminobenzoyl)amino]pentanedioic acid Chemical compound NC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 GADGMZDHLQLZRI-UHFFFAOYSA-N 0.000 claims description 3
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
MCBAUZCCHPWCRR-UHFFFAOYSA-N CC(O)C(=S)OCC(O)CO Chemical compound CC(O)C(=S)OCC(O)CO MCBAUZCCHPWCRR-UHFFFAOYSA-N 0.000 claims description 3
229920001503 Glucan Polymers 0.000 claims description 3
FFFHZYDWPBMWHY-VKHMYHEASA-N L-homocysteine Chemical compound OC(=O)[C@@H](N)CCS FFFHZYDWPBMWHY-VKHMYHEASA-N 0.000 claims description 3
AXFZADXWLMXITO-UHFFFAOYSA-N N-acetylcysteamine Chemical compound CC(=O)NCCS AXFZADXWLMXITO-UHFFFAOYSA-N 0.000 claims description 3
VHFSMDHANDABQK-UHFFFAOYSA-N azane;2-sulfanylpropanoic acid Chemical compound [NH4+].CC(S)C([O-])=O VHFSMDHANDABQK-UHFFFAOYSA-N 0.000 claims description 3
WNZWVZCUFRJIBG-UHFFFAOYSA-N n-(2-sulfanylethyl)propanamide Chemical compound CCC(=O)NCCS WNZWVZCUFRJIBG-UHFFFAOYSA-N 0.000 claims description 3
159000000000 sodium salts Chemical class 0.000 claims description 3
229940061629 trideceth-9 Drugs 0.000 claims description 3
229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 2
XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 2
MZCAZOUPSJQYMW-UHFFFAOYSA-N 2,3-dihydroxypropyl 2-sulfanylpropanoate Chemical compound CC(S)C(=O)OCC(O)CO MZCAZOUPSJQYMW-UHFFFAOYSA-N 0.000 claims 1
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AGBQKNBQESQNJD-UHFFFAOYSA-M lipoate Chemical compound [O-]C(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-M 0.000 claims 1
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230000003750 conditioning effect Effects 0.000 abstract description 11
230000008901 benefit Effects 0.000 abstract description 9
238000011038 discontinuous diafiltration by volume reduction Methods 0.000 abstract description 5
235000002639 sodium chloride Nutrition 0.000 description 94
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CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 13
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NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 13
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OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 8
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