BR112017017446A2 - componentes catalisadores para a polimerização de olefinas - Google Patents

componentes catalisadores para a polimerização de olefinas

Info

Publication number
BR112017017446A2
BR112017017446A2 BR112017017446A BR112017017446A BR112017017446A2 BR 112017017446 A2 BR112017017446 A2 BR 112017017446A2 BR 112017017446 A BR112017017446 A BR 112017017446A BR 112017017446 A BR112017017446 A BR 112017017446A BR 112017017446 A2 BR112017017446 A2 BR 112017017446A2
Authority
BR
Brazil
Prior art keywords
olefin polymerization
catalyst components
electron donor
stereospecificity
alkylaluminum
Prior art date
Application number
BR112017017446A
Other languages
English (en)
Other versions
BR112017017446B1 (pt
Inventor
Mignogna Alessandro
Morini Giampiero
Original Assignee
Basell Poliolefine Italia Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia Srl filed Critical Basell Poliolefine Italia Srl
Publication of BR112017017446A2 publication Critical patent/BR112017017446A2/pt
Publication of BR112017017446B1 publication Critical patent/BR112017017446B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6495Catalysts containing a specific non-metal or metal-free compound organic containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6498Catalysts containing a specific non-metal or metal-free compound organic containing another heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/655Pretreating with metals or metal-containing compounds with aluminium or compounds thereof

Abstract

trata-se de um componente catalisador sólido para a polimerização de olefinas que compreende mg, ti e um doador de elétrons de fórmula (i) ou (ii). quando ativado com um alquilalumínio e, opcionalmente, um doador de elétrons externo, tem a capacidade de proporcionar alta atividade e estereoespecificidade na polimerização de olefinas.
BR112017017446-4A 2015-03-10 2016-03-07 Componente catalisador sólido, catalisador e processo para a (co)polimerização de olefinas BR112017017446B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15158467 2015-03-10
EP15158467.9 2015-03-10
PCT/EP2016/054773 WO2016142335A1 (en) 2015-03-10 2016-03-07 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
BR112017017446A2 true BR112017017446A2 (pt) 2018-04-03
BR112017017446B1 BR112017017446B1 (pt) 2022-04-12

Family

ID=52629480

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017017446-4A BR112017017446B1 (pt) 2015-03-10 2016-03-07 Componente catalisador sólido, catalisador e processo para a (co)polimerização de olefinas

Country Status (6)

Country Link
US (1) US10030082B2 (pt)
EP (1) EP3268397B1 (pt)
CN (1) CN107406541B (pt)
BR (1) BR112017017446B1 (pt)
ES (1) ES2730110T3 (pt)
WO (1) WO2016142335A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112021024297A2 (pt) * 2019-07-03 2022-01-11 Basell Poliolefine Italia Srl Componente de catalisador para a polimerização de olefinas, catalisador, e, processo para a (co)polimerização de olefinas
WO2021055212A1 (en) * 2019-09-18 2021-03-25 W.R. Grace & Co.-Conn. Catalyst composition and system having extended lifetime
CN114716587B (zh) * 2021-01-05 2023-06-13 中国科学院化学研究所 含苯乙酸酯类化合物的烯烃聚合固体催化剂组分及其制备方法与应用

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE363977B (pt) 1968-11-21 1974-02-11 Montedison Spa
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1262935B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1256648B (it) 1992-12-11 1995-12-12 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione delle olefine
AUPO591797A0 (en) 1997-03-27 1997-04-24 Commonwealth Scientific And Industrial Research Organisation High avidity polyvalent and polyspecific reagents
ES2213898T3 (es) 1997-03-29 2004-09-01 Basell Poliolefine Italia S.P.A. Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos.
DE19927979A1 (de) * 1999-06-18 2000-10-12 Basf Ag Verfahren zur Hydrierung von Alkylendiolbenzoaten unter Verwendung eines Makroporen aufweisenden Katalysators
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
CN1942488B (zh) * 2004-04-02 2010-12-08 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的组份和催化剂
US7491781B2 (en) 2005-03-08 2009-02-17 Ineos Usa Llc Propylene polymer catalyst donor component
EP2225287B1 (en) * 2007-12-28 2011-08-31 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
BRPI0918698A8 (pt) 2008-12-31 2017-09-19 Grace W R & Co Composição de procatalisador e processo para produzir um polímero baseado em olefina
WO2011068775A1 (en) 2009-12-02 2011-06-09 Dow Global Technologies Inc. Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
MX2012006370A (es) 2009-12-02 2012-09-07 Dow Global Technologies Llc Compuestos de dicarbonato puenteados por dos atomos como donadores internos en catalizadores para la fabricacion de polipropileno.
CN103764689B (zh) 2011-09-20 2016-03-30 东邦钛株式会社 烯烃类聚合用固体催化剂成分、烯烃类聚合用催化剂及烯烃类聚合物的制造方法
EP2636687A1 (en) * 2012-03-07 2013-09-11 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
EP2803679A1 (en) 2013-05-17 2014-11-19 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins

Also Published As

Publication number Publication date
BR112017017446B1 (pt) 2022-04-12
EP3268397A1 (en) 2018-01-17
US10030082B2 (en) 2018-07-24
CN107406541B (zh) 2020-03-31
ES2730110T3 (es) 2019-11-08
CN107406541A (zh) 2017-11-28
US20180057621A1 (en) 2018-03-01
EP3268397B1 (en) 2019-04-17
WO2016142335A1 (en) 2016-09-15

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B15K Others concerning applications: alteration of classification

Free format text: A CLASSIFICACAO ANTERIOR ERA: C08F 4/651

Ipc: C08F 110/06 (2006.01), C08F 10/06 (2006.01), C08F

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/03/2016, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 8A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2765 DE 02-01-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.