BR112017009432A2 - método para alquilação de carga de alimentação. - Google Patents

método para alquilação de carga de alimentação.

Info

Publication number
BR112017009432A2
BR112017009432A2 BR112017009432-0A BR112017009432A BR112017009432A2 BR 112017009432 A2 BR112017009432 A2 BR 112017009432A2 BR 112017009432 A BR112017009432 A BR 112017009432A BR 112017009432 A2 BR112017009432 A2 BR 112017009432A2
Authority
BR
Brazil
Prior art keywords
alkylating
zeolite
catalyst composition
feedstock
molar ratio
Prior art date
Application number
BR112017009432-0A
Other languages
English (en)
Other versions
BR112017009432B1 (pt
Inventor
Jan Deng-Yang
Cox Pelin
J. Schmidt Robert
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Publication of BR112017009432A2 publication Critical patent/BR112017009432A2/pt
Publication of BR112017009432B1 publication Critical patent/BR112017009432B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/085—Isopropylbenzene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)

Abstract

um método para alquilação de uma carga de alimentação é descrito. o método inclui colocar a carga de alimentação que compreende pelo menos um composto aromático alquilatável e um agente alquilante em contato com uma primeira composição de catalisador alquilante sob condições alquilantes, sendo que a primeira composição de catalisador alquilante compreende zeólita uzm-8 e um ligante, a primeira composição de catalisador alquilante tem 20 a 30% em peso de zeólita uzm-8 e o catalisador tem uma razão molar de nitrogênio para alumínio de zeólita de entre 0,01 a 0,040; em que uma seletividade alquilada total em uma temperatura e uma razão molar de composto aromático alquilatável para agente alquilante é maior do que 99,0%.
BR112017009432-0A 2014-11-07 2015-11-04 Método para alquilação de carga de alimentação BR112017009432B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/535933 2014-11-07
US14/535,933 US20160130196A1 (en) 2014-11-07 2014-11-07 Highly selective alkylation process with low zeolite catalyst composition
PCT/US2015/058925 WO2016073543A2 (en) 2014-11-07 2015-11-04 Highly selective alkylation process with low zeolite catalyst composition

Publications (2)

Publication Number Publication Date
BR112017009432A2 true BR112017009432A2 (pt) 2018-01-02
BR112017009432B1 BR112017009432B1 (pt) 2020-10-06

Family

ID=55910022

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017009432-0A BR112017009432B1 (pt) 2014-11-07 2015-11-04 Método para alquilação de carga de alimentação

Country Status (9)

Country Link
US (1) US20160130196A1 (pt)
EP (1) EP3215477B1 (pt)
JP (1) JP2017537076A (pt)
KR (1) KR102349074B1 (pt)
CN (1) CN107108400A (pt)
BR (1) BR112017009432B1 (pt)
ES (1) ES2815534T3 (pt)
SG (1) SG11201703661RA (pt)
WO (1) WO2016073543A2 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160289140A1 (en) * 2015-03-31 2016-10-06 Uop Llc Highly selective alkylation process with low zeolite catalyst composition
CN112973778B (zh) * 2021-02-05 2022-03-22 浙江大学 一种铁锆双金属负载型催化剂及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL76445C (pt) 1950-03-08
US7638667B2 (en) 2003-03-21 2009-12-29 Uop Llc Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition
US7268267B2 (en) 2003-03-21 2007-09-11 Uop Llc Alkylation process using UZM-8 zeolite
US7091390B2 (en) 2003-03-21 2006-08-15 Uop Llc Hydrocarbon conversion processes using catalysts comprising UZM-8 and UZM-8HS compositions
US6756030B1 (en) 2003-03-21 2004-06-29 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-8
US7420098B2 (en) * 2007-01-12 2008-09-02 Uop Llc Dual zone aromatic alkylation process
BRPI0920705B1 (pt) * 2008-10-10 2018-02-06 Exxonmobil Chemical Patents Inc. Processo para a produção de compostos alquilaromáticos
US8518847B2 (en) 2009-09-30 2013-08-27 Uop Llc Aromatic alkylation catalyst
RU2528825C2 (ru) * 2010-03-10 2014-09-20 Эксонмобил Кемикэл Пейтентс Инк. Получение алкилированных ароматических соединений
US8853481B2 (en) 2012-10-26 2014-10-07 Uop Llc Highly selective alkylation process with low zeolite catalyst composition

Also Published As

Publication number Publication date
US20160130196A1 (en) 2016-05-12
BR112017009432B1 (pt) 2020-10-06
CN107108400A (zh) 2017-08-29
EP3215477B1 (en) 2020-07-01
KR102349074B1 (ko) 2022-01-11
WO2016073543A2 (en) 2016-05-12
SG11201703661RA (en) 2017-06-29
EP3215477A4 (en) 2018-03-07
JP2017537076A (ja) 2017-12-14
KR20170080650A (ko) 2017-07-10
ES2815534T3 (es) 2021-03-30
WO2016073543A3 (en) 2016-07-07
EP3215477A2 (en) 2017-09-13

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 04/11/2015, OBSERVADAS AS CONDICOES LEGAIS.