BR112016013566B1 - Composição de polímero, isolamento do cabo de alimentação, seu processo de produção e cabo de alimentação - Google Patents
Composição de polímero, isolamento do cabo de alimentação, seu processo de produção e cabo de alimentação Download PDFInfo
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- BR112016013566B1 BR112016013566B1 BR112016013566-0A BR112016013566A BR112016013566B1 BR 112016013566 B1 BR112016013566 B1 BR 112016013566B1 BR 112016013566 A BR112016013566 A BR 112016013566A BR 112016013566 B1 BR112016013566 B1 BR 112016013566B1
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- Prior art keywords
- polymer composition
- power cable
- polyolefin
- cross
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- 239000000203 mixture Substances 0.000 title claims abstract description 400
- 229920000642 polymer Polymers 0.000 title claims abstract description 322
- 238000004519 manufacturing process Methods 0.000 title abstract description 23
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- 238000000034 method Methods 0.000 claims description 83
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- 239000000155 melt Substances 0.000 claims description 34
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- 229920001519 homopolymer Polymers 0.000 claims description 11
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
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- CIYWARODCYRXIC-UHFFFAOYSA-N dec-1-ene Chemical compound CCCCCCCCC=C.CCCCCCCCC=C CIYWARODCYRXIC-UHFFFAOYSA-N 0.000 description 3
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- 238000004458 analytical method Methods 0.000 description 2
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- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical class ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 1
- IMYCVFRTNVMHAD-UHFFFAOYSA-N 1,1-bis(2-methylbutan-2-ylperoxy)cyclohexane Chemical compound CCC(C)(C)OOC1(OOC(C)(C)CC)CCCCC1 IMYCVFRTNVMHAD-UHFFFAOYSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- CCNDOQHYOIISTA-UHFFFAOYSA-N 1,2-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1C(C)(C)OOC(C)(C)C CCNDOQHYOIISTA-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 1
- AXWJKQDGIVWVEW-UHFFFAOYSA-N 2-(dimethylamino)butanedioic acid Chemical compound CN(C)C(C(O)=O)CC(O)=O AXWJKQDGIVWVEW-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 1
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- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
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- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 238000012565 NMR experiment Methods 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
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- BXIQXYOPGBXIEM-UHFFFAOYSA-N butyl 4,4-bis(tert-butylperoxy)pentanoate Chemical compound CCCCOC(=O)CCC(C)(OOC(C)(C)C)OOC(C)(C)C BXIQXYOPGBXIEM-UHFFFAOYSA-N 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/01—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
- H01B7/0275—Disposition of insulation comprising one or more extruded layers of insulation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| EP13198412 | 2013-12-19 | ||
| EP13198412.2 | 2013-12-19 | ||
| PCT/EP2014/067628 WO2015090639A1 (en) | 2013-12-19 | 2014-08-19 | A new polymer composition, power cable insulation and power cable |
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| BR112016013566A2 BR112016013566A2 (https=) | 2017-08-08 |
| BR112016013566B1 true BR112016013566B1 (pt) | 2022-04-19 |
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| EP (2) | EP3569648B1 (https=) |
| JP (2) | JP6660880B2 (https=) |
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| PL (2) | PL3083795T3 (https=) |
| RU (1) | RU2690182C1 (https=) |
| WO (1) | WO2015090639A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| AU2010318182B2 (en) * | 2009-11-11 | 2014-07-24 | Borealis Ag | Crosslinkable polymer composition and cable with advantageous electrical properties |
| EP3591670A1 (en) * | 2010-11-03 | 2020-01-08 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| RU2684778C1 (ru) | 2013-12-19 | 2019-04-15 | Бореалис Аг | Новая полимерная композиция с низким ПТР, изоляция силового кабеля и силовой кабель |
| EP3083798B1 (en) * | 2013-12-19 | 2019-11-06 | Borealis AG | A new crosslinked low mfr polymer composition, power cable insulation and power cable |
| KR102253901B1 (ko) | 2013-12-19 | 2021-05-20 | 보레알리스 아게 | 신규 가교결합된 중합체 조성물, 전력 케이블 절연 및 전력 케이블 |
| CN110437525B (zh) | 2013-12-19 | 2022-09-09 | 博里利斯股份公司 | 聚合物组合物、电力电缆绝缘和电力电缆 |
| CN113517085A (zh) * | 2013-12-19 | 2021-10-19 | 博里利斯有限公司 | 电hv输电线缆 |
| EA034758B1 (ru) | 2014-08-19 | 2020-03-17 | Бореалис Аг | Новая сшитая полимерная композиция, структурный слой и кабель |
| JP6610411B2 (ja) * | 2016-04-25 | 2019-11-27 | 住友電装株式会社 | 導電部材 |
| KR102178359B1 (ko) | 2016-11-10 | 2020-11-12 | 주식회사 엘지화학 | 가교 폴리에틸렌 조성물 |
| US20190345277A1 (en) * | 2016-11-16 | 2019-11-14 | Dow Global Technologies Llc | Composition with Balance of Dissipation Factor and Additive Acceptance |
| MX2020001927A (es) * | 2017-08-30 | 2020-03-24 | Dow Global Technologies Llc | Formulacion de poliolefina que contiene peroxido. |
| WO2019210040A1 (en) * | 2018-04-26 | 2019-10-31 | Dow Global Technologies Llc | Polyolefin additive formulations |
| KR20220152082A (ko) * | 2021-05-07 | 2022-11-15 | 주식회사 엘지화학 | 가교구조 함유 올레핀고분자 다공지지체, 이를 포함하는 리튬 이차전지용 가교구조 함유 분리막, 및 상기 분리막을 구비한 리튬 이차전지 |
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| US3401020A (en) | 1964-11-25 | 1968-09-10 | Phillips Petroleum Co | Process and apparatus for the production of carbon black |
| US3922335A (en) | 1974-02-25 | 1975-11-25 | Cabot Corp | Process for producing carbon black |
| JPS5938993B2 (ja) | 1980-03-11 | 1984-09-20 | 電気化学工業株式会社 | カ−ボンブラックの製造装置 |
| US4391789A (en) | 1982-04-15 | 1983-07-05 | Columbian Chemicals Company | Carbon black process |
| JPS63190206A (ja) * | 1987-01-30 | 1988-08-05 | 株式会社フジクラ | 電線・ケ−ブル用絶縁体組成物 |
| JP2579493B2 (ja) | 1987-08-26 | 1997-02-05 | 株式会社フジクラ | 絶縁体組成物 |
| JP2522966B2 (ja) * | 1987-10-13 | 1996-08-07 | 株式会社フジクラ | ポリエチレン組成物 |
| JPH0269541A (ja) | 1988-09-02 | 1990-03-08 | Fujikura Ltd | 絶縁組成物 |
| SE9103077D0 (sv) | 1991-10-22 | 1991-10-22 | Neste Oy | Omaettad etensampolymer och saett foer framstaellning daerav |
| SG49195A1 (en) | 1992-03-05 | 1998-05-18 | Cabot Corp | Process for producing carbon blacks and new carbon blacks |
| SE504364C2 (sv) | 1995-05-12 | 1997-01-20 | Borealis Holding As | Kiselinnehållande etenpolymer baserad på alfa, omega- divnylsiloframställning därav och användning av denna i kompositioner för elektriska kablar |
| CN1214400C (zh) * | 2000-07-26 | 2005-08-10 | 古河电气工业株式会社 | 绝缘的电力电缆 |
| JP4714981B2 (ja) | 2000-10-24 | 2011-07-06 | 日油株式会社 | エチレン系ポリマー組成物 |
| JP4928728B2 (ja) | 2004-12-28 | 2012-05-09 | 日本ポリエチレン株式会社 | 水架橋用ポリエチレン系樹脂原料及び水架橋用ポリエチレン系樹脂組成物並びにそれらを用いた水架橋ポリエチレン系樹脂成形体 |
| ES2335894T3 (es) | 2005-02-28 | 2010-04-06 | Borealis Technology Oy | Procedimiento para preparar composiciones polimericas reticuladas. |
| ES2311181T3 (es) * | 2005-02-28 | 2009-02-01 | Borealis Technology Oy | Composicion polimerica retardante de la combustion. |
| KR100718022B1 (ko) * | 2006-04-25 | 2007-05-14 | 한화석유화학 주식회사 | 트리 내성 가교 폴리올레핀 조성물 |
| RU2394854C1 (ru) | 2008-10-23 | 2010-07-20 | Общество С Ограниченной Ответственностью "Группа Полипластик" | Способ получения композиции для перекисносшитого полиэтилена |
| EA022397B1 (ru) * | 2009-11-11 | 2015-12-30 | Бореалис Аг | Полимерная композиция, силовой кабель, включающий полимерную композицию, и способ его получения |
| AU2010318182B2 (en) | 2009-11-11 | 2014-07-24 | Borealis Ag | Crosslinkable polymer composition and cable with advantageous electrical properties |
| CA2792989C (en) | 2010-03-17 | 2018-08-14 | Borealis Ag | Polymer composition for w&c application with advantageous electrical properties |
| ES2406076T3 (es) * | 2010-10-07 | 2013-06-05 | Borealis Ag | Composición de polímero |
| EP3591670A1 (en) * | 2010-11-03 | 2020-01-08 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| KR101891366B1 (ko) | 2011-05-04 | 2018-08-23 | 보레알리스 아게 | 전기 장치용 중합체 조성물 |
| KR101362560B1 (ko) | 2011-08-08 | 2014-02-14 | 주식회사 엘지화학 | 가교 폴리에틸렌 조성물 |
| CN110437525B (zh) | 2013-12-19 | 2022-09-09 | 博里利斯股份公司 | 聚合物组合物、电力电缆绝缘和电力电缆 |
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2014
- 2014-08-19 CN CN201910754263.4A patent/CN110437525B/zh active Active
- 2014-08-19 EP EP19185881.0A patent/EP3569648B1/en not_active Revoked
- 2014-08-19 BR BR112016013566-0A patent/BR112016013566B1/pt active IP Right Grant
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- 2014-08-19 WO PCT/EP2014/067628 patent/WO2015090639A1/en not_active Ceased
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- 2014-08-19 PL PL14752639T patent/PL3083795T3/pl unknown
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- 2014-08-19 PL PL19185881T patent/PL3569648T3/pl unknown
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2020
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Also Published As
| Publication number | Publication date |
|---|---|
| CA2933234C (en) | 2022-03-01 |
| EP3569648A1 (en) | 2019-11-20 |
| JP2020105520A (ja) | 2020-07-09 |
| KR102253908B1 (ko) | 2021-05-20 |
| US10347390B2 (en) | 2019-07-09 |
| JP6660880B2 (ja) | 2020-03-11 |
| CN105829425B (zh) | 2019-09-10 |
| JP6971342B2 (ja) | 2021-11-24 |
| PL3569648T3 (pl) | 2021-04-19 |
| CN110437525A (zh) | 2019-11-12 |
| EP3569648B1 (en) | 2020-09-30 |
| US20160322124A1 (en) | 2016-11-03 |
| RU2016125879A (ru) | 2018-01-24 |
| JP2017503050A (ja) | 2017-01-26 |
| WO2015090639A1 (en) | 2015-06-25 |
| EP3083795B1 (en) | 2019-10-02 |
| CN105829425A (zh) | 2016-08-03 |
| CA2933234A1 (en) | 2015-06-25 |
| RU2690182C1 (ru) | 2019-05-31 |
| CN110437525B (zh) | 2022-09-09 |
| PL3083795T3 (pl) | 2020-01-31 |
| KR20160119073A (ko) | 2016-10-12 |
| EP3083795A1 (en) | 2016-10-26 |
| BR112016013566A2 (https=) | 2017-08-08 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/08/2014, OBSERVADAS AS CONDICOES LEGAIS. |