BR112015000966B1 - método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato - Google Patents
método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato Download PDFInfo
- Publication number
- BR112015000966B1 BR112015000966B1 BR112015000966A BR112015000966A BR112015000966B1 BR 112015000966 B1 BR112015000966 B1 BR 112015000966B1 BR 112015000966 A BR112015000966 A BR 112015000966A BR 112015000966 A BR112015000966 A BR 112015000966A BR 112015000966 B1 BR112015000966 B1 BR 112015000966B1
- Authority
- BR
- Brazil
- Prior art keywords
- salts
- phosphonate
- phosphonomethyl
- glycine
- group
- Prior art date
Links
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 title abstract 5
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 4
- -1 phosphonate ester salts Chemical class 0.000 title abstract 4
- 150000003839 salts Chemical class 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- ROKAXOISGALEAP-UHFFFAOYSA-N [2,5-dioxo-4-(phosphonomethyl)piperazin-1-yl]methylphosphonic acid Chemical compound OP(O)(=O)CN1CC(=O)N(CP(O)(O)=O)CC1=O ROKAXOISGALEAP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12176751 | 2012-07-17 | ||
| PCT/EP2013/065122 WO2014012988A1 (en) | 2012-07-17 | 2013-07-17 | Method for the synthesis of n-(phosphonomethyl)glycine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015000966A2 BR112015000966A2 (pt) | 2017-06-27 |
| BR112015000966B1 true BR112015000966B1 (pt) | 2020-04-28 |
Family
ID=49000444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015000966A BR112015000966B1 (pt) | 2012-07-17 | 2013-07-17 | método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9150599B2 (https=) |
| EP (1) | EP2875034B1 (https=) |
| CN (1) | CN104812763B (https=) |
| BR (1) | BR112015000966B1 (https=) |
| ES (1) | ES2632779T3 (https=) |
| IN (1) | IN2015DN01078A (https=) |
| PL (1) | PL2875034T3 (https=) |
| RU (1) | RU2674023C9 (https=) |
| WO (1) | WO2014012988A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2875036A1 (en) | 2012-07-17 | 2015-05-27 | Straitmark Holding AG | Method for the synthesis of aminoalkylenephosphonic acid |
| BR112015000995B1 (pt) | 2012-07-17 | 2020-04-28 | Monsanto Technology Llc | método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato |
| RU2674022C9 (ru) | 2012-07-17 | 2019-01-24 | МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи | Способ синтеза альфа-аминоалкиленфосфоновой кислоты |
| RU2015103314A (ru) | 2012-07-17 | 2016-09-10 | Страйтмарк Холдинг Аг | Способ синтеза N-фосфонометилиминодиуксусной кислоты |
| CN112898338A (zh) * | 2019-12-04 | 2021-06-04 | 利尔化学股份有限公司 | 草铵膦中间体及草铵膦的制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3799758A (en) | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3969398A (en) | 1974-05-01 | 1976-07-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| HU173170B (hu) | 1974-06-27 | 1979-03-28 | Chinoin Gyogyszer Es Vegyeszet | Sposob poluchenija n-fosfonometil-glicina |
| US3927080A (en) | 1974-09-03 | 1975-12-16 | Monsanto Co | Process for producing N-phosphonomethyl glycine |
| IL48619A (en) | 1974-12-11 | 1978-04-30 | Monsanto Co | Process for the production of n-(phosphonomethyl)-glycine compounds |
| US4084499A (en) * | 1977-01-21 | 1978-04-18 | Moehlenpah Walter George | Apparatus for fabricating wood structures |
| CH647528A5 (fr) | 1978-10-27 | 1985-01-31 | Bcap Biolog Chem Act Pat | Procede pour la preparation de n-phosphonomethylglycine. |
| US4624937A (en) | 1984-05-10 | 1986-11-25 | Monsanto Company | Process for removing surface oxides from activated carbon catalyst |
| US4804499A (en) * | 1985-09-23 | 1989-02-14 | Monsanto Company | Process for the preparation of N-substituted aminomethylphosphonic acids |
| JP2001511810A (ja) | 1997-02-13 | 2001-08-14 | モンサント カンパニー | アミノカルボン酸の製造方法 |
| BR9912923A (pt) | 1998-08-12 | 2001-10-09 | Monsanto Co | Processo contìnuo para preparação de ácido n-(fosfonometil) iminodiacético |
| AU2001275182A1 (en) | 2000-06-01 | 2001-12-11 | Monsanto Technology Llc | Metal-catalysed carboxymethylation in the presence of a promoter |
| DE10130135A1 (de) * | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von N-Phosphonomethylglycin |
| AU2006232348B2 (en) | 2005-04-01 | 2010-11-25 | Monsanto Technology Llc | Control of N-(phosphonomethyl) iminodiacetic acid conversion in manufacture of glyphosate |
| CL2008003539A1 (es) | 2007-11-28 | 2009-07-03 | Procedimiento para la produccion de p4o6 que comprende mezclar o2 o una mezcla de o2 mas un gas inerte y fosforo en donde el producto obtenido se mantiene dentro de una unidad de reaccion a una temperatura entre los 1600 y 2000 k durante por lo menos 1 segundo. | |
| WO2009130322A1 (en) * | 2008-04-25 | 2009-10-29 | Straitmark Holding Ag | Method for the manufacture of aminoalkylene phosphonic acid |
| BRPI0921736B1 (pt) | 2008-11-12 | 2020-03-24 | Monsanto Technology Llc | Processo para a fabricação de p4o6 com alto rendimento |
-
2013
- 2013-07-17 BR BR112015000966A patent/BR112015000966B1/pt active IP Right Grant
- 2013-07-17 US US14/415,687 patent/US9150599B2/en active Active
- 2013-07-17 ES ES13750513.7T patent/ES2632779T3/es active Active
- 2013-07-17 IN IN1078DEN2015 patent/IN2015DN01078A/en unknown
- 2013-07-17 WO PCT/EP2013/065122 patent/WO2014012988A1/en not_active Ceased
- 2013-07-17 PL PL13750513T patent/PL2875034T3/pl unknown
- 2013-07-17 CN CN201380037315.7A patent/CN104812763B/zh active Active
- 2013-07-17 EP EP13750513.7A patent/EP2875034B1/en active Active
- 2013-07-17 RU RU2015103316A patent/RU2674023C9/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2875034B1 (en) | 2017-05-03 |
| WO2014012988A1 (en) | 2014-01-23 |
| EP2875034A1 (en) | 2015-05-27 |
| RU2674023C2 (ru) | 2018-12-04 |
| RU2015103316A (ru) | 2016-09-10 |
| IN2015DN01078A (https=) | 2015-06-26 |
| CN104812763A (zh) | 2015-07-29 |
| ES2632779T3 (es) | 2017-09-15 |
| PL2875034T3 (pl) | 2017-12-29 |
| CN104812763B (zh) | 2016-11-23 |
| US20150175635A1 (en) | 2015-06-25 |
| RU2674023C9 (ru) | 2019-01-24 |
| BR112015000966A2 (pt) | 2017-06-27 |
| US9150599B2 (en) | 2015-10-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B25A | Requested transfer of rights approved |
Owner name: MONSANTO TECHNOLOGY LLC (US) |
|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/07/2013, OBSERVADAS AS CONDICOES LEGAIS. |