BR112014031820B1 - aduto de politioéter e composição - Google Patents

aduto de politioéter e composição Download PDF

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Publication number
BR112014031820B1
BR112014031820B1 BR112014031820-4A BR112014031820A BR112014031820B1 BR 112014031820 B1 BR112014031820 B1 BR 112014031820B1 BR 112014031820 A BR112014031820 A BR 112014031820A BR 112014031820 B1 BR112014031820 B1 BR 112014031820B1
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BR
Brazil
Prior art keywords
certain embodiments
adduct
groups
group
sulfur
Prior art date
Application number
BR112014031820-4A
Other languages
English (en)
Portuguese (pt)
Other versions
BR112014031820A2 (pt
Inventor
Lawrence G. Anderson
Renhe Lin
Juexiao Cai
Marfi Ito
Raquel Keledjian
Original Assignee
Prc-Desoto International, Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/529,237 external-priority patent/US8871896B2/en
Application filed by Prc-Desoto International, Inc filed Critical Prc-Desoto International, Inc
Publication of BR112014031820A2 publication Critical patent/BR112014031820A2/pt
Publication of BR112014031820B1 publication Critical patent/BR112014031820B1/pt

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J181/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
    • C09J181/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/04Polythioethers from mercapto compounds or metallic derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/04Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/14Polysulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/04Polysulfides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D181/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
    • C09D181/04Polysulfides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J181/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
    • C09J181/04Polysulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Sealing Material Composition (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
BR112014031820-4A 2012-06-21 2013-06-21 aduto de politioéter e composição BR112014031820B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/529,237 2012-06-21
US13/529,237 US8871896B2 (en) 2012-06-21 2012-06-21 Michael addition curing chemistries for sulfur-containing polymer compositions
US13/659,152 2012-10-24
US13/659,152 US9018322B2 (en) 2012-06-21 2012-10-24 Controlled release amine-catalyzed, Michael addition-curable sulfur-containing polymer compositions
PCT/US2013/046948 WO2013192480A2 (en) 2012-06-21 2013-06-21 Michael addition curing chemistries for sulfur-containing polymer compositions

Publications (2)

Publication Number Publication Date
BR112014031820A2 BR112014031820A2 (pt) 2017-06-27
BR112014031820B1 true BR112014031820B1 (pt) 2021-03-09

Family

ID=48700006

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014031820-4A BR112014031820B1 (pt) 2012-06-21 2013-06-21 aduto de politioéter e composição

Country Status (13)

Country Link
US (2) US9018322B2 (enExample)
EP (2) EP2864395B1 (enExample)
JP (1) JP6054524B2 (enExample)
KR (1) KR101674838B1 (enExample)
CN (1) CN104487488B (enExample)
AU (1) AU2013277027B2 (enExample)
BR (1) BR112014031820B1 (enExample)
CA (1) CA2876944C (enExample)
ES (1) ES2722250T3 (enExample)
IN (1) IN2014DN10829A (enExample)
MX (1) MX379006B (enExample)
RU (1) RU2608739C2 (enExample)
WO (1) WO2013192480A2 (enExample)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9056949B2 (en) 2013-06-21 2015-06-16 Prc-Desoto International, Inc. Michael addition curing chemistries for sulfur-containing polymer compositions employing bis(sulfonyl)alkanols
US9006360B2 (en) * 2012-10-24 2015-04-14 Prc-Desoto International, Inc. Controlled-release amine-catalyzed, sulfur-containing polymer and epdxy compositions
US9062139B2 (en) 2013-03-15 2015-06-23 Prc-Desoto International, Inc. Sulfone-containing polythioethers, compositions thereof, and methods of synthesis
US9518197B2 (en) 2014-03-07 2016-12-13 Prc-Desoto International, Inc. Cure-on-demand moisture-curable urethane-containing fuel resistant prepolymers and compositions thereof
US9328275B2 (en) * 2014-03-07 2016-05-03 Prc Desoto International, Inc. Phosphine-catalyzed, michael addition-curable sulfur-containing polymer compositions
US9328274B2 (en) 2014-03-07 2016-05-03 Prc-Desoto International, Inc. Michael acceptor-terminated urethane-containing fuel resistant prepolymers and compositions thereof
US9683129B2 (en) 2014-12-04 2017-06-20 Prc-Desoto International, Inc. Polythioether sealants with extended working time
US9422451B2 (en) * 2015-01-09 2016-08-23 Prc-Desoto International, Inc. Low density fuel resistant sulfur-containing polymer compositions and uses thereof
US10246565B2 (en) * 2015-03-24 2019-04-02 The Boeing Company Rapidly curing adhesives using encapsulated catalyst and focused ultrasound
US9951252B2 (en) 2015-08-10 2018-04-24 Prc-Desoto International, Inc. Moisture-curable fuel-resistant sealant systems
BR112018009837A8 (pt) 2015-11-19 2019-02-26 Ppg Ind Ohio Inc composição catalítica e composição curável
US10035926B2 (en) * 2016-04-22 2018-07-31 PRC—DeSoto International, Inc. Ionic liquid catalysts in sulfur-containing polymer compositions
DE102016111418A1 (de) * 2016-06-22 2017-12-28 Carl Zeiss Smart Optics Gmbh Temporärer Schutzlack für Optikelement
US10370561B2 (en) 2016-06-28 2019-08-06 Prc-Desoto International, Inc. Urethane/urea-containing bis(alkenyl) ethers, prepolymers prepared using urethane/urea-containing bis(alkenyl) ethers, and uses thereof
US11198757B2 (en) 2016-11-03 2021-12-14 3M Innovative Properties Company Compositions including a photolatent amine, camphorquinone, and coumarin and related methods
KR20190082219A (ko) 2016-11-03 2019-07-09 쓰리엠 이노베이티브 프로퍼티즈 컴파니 실란트를 항공기 구성요소에 적용하는 방법
EP3674376B1 (en) * 2017-08-23 2024-12-11 Kansai Paint Co., Ltd Cationic electrodeposition composition and method for electrodeposition
US11098222B2 (en) 2018-07-03 2021-08-24 Prc-Desoto International, Inc. Sprayable polythioether coatings and sealants
US20210371667A1 (en) 2018-09-27 2021-12-02 3M Innovative Properties Company Composition including amino-functional silanes and method of applying a sealant to a substrate
US10843180B2 (en) * 2018-10-02 2020-11-24 Prc-Desoto International, Inc. Delayed cure micro-encapsulated catalysts
CN113079699A (zh) 2018-11-19 2021-07-06 3M创新有限公司 包含多硫醇、聚环氧化物、聚合物催化剂和传导填料的组合物以及与该组合物相关的方法
US10981158B2 (en) 2018-12-20 2021-04-20 Ppg Industries Ohio, Inc. Catalytic compositions and thiolene-based compositions with extended pot life
US11015097B2 (en) 2019-03-06 2021-05-25 Prc-Desoto International, Inc. Chemically resistant sealant compositions and uses thereof
WO2020202076A1 (en) 2019-04-04 2020-10-08 3M Innovative Properties Company Method of irradiating a composition through a substrate
EP3747925A1 (en) * 2019-06-07 2020-12-09 Henkel AG & Co. KGaA Radiation-curable composition by anionic polymerization
US11414524B2 (en) * 2019-10-28 2022-08-16 Eastern Michigan University Organic-inorganic polymeric compositions, related articles, and related methods
US11437162B2 (en) 2019-12-31 2022-09-06 Industrial Technology Research Institute Conductive material composition and conductive material prepared therefrom
WO2021150844A1 (en) 2020-01-24 2021-07-29 Sirrus, Inc. Compositions containing 1,1-disubstituted activated alkenes useful in additive manufacturing and articles formed therefrom
WO2021231288A1 (en) 2020-05-15 2021-11-18 Nippon Shokubai Co., Ltd. Improved dicarbonyl substituted-1-alkene compositions
US20240239960A1 (en) * 2021-04-27 2024-07-18 Ppg Industries Ohio, Inc. Multiple cure coreactive compositions for additive manufacturing and uses thereof
US11708459B2 (en) 2021-10-21 2023-07-25 Inkbit, LLC Vinyl sulfonyl agents for thiol-ene polymerization and related uses
WO2024238268A2 (en) * 2023-05-12 2024-11-21 Arkema Inc. Accelerated peroxide-cured resin compositions having extended open times

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3138573A (en) 1960-05-23 1964-06-23 Coast Pro Seal & Mfg Co Elastomeric polymer and process for making the same
US3215677A (en) * 1961-10-16 1965-11-02 Coast Pro Seal & Mfg Co One part castable liquid thiol-terminated polymer and method of cure
US4059570A (en) * 1974-10-18 1977-11-22 Exxon Research & Engineering Co. Polythioether polyurethanes and their preparation
US4366307A (en) 1980-12-04 1982-12-28 Products Research & Chemical Corp. Liquid polythioethers
US4468202A (en) 1982-02-08 1984-08-28 Howard Cohen Method for making dental impressions
US4609762A (en) 1984-01-30 1986-09-02 Products Research & Chemical Corp. Thioethers having a high sulfur content and method therefor
US4623711A (en) 1985-08-21 1986-11-18 Products Research & Chemical Corp. Modified disulfide polymer composition and method for making same from mercaptan terminated disulfide polymer and diethyl formal mercaptan terminated polysulfide
US4983705A (en) * 1989-01-17 1991-01-08 Dayco Products, Inc. Thermoplastic elastomeric polyimide linked by oligomeric thio chain
US5061566A (en) 1989-12-28 1991-10-29 Chomerics, Inc. Corrosion inhibiting emi/rfi shielding coating and method of its use
US5270364A (en) 1991-09-24 1993-12-14 Chomerics, Inc. Corrosion resistant metallic fillers and compositions containing same
US5225472A (en) 1992-05-19 1993-07-06 Courtaulds Aerospace, Inc. Low viscosity polythiol and method therefor
JPH09111135A (ja) 1995-10-23 1997-04-28 Mitsubishi Materials Corp 導電性ポリマー組成物
AU713518B2 (en) * 1996-03-13 1999-12-02 Tokuyama Corporation Photopolymerizable di(meth)acrylate oligomer composition and transparent cured product thereof
US6509418B1 (en) 1997-02-19 2003-01-21 Prc-Desoto International, Inc. Sealants and potting formulations including mercapto-terminated polymers produced by the reaction of a polythiol and polyvinyl ether monomer
US5912319A (en) 1997-02-19 1999-06-15 Courtaulds Aerospace, Inc. Compositions and method for producing fuel resistant liquid polythioether polymers with good low temperature flexibility
ES2196549T3 (es) * 1997-02-19 2003-12-16 Prc Desoto Int Inc Composicion y metodo para producir polimeros de politioeter liquidos resistentes al combustible con buena flexibilidad a baja temperatura.
US6123179A (en) 1998-02-26 2000-09-26 Kun Teng Industry Co., Ltd Bicycle freewheel hub
KR20010111590A (ko) * 1999-04-26 2001-12-19 샬크비즈크 피이터 코르넬리스; 페트귄터 머캅토-작용기 화합물을 포함하는 조성물
US6525168B2 (en) 2000-03-09 2003-02-25 Pbt Brands, Inc. Chemically resistant polythiothers and formation thereof
CA2459374C (en) * 2001-10-17 2011-02-08 Ciba Specialty Chemicals Holding Inc. Photoactivable nitrogen bases
US20050010003A1 (en) 2003-07-11 2005-01-13 Prc-Desoto International, Inc. Epoxy-capped polythioethers
US7622548B2 (en) * 2003-07-11 2009-11-24 Prc Desoto International, Inc. Epoxy- or amine/hydroxy-capped polythioethers
US7390859B2 (en) * 2005-02-08 2008-06-24 Ppg Industries Ohio, Inc. Compositions and methods of making compositions exhibiting fuel resistance
US8349951B2 (en) * 2005-05-31 2013-01-08 Prc Desoto International, Inc. Polythioether polymers and curable compositions containing them
US20070096396A1 (en) * 2005-10-27 2007-05-03 Sawant Suresh G Dimercaptan terminated polythioether polymers and methods for making and using the same
US20070173602A1 (en) * 2006-01-25 2007-07-26 Brinkman Larry F Encapsulated Michael addition catalyst
US7879955B2 (en) 2007-05-01 2011-02-01 Rao Chandra B Compositions including a polythioether
US8816023B2 (en) 2008-08-13 2014-08-26 Ppg Industries Ohio, Inc Lightweight particles and compositions containing them
US8143370B2 (en) * 2009-07-09 2012-03-27 Prc-Desoto International, Inc. One-part moisture curable sealant and method of making the same
US8729198B2 (en) * 2010-08-13 2014-05-20 Prc Desoto International, Inc. Compositions comprising thiol-terminated polymers and sulfur-containing ethylenically unsaturated silanes and related cured sealants
US9080004B2 (en) * 2010-10-07 2015-07-14 Prc-Desoto International, Inc. Diethylene glycol monomethyl ether resistant coating
US8871896B2 (en) * 2012-06-21 2014-10-28 Prc Desoto International, Inc. Michael addition curing chemistries for sulfur-containing polymer compositions

Also Published As

Publication number Publication date
IN2014DN10829A (enExample) 2015-09-04
WO2013192480A3 (en) 2014-02-13
MX379006B (es) 2025-03-11
RU2015101718A (ru) 2016-08-10
ES2722250T3 (es) 2019-08-08
US9018322B2 (en) 2015-04-28
JP6054524B2 (ja) 2016-12-27
MX2014015630A (es) 2015-07-06
WO2013192480A2 (en) 2013-12-27
AU2013277027B2 (en) 2015-08-27
EP2864395A2 (en) 2015-04-29
BR112014031820A2 (pt) 2017-06-27
KR20150023044A (ko) 2015-03-04
EP3495435A1 (en) 2019-06-12
AU2013277027A1 (en) 2015-01-22
RU2608739C2 (ru) 2017-01-23
EP2864395B1 (en) 2019-03-13
CA2876944A1 (en) 2013-12-27
US20130345389A1 (en) 2013-12-26
CA2876944C (en) 2016-12-13
US20150099858A1 (en) 2015-04-09
HK1204634A1 (en) 2015-11-27
CN104487488A (zh) 2015-04-01
US9499668B2 (en) 2016-11-22
CN104487488B (zh) 2016-08-03
KR101674838B1 (ko) 2016-11-09
JP2015520293A (ja) 2015-07-16

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