BR112014026394A2 - catalisadores de hidrogenação, método para os produzir e sua utilização para preparar peróxido de hidrogênio - Google Patents

catalisadores de hidrogenação, método para os produzir e sua utilização para preparar peróxido de hidrogênio

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Publication number
BR112014026394A2
BR112014026394A2 BR112014026394A BR112014026394A BR112014026394A2 BR 112014026394 A2 BR112014026394 A2 BR 112014026394A2 BR 112014026394 A BR112014026394 A BR 112014026394A BR 112014026394 A BR112014026394 A BR 112014026394A BR 112014026394 A2 BR112014026394 A2 BR 112014026394A2
Authority
BR
Brazil
Prior art keywords
catalyst
hydrogen peroxide
weight
producing
hydrogenation catalysts
Prior art date
Application number
BR112014026394A
Other languages
English (en)
Inventor
Lemaire Arnaud
Pierre Ganhy Jean
Dournel Pierre
Original Assignee
Solvay
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay filed Critical Solvay
Publication of BR112014026394A2 publication Critical patent/BR112014026394A2/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1/1 resumo "catalisadores de hidrogenação, método para os produzir e sua utilização para preparar peróxido de hidrogênio" a presente invenção descreve um catalisador de hidrogenação baseado em paládio em um suporte de óxido de silício (sio2), óxido de alumínio (al2o3) ou aluminossilicato em que o catalisador compreende uma quantidade de paládio de 1,5 a 2,5 % em peso em relação ao peso do catalisador e uma quantidade de prata de 0,1 a 0,5 % em peso em relação ao peso do catalisador e em que de preferência o catalisador compreende ainda ouro em uma quantidade de até 0,1 % em peso em relação ao peso do catalisador. o suporte preferido em uma forma de realização da invenção é um suporte de óxido de delta-alumínio (delta-al2o3). o catalisador pode ser usado em vários tipos de hidrogenação, e de preferência o catalisador é proposto para ser usado na produção de peróxido de hidrogênio pelo processo de auto-oxidação.
BR112014026394A 2012-04-27 2013-04-17 catalisadores de hidrogenação, método para os produzir e sua utilização para preparar peróxido de hidrogênio BR112014026394A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12165962 2012-04-27
PCT/EP2013/057962 WO2013160163A1 (en) 2012-04-27 2013-04-17 Hydrogenation catalysts, method for making same and use thereof for preparing hydrogen peroxide

Publications (1)

Publication Number Publication Date
BR112014026394A2 true BR112014026394A2 (pt) 2017-06-27

Family

ID=48095882

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014026394A BR112014026394A2 (pt) 2012-04-27 2013-04-17 catalisadores de hidrogenação, método para os produzir e sua utilização para preparar peróxido de hidrogênio

Country Status (5)

Country Link
AR (1) AR090855A1 (pt)
BR (1) BR112014026394A2 (pt)
CL (1) CL2014002910A1 (pt)
UY (1) UY34766A (pt)
WO (1) WO2013160163A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017028905A1 (en) * 2015-08-18 2017-02-23 Solvay Sa Gold containing catalyst for the selective deoxygenation of quinone epoxides
CN106179427B (zh) * 2016-07-06 2019-06-18 江苏晶晶新材料有限公司 一种高效长寿命蒽醌降解物再生催化剂及其制备方法
CN109833869A (zh) * 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 一种浆态床加氢催化剂及其制备方法和应用
CN108892108A (zh) * 2018-09-03 2018-11-27 江山市双氧水有限公司 一种双氧水稀品生产装置中涉及氢化液贮槽的工艺系统
KR20220156936A (ko) 2020-03-23 2022-11-28 바스프 에스이 Po 제조를 위한 dibc 무함유 h2o2
EP3906998A1 (en) 2020-05-05 2021-11-10 BASF Corporation Supported transition metal nanoparticle catalyst and use thereof as a hydrogenation catalyst
US11712689B2 (en) * 2020-06-08 2023-08-01 University Of South Carolina High activity platinum and nickel yolk-shell catalysts

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2158525A (en) 1935-10-10 1939-05-16 Ig Farbenindustrie Ag Production of hydrogen peroxide
IT360853A (pt) 1937-04-07
JPS495120B1 (pt) * 1969-10-03 1974-02-05
JP2000510042A (ja) 1996-05-14 2000-08-08 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー 耐火性担体上にナノ微粒子状金属を有する触媒組成物
BR9712193A (pt) 1996-10-04 1999-08-31 . Catalisadores de hidrogenação à base de paládio, platina ou ródio, sobre um suporte de óxidos de zircónio e de silício, processo de fabricação e utilização dos mesmos, e, processo de fabricação de peróxido de hidrogênio.
DE19642770A1 (de) 1996-10-16 1998-04-23 Basf Ag Verfahren zur Herstellung von Wasserstoffperoxid
US6346228B1 (en) 1999-02-19 2002-02-12 Council Of Scientific And Industrial Research Hydrophobic multicomponent catalyst useful for direct oxidation of hydrogen to hydrogen peroxide
DE19912733A1 (de) 1999-03-20 2000-09-21 Degussa Verfahren zur Herstellung von Wasserstoffperoxid durch Direktsynthese
US6432376B1 (en) 2000-09-05 2002-08-13 Council Of Scientific & Industrial Research Membrane process for the production of hydrogen peroxide by non-hazardous direct oxidation of hydrogen by oxygen using a novel hydrophobic composite Pd-membrane catalyst
US6448199B1 (en) 2000-09-05 2002-09-10 Council Of Scientific & Industrial Research Hydrophobic composite Pd-membrane catalyst useful for non-hazardous direct oxidation of hydrogen by oxygen to hydrogen peroxide and method of its preparation
EP1195197B1 (en) 2000-10-06 2015-07-08 Akzo Nobel N.V. Catalyst carrier comprising a fibre paper impregnated with micro fibres, process for its production and its uses
DE10153546A1 (de) 2001-10-30 2003-05-22 Degussa Direktsynthese von Wasserstoffperoxid und deren Integration in Oxidationsprozesse
US20100152022A1 (en) 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method

Also Published As

Publication number Publication date
AR090855A1 (es) 2014-12-10
CL2014002910A1 (es) 2015-01-30
WO2013160163A1 (en) 2013-10-31
UY34766A (es) 2013-09-30

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]