BR112013004268A8 - formação sequencial de catalisador de ziegler-natta usando componentes não combinados - Google Patents
formação sequencial de catalisador de ziegler-natta usando componentes não combinados Download PDFInfo
- Publication number
- BR112013004268A8 BR112013004268A8 BR112013004268A BR112013004268A BR112013004268A8 BR 112013004268 A8 BR112013004268 A8 BR 112013004268A8 BR 112013004268 A BR112013004268 A BR 112013004268A BR 112013004268 A BR112013004268 A BR 112013004268A BR 112013004268 A8 BR112013004268 A8 BR 112013004268A8
- Authority
- BR
- Brazil
- Prior art keywords
- contacting
- reaction product
- agent
- magnesium
- compound
- Prior art date
Links
- 239000011954 Ziegler–Natta catalyst Substances 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 4
- -1 alkyl magnesium compound Chemical class 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 229910052749 magnesium Inorganic materials 0.000 abstract 4
- 239000011777 magnesium Substances 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004034 viscosity adjusting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
formação sequencial de catalisador de ziegler-natta usando componentes não combinados. a presente invenção refere-se a um método de formar catalisadores, incluindo contatar um composto de alquil magnésio com um modificador da viscosidade, antes de contatar com um álcool, para formar um composto de dialcóxido de magnésio; contatar o composto de diailcó de magnásio; contator o composto de dialcóxido de magnésio com um primeiro alcóxido de titânio e um primeiro agente, para formar um primeiro produto de reação em solução "a", em que o alcóxido de titânio e o primeiro agente são componentes individuais não combinados antes de contatar o dialcóxido de magnésio; contatar o primeiro produto de reação em solução "a" com um segundo alcóxido de titânia, para formar um segundo produto de reação em solução "b", contatar o segundo produto de reação em solução "b" com um segundo agente, para formar um primeiro produto de reação sólido "c", contatar o primeiro produto de reação sólido "c" com um terceiro agente, para formar um segundo produto de reação sólido "d"; e contatar o segundo produto de reação sólido "d" com um agente redutor, para formar um componente de catalisador.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/861,349 US20120046429A1 (en) | 2010-08-23 | 2010-08-23 | Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components |
| PCT/US2011/044305 WO2012036785A1 (en) | 2010-08-23 | 2011-07-18 | Sequential formation of ziegler-natta catalyst using non-blended components |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112013004268A2 BR112013004268A2 (pt) | 2016-08-02 |
| BR112013004268A8 true BR112013004268A8 (pt) | 2018-07-10 |
Family
ID=45594582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112013004268A BR112013004268A8 (pt) | 2010-08-23 | 2011-07-18 | formação sequencial de catalisador de ziegler-natta usando componentes não combinados |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20120046429A1 (pt) |
| EP (1) | EP2608883B1 (pt) |
| CN (1) | CN103068484A (pt) |
| BR (1) | BR112013004268A8 (pt) |
| CA (1) | CA2807727C (pt) |
| ES (1) | ES2736002T3 (pt) |
| MX (1) | MX352514B (pt) |
| TW (1) | TWI530322B (pt) |
| WO (1) | WO2012036785A1 (pt) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10711077B2 (en) * | 2011-02-07 | 2020-07-14 | Fina Technology, Inc. | Ziegler-natta catalyst composition with controlled morphology |
| US9624321B2 (en) * | 2014-06-13 | 2017-04-18 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
| US9650448B2 (en) * | 2014-06-13 | 2017-05-16 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
| CN105622798B (zh) * | 2014-11-06 | 2018-08-17 | 中国石油化工股份有限公司 | 一种烯烃聚合用的催化剂组分、制备方法及其应用 |
| US11214633B2 (en) * | 2019-09-10 | 2022-01-04 | Braskem America, Inc. | Ziegler-Natta catalyst systems and methods of controlling particle size |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US5567665A (en) * | 1994-03-31 | 1996-10-22 | Union Carbide Chemicals & Plastics Technology Corporation | Shape-shifted magnesium alkoxide component for polymerizing olefins |
| US4855271A (en) * | 1987-06-22 | 1989-08-08 | Phillips Petroleum Company | Catalyst and polymerization of olefins |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5456471A (en) | 1992-08-18 | 1995-10-10 | Macdonald; Donald K. | Golf practice apparatus and fabricating process |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| AU682821B2 (en) | 1993-04-26 | 1997-10-23 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US6245705B1 (en) | 1993-11-18 | 2001-06-12 | Univation Technologies | Cocatalysts for metallocene-based olefin polymerization catalyst systems |
| US5525678A (en) | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| US5945366A (en) | 1995-08-21 | 1999-08-31 | Toho Titanium Co., Ltd. | Solid catalyst component for polymerization of olefins and catalyst |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| US6734134B1 (en) | 1997-01-28 | 2004-05-11 | Fina Technology, Inc. | Ziegler-natta catalyst for tuning MWD of polyolefin, method of making, method of using, and polyolefins made therewith |
| US6864207B2 (en) | 1997-01-28 | 2005-03-08 | Fina Technology, Inc. | Ziegler-Natta catalyst for polyolefins |
| US6174971B1 (en) | 1997-01-28 | 2001-01-16 | Fina Technology, Inc. | Ziegler-natta catalysts for olefin polymerization |
| US6930071B2 (en) * | 1997-01-28 | 2005-08-16 | Fina Technology, Inc. | Ziegler-natta catalyst for polyolefins |
| US6693058B1 (en) * | 1997-01-28 | 2004-02-17 | Fina Technology, Inc. | Ziegler-natta catalyst for narrow to broad MWD of polyoefins, method of making, method of using, and polyolefins made therewith |
| US6242545B1 (en) | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
| US6124507A (en) | 1997-12-10 | 2000-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donors |
| US6207606B1 (en) | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
| US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| US6147173A (en) | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| US6180735B1 (en) | 1998-12-17 | 2001-01-30 | Univation Technologies | Catalyst composition and methods for its preparation and use in a polymerization process |
| US6339134B1 (en) | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
| CA2369170A1 (en) * | 1999-06-30 | 2001-01-04 | Robert Charles Job | Magnesium/titanium alkoxide complexes and polymerization catalysts made therefrom |
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6271323B1 (en) | 1999-10-28 | 2001-08-07 | Univation Technologies, Llc | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
| US6380328B1 (en) | 1999-12-10 | 2002-04-30 | Univation Technologies, Llc | Catalyst systems and their use in a polymerization process |
| US6346586B1 (en) | 1999-10-22 | 2002-02-12 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
| US6420580B1 (en) | 1999-11-05 | 2002-07-16 | Univation Technologies, Llc | Catalyst compositions and method of polymerization therewith |
| US6340730B1 (en) | 1999-12-06 | 2002-01-22 | Univation Technologies, Llc | Multiple catalyst system |
| US6359072B1 (en) | 2000-02-16 | 2002-03-19 | Univation Technologies, Llc | Polyethylene films having improved optical properties |
| CN100450620C (zh) * | 2003-09-22 | 2009-01-14 | 弗纳技术股份有限公司 | 用于聚烯烃的齐格勒-纳塔催化剂 |
| US20070003720A1 (en) * | 2005-06-22 | 2007-01-04 | Fina Technology, Inc. | Cocatalysts useful for preparing polyethylene pipe |
| FR2889533B1 (fr) | 2005-08-03 | 2007-10-12 | Lab Francais Du Fractionnement | Anticorps diriges contre le recepteur du ldl |
| US7473664B2 (en) * | 2006-06-23 | 2009-01-06 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst |
| US10351640B2 (en) | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
-
2010
- 2010-08-23 US US12/861,349 patent/US20120046429A1/en not_active Abandoned
-
2011
- 2011-07-18 EP EP11825593.4A patent/EP2608883B1/en not_active Not-in-force
- 2011-07-18 CA CA2807727A patent/CA2807727C/en not_active Expired - Fee Related
- 2011-07-18 BR BR112013004268A patent/BR112013004268A8/pt not_active IP Right Cessation
- 2011-07-18 ES ES11825593T patent/ES2736002T3/es active Active
- 2011-07-18 CN CN2011800407686A patent/CN103068484A/zh active Pending
- 2011-07-18 TW TW100125310A patent/TWI530322B/zh not_active IP Right Cessation
- 2011-07-18 MX MX2013001995A patent/MX352514B/es active IP Right Grant
- 2011-07-18 WO PCT/US2011/044305 patent/WO2012036785A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CA2807727C (en) | 2018-04-17 |
| EP2608883B1 (en) | 2019-04-17 |
| ES2736002T3 (es) | 2019-12-23 |
| CA2807727A1 (en) | 2012-03-22 |
| EP2608883A4 (en) | 2014-01-22 |
| TWI530322B (zh) | 2016-04-21 |
| WO2012036785A1 (en) | 2012-03-22 |
| MX352514B (es) | 2017-11-28 |
| EP2608883A1 (en) | 2013-07-03 |
| BR112013004268A2 (pt) | 2016-08-02 |
| MX2013001995A (es) | 2013-05-13 |
| CN103068484A (zh) | 2013-04-24 |
| US20120046429A1 (en) | 2012-02-23 |
| TW201217052A (en) | 2012-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112012027074A2 (pt) | formatação de catalisador ziegler-natta usando componentes não misturados | |
| BR112013004268A2 (pt) | formação sequencial de catalisador de ziegler-natta usando componentes não combinados | |
| BR112014017451A2 (pt) | processo para obtenção de fibra de cítricos a partir de casca de cítricos | |
| BRPI0905733B8 (pt) | composição, formulação farmacêutica, método para a produção de uma composição farmacêutica e uso de uma formulação farmacêutica | |
| BR112015001477A2 (pt) | composições de produto destinado ao consumidor que compreendem polímeros condicionantes de organopolissiloxanos | |
| DOP2014000170A (es) | Compuestos de imidazopirrolidinona | |
| BR112012024963A2 (pt) | organossilicones | |
| MX2011008912A (es) | Composicion de espuma topica. | |
| BR112013020816A2 (pt) | substrato sólido poroso desintegrável para aplicações para cuidados pessoais com a saúde | |
| MX344936B (es) | Aditivos estabilizadores para pigmentos termocrómicos. | |
| BR112013033402A2 (pt) | produtos de madeira revestida e método para produzir produtos de madeira revestida | |
| BR112015009105A2 (pt) | esfera, polímero de hialuronato e glucomanana, usos de um polímero de hialuronato e glucomanana e de uma esfera, composição cosmética ou dermatológica para administração tópica, e, processo para sintetizar uma esfera | |
| BR112014030113A2 (pt) | composição de catalisador, processo para a produção de álcoois ou olefinas, álcoois ou olefinas, e, complexo metálico | |
| MX2013008046A (es) | Hidrogeles a base de esteres de acido poliisobutenosuccinico. | |
| BR112014004223A2 (pt) | processo de síntese de ésteres de ácidos ômega - amino - alcanoicos em c11 e c12, comportando uma etapa de nitrilação | |
| BR112015030724A2 (pt) | processo de polimerização na presença de uma composição com ação antiestática | |
| MX2013015415A (es) | Proceso para fabricar compuestos beta-hidroxiamino. | |
| MX2014010940A (es) | El uso de antitrombina en el tratamiento de preeclampsia. | |
| BR112015011811A2 (pt) | catalisador de hidrotratamento, compreendendo um suporte obtido a partir de um gel de alumina e método de preparo desse catalisador | |
| BR112014012078A8 (pt) | método de preparação de uma espuma | |
| BRPI1003940B8 (pt) | Composição para cuidado de saúde compreendendo um tensoativo polimerizado de baixo dp e um espessante micelar | |
| AR077196A1 (es) | Champu concentrado | |
| MY172078A (en) | Multihydric compound dehydration systems, catalyst compositions, and methods | |
| BR112015026116A2 (pt) | método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetona | |
| BR112012017021A2 (pt) | sistemas catalisadores ziegler-natta e polímeros formados a partir destes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] | ||
| B12B | Appeal against refusal [chapter 12.2 patent gazette] | ||
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 11A ANUIDADE. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2679 DE 10-05-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |