BR0315097A - Estabilizadores enxertáveis de difenilamina substituìda com 4-amino-3-sulfinil para vulcanizados - Google Patents
Estabilizadores enxertáveis de difenilamina substituìda com 4-amino-3-sulfinil para vulcanizadosInfo
- Publication number
- BR0315097A BR0315097A BR0315097-6A BR0315097A BR0315097A BR 0315097 A BR0315097 A BR 0315097A BR 0315097 A BR0315097 A BR 0315097A BR 0315097 A BR0315097 A BR 0315097A
- Authority
- BR
- Brazil
- Prior art keywords
- amino
- vulcanized
- stabilizers
- allyl
- benzyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003381 stabilizer Substances 0.000 title abstract 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 title 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 3
- 229920001971 elastomer Polymers 0.000 abstract 3
- 239000000806 elastomer Substances 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000002845 discoloration Methods 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C317/32—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
- C07C317/36—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atoms of the amino groups bound to hydrogen atoms or to carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
- C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
- C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
- C07C323/36—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
- C08K5/3725—Sulfides, e.g. R-(S)x-R' containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Hydrogenated Pyridines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"ESTABILIZADORES ENXERTáVEIS DE DIFENILAMINA SUBSTITUìDA COM 4-AMINO-3-SULFINIL PARA VULCANIZADOS". A presente invenção refere-se a compostos da fórmula I em que R~ 1~, é C~ 1~-C~ 18~alquila, C~ 5~-C~ 12~-cicloalquila, fenila, benzila, ou alila; n é 1 ou 2; se n é 1, R~ 2~ é C~ 4~-C~ 18~alquila, C~ 5~-C~ 12~-cicloalquila, arila ou heteroarila, benzila, alila, (CH~ 2~)~ m~COOR~ 3~, ou é (CH~ 2~)~ m~CN; se n é 2, R~ 2~ é -S-(CH~ 2~)~ p~-S ou -S-(CH~ 2~)~ 2~-[O-(CH~ 2~)~ 2~]~ m~-S- R~ 3~ é C~ 1~-C~ 18~alquila, benzila, alila; m é 1 ou 2; e p é um número de 2 a 12; são apropriados como estabilizador para um elastómero para evitar degradação oxidativa, térmica, dinâmica, induzida por luz e/ou induzida por ozónio. Eles são também apropriados como estabilizadores para elastómeros para evitar a descoloração por contato de substratos que entram em contato com elastómeros.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02405864 | 2002-10-07 | ||
PCT/EP2003/010836 WO2004031287A1 (en) | 2002-10-07 | 2003-09-30 | Graftable 4-amino-3-sulfinyl-substitued diphenylamine stabilizers for vulcanizates |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0315097A true BR0315097A (pt) | 2005-08-16 |
Family
ID=32050145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0315097-6A Pending BR0315097A (pt) | 2002-10-07 | 2003-09-30 | Estabilizadores enxertáveis de difenilamina substituìda com 4-amino-3-sulfinil para vulcanizados |
Country Status (11)
Country | Link |
---|---|
US (1) | US20060041045A1 (pt) |
EP (1) | EP1549710A1 (pt) |
JP (1) | JP2006502197A (pt) |
KR (1) | KR20050052503A (pt) |
CN (1) | CN1688647A (pt) |
AU (1) | AU2003271662A1 (pt) |
BR (1) | BR0315097A (pt) |
CA (1) | CA2494341A1 (pt) |
MX (1) | MXPA05002089A (pt) |
RU (1) | RU2005114372A (pt) |
WO (1) | WO2004031287A1 (pt) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007042418A2 (en) * | 2005-10-11 | 2007-04-19 | Ciba Specialty Chemicals Holding Inc. | Non-staining antidegradants for vulcanized elastomers |
US7846884B2 (en) | 2005-11-29 | 2010-12-07 | Chemtura Corporation | Lubricating oil compositions |
JP5811845B2 (ja) * | 2009-11-13 | 2015-11-11 | 日本ゼオン株式会社 | ジフェニルアミン系化合物、及び老化防止剤、並びにポリマー組成物 |
CN103285921B (zh) * | 2013-06-09 | 2015-02-11 | 东南大学 | 硅橡胶固载化有机催化剂及其制备方法和用途 |
CN106674591B (zh) * | 2016-12-07 | 2019-02-01 | 绍兴瑞康生物科技有限公司 | 一种含硫醚长效抗高温抗氧化稳定剂及其应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1228135B1 (en) * | 1999-10-18 | 2004-04-14 | Ciba SC Holding AG | Stabilizers and antiozonants for elastomers |
CN1238340C (zh) * | 2000-11-21 | 2006-01-25 | 弗莱克塞斯美国公司 | 烷基硫基-和芳基(杂酰基)硫基-取代对亚苯基二胺、它们的制备方法和在橡胶中的用途 |
JP4938206B2 (ja) * | 2001-04-06 | 2012-05-23 | チバ ホールディング インコーポレーテッド | ポリマー上へグラフト化されたスルホキシド又はスルホン |
-
2003
- 2003-09-30 BR BR0315097-6A patent/BR0315097A/pt active Pending
- 2003-09-30 RU RU2005114372/04A patent/RU2005114372A/ru not_active Application Discontinuation
- 2003-09-30 KR KR1020057004553A patent/KR20050052503A/ko not_active Application Discontinuation
- 2003-09-30 CA CA002494341A patent/CA2494341A1/en not_active Abandoned
- 2003-09-30 MX MXPA05002089A patent/MXPA05002089A/es not_active Application Discontinuation
- 2003-09-30 EP EP03753481A patent/EP1549710A1/en not_active Withdrawn
- 2003-09-30 AU AU2003271662A patent/AU2003271662A1/en not_active Abandoned
- 2003-09-30 US US10/529,414 patent/US20060041045A1/en not_active Abandoned
- 2003-09-30 CN CNA038238233A patent/CN1688647A/zh active Pending
- 2003-09-30 WO PCT/EP2003/010836 patent/WO2004031287A1/en not_active Application Discontinuation
- 2003-09-30 JP JP2004540751A patent/JP2006502197A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
CN1688647A (zh) | 2005-10-26 |
JP2006502197A (ja) | 2006-01-19 |
CA2494341A1 (en) | 2004-04-15 |
EP1549710A1 (en) | 2005-07-06 |
MXPA05002089A (es) | 2005-06-06 |
RU2005114372A (ru) | 2006-01-20 |
US20060041045A1 (en) | 2006-02-23 |
AU2003271662A1 (en) | 2004-04-23 |
WO2004031287A1 (en) | 2004-04-15 |
KR20050052503A (ko) | 2005-06-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |