BR0311514A - Método de craqueamento de um suprimento de hidrocarboneto sob condições do fcc - Google Patents
Método de craqueamento de um suprimento de hidrocarboneto sob condições do fccInfo
- Publication number
- BR0311514A BR0311514A BR0311514-3A BR0311514A BR0311514A BR 0311514 A BR0311514 A BR 0311514A BR 0311514 A BR0311514 A BR 0311514A BR 0311514 A BR0311514 A BR 0311514A
- Authority
- BR
- Brazil
- Prior art keywords
- kaolin
- cracking
- zeolite
- supply under
- hydrocarbon supply
- Prior art date
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 2
- 238000005336 cracking Methods 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 7
- 235000012211 aluminium silicate Nutrition 0.000 abstract 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 7
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 239000011159 matrix material Substances 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 2
- 239000004005 microsphere Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/62—Synthesis on support in or on other molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
"MéTODO DE CRAQUEAMENTO DE UM SUPRIMENTO DE HIDROCARBONETO SOB CONDIçõES DO FCC". Trata-se de um aditivo para melhorar a atividade de um catalisador FCC que contém zeólito e componentes de matriz que compreendem micro-esferas de zeólito tendo uma nova morfologia que compreende uma matriz macroporosa e zeólito cristalizado revestindo livremente as paredes dos poros da matriz. Os aditivos formados a partir de micro-esferas contendo um meta-caulim e caulim calcinado através de sua exotérmica, sendo o caulim calcinado é derivado de um caulim que tem um alto volume porsr. Caulim tendo um alto volume de poro pode ser um caulim ultra-fino pulverizado ou um caulim que tenham sido pulverizado para ter um ponto de pasta fluida incipiente menor do que 57% de sólidos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/158,107 US7101473B2 (en) | 2002-05-31 | 2002-05-31 | Method of enhancing the activity of FCC catalysts |
PCT/US2003/015745 WO2003101614A1 (en) | 2002-05-31 | 2003-05-20 | Method of enhancing the activity of fcc catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0311514A true BR0311514A (pt) | 2005-05-24 |
Family
ID=29582604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0311514-3A BR0311514A (pt) | 2002-05-31 | 2003-05-20 | Método de craqueamento de um suprimento de hidrocarboneto sob condições do fcc |
Country Status (13)
Country | Link |
---|---|
US (1) | US7101473B2 (pt) |
EP (1) | EP1509321A1 (pt) |
JP (1) | JP2005528201A (pt) |
KR (1) | KR20050005512A (pt) |
CN (1) | CN1319648C (pt) |
AU (1) | AU2003243265B2 (pt) |
BR (1) | BR0311514A (pt) |
CA (1) | CA2487726A1 (pt) |
IN (1) | IN2000KO01835A (pt) |
MX (1) | MXPA04011899A (pt) |
MY (1) | MY134284A (pt) |
TW (1) | TWI281878B (pt) |
WO (1) | WO2003101614A1 (pt) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI341218B (en) * | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
US9433934B2 (en) * | 2006-03-02 | 2016-09-06 | Basf Corporation | In-situ produced Y-faujasite from kaolin-derived, pre-shaped particles and the method of preparation and the use thereof |
JP5008666B2 (ja) * | 2006-06-28 | 2012-08-22 | 出光興産株式会社 | 脱硫機能付加流動接触分解触媒及びその製造方法並びに該脱硫機能付加流動接触分解触媒を用いた低硫黄接触分解ガソリンの製造方法 |
CA2669210C (en) | 2006-11-13 | 2015-05-26 | Albemarle Netherlands B.V. | Process for the preparation of an fcc catalyst |
US8278235B2 (en) * | 2007-06-20 | 2012-10-02 | Basf Corporation | Structurally enhanced cracking catalysts |
US9108181B2 (en) | 2007-06-20 | 2015-08-18 | Basf Corporation | Structurally enhanced cracking catalysts |
ITMI20081036A1 (it) * | 2008-06-06 | 2009-12-07 | Eni Spa | Processo di cracking e catalizzatori migliorati per detto processo |
CN102371165B (zh) * | 2010-08-26 | 2013-06-05 | 中国石油化工股份有限公司 | 用于降低FCC再生烟气CO和NOx排放的低堆比组合物 |
WO2013039950A2 (en) * | 2011-09-15 | 2013-03-21 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US10286391B2 (en) | 2012-02-17 | 2019-05-14 | Inaeris Technologies, Llc | Catalyst system having meso and macro hierarchical pore structure |
EP2990463B1 (en) * | 2014-08-27 | 2018-07-11 | Indian Oil Corporation Limited | A catalyst additive composition for catalytic cracking, a process of preparation thereof and cracking processes of using thereof |
CN106311359B (zh) * | 2015-06-16 | 2019-07-26 | 中国石油化工股份有限公司 | 一种分子筛催化剂及其制备方法 |
US10619110B2 (en) | 2018-04-11 | 2020-04-14 | Saudi Arabian Oil Company | Hydrocracking and hydrotreating catalytic compositions comprising a zeolite and regenerated, spent catalyst and uses thereof |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3533962A (en) * | 1965-06-14 | 1970-10-13 | Air Prod & Chem | Mulling precursor for cracking catalyst |
US3458454A (en) * | 1966-07-29 | 1969-07-29 | Air Prod & Chem | Fluidizable cracking catalyst |
US3506594A (en) * | 1968-06-20 | 1970-04-14 | Engelhard Min & Chem | Microspherical zeolitic molecular sieve composite catalyst and preparation thereof |
US3676330A (en) * | 1969-12-15 | 1972-07-11 | Mobil Oil Corp | Zeolite-containing catalyst, synthesis and use thereof |
CA990708A (en) | 1970-09-24 | 1976-06-08 | Warren S. Briggs | Process for preparing a zeolite containing petroleum cracking catalyst |
US3944482A (en) * | 1973-08-08 | 1976-03-16 | Gulf Research & Development Company | Process for the cracking of high metals content feedstocks |
US4493902A (en) * | 1983-02-25 | 1985-01-15 | Engelhard Corporation | Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making |
US5976355A (en) | 1984-03-09 | 1999-11-02 | Stone & Webster Engineering Corp. | Low residence time catalytic cracking process |
US5077253A (en) * | 1987-12-28 | 1991-12-31 | Mobil Oil Corporation | Layered cracking catalyst and method of manufacture and use thereof |
US5179054A (en) * | 1987-12-28 | 1993-01-12 | Mobil Oil Corporation | Layered cracking catalyst and method of manufacture and use thereof |
US5023220A (en) * | 1988-11-16 | 1991-06-11 | Engelhard Corporation | Ultra high zeolite content FCC catalysts and method for making same from microspheres composed of a mixture of calcined kaolin clays |
US5052814A (en) * | 1990-09-19 | 1991-10-01 | Texaco Inc. | Shallow marine seismic system and method |
US5300469A (en) | 1992-12-08 | 1994-04-05 | Engelhard Corporation | Composition for passivating vanadium in catalytic cracking and preparation thereof |
US5358632A (en) | 1993-07-16 | 1994-10-25 | Uop | FCC feed injection with non-quiescent mixing |
US5462652A (en) | 1993-09-24 | 1995-10-31 | Uop | Short contact FCC process with catalyst blending |
US5413978A (en) | 1993-11-30 | 1995-05-09 | Engelhard Corporation | Catalytically inert particles for blending with petroleum cracking catalyst |
US5763347A (en) * | 1994-07-08 | 1998-06-09 | Exxon Research And Engineering Company | In-situ crystallized zeolite containing composition (LAI-ISC) |
US5723040A (en) | 1994-09-22 | 1998-03-03 | Stone & Webster Engineering Corporation | Fluid catalytic cracking process and apparatus |
US5662868A (en) | 1994-09-22 | 1997-09-02 | Stone & Webster Engineering Corporation | Short residence time cracking apparatus and process |
US5521133A (en) | 1994-11-29 | 1996-05-28 | Engelhard Corporation | Phosphorus bound porous microspheres |
US5993645A (en) | 1995-12-08 | 1999-11-30 | Engelhard Corporation | Catalyst for cracking oil feedstocks contaminated with metal |
FI101156B (fi) * | 1996-08-30 | 1998-04-30 | Fortum Oil Oy | Kiertomassareaktoriin perustuva menetelmä ja laite hiilivetyjen konver toimiseksi |
JPH11561A (ja) * | 1997-06-13 | 1999-01-06 | Tonen Corp | 重質油の接触分解用添加触媒 |
US6004527A (en) | 1997-09-29 | 1999-12-21 | Abb Lummus Global Inc. | Method for making molecular sieves and novel molecular sieve compositions |
US6010618A (en) | 1997-12-05 | 2000-01-04 | Uop Llc | FCC process with two zone short contact time reaction conduit |
US6063263A (en) * | 1998-04-24 | 2000-05-16 | Uop Llc | Process for feed contacting with immediate catalyst separation |
US6635169B1 (en) * | 1999-09-20 | 2003-10-21 | Mobil Oil Corporation | Method for reducing gasoline sulfur in fluid catalytic cracking |
US6656347B2 (en) * | 2000-09-22 | 2003-12-02 | Engelhard Corporation | Structurally enhanced cracking catalysts |
JP4991083B2 (ja) | 2000-09-22 | 2012-08-01 | バスフ・カタリスツ・エルエルシー | 構造的に強化された分解用触媒 |
US6696378B2 (en) | 2001-08-31 | 2004-02-24 | Engelhard Corporation | Fluid catalytic cracking catalyst manufacturing process |
-
2002
- 2002-05-31 US US10/158,107 patent/US7101473B2/en not_active Expired - Fee Related
-
2003
- 2003-05-20 CA CA002487726A patent/CA2487726A1/en not_active Abandoned
- 2003-05-20 AU AU2003243265A patent/AU2003243265B2/en not_active Expired - Fee Related
- 2003-05-20 WO PCT/US2003/015745 patent/WO2003101614A1/en active Application Filing
- 2003-05-20 CN CNB038181770A patent/CN1319648C/zh not_active Expired - Fee Related
- 2003-05-20 KR KR20047019373A patent/KR20050005512A/ko not_active Application Discontinuation
- 2003-05-20 MX MXPA04011899A patent/MXPA04011899A/es unknown
- 2003-05-20 EP EP03756188A patent/EP1509321A1/en not_active Withdrawn
- 2003-05-20 BR BR0311514-3A patent/BR0311514A/pt not_active IP Right Cessation
- 2003-05-20 JP JP2004508956A patent/JP2005528201A/ja active Pending
- 2003-05-26 TW TW092114157A patent/TWI281878B/zh not_active IP Right Cessation
- 2003-05-29 MY MYPI20031985A patent/MY134284A/en unknown
-
2004
- 2004-12-02 IN IN1835KO2000 patent/IN2000KO01835A/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2005528201A (ja) | 2005-09-22 |
AU2003243265B2 (en) | 2009-01-08 |
IN2000KO01835A (pt) | 2006-07-14 |
WO2003101614A1 (en) | 2003-12-11 |
CA2487726A1 (en) | 2003-12-11 |
US20030221991A1 (en) | 2003-12-04 |
TWI281878B (en) | 2007-06-01 |
US7101473B2 (en) | 2006-09-05 |
EP1509321A1 (en) | 2005-03-02 |
MY134284A (en) | 2007-11-30 |
MXPA04011899A (es) | 2005-03-31 |
CN1319648C (zh) | 2007-06-06 |
TW200401669A (en) | 2004-02-01 |
AU2003243265A1 (en) | 2003-12-19 |
KR20050005512A (ko) | 2005-01-13 |
CN1671473A (zh) | 2005-09-21 |
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