BR0309023A - Processo para converter álcoois em compostos de carbonila - Google Patents
Processo para converter álcoois em compostos de carbonilaInfo
- Publication number
- BR0309023A BR0309023A BR0309023-0A BR0309023A BR0309023A BR 0309023 A BR0309023 A BR 0309023A BR 0309023 A BR0309023 A BR 0309023A BR 0309023 A BR0309023 A BR 0309023A
- Authority
- BR
- Brazil
- Prior art keywords
- carbonyl compounds
- copper salt
- alcohols
- converting
- converting alcohols
- Prior art date
Links
- 150000001298 alcohols Chemical class 0.000 title abstract 3
- 150000001728 carbonyl compounds Chemical class 0.000 title abstract 2
- 150000001879 copper Chemical class 0.000 abstract 3
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
Abstract
"PROCESSO PARA CONVERTER áLCOOIS EM COMPOSTOS DE CARBONILA". A presente invenção fornece um processo para converter seletivamente álcoois diidróxi ou poliidróxi em compostos de carbonila usando dioxigênio (0~ 2~) como oxidante na presença de um sistema catalítico constituído por (1) um sal de cobre, um sal de cobre contendo um ligando heterocíclico ou um sal complexo de cobre e (2) uma base.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02405269 | 2002-04-05 | ||
PCT/EP2003/050079 WO2003084911A1 (en) | 2002-04-05 | 2003-03-26 | Process for converting alcohols to carbonyl compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0309023A true BR0309023A (pt) | 2005-02-01 |
Family
ID=28686033
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0309023-0A BR0309023A (pt) | 2002-04-05 | 2003-03-26 | Processo para converter álcoois em compostos de carbonila |
Country Status (10)
Country | Link |
---|---|
US (1) | US20050203315A1 (pt) |
EP (1) | EP1492753A1 (pt) |
JP (1) | JP2005521740A (pt) |
KR (1) | KR20040102069A (pt) |
CN (1) | CN1642892A (pt) |
AU (1) | AU2003240753A1 (pt) |
BR (1) | BR0309023A (pt) |
CA (1) | CA2480788A1 (pt) |
MX (1) | MXPA04009693A (pt) |
WO (1) | WO2003084911A1 (pt) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2912407B1 (fr) * | 2007-02-14 | 2010-10-08 | Arkema France | Procede de fonctionnalisation des carbohydrates. |
JP5534132B2 (ja) * | 2009-03-12 | 2014-06-25 | Jx日鉱日石エネルギー株式会社 | カルボニル化合物の製造方法、触媒及びその製造方法 |
CN102617307B (zh) * | 2011-01-28 | 2016-03-02 | 陈婷 | 芳基1,2-二醇转化为酮的环境友好性氧化新工艺 |
US20130143774A1 (en) * | 2011-12-05 | 2013-06-06 | The Regents Of The University Of California | Methods and compositions for generating polynucleic acid fragments |
JP6011768B2 (ja) * | 2012-03-08 | 2016-10-19 | 国立大学法人京都大学 | 連続的な不斉合成法及びその方法に用いるdnaを含有するハイブリッド触媒 |
JP6099133B2 (ja) * | 2013-03-11 | 2017-03-22 | 株式会社ダイセル | ケトール化合物の製造方法 |
CN108069841B (zh) * | 2016-11-14 | 2020-07-21 | 中国科学院大连化学物理研究所 | 一种光催化氧化裂解β–羟基化合物C–C键制备醛类化合物的方法 |
CN106588957B (zh) * | 2016-12-07 | 2019-04-05 | 苏州大学 | 一种基于含氮杂环硫醇配体的一价铜化合物及其制备方法与应用 |
CN106596775B (zh) * | 2016-12-19 | 2019-06-07 | 广电计量检测(成都)有限公司 | 塑料中十四氢化-1,4a-二甲基-7-(1-甲基乙基)-1-菲甲醇的检测方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4092306A (en) * | 1973-07-09 | 1978-05-30 | Glaxo Laboratories Limited | Oxidation of hydrazones to the corresponding diazo compounds in the presence of a phase transfer and an oxidation catalyst which is iodine, an iodide or an iodonium salt |
IL122896A0 (en) * | 1995-07-11 | 1998-08-16 | Zeneca Ltd | Preparation of aldehydes or ketones from alcohols |
ATE240285T1 (de) * | 1999-11-19 | 2003-05-15 | Ciba Sc Holding Ag | Verfahren zur selektiven oxidation von alkoholen unter verwendung leicht abtrennbarer nitroxylradikale |
-
2003
- 2003-03-26 AU AU2003240753A patent/AU2003240753A1/en not_active Abandoned
- 2003-03-26 KR KR20047015852A patent/KR20040102069A/ko not_active Application Discontinuation
- 2003-03-26 EP EP03730164A patent/EP1492753A1/en not_active Withdrawn
- 2003-03-26 JP JP2003582110A patent/JP2005521740A/ja not_active Withdrawn
- 2003-03-26 CA CA002480788A patent/CA2480788A1/en not_active Abandoned
- 2003-03-26 US US10/509,779 patent/US20050203315A1/en not_active Abandoned
- 2003-03-26 BR BR0309023-0A patent/BR0309023A/pt not_active Application Discontinuation
- 2003-03-26 MX MXPA04009693A patent/MXPA04009693A/es unknown
- 2003-03-26 CN CNA038073803A patent/CN1642892A/zh active Pending
- 2003-03-26 WO PCT/EP2003/050079 patent/WO2003084911A1/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CA2480788A1 (en) | 2003-10-16 |
AU2003240753A1 (en) | 2003-10-20 |
EP1492753A1 (en) | 2005-01-05 |
JP2005521740A (ja) | 2005-07-21 |
KR20040102069A (ko) | 2004-12-03 |
US20050203315A1 (en) | 2005-09-15 |
WO2003084911A1 (en) | 2003-10-16 |
CN1642892A (zh) | 2005-07-20 |
MXPA04009693A (es) | 2005-01-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |