BR0117052A - Reator de membrana catalìtica para quebrar sulfeto de hidrogênio em enxofre e hidrogênio e separar os produtos da quebra e processo para quebra catalìtica do mesmo - Google Patents
Reator de membrana catalìtica para quebrar sulfeto de hidrogênio em enxofre e hidrogênio e separar os produtos da quebra e processo para quebra catalìtica do mesmoInfo
- Publication number
- BR0117052A BR0117052A BR0117052-0A BR0117052A BR0117052A BR 0117052 A BR0117052 A BR 0117052A BR 0117052 A BR0117052 A BR 0117052A BR 0117052 A BR0117052 A BR 0117052A
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogen
- breaking
- sulfur
- membrane reactor
- hydrogen sulfide
- Prior art date
Links
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 5
- 239000001257 hydrogen Substances 0.000 title abstract 5
- 239000012528 membrane Substances 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title abstract 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title abstract 3
- 239000011593 sulfur Substances 0.000 title abstract 3
- 229910052717 sulfur Inorganic materials 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 230000015556 catabolic process Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000919 ceramic Substances 0.000 abstract 2
- -1 HYDROGEN HYDROGEN Chemical class 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/04—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
- B01D53/885—Devices in general for catalytic purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/025—Aluminium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J15/00—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
- B01J15/005—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2425—Tubular reactors in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/244—Concentric tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
- B01J35/59—Membranes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0495—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by dissociation of hydrogen sulfide into the elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
"REATOR DE MEMBRANA CATALìTICA PARA QUEBRAR SULFETO DE HIDROGêNIO EM ENXOFRE E HIDROGêNIO E SEPARAR OS PRODUTOS DA QUEBRA E PROCESSO PARA QUEBRA CATALìTICA DO MESMO". A invenção se refere a um reator de membrana catalítica compreendendo (i) um corpo, (ii) um elemento de membrana tubular porosa de cerâmica que é disposto co-axialmente dentro do corpo para remover o hidrogênio e (iii) um catalisador para a decomposição térmica do sulfeto de hidrogênio em enxofre e hidrogênio. De acordo com a invenção, uma camada do catalisador é depositada diretamente no elemento de membrana tubular porosa de cerâmica. A invenção pode ser usada no tratamento de gases que contêm sulfeto de hidrogênio.,
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/ES2001/000244 WO2002102710A1 (es) | 2001-06-15 | 2001-06-15 | Reactor catalítico de membrana para la descomposición del sulfuro de hidrógeno en hidrógeno y azufre y la separación de los productos de dicha composición |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0117052A true BR0117052A (pt) | 2004-07-27 |
Family
ID=8244352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0117052-0A BR0117052A (pt) | 2001-06-15 | 2001-06-15 | Reator de membrana catalìtica para quebrar sulfeto de hidrogênio em enxofre e hidrogênio e separar os produtos da quebra e processo para quebra catalìtica do mesmo |
Country Status (7)
Country | Link |
---|---|
US (1) | US20040141910A1 (pt) |
EP (1) | EP1411029A1 (pt) |
CN (1) | CN1541184A (pt) |
BR (1) | BR0117052A (pt) |
CA (1) | CA2450938A1 (pt) |
MX (1) | MXPA03011640A (pt) |
WO (1) | WO2002102710A1 (pt) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2488295A1 (en) * | 2002-06-04 | 2003-12-11 | University Of Wyoming | Membrane for hydrogen recovery from streams containing hydrogen sulfide |
US7648566B2 (en) * | 2006-11-09 | 2010-01-19 | General Electric Company | Methods and apparatus for carbon dioxide removal from a fluid stream |
US7966829B2 (en) * | 2006-12-11 | 2011-06-28 | General Electric Company | Method and system for reducing CO2 emissions in a combustion stream |
DE102008013041A1 (de) * | 2008-03-06 | 2009-09-10 | Volkswagen Ag | Reinigung eines Abgases |
WO2009132031A2 (en) * | 2008-04-21 | 2009-10-29 | Swapsol Corp. | Hydrogen sulfide conversion to hydrogen |
US8597383B2 (en) | 2011-04-11 | 2013-12-03 | Saudi Arabian Oil Company | Metal supported silica based catalytic membrane reactor assembly |
US9745191B2 (en) | 2011-04-11 | 2017-08-29 | Saudi Arabian Oil Company | Auto thermal reforming (ATR) catalytic structures |
CN102824822B (zh) * | 2012-09-12 | 2014-12-31 | 南京工业大学 | 一种膜分离空气净化装置 |
CN105330290A (zh) * | 2015-10-19 | 2016-02-17 | 华南理工大学 | 一种用于h2s分解的混合导体陶瓷膜的制备及测试方法 |
GB201616517D0 (en) * | 2016-09-29 | 2016-11-16 | Akay Galip | Integrated intensified catalytic chemical conversion processes |
CN110124652B (zh) * | 2018-02-09 | 2022-02-11 | 中国石油化工股份有限公司 | 含有改性碳纳米管的分解硫化氢的催化剂及其制备方法和应用 |
CN110124651B (zh) * | 2018-02-09 | 2022-03-04 | 中国石油化工股份有限公司 | 含有碳纳米笼的分解硫化氢的催化剂及其制备方法和应用 |
CN110127602B (zh) * | 2018-02-09 | 2020-09-25 | 中国石油化工股份有限公司 | 应用催化剂分解硫化氢的方法 |
CN110124653B (zh) * | 2018-02-09 | 2022-03-04 | 中国石油化工股份有限公司 | 分解硫化氢的催化剂及其制备方法和应用 |
CN110734782B (zh) * | 2018-07-19 | 2021-07-23 | 中山市亿鼎杰纳米科技有限公司 | 一种劣质重油的加氢处理方法 |
IT201900006957A1 (it) * | 2019-05-17 | 2020-11-17 | Milano Politecnico | Forno per campi gas, per raffinerie e per il processo di reforming |
IL296627A (en) * | 2020-03-20 | 2022-11-01 | Standard H2 Inc | Process and apparatus for obtaining hydrogen and sulfur from hydrogen sulfide |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4039613A (en) * | 1973-10-29 | 1977-08-02 | Agency Of Industrial Science & Technology | Process for production of hydrogen and sulfur from hydrogen sulfide as raw material |
DE3925985C2 (de) * | 1989-08-05 | 1998-08-20 | Metallgesellschaft Ag | Verfahren zum Verbrennen eines H¶2¶S-haltigen Gases |
US5229102A (en) * | 1989-11-13 | 1993-07-20 | Medalert, Inc. | Catalytic ceramic membrane steam-hydrocarbon reformer |
US5965100A (en) * | 1995-04-25 | 1999-10-12 | Khanmamedov; Tofik K. | Process for recovery of sulfur from an acid gas stream |
US5891415A (en) * | 1995-05-17 | 1999-04-06 | Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya | Process for selective oxidation of hydrogen sulfide to elemental sulfur |
US5843395A (en) * | 1997-03-17 | 1998-12-01 | Wang; Chi S. | Process for hydrogen production from hydrogen sulfide dissociation |
FR2773085B1 (fr) * | 1997-12-29 | 2000-02-18 | Elf Exploration Prod | Procede catalytique pour oxyder directement en soufre, a basse temperature, l'h2s contenu en faible concentration dans un gaz et catalyseur pour sa mise en oeuvre |
US6235417B1 (en) * | 1999-04-30 | 2001-05-22 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources | Two-phase hydrogen permeation membrane |
CA2488295A1 (en) * | 2002-06-04 | 2003-12-11 | University Of Wyoming | Membrane for hydrogen recovery from streams containing hydrogen sulfide |
-
2001
- 2001-06-15 CA CA002450938A patent/CA2450938A1/en not_active Abandoned
- 2001-06-15 BR BR0117052-0A patent/BR0117052A/pt not_active Application Discontinuation
- 2001-06-15 WO PCT/ES2001/000244 patent/WO2002102710A1/es not_active Application Discontinuation
- 2001-06-15 CN CNA018235190A patent/CN1541184A/zh active Pending
- 2001-06-15 EP EP20010940594 patent/EP1411029A1/en not_active Withdrawn
- 2001-06-15 MX MXPA03011640A patent/MXPA03011640A/es not_active Application Discontinuation
-
2003
- 2003-12-15 US US10/736,212 patent/US20040141910A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20040141910A1 (en) | 2004-07-22 |
EP1411029A1 (en) | 2004-04-21 |
CN1541184A (zh) | 2004-10-27 |
WO2002102710A1 (es) | 2002-12-27 |
MXPA03011640A (es) | 2005-10-05 |
CA2450938A1 (en) | 2002-12-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |