BR0108860A - Processo para a ramificação de ácidos graxos saturados e/ou insaturados e/ou seus alquil ésteres - Google Patents
Processo para a ramificação de ácidos graxos saturados e/ou insaturados e/ou seus alquil ésteresInfo
- Publication number
- BR0108860A BR0108860A BR0108860-2A BR0108860A BR0108860A BR 0108860 A BR0108860 A BR 0108860A BR 0108860 A BR0108860 A BR 0108860A BR 0108860 A BR0108860 A BR 0108860A
- Authority
- BR
- Brazil
- Prior art keywords
- fatty acids
- alkyl esters
- unsaturated fatty
- catalyst
- isomerization reaction
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Fats And Perfumes (AREA)
Abstract
"PROCESSO PARA A RAMIFICAçãO DE áCIDOS GRAXOS SATURADOS E/OU INSATURADOS E/OU SEUS ALQUIL éSTERES". Um processo para a ramificação de ácidos graxos saturados e/ou insaturados e/ou seus alquil ésteres compreender submeter os ácidos graxos e/ou alquil ésteres a uma reação de isomerização de esqueleto usando um catalisador compreendendo uma estrutura porosa cristalina tendo ali incorporado um metal para formar sítios de metal sobre o dito catalisador e isolando ácidos graxos ramificados, seus alquil ésteres, ou misturas dos mesmos, a partir de uma mistura de reação obtida através da dita reação de isomerização de esqueleto. O catalisador usado na reação de isomerização é preferivelmente um catalisador zeólito contendo sítios de metal de um metal do Grupo VIII. O processo produz uma mistura de ácidos graxos e/ou alquil ésteres que contêm quantidades significantes de moléculas ramificadas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18692400P | 2000-03-03 | 2000-03-03 | |
US60/186,924 | 2000-03-03 | ||
PCT/US2001/006908 WO2001066507A2 (en) | 2000-03-03 | 2001-03-02 | Process for the branching of saturated and/or unsaturated fatty acids and/or alkyl esters thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0108860A true BR0108860A (pt) | 2004-02-25 |
BR0108860B1 BR0108860B1 (pt) | 2012-10-02 |
Family
ID=22686852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0108860-2A BR0108860B1 (pt) | 2000-03-03 | 2001-03-02 | processo para ramificação de ácidos graxos saturados e/ou seus alquil ésteres. |
Country Status (12)
Country | Link |
---|---|
US (1) | US6455716B2 (pt) |
EP (1) | EP1268386B1 (pt) |
JP (1) | JP2003525922A (pt) |
CN (1) | CN1255369C (pt) |
AT (1) | ATE272602T1 (pt) |
AU (1) | AU2001243406A1 (pt) |
BR (1) | BR0108860B1 (pt) |
CA (1) | CA2398578C (pt) |
DE (1) | DE60104664T2 (pt) |
ES (1) | ES2225504T3 (pt) |
MX (1) | MXPA02008666A (pt) |
WO (1) | WO2001066507A2 (pt) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2225504T3 (es) * | 2000-03-03 | 2005-03-16 | THE PROCTER & GAMBLE COMPANY | Procedimiento para ramificar acidos grasos saturados y/o insaturados y/o sus esteres alquilicos. |
JP2004534095A (ja) * | 2001-07-10 | 2004-11-11 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 脂肪酸の骨格異性化 |
US6723862B2 (en) * | 2002-04-02 | 2004-04-20 | Akzo Nobel N.V. | Fatty acid isomerization with mesoporous zeolites |
US6946567B2 (en) * | 2002-04-02 | 2005-09-20 | Akzo Nobel N.V. | Skeletal isomerization of alkyl esters and derivatives prepared therefrom |
US7098353B2 (en) * | 2003-04-11 | 2006-08-29 | Akzo Nobel N.V. | Metal ion exchanged solid materials as catalysts for the skeletal isomerization of fatty acids and alkyl esters thereof |
WO2005030693A1 (en) * | 2003-09-25 | 2005-04-07 | Unichema Chemie B.V. | Process |
WO2005123890A1 (en) * | 2004-06-22 | 2005-12-29 | Akzo Nobel N.V. | Branched biodiesels |
WO2007041851A1 (en) * | 2005-10-12 | 2007-04-19 | Valorbec Societe En Commandite, Represented By Gestion Valéo, S.E.C. | Silica nanoboxes, method of making and use thereof |
US20070124992A1 (en) * | 2005-12-01 | 2007-06-07 | Her Majesty In Right Of Canada | Methods for concentration and extraction of lubricity compounds and biologically active fractions from naturally derived fats, oils and greases |
US7850745B2 (en) * | 2005-12-01 | 2010-12-14 | Her Majesty In Right Of Canada As Represented By The Minister Of Agriculture And Agri-Food Canada | Method for concentration and extraction of lubricity compounds from vegetable and animal oils |
EP2024467A2 (en) * | 2006-05-19 | 2009-02-18 | The Procter and Gamble Company | Process for decarboxylation of fatty acids and oils to produce paraffins or olefins |
EP2200443B2 (en) | 2007-09-17 | 2021-06-30 | Cornell University | Branched chain fatty acids for prevention or treatment of gastrointestinal disorders |
WO2009095711A1 (en) * | 2008-02-01 | 2009-08-06 | Johnson Matthey Plc | Process for the conversion of fatty acids and derivatives thereof |
US9115076B2 (en) * | 2010-04-26 | 2015-08-25 | The United States Of America, As Represented By The Secretary Of Agriculture | Process for preparing saturated branched chain fatty acids |
US20110263884A1 (en) * | 2010-04-26 | 2011-10-27 | Helen Ngo | Process for Preparing Saturated Branched Chain Fatty Acids |
US8748641B2 (en) * | 2010-05-05 | 2014-06-10 | The United States Of America, As Represented By The Secretary Of Agriculture | Process for preparing saturated branched chain fatty acids |
WO2011153196A1 (en) * | 2010-06-01 | 2011-12-08 | University Of Louisville Research Foundation, Inc. | Catalytic isomerisation of fatty acid esters |
US8772562B2 (en) | 2010-11-10 | 2014-07-08 | Exxonmobil Research And Engineering Company | Process for making basestocks from renewable feedstocks |
WO2012135728A1 (en) | 2011-03-30 | 2012-10-04 | University Of Louisville Research Foundation, Inc. | Catalytic isomerisation of linear olefinic hydrocarbons |
FI126203B (fi) * | 2011-07-06 | 2016-08-15 | Upm Kymmene Corp | Menetelmä hiilivetykomponenttien valmistamiseksi |
ITTO20111177A1 (it) * | 2011-12-20 | 2013-06-21 | Co Ma Se S R L | Procedimento di produzione di bioliquidi o biocarburanti |
GB201219224D0 (en) | 2012-10-25 | 2012-12-12 | Croda Int Plc | Process |
US9868679B2 (en) | 2013-03-15 | 2018-01-16 | The United States Of America, As Represented By The Secretary Of Agriculture | Process for isomerization and decarboxylation of unsaturated organic compounds with a metal catalyst or catalyst precursor |
US10364209B2 (en) * | 2017-08-31 | 2019-07-30 | The United States Of America, As Represented By The Secretary Of Agriculture | Methods for preparing oils containing at least 2% alkyl-branching on the hydrocarbon chain |
FR3108608A1 (fr) * | 2020-03-27 | 2021-10-01 | Global Bioenergies | Oléfines ramifiées fonctionnalisées et leur procédé de préparation |
CN112958147B (zh) * | 2021-02-23 | 2022-11-18 | 华南理工大学 | 双功能催化剂及其制备方法、硬脂酸制备异构烷烃的方法 |
US20240254408A1 (en) | 2021-05-27 | 2024-08-01 | Katholieke Universiteit Leuven | Mixture of monobranched and polybranched fatty acids |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3090807A (en) | 1958-07-31 | 1963-05-21 | Basf Ag | Isomerization of saturated aliphatic carboxylic acids |
JPS57140744A (en) * | 1981-02-24 | 1982-08-31 | Mitsubishi Chem Ind Ltd | Isomerization of diacetoxybutene |
US4430252A (en) | 1982-12-10 | 1984-02-07 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition by an organic solution method |
US4560790A (en) | 1982-12-10 | 1985-12-24 | Exxon Research & Engineering Co. | Process for synthesizing α,β-ethylenically unsaturated products using a multicomponent acidic catalyst composition |
US5189202A (en) * | 1987-07-30 | 1993-02-23 | Lucky, Ltd. | Process for the preparation of 3,3-dimethyl-4-pentenoic acid |
US4882307A (en) | 1987-09-02 | 1989-11-21 | Mobil Oil Corporation | Process for preparing noble metal-containing zeolites |
FR2622473B1 (fr) | 1987-11-03 | 1993-07-02 | Inst Francais Du Petrole | Catalyseur d'isomerisation des paraffines normales comprenant une mordenite et du titane |
DE3807409A1 (de) | 1988-03-07 | 1989-09-21 | Henkel Kgaa | Verfahren zur isolierung bzw. reinigung von im wesentlichen methylverzweigten, gesaettigten c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)4(pfeil abwaerts)-c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)4(pfeil abwaerts)-fettsaeuren |
DE4009505A1 (de) | 1990-03-24 | 1991-09-26 | Henkel Kgaa | Verfahren zur herstellung verzweigter fettsaeuren und deren ester |
US5306855A (en) | 1991-02-15 | 1994-04-26 | Catalytica, Inc. | Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons |
US5840942A (en) | 1993-12-02 | 1998-11-24 | Baker Hughes Incorporated | Catalyzed synthesis of aryl-substituted fatty acids and fatty esters and compositions related thereto |
JP3303947B2 (ja) * | 1994-05-18 | 2002-07-22 | 花王株式会社 | 分岐脂肪酸及び分岐脂肪酸エステルの製造法 |
US5525126A (en) | 1994-10-31 | 1996-06-11 | Agricultural Utilization Research Institute | Process for production of esters for use as a diesel fuel substitute using a non-alkaline catalyst |
ATE187954T1 (de) | 1995-11-16 | 2000-01-15 | Unichema Chemie Bv | Isomerisierung der fettsäure |
WO1998007680A1 (en) | 1996-08-16 | 1998-02-26 | Unichema Chemie B.V. | Process for preparation of branched fatty acids |
ES2225504T3 (es) * | 2000-03-03 | 2005-03-16 | THE PROCTER & GAMBLE COMPANY | Procedimiento para ramificar acidos grasos saturados y/o insaturados y/o sus esteres alquilicos. |
-
2001
- 2001-03-02 ES ES01916375T patent/ES2225504T3/es not_active Expired - Lifetime
- 2001-03-02 AU AU2001243406A patent/AU2001243406A1/en not_active Abandoned
- 2001-03-02 WO PCT/US2001/006908 patent/WO2001066507A2/en active IP Right Grant
- 2001-03-02 CN CN01806030.7A patent/CN1255369C/zh not_active Expired - Fee Related
- 2001-03-02 JP JP2001565328A patent/JP2003525922A/ja not_active Ceased
- 2001-03-02 EP EP01916375A patent/EP1268386B1/en not_active Expired - Lifetime
- 2001-03-02 CA CA002398578A patent/CA2398578C/en not_active Expired - Fee Related
- 2001-03-02 BR BRPI0108860-2A patent/BR0108860B1/pt not_active IP Right Cessation
- 2001-03-02 AT AT01916375T patent/ATE272602T1/de not_active IP Right Cessation
- 2001-03-02 US US09/798,600 patent/US6455716B2/en not_active Expired - Lifetime
- 2001-03-02 MX MXPA02008666A patent/MXPA02008666A/es active IP Right Grant
- 2001-03-02 DE DE60104664T patent/DE60104664T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2398578A1 (en) | 2001-09-13 |
US20010044550A1 (en) | 2001-11-22 |
EP1268386B1 (en) | 2004-08-04 |
DE60104664D1 (de) | 2004-09-09 |
WO2001066507A2 (en) | 2001-09-13 |
MXPA02008666A (es) | 2003-02-24 |
JP2003525922A (ja) | 2003-09-02 |
EP1268386A2 (en) | 2003-01-02 |
BR0108860B1 (pt) | 2012-10-02 |
CA2398578C (en) | 2007-04-03 |
AU2001243406A1 (en) | 2001-09-17 |
CN1255369C (zh) | 2006-05-10 |
CN1498200A (zh) | 2004-05-19 |
DE60104664T2 (de) | 2005-08-04 |
ES2225504T3 (es) | 2005-03-16 |
ATE272602T1 (de) | 2004-08-15 |
US6455716B2 (en) | 2002-09-24 |
WO2001066507A3 (en) | 2002-05-02 |
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Legal Events
Date | Code | Title | Description |
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B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 02/10/2012, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 13A ANUIDADE. |
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B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2260 DE 29-04-2014 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |