BE800006A - Cyclopropane carboxylic esters derivs - insecticides - Google Patents
Cyclopropane carboxylic esters derivs - insecticidesInfo
- Publication number
- BE800006A BE800006A BE131503A BE131503A BE800006A BE 800006 A BE800006 A BE 800006A BE 131503 A BE131503 A BE 131503A BE 131503 A BE131503 A BE 131503A BE 800006 A BE800006 A BE 800006A
- Authority
- BE
- Belgium
- Prior art keywords
- alkyl
- hal
- alkenyl
- carboxylic esters
- triple bond
- Prior art date
Links
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical class OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 7
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- QYXWBCXRYGAKSA-UHFFFAOYSA-N 2,2-dimethyl-3-oxocyclopropane-1-carboxylic acid Chemical compound CC1(C)C(C(O)=O)C1=O QYXWBCXRYGAKSA-UHFFFAOYSA-N 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 125000002993 cycloalkylene group Chemical group 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 125000002541 furyl group Chemical group 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/292—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with chromium derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/546—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
- C07D209/49—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/535—Organo-phosphoranes
- C07F9/5352—Phosphoranes containing the structure P=C-
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Molecular Biology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Indole Compounds (AREA)
- Furan Compounds (AREA)
Abstract
carboxylic esters are of formula (I) where R' = H or Me; R2 = H, hal or alkyl; R3 = H, hal, alkyl (is not = R2) or carboxy with >=2C if R2 = Me; or R2R3C = a cycloalkylene residue with >=1 exocyclic double bond; with the proviso's that R1=R2=H when R1 = Me, and R3 >=2C with R1= R2 = H; and R = H, alkyl, PhCH2C triple bond CCH2- or PhOCH2C triple bond CCH2-, where Z = O, S, CH2, CO, Y = H, alkyl, alkenyl, alkynyl or aryl or furyl opt. substd. in the ring by >=1 alkyl, alkenyl, alkynyl, alkoxy or hal; R7 and R8 = H, alkyl, or alkenyl, R9 = H or Me; R10 and R11 = H or alkyl; R12 = an organic residue with an unsatd. C-C bond alpha to the CH2 gp., A is an aromatic. dihydro or tetrahydro ring; X1-X4 = H, Cl or Me; Z3 = CH2, O, CO or S, Z1 and Z2 = Cl or Me, D = H, CN or C triple bond CH; n = 0-2 and Me = CH3; with the proviso's that R is not = H, Et or allethronyl when R1 = H, R2=R3=Cl and I is racemic. I are prepd. by (a) esterification or transesterification (b) condensing a phosphorane R2R3C=P(Z4)3 with a 3-aldehyde or 3-keto 2, 2-dimethyl cyclopropane carboxylic ester.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2480972 | 1972-05-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE800006A true BE800006A (en) | 1973-09-17 |
Family
ID=10217568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE131503A BE800006A (en) | 1972-05-25 | 1973-05-24 | Cyclopropane carboxylic esters derivs - insecticides |
Country Status (5)
| Country | Link |
|---|---|
| JP (3) | JPS5812247B2 (en) |
| BE (1) | BE800006A (en) |
| BR (1) | BR7303782D0 (en) |
| GT (1) | GT197432956A (en) |
| ZA (1) | ZA733528B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2449546A1 (en) * | 1973-10-18 | 1975-04-24 | Sumitomo Chemical Co | INSECTICIDAL AGENTS |
| US4081488A (en) * | 1975-12-24 | 1978-03-28 | Fmc Corporation | Process for preparing 1,1-dihalo-4-methyl-1,3-pentadienes |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4178384A (en) | 1976-03-22 | 1979-12-11 | Fmc Corporation | Pyrethroid insect repellent |
| US4152455A (en) | 1977-02-02 | 1979-05-01 | Fmc Corporation | Insecticidal α-trifluoromethyl-3-phenoxybenzyl carboxylates |
| JPH0712336Y2 (en) * | 1991-09-02 | 1995-03-22 | 佐藤農機株式会社 | Fruit and vegetable feeder |
| JPH0648868U (en) * | 1992-11-02 | 1994-07-05 | 高橋水機株式会社 | Automatic feeding device for objects to be sorted such as people to the weight sorter |
-
1973
- 1973-05-23 BR BR003782/73A patent/BR7303782D0/en unknown
- 1973-05-24 ZA ZA733528A patent/ZA733528B/en unknown
- 1973-05-24 BE BE131503A patent/BE800006A/en not_active IP Right Cessation
-
1974
- 1974-05-15 GT GT197432956A patent/GT197432956A/en unknown
-
1980
- 1980-10-24 JP JP55150032A patent/JPS5812247B2/en not_active Expired
-
1982
- 1982-06-16 JP JP57102315A patent/JPS6011018B2/en not_active Expired
- 1982-10-15 JP JP57180045A patent/JPS58146503A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2449546A1 (en) * | 1973-10-18 | 1975-04-24 | Sumitomo Chemical Co | INSECTICIDAL AGENTS |
| US4081488A (en) * | 1975-12-24 | 1978-03-28 | Fmc Corporation | Process for preparing 1,1-dihalo-4-methyl-1,3-pentadienes |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7303782D0 (en) | 1973-12-20 |
| JPS5812247B2 (en) | 1983-03-07 |
| GT197432956A (en) | 1975-11-06 |
| JPH036122B2 (en) | 1991-01-29 |
| JPS5716806A (en) | 1982-01-28 |
| ZA733528B (en) | 1974-04-24 |
| JPS58146503A (en) | 1983-09-01 |
| JPS5813543A (en) | 1983-01-26 |
| JPS6011018B2 (en) | 1985-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CA | Change of address of the owner of the patent | ||
| RE20 | Patent expired |
Owner name: BRITISH TECHNILOGY GROUP LTD Effective date: 19930524 |