BE581030A - - Google Patents
Info
- Publication number
- BE581030A BE581030A BE581030DA BE581030A BE 581030 A BE581030 A BE 581030A BE 581030D A BE581030D A BE 581030DA BE 581030 A BE581030 A BE 581030A
- Authority
- BE
- Belgium
- Prior art keywords
- boron
- alkyl
- compounds
- reaction
- diborane
- Prior art date
Links
- 229910052796 boron Inorganic materials 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- -1 boron halides Chemical class 0.000 claims description 8
- PPWPWBNSKBDSPK-UHFFFAOYSA-N [B].[C] Chemical class [B].[C] PPWPWBNSKBDSPK-UHFFFAOYSA-N 0.000 claims description 5
- LNDKNSMGUSCVEE-UHFFFAOYSA-N boron;methane Chemical class [B].C LNDKNSMGUSCVEE-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 description 14
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910000085 borane Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 229910015900 BF3 Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012279 sodium borohydride Substances 0.000 description 4
- 229910000033 sodium borohydride Inorganic materials 0.000 description 4
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001347 alkyl bromides Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 229910010277 boron hydride Inorganic materials 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GDLYCTKVUHXJBM-UHFFFAOYSA-N diphenylborane Chemical compound C=1C=CC=CC=1BC1=CC=CC=C1 GDLYCTKVUHXJBM-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000926 not very toxic Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- MXSVLWZRHLXFKH-UHFFFAOYSA-N triphenylborane Chemical compound C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 MXSVLWZRHLXFKH-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE581030A true BE581030A (d) |
Family
ID=191184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE581030D BE581030A (d) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE581030A (d) |
-
0
- BE BE581030D patent/BE581030A/fr unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2914781B2 (ja) | シラシクロアルカンの調製方法 | |
| EP1458729B1 (fr) | Composes (aryl) (amino)boranes, procede pour leur preparation | |
| EP0030528B1 (fr) | Procédé pour la fixation de groupes alkyles, aralkyles ou cycloalkyles sur une chaîne carbonée portant un groupe fonctionnel | |
| BE581030A (d) | ||
| EP2102218A2 (fr) | Procede de preparation de composes 1,3,2-oxazaborolidines | |
| FR2599369A1 (fr) | Procede de preparation de disilylmethanes | |
| EP0171307B1 (fr) | Procédé de fabrication de composés silylmétallocènes et composés obtenus par ce procédé | |
| JPH06172371A (ja) | ヘキサアルキルジスタナンの製法 | |
| US4739096A (en) | Process for producing catecholborane | |
| FR3101633A1 (fr) | Procédé de préparation d’alcénylaminoboranes et de leurs dérivés, et leurs utilisations | |
| EP4341214B1 (fr) | Procédé de production d´azote ammoniacal | |
| EP0398774B1 (fr) | Procédé de préparation de dérivés bromés notamment à partir d'alcools | |
| EP0061408B1 (fr) | Nouveaux monoalcoyle boranes chiraux | |
| FR2775478A1 (fr) | Procede utile pour la silylation de l'acide triflique | |
| CA1205825A (fr) | Procede de preparation de derives du cyclopropane | |
| FR2862972A1 (fr) | Reactif et procede d'obtention d'un derive fluore et silyle | |
| EP0931057B1 (fr) | Procede pour la preparation de derives de 4-methyl-biphenyle | |
| EP0702667B1 (fr) | Procede de preparation de composes difonctionnels de haute purete enantiomerique | |
| EP0146439B1 (fr) | Procédé de préparation de dérivés acétyléniques, nouveaux dérivés obtenus et leur emploi | |
| EP0931059B1 (fr) | Procede pour la preparation d'un cyanobiphenyle | |
| FR2769911A1 (fr) | Procede pour preparer des derives de 5-perfluoroalkyluracile | |
| FR2525590A1 (fr) | Preparation en phase liquide d'esters d'acides delta-cetocarboxyliques utilisant un catalyseur insoluble dans la phase liquide | |
| FR3139338A1 (fr) | Procédé de préparation d’alcénylaminoboranes avec ou sans catalyseur, et de leurs dérivés, et leurs utilisations | |
| FR2664265A1 (fr) | Procede de fabrication de bromures insatures. | |
| WO2019211319A1 (en) | Functionalized semiconductor nanoparticles and method for the manufacture thereof |