BE545074A - - Google Patents

Info

Publication number

BE545074A

BE545074A BE545074DA BE545074A BE 545074 A BE545074 A BE 545074A BE 545074D A BE545074D A BE 545074DA BE 545074 A BE545074 A BE 545074A

Authority

BE

Belgium

Prior art keywords

formula

copper

dyes

desc

clms page

Prior art date

Links

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• 239000000975 dye Substances 0.000 claims description 44
• 239000002253 acid Substances 0.000 claims description 22
• 229910052802 copper Inorganic materials 0.000 claims description 16
• 239000010949 copper Substances 0.000 claims description 16
• RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
• 238000000034 method Methods 0.000 claims description 9
• 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 7
• 239000000203 mixture Substances 0.000 claims description 7
• 150000007513 acids Chemical class 0.000 claims description 6
• 239000000126 substance Substances 0.000 claims description 5
• 150000001879 copper Chemical class 0.000 claims description 4
• 238000004043 dyeing Methods 0.000 claims description 3
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
• 125000001424 substituent group Chemical group 0.000 claims description 3
• 230000015572 biosynthetic process Effects 0.000 claims description 2
• 239000003795 chemical substances by application Substances 0.000 claims description 2
• 238000005755 formation reaction Methods 0.000 claims description 2
• 239000000463 material Substances 0.000 claims description 2
• 238000002360 preparation method Methods 0.000 claims description 2
• 206010035148 Plague Diseases 0.000 claims 1
• 241000607479 Yersinia pestis Species 0.000 claims 1
• 238000003776 cleavage reaction Methods 0.000 claims 1
• 239000003760 tallow Substances 0.000 claims 1
• 101700082413 tant Proteins 0.000 claims 1
• CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 9
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• 239000000835 fiber Substances 0.000 description 5
• 229920000742 Cotton Polymers 0.000 description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
• LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
• 239000001187 sodium carbonate Substances 0.000 description 4
• 229910000029 sodium carbonate Inorganic materials 0.000 description 4
• 238000006243 chemical reaction Methods 0.000 description 3
• 239000004744 fabric Substances 0.000 description 3
• 239000004627 regenerated cellulose Substances 0.000 description 3
• QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
• 230000001808 coupling Effects 0.000 description 2
• 238000010168 coupling process Methods 0.000 description 2
• 238000005859 coupling reaction Methods 0.000 description 2
• NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
• -1 methYl Chemical class 0.000 description 2
• PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
• 238000007747 plating Methods 0.000 description 2
• 235000010288 sodium nitrite Nutrition 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• UIMPAOAAAYDUKQ-UHFFFAOYSA-N 1-methoxy-4-(4-methoxyphenyl)benzene Chemical group C1=CC(OC)=CC=C1C1=CC=C(OC)C=C1 UIMPAOAAAYDUKQ-UHFFFAOYSA-N 0.000 description 1
• USWINTIHFQKJTR-UHFFFAOYSA-N 3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(O)=CC2=C1 USWINTIHFQKJTR-UHFFFAOYSA-N 0.000 description 1
• DOBIZWYVJFIYOV-UHFFFAOYSA-N 7-hydroxynaphthalene-1,3-disulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=CC(O)=CC=C21 DOBIZWYVJFIYOV-UHFFFAOYSA-N 0.000 description 1
• NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
• 210000000988 Bone and Bones Anatomy 0.000 description 1
• 239000005749 Copper compound Substances 0.000 description 1
• ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
• 241000530268 Lycaena heteronea Species 0.000 description 1
• ODGAOXROABLFNM-UHFFFAOYSA-N Polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
• 229920001807 Urea-formaldehyde Polymers 0.000 description 1
• 150000001412 amines Chemical class 0.000 description 1
• 125000003277 amino group Chemical group 0.000 description 1
• VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
• 235000011114 ammonium hydroxide Nutrition 0.000 description 1
• 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
• 239000000987 azo dye Substances 0.000 description 1
• 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
• 238000010504 bond cleavage reaction Methods 0.000 description 1
• 125000004432 carbon atoms Chemical group C* 0.000 description 1
• 229920002678 cellulose Polymers 0.000 description 1
• 239000001913 cellulose Substances 0.000 description 1
• 239000003086 colorant Substances 0.000 description 1
• 150000001880 copper compounds Chemical class 0.000 description 1
• 229910000365 copper sulfate Inorganic materials 0.000 description 1
• SXBOEBVXYQFVJM-UHFFFAOYSA-L copper;2-azanidylpentanedioate Chemical compound [Cu+2].[O-]C(=O)C([NH-])CCC([O-])=O SXBOEBVXYQFVJM-UHFFFAOYSA-L 0.000 description 1
• 230000027326 copulation Effects 0.000 description 1
• 238000009826 distribution Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 238000010304 firing Methods 0.000 description 1
• 230000003311 flocculating Effects 0.000 description 1
• 238000005189 flocculation Methods 0.000 description 1
• 230000016615 flocculation Effects 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 230000001264 neutralization Effects 0.000 description 1
• 150000002816 nickel compounds Chemical class 0.000 description 1
• 239000011541 reaction mixture Substances 0.000 description 1
• 238000005185 salting out Methods 0.000 description 1
• 229910052938 sodium sulfate Inorganic materials 0.000 description 1
• 235000011152 sodium sulphate Nutrition 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000007858 starting material Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 229920003002 synthetic resin Polymers 0.000 description 1
• 239000000057 synthetic resin Substances 0.000 description 1
• 230000001131 transforming Effects 0.000 description 1
• XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(Z)-18-[1,3-bis[[(Z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical group [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 1
• 230000037303 wrinkles Effects 0.000 description 1