BE543377A - - Google Patents
Info
- Publication number
- BE543377A BE543377A BE543377DA BE543377A BE 543377 A BE543377 A BE 543377A BE 543377D A BE543377D A BE 543377DA BE 543377 A BE543377 A BE 543377A
- Authority
- BE
- Belgium
- Prior art keywords
- bis
- ethylene
- parts
- trans
- mixture
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 72
- 239000005977 Ethylene Substances 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 36
- 230000000855 fungicidal Effects 0.000 claims description 30
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 241000233866 Fungi Species 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 9
- 230000003750 conditioning Effects 0.000 claims description 9
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 125000000816 ethylene group Chemical class [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- YTPMCWYIRHLEGM-UHFFFAOYSA-N 1-(2-propylsulfonylethenylsulfonyl)propane Chemical group CCCS(=O)(=O)C=CS(=O)(=O)CCC YTPMCWYIRHLEGM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- YTPMCWYIRHLEGM-BQYQJAHWSA-N 1-[(E)-2-propylsulfonylethenyl]sulfonylpropane Chemical group CCCS(=O)(=O)\C=C\S(=O)(=O)CCC YTPMCWYIRHLEGM-BQYQJAHWSA-N 0.000 claims description 2
- WERZWRCQQURDDW-UHFFFAOYSA-N 1-(2-propylsulfanylethenylsulfanyl)propane Chemical group CCCSC=CSCCC WERZWRCQQURDDW-UHFFFAOYSA-N 0.000 claims 1
- OQMWNKDFIAFJEO-LCYFTJDESA-N 1-chloro-2-[(Z)-2-chloro-1-(4-chlorophenyl)ethenyl]benzene Chemical compound C=1C=CC=C(Cl)C=1C(=C/Cl)\C1=CC=C(Cl)C=C1 OQMWNKDFIAFJEO-LCYFTJDESA-N 0.000 claims 1
- -1 benzylsulfonyl Chemical group 0.000 description 25
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 22
- 229920001098 polystyrene-block-poly(ethylene/propylene) Polymers 0.000 description 22
- 239000004480 active ingredient Substances 0.000 description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 19
- 239000000417 fungicide Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 18
- 239000002904 solvent Substances 0.000 description 14
- 239000004094 surface-active agent Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 11
- 229960000583 Acetic Acid Drugs 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- 238000007792 addition Methods 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011814 protection agent Substances 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- DLMKAVFNJZJSNR-UHFFFAOYSA-N 1,2-bis(ethylsulfanyl)ethene Chemical group CCSC=CSCC DLMKAVFNJZJSNR-UHFFFAOYSA-N 0.000 description 4
- NTMMGQNGLZAENV-UHFFFAOYSA-N 1-(2-butylsulfonylethenylsulfonyl)butane Chemical group CCCCS(=O)(=O)C=CS(=O)(=O)CCCC NTMMGQNGLZAENV-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 230000000875 corresponding Effects 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 235000013312 flour Nutrition 0.000 description 4
- 239000012362 glacial acetic acid Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000005457 ice water Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052903 pyrophyllite Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-Dichloroethene Chemical group ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 description 3
- CODBNMJEAYHFOU-UHFFFAOYSA-N 2-(2-propan-2-ylsulfonylethenylsulfonyl)propane Chemical group CC(C)S(=O)(=O)C=CS(=O)(=O)C(C)C CODBNMJEAYHFOU-UHFFFAOYSA-N 0.000 description 3
- IKPKTPDXWIZMSS-UHFFFAOYSA-N C(CCCCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCCCC Chemical group C(CCCCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCCCC IKPKTPDXWIZMSS-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 230000000240 adjuvant Effects 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000005712 crystallization Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000006124 n-propyl sulfonyl group Chemical group 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 230000000361 pesticidal Effects 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- IRLNDARFTZAVFE-UHFFFAOYSA-N 1,2-bis(methylsulfonyl)ethene Chemical group CS(=O)(=O)C=CS(C)(=O)=O IRLNDARFTZAVFE-UHFFFAOYSA-N 0.000 description 2
- ONVBDYWGWKUWMH-UHFFFAOYSA-N 1-methyl-4-[2-(4-methylphenyl)sulfonylethenylsulfonyl]benzene Chemical group C1=CC(C)=CC=C1S(=O)(=O)C=CS(=O)(=O)C1=CC=C(C)C=C1 ONVBDYWGWKUWMH-UHFFFAOYSA-N 0.000 description 2
- YGBXMKGCEHIWMO-UHFFFAOYSA-N 2-(benzenesulfonyl)ethenylsulfonylbenzene Chemical group C=1C=CC=CC=1S(=O)(=O)C=CS(=O)(=O)C1=CC=CC=C1 YGBXMKGCEHIWMO-UHFFFAOYSA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- UOWXGPJSKQBKLS-UHFFFAOYSA-N C(CCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCC Chemical group C(CCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCC UOWXGPJSKQBKLS-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N Carbon tetrachloride Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N Ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Ethylene tetrachloride Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 241000227653 Lycopersicon Species 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- 241000233622 Phytophthora infestans Species 0.000 description 2
- VZJVWSHVAAUDKD-UHFFFAOYSA-N Potassium permanganate Chemical compound [K+].[O-][Mn](=O)(=O)=O VZJVWSHVAAUDKD-UHFFFAOYSA-N 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- DGMCGTFMFPEQLT-UHFFFAOYSA-M aluminum;magnesium;silicon;hydroxide;tetradecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.[OH-].[Mg].[Mg].[Al].[Al].[Si].[Si].[Si].[Si] DGMCGTFMFPEQLT-UHFFFAOYSA-M 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N triclene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- GYSFJIQTRDNGAM-UHFFFAOYSA-N 1,2-bis(ethylsulfonyl)ethene Chemical group CCS(=O)(=O)C=CS(=O)(=O)CC GYSFJIQTRDNGAM-UHFFFAOYSA-N 0.000 description 1
- HWRMMWBUMQCMJK-UHFFFAOYSA-N 1-ethenylsulfanylpropane Chemical group CCCSC=C HWRMMWBUMQCMJK-UHFFFAOYSA-N 0.000 description 1
- HTAMRUHHHVQRON-UHFFFAOYSA-N 1-ethenylsulfonyldodecane Chemical group CCCCCCCCCCCCS(=O)(=O)C=C HTAMRUHHHVQRON-UHFFFAOYSA-N 0.000 description 1
- BJEWLOAZFAGNPE-UHFFFAOYSA-N 1-ethenylsulfonylethane Chemical group CCS(=O)(=O)C=C BJEWLOAZFAGNPE-UHFFFAOYSA-N 0.000 description 1
- GKRDUERMXXKTEG-UHFFFAOYSA-N 1-ethenylsulfonylpentane Chemical group CCCCCS(=O)(=O)C=C GKRDUERMXXKTEG-UHFFFAOYSA-N 0.000 description 1
- QCFGXOUBDVCCJU-UHFFFAOYSA-N 1-sulfonylethene Chemical class C=C=S(=O)=O QCFGXOUBDVCCJU-UHFFFAOYSA-N 0.000 description 1
- LFSAPCRASZRSKS-UHFFFAOYSA-N 2-methylcyclohexan-1-one Chemical compound CC1CCCCC1=O LFSAPCRASZRSKS-UHFFFAOYSA-N 0.000 description 1
- 241001157812 Alternaria brassicicola Species 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N Amyl acetate Chemical class CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 210000001772 Blood Platelets Anatomy 0.000 description 1
- QLECUINMNLEWNL-UHFFFAOYSA-N BrS(=O)(=O)C=CS(=O)(=O)Br Chemical group BrS(=O)(=O)C=CS(=O)(=O)Br QLECUINMNLEWNL-UHFFFAOYSA-N 0.000 description 1
- MSROQIVMNCOPHG-UHFFFAOYSA-N C(C(C)C)S(=O)(=O)C=CS(=O)(=O)CC(C)C Chemical group C(C(C)C)S(=O)(=O)C=CS(=O)(=O)CC(C)C MSROQIVMNCOPHG-UHFFFAOYSA-N 0.000 description 1
- YFDHACCJBNUHNJ-UHFFFAOYSA-N C(CCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCC Chemical group C(CCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCC YFDHACCJBNUHNJ-UHFFFAOYSA-N 0.000 description 1
- HNDSSAAJCJAILS-UHFFFAOYSA-N C(CCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCC Chemical group C(CCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCC HNDSSAAJCJAILS-UHFFFAOYSA-N 0.000 description 1
- JJIVTTHWDRNMKO-UHFFFAOYSA-N C(CCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCC Chemical group C(CCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCC JJIVTTHWDRNMKO-UHFFFAOYSA-N 0.000 description 1
- HGYWNSYWTQHIJJ-UHFFFAOYSA-N C(CCCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCCC Chemical group C(CCCCCCCCCC)S(=O)(=O)C=CS(=O)(=O)CCCCCCCCCCC HGYWNSYWTQHIJJ-UHFFFAOYSA-N 0.000 description 1
- QDUXEYPUMAZWPD-UHFFFAOYSA-N C(CCCCCCCCCCC)SC=CSCCCCCCCCCCCC Chemical compound C(CCCCCCCCCCC)SC=CSCCCCCCCCCCCC QDUXEYPUMAZWPD-UHFFFAOYSA-N 0.000 description 1
- ZGDYMQNJZADYOA-UHFFFAOYSA-N C1(=C(C=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)C)C Chemical group C1(=C(C=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)C)C ZGDYMQNJZADYOA-UHFFFAOYSA-N 0.000 description 1
- CUEWXKSFEBQKNF-UHFFFAOYSA-N C1(=CC=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)C Chemical group C1(=CC=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)C CUEWXKSFEBQKNF-UHFFFAOYSA-N 0.000 description 1
- ABUFRLWNPRAGAL-UHFFFAOYSA-N C1(=CC=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)[N+](=O)[O-] Chemical group C1(=CC=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)[N+](=O)[O-] ABUFRLWNPRAGAL-UHFFFAOYSA-N 0.000 description 1
- DWUBAMFQXLXQEW-UHFFFAOYSA-N CS(=O)(=O)C=CS(=O)(=O)C1=CC=CC=C1 Chemical group CS(=O)(=O)C=CS(=O)(=O)C1=CC=CC=C1 DWUBAMFQXLXQEW-UHFFFAOYSA-N 0.000 description 1
- 229960005069 Calcium Drugs 0.000 description 1
- 229960003563 Calcium Carbonate Drugs 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000007842 Glycine max Species 0.000 description 1
- 101710024788 HOMER1 Proteins 0.000 description 1
- 241000728904 Iais Species 0.000 description 1
- GUWSLQUAAYEZAF-UHFFFAOYSA-L Lead(II) acetate Chemical compound O1C(C)=O[Pb]21O=C(C)O2 GUWSLQUAAYEZAF-UHFFFAOYSA-L 0.000 description 1
- 241001518731 Monilinia fructicola Species 0.000 description 1
- 241001182492 Nes Species 0.000 description 1
- 240000008962 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N Oleyl alcohol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- SUVIGLJNEAMWEG-UHFFFAOYSA-N Propanethiol Chemical compound CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N Sec-Butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N Sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- LEMWQWOTZUTNIS-UHFFFAOYSA-N [N+](=O)([O-])C1=C(C=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)[N+](=O)[O-] Chemical group [N+](=O)([O-])C1=C(C=CC=C1)S(=O)(=O)C=CS(=O)(=O)C1=C(C=CC=C1)[N+](=O)[O-] LEMWQWOTZUTNIS-UHFFFAOYSA-N 0.000 description 1
- REOSBMQHXAKDEJ-UHFFFAOYSA-N [N+](=O)([O-])C1=CC=C(C=C1)S(=O)(=O)C=CS(=O)(=O)C1=CC=C(C=C1)[N+](=O)[O-] Chemical group [N+](=O)([O-])C1=CC=C(C=C1)S(=O)(=O)C=CS(=O)(=O)C1=CC=C(C=C1)[N+](=O)[O-] REOSBMQHXAKDEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229920002892 amber Polymers 0.000 description 1
- 230000000844 anti-bacterial Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000003115 biocidal Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing Effects 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KARVSHNNUWMXFO-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane;hydrate Chemical compound O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O KARVSHNNUWMXFO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 201000009910 diseases by infectious agent Diseases 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- QDXBVEACAWKSFL-UHFFFAOYSA-N ethenethiol Chemical class SC=C QDXBVEACAWKSFL-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000006125 ethylsulfonyl group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 230000002458 infectious Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000749 insecticidal Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000003902 lesions Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- AMBKPYJJYUKNFI-UHFFFAOYSA-N methylsulfanylethene Chemical group CSC=C AMBKPYJJYUKNFI-UHFFFAOYSA-N 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000006126 n-butyl sulfonyl group Chemical group 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000003389 potentiating Effects 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 238000004642 transportation engineering Methods 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000003799 water insoluble solvent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
- C07C315/02—Preparation of sulfones; Preparation of sulfoxides by formation of sulfone or sulfoxide groups by oxidation of sulfides, or by formation of sulfone groups by oxidation of sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
- C07C317/08—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE543377A true BE543377A (ja) |
Family
ID=171722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE543377D BE543377A (ja) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE543377A (ja) |
-
0
- BE BE543377D patent/BE543377A/fr unknown
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