BE510074A - - Google Patents
Info
- Publication number
- BE510074A BE510074A BE510074DA BE510074A BE 510074 A BE510074 A BE 510074A BE 510074D A BE510074D A BE 510074DA BE 510074 A BE510074 A BE 510074A
- Authority
- BE
- Belgium
- Prior art keywords
- polymerization
- emulsifier
- emi
- oxygen
- properties
- Prior art date
Links
- 239000003995 emulsifying agent Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 11
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- XKGDWZQXVZSXAO-ADYSOMBNSA-N Ricinoleic Acid methyl ester Chemical class CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC XKGDWZQXVZSXAO-ADYSOMBNSA-N 0.000 claims description 2
- BJHIKXHVCXFQLS-PYWDMBMJSA-N sorbose group Chemical group OCC(=O)[C@H](O)[C@@H](O)[C@H](O)CO BJHIKXHVCXFQLS-PYWDMBMJSA-N 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical class [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- WYPBVHPKMJYUEO-NBTZWHCOSA-M sodium;(9z,12z)-octadeca-9,12-dienoate Chemical compound [Na+].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O WYPBVHPKMJYUEO-NBTZWHCOSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE307335X | 1952-03-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE510074A true BE510074A (de) |
Family
ID=3867501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE510074D BE510074A (de) | 1952-03-19 |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE510074A (de) |
| CH (1) | CH307335A (de) |
| FR (1) | FR1072806A (de) |
-
0
- BE BE510074D patent/BE510074A/fr unknown
-
1953
- 1953-03-09 FR FR1072806D patent/FR1072806A/fr not_active Expired
- 1953-03-09 CH CH307335D patent/CH307335A/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH307335A (fr) | 1955-05-31 |
| FR1072806A (fr) | 1954-09-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4035329A (en) | Process for the continuous production of an ethylene/vinyl acetate copolymer dispersion | |
| EP0120524B1 (de) | Polymerisationsverfahren von Vinylidenfluorid in einer wässrigen Suspension | |
| EP2673307B2 (de) | Durch organische peroxide mit hoher produktivität initialisierte polymerisation freier radikale aus äthylen | |
| JPH05320253A (ja) | テトラフルオロエチレンポリマーの製造方法 | |
| US4186121A (en) | Process for obtaining colloidal dispersion of polymeric tetrafluoroethylene | |
| EP1006129A2 (de) | Process für das Polymerisieren von Tetrafluorethylen | |
| US3637633A (en) | Peroxy compounds | |
| NO138336B (no) | Analogifremgangsmaate for fremstilling av terapeutisk aktive benzofuranderivater | |
| AU689621B2 (en) | Suspending agent for suspension polymerization of vinyl compound | |
| EP0150640B1 (de) | Verfahren zur Polymerisation von Chloropren | |
| EP0192508B1 (de) | Härtbare Polymere auf Basis von ungesättigten Estern von Furancarbonsäure, Verfahren zu deren Herstellung und deren Verwendung bei der Herstellung von Überzügen | |
| FR2508463A1 (fr) | Procede de preparation continue de polymeres en emulsion inverse | |
| FR2850387A1 (fr) | Procede de fabrication de pvdf | |
| JPS6050813B2 (ja) | テトラフルオロエチレン−ヘキサフルオロプロピレン共重合体の製造方法 | |
| FR2511008A1 (fr) | Procede de preparation de latex de polymeres d'acetate de vinyle | |
| US2553982A (en) | Method of polymerizing phenolcontaining vinylidene chloride | |
| FR2480758A1 (fr) | Procede de polymerisation d'un monomere du type chlorure de vinyle en presence de catalyseurs du type peroxyde | |
| BE1012395A3 (fr) | Procede de polymerisation de monomeres halogenes. | |
| FR2479238A1 (fr) | Procede de preparation de resines styreniques renforcees par du caoutchouc et resines obtenues par ce procede | |
| WO2018115790A1 (fr) | Utilisation d'au moins un composé phénolique pour stabiliser des réactions de copolymérisation d'éthylène | |
| US3174952A (en) | Terpolymer vinylacetate-2-oxymethyl-1, 4-endomethylene-cyclohexene-(5)-ethylene and process therefor | |
| WO2000032659A1 (fr) | Procede de preparation de copolymeres halogenes, copolymeres obtenus et utilisation de ceux-ci | |
| JPS5811889B2 (ja) | 塩化ビニル系重合体の製造方法 | |
| JPH0131762B2 (de) | ||
| FR2824561A1 (fr) | Latex adhesif a base de polychloroprene fonctionnalise carboxylique et a faible retention d'eau |