BE497094A - - Google Patents

Info

Publication number

BE497094A

BE497094A BE497094DA BE497094A BE 497094 A BE497094 A BE 497094A BE 497094D A BE497094D A BE 497094DA BE 497094 A BE497094 A BE 497094A

Authority

BE

Belgium

Prior art keywords

magnesium

arsenic

oxide

red

manganese

Prior art date

Links

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• 239000000126 substance Substances 0.000 claims description 46
• 239000000395 magnesium oxide Substances 0.000 claims description 21
• CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 21
• AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 21
• 150000001875 compounds Chemical class 0.000 claims description 20
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 14
• 229910052749 magnesium Inorganic materials 0.000 claims description 14
• 239000011777 magnesium Substances 0.000 claims description 14
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
• 229910052785 arsenic Inorganic materials 0.000 claims description 10
• RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 10
• 238000010438 heat treatment Methods 0.000 claims description 10
• 229910052748 manganese Inorganic materials 0.000 claims description 10
• 239000011572 manganese Substances 0.000 claims description 10
• 239000000203 mixture Substances 0.000 claims description 8
• IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 claims description 7
• 229910000413 arsenic oxide Inorganic materials 0.000 claims description 7
• 229960002594 arsenic trioxide Drugs 0.000 claims description 7
• 238000004020 luminiscence type Methods 0.000 claims description 7
• 238000002360 preparation method Methods 0.000 claims description 7
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
• 229910052760 oxygen Inorganic materials 0.000 claims description 6
• 239000001301 oxygen Substances 0.000 claims description 6
• 238000000034 method Methods 0.000 claims description 5
• 230000001590 oxidative effect Effects 0.000 claims description 5
• 230000004907 flux Effects 0.000 claims description 4
• COHDHYZHOPQOFD-UHFFFAOYSA-N arsenic pentoxide Chemical compound O=[As](=O)O[As](=O)=O COHDHYZHOPQOFD-UHFFFAOYSA-N 0.000 claims description 3
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
• 230000008569 process Effects 0.000 claims description 3
• 239000007795 chemical reaction product Substances 0.000 claims description 2
• ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 2
• 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 2
• 150000002222 fluorine compounds Chemical class 0.000 claims 1
• 238000004519 manufacturing process Methods 0.000 claims 1
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 7
• 230000008901 benefit Effects 0.000 description 6
• 239000003086 colorant Substances 0.000 description 5
• GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 4
• 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 4
• 239000000725 suspension Substances 0.000 description 4
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
• 238000006243 chemical reaction Methods 0.000 description 3
• 230000005284 excitation Effects 0.000 description 3
• MCSXGCZMEPXKIW-UHFFFAOYSA-N 3-hydroxy-4-[(4-methyl-2-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound Cc1ccc(N=Nc2c(O)c(cc3ccccc23)C(=O)Nc2cccc(c2)[N+]([O-])=O)c(c1)[N+]([O-])=O MCSXGCZMEPXKIW-UHFFFAOYSA-N 0.000 description 2
• DJHGAFSJWGLOIV-UHFFFAOYSA-L Arsenate2- Chemical compound O[As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-L 0.000 description 2
• PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
• 230000002349 favourable effect Effects 0.000 description 2
• 239000012467 final product Substances 0.000 description 2
• 229910052731 fluorine Inorganic materials 0.000 description 2
• 239000011737 fluorine Substances 0.000 description 2
• 239000011656 manganese carbonate Substances 0.000 description 2
• 235000006748 manganese carbonate Nutrition 0.000 description 2
• 239000000463 material Substances 0.000 description 2
• 229910052753 mercury Inorganic materials 0.000 description 2
• 230000005855 radiation Effects 0.000 description 2
• 238000001228 spectrum Methods 0.000 description 2
• DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
• LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
• 238000004458 analytical method Methods 0.000 description 1
• AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
• 125000001870 arsonato group Chemical group O=[As]([O-])([O-])[*] 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 238000000576 coating method Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 238000002425 crystallisation Methods 0.000 description 1
• 230000008025 crystallization Effects 0.000 description 1
• 239000012153 distilled water Substances 0.000 description 1
• 238000001704 evaporation Methods 0.000 description 1
• 230000008020 evaporation Effects 0.000 description 1
• 238000000695 excitation spectrum Methods 0.000 description 1
• 239000000706 filtrate Substances 0.000 description 1
• 229910052732 germanium Inorganic materials 0.000 description 1
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
• YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
• 230000007246 mechanism Effects 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 238000007254 oxidation reaction Methods 0.000 description 1
• PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
• 239000000047 product Substances 0.000 description 1
• 230000009257 reactivity Effects 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 238000001429 visible spectrum Methods 0.000 description 1