BE446309A - - Google Patents

Info

Publication number
BE446309A
BE446309A BE446309DA BE446309A BE 446309 A BE446309 A BE 446309A BE 446309D A BE446309D A BE 446309DA BE 446309 A BE446309 A BE 446309A
Authority
BE
Belgium
Prior art keywords
emi
solvents
lactones
plasticizers
artificial materials
Prior art date
Application number
Other languages
French (fr)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication of BE446309A publication Critical patent/BE446309A/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Description

       

   <EMI ID=1.1> 

  
 <EMI ID=2.1> 

  
Le façonnage de toute une série de polymères supérieurs connus en forme de films, de fibres et d'autres produits constitue un problème technique qui, jusqu'à présent, n'a pas été résolu de façon entièrement satisfaisante, car pour différents de ces composés, les solvants et les plastifiants ne donnent aucun résultat ou bien encore, pour l'une ou l'autre de ces matières artificielles, les solvants connus sont, soit trop chers, soit trop difficiles à régénérer. Dans d'autres cas, les solvants connus jusqu'à présent ont une forte action corrosive ou sont très nuisibles pour la santé ou présentent un

  
 <EMI ID=3.1> 

  
auxquels supplique ce qui vient d'être dit, sous l'une ou

  
1 i

  
l'autre forme sont, par exemple, lè.polyacylnitrile, le chlo-

  
 <EMI ID=4.1> 

  
vinyle qui a subi un chlorage supplémentaire à des points de ramollissement supérieurs à 100[deg.], le polyvinylcarbazol, le

  
 <EMI ID=5.1> 

  
tres.

  
La Demanderesse a trouvé qu'il existe pour les groupes entièrement différents de matières artificielles qui viennent' d'être mentionnées, des solvants et des plastifiants extrêmement efficaces parmi les lactones des oxy-acides, préférable-

  
 <EMI ID=6.1> 

  
simple déjà, le butyro-lactone, qui récemment est devenu d'un accès relativement facile au point de vue industriel, possède un pouvoir de dissolution extrêmement varié qui permet de préparer sans difficulté des solutions à pourcentages élevés de la plupart des matières artificielles qui viennent d'être citées. Cependant ce pouvoir de dissolution n'est pas limité au butyro-

  
 <EMI ID=7.1> 

  
 <EMI ID=8.1> 

  
 <EMI ID=9.1> 

  
favorable.

  
Est digne de mention, en outre, le fait que ces composés ne doivent pas être employés comme solvants à l'état pur, mais, étant donné qu'ils sont miscibles avec le plus grand nombre des solvants organiques connus jusqu'à l'heure actuelle, peuvent être, à tout moment, coupés avec ces solvants.

  
Alors que, jusqu'à présent, les lactones cités à titre d'exemple jusqu'à présent devaient être considérés surtout com-

  
 <EMI ID=10.1> 

  
pérature ordinaire et ont aussi des points d'ébullition relativement bas, les lactones à substituants aliphatiques et sur-

  
 <EMI ID=11.1>  comme des plastifiants excellents. Les laotones de l'espèce

  
 <EMI ID=12.1> 

  
propionique et d'autres.

  
Ces composés, qui constituent presque tous des corps solides à la température ordinaire, s'incorporent aux matières artificielles qui doivent être ramollies par pétrissage ou laminage suivant des procédés connus en soi avec le secours de la chaleur à raison de quantités allant jusqu'à 50 %, ce qui plastifie les polymères supérieurs et permet de travailler ensuite ceux-ci plus facilement. De même que pour l'emploi des lactones comme solvants, il n'est pas nécessaire non plus, dans ce cas; d*employer des lactones purs, on obtient souvent des effets nouveaux en se servant de mélanges de plastifiants déjà connus avec des lactones.

   On mentionnera encore expressément que l'emploi des laotones n'est nullement limité aux polymères linéaires supérieurs mentionnés à l'origine, mais qu'un grand nombre encore d'autres matières artificielles staccomodent très bien du groupe de solvants et de plastifiants revendiqué par la présente demande de brevet.



   <EMI ID = 1.1>

  
 <EMI ID = 2.1>

  
The shaping of a whole series of known higher polymers into films, fibers and other products is a technical problem which, heretofore, has not been solved entirely satisfactorily, since for different of these compounds , the solvents and the plasticizers do not give any result or else, for one or the other of these artificial materials, the known solvents are either too expensive or too difficult to regenerate. In other cases, the solvents known hitherto have a strong corrosive action or are very harmful to health or present a

  
 <EMI ID = 3.1>

  
to whom what has just been said, under one or

  
1 i

  
the other form are, for example, polyacylnitrile, chlo-

  
 <EMI ID = 4.1>

  
vinyl which has undergone additional chlorination at softening points greater than 100 [deg.], polyvinylcarbazol,

  
 <EMI ID = 5.1>

  
very.

  
We have found that for the entirely different groups of artificial materials which have just been mentioned, extremely effective solvents and plasticizers exist among lactones and preferably oxy acids.

  
 <EMI ID = 6.1>

  
Simple already, butyro-lactone, which has recently become relatively easily accessible from an industrial point of view, possesses an extremely varied dissolving power which makes it possible to prepare without difficulty solutions at high percentages of most of the artificial materials which come. to be cited. However, this dissolving power is not limited to butyro-

  
 <EMI ID = 7.1>

  
 <EMI ID = 8.1>

  
 <EMI ID = 9.1>

  
favorable.

  
Noteworthy, moreover, is the fact that these compounds should not be used as solvents in their pure state, but, since they are miscible with the greatest number of organic solvents known until now. current, can be cut with these solvents at any time.

  
Whereas, until now, the lactones cited by way of example until now had to be considered above all as

  
 <EMI ID = 10.1>

  
ordinary temperature and also have relatively low boiling points, aliphatic and over-substituted lactones

  
 <EMI ID = 11.1> as excellent plasticizers. Laotones of the species

  
 <EMI ID = 12.1>

  
propionic and others.

  
These compounds, which almost all constitute solid bodies at room temperature, are incorporated into artificial materials which must be softened by kneading or rolling according to processes known per se with the aid of heat in quantities of up to 50 %, which plasticizes the higher polymers and then allows them to be processed more easily. As for the use of lactones as solvents, it is not necessary either, in this case; With the use of pure lactones, new effects are often obtained by using mixtures of plasticizers already known with lactones.

   It will also be expressly mentioned that the use of laotones is by no means limited to the higher linear polymers originally mentioned, but that a large number of other artificial materials are very well suited to the group of solvents and plasticizers claimed by present patent application.


    

Claims (1)

REVENDICATION. CLAIM. Façonnage des polymères linéaires supérieurs, caractérisé par le fait que l'on emploie, comme solvants où-comme plastifiants, des lactones, seuls ou en mélange avec d'autres composés. Shaping of higher linear polymers, characterized in that one uses, as solvents or as plasticizers, lactones, alone or in admixture with other compounds.
BE446309D 1941-07-04 BE446309A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE883764X 1941-07-04

Publications (1)

Publication Number Publication Date
BE446309A true BE446309A (en)

Family

ID=6832196

Family Applications (1)

Application Number Title Priority Date Filing Date
BE446309D BE446309A (en) 1941-07-04

Country Status (2)

Country Link
BE (1) BE446309A (en)
FR (1) FR883764A (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2535664A (en) * 1945-08-09 1950-12-26 Monsanto Chemicals Plasticizing synthetic rubber
US2624723A (en) * 1947-03-03 1953-01-06 Allied Chem & Dye Corp Lactone derivatives and method of making
US2544385A (en) * 1948-03-25 1951-03-06 Monsanto Chemicals Synthetic fiber preparation
US2503200A (en) * 1948-03-25 1950-04-04 Monsanto Chemicals Separation of gamma-valerolactone from water
US2654652A (en) * 1949-08-02 1953-10-06 Du Pont Dyeing of acrylonitrile polymers with acetate dyes
DE932692C (en) * 1949-08-18 1955-09-08 Glanzstoff Ag Process for the production of artificial structures from polyvinyl chloride or copolymers of vinyl chloride
US2808311A (en) * 1954-10-15 1957-10-01 Du Pont Process of setting the crimp in acrylonitrile polymer fibers with chemical shrinking and setting agents
US2869974A (en) * 1955-03-02 1959-01-20 Du Pont Process for shrinking polyacrylonitrile textiles with specific chemical shrinking agents
US2869975A (en) * 1955-03-28 1959-01-20 Du Pont Process for shrinking and setting polyacrylonitrile textile filaments with specific chemical shrinking agents
US2958677A (en) * 1955-05-10 1960-11-01 Phillips Petroleum Co Purification of polymers of the polyamide type

Also Published As

Publication number Publication date
FR883764A (en) 1943-07-16

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