US962877A - Celluloid composition. - Google Patents
Celluloid composition. Download PDFInfo
- Publication number
- US962877A US962877A US31946506A US1906319465A US962877A US 962877 A US962877 A US 962877A US 31946506 A US31946506 A US 31946506A US 1906319465 A US1906319465 A US 1906319465A US 962877 A US962877 A US 962877A
- Authority
- US
- United States
- Prior art keywords
- celluloid
- composition
- fatty acid
- halogenized
- derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002160 Celluloid Polymers 0.000 title description 15
- 239000000203 mixture Substances 0.000 title description 15
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 14
- 229920002678 cellulose Polymers 0.000 description 11
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 6
- 229920001220 nitrocellulos Polymers 0.000 description 6
- 229940079938 nitrocellulose Drugs 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- -1 stearic Chemical class 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000651994 Curio Species 0.000 description 1
- 101100381997 Danio rerio tbc1d32 gene Proteins 0.000 description 1
- 101100381999 Mus musculus Tbc1d32 gene Proteins 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
- C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
Definitions
- the invention consists in admixing r a s sociating, by the aid of a suitable solvent,-
- a halogenized fatty acid or derivative such as the methyl": p gpy le e atesilt ernule. l nt) :iri j fififieumtiv ie: A; n'ated fatty aci d.
- halogenized fat y a'cid ITn'ea'iT fatty acid such as stearic, palmitid or myristic acid, in which a part of the hy; drogen is replaced by a halogen, such as fluorin,"ghlgri 1 i,f0r bromi ll1e compositibiiTiTa'ybe varied in'a'iiuinber of Ways to suit the special requirements of its use.
- the proportion of the halogenized fatty acid or derivative may be increased until it exceeds the pyroxylin or cellulose ester.
- a smaller proportion of a halogenized fatty acid or derivative may be used, or if great toughness is not important, the Lhalogenizing of the fatty acid may be carried to such an extent as to resinize the same.
- - Stearic acid or palmitic acid when chlorinated in the usual way for several days in a-heated condition (preferably with the aid of a.catalytic agent, such as i odi 1 r i i i t ip 1 orrv chlolid) passes through various stages, commencing with the solid fatty acid, thence to an oily liquid when cold, and finally through progressively increasing degrees of viscosity, as each additional atom of hydrogenis replaced by chlorin until a resinous solid results. The further this treatment is carried the higher will be the non
- a solid solvent of pyroxylin and cellulose esters when heated with the same with the aid of a common solvent.
- the presence of the halogenized fatty acid or fatty' acid derivative imparts decreased inflannnability to the product; in fact, when a halogenized fatty acid or fatty acid derivative is thus admixed in aryingproportions with pyrlylin or ;cellulose ,ester, the compound can be burned only with great difficulty.
- a composition closely resembling celluloid can be obtained, since the halogenized solid solvent possesses the desirable A properties of camphor in celluloid without beingin the least volatile.
- the halogenized solid solvent is added to the cellulose ester or yroxylin and with the aid of a common so vent, such as acetone, the composition may bemanufactured into rods, sheets, films or other articles by the well-known methods of manipulating celluloid.
- a celluloid composition comprising pyroxylin or other cellulose ester, combined with a halogenized fatty acid or its derivative, substantially as set forth.
- a celluloid composition comprising pyroxylin orother cellulose ester, combined with halo enized stearic acid, substantially as set fort 4
- a celluloid composition comprising pyroxylin or other cellulose ester, combined with chlorinated stearic acid, substantially as set forth.
- a celluloid composition comprising an ester of cellulose of'the acetic series of fatty acids, combined with a halogenized fatty acid or its derivative, substantially as set forth.
- a celluloid composition comprising an ester of cellulose of the acetic series of fatty acids, combined with a chlorinated fatty acid or its derivative, substantially as set forth. 7
- a celluloid composition comprising an 2.
- a celluloid composition comprising pyester of cellulose ofthe acetic series of fatty .;Th is specification signed and witnessed acigs, combine?l with lflalofienized stearic this 29th day of May 1906.
- Y aci substantia y as set ort 8.
- a celluloid composition comprising an JGNAS AYLSWORTH 5 ester of cellulose of the acetic series of fatty witnesseses:
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
To all whom it may concern.
' following is a description.
as 962.2??? Y PATENT curios;
JONAS W. AYLSWORTH, OF EAST ORANGE, NEW JERSEY,
'GEII LLULOID COMPOSITION.
No Drawing. Application filed May 31,
Be it known that I, JoNAs W. AYLswoR'rH, a citizen of the United States, residing at 223 Midland avenue,- East Orange, in the county of Essex and State of New Jersey, .have invented a certain new and useful Improved Celluloid Composition, of which the The object of my invention is to render celluloid and similar compositions .less mflammable, while at the same time preserviiig tliiir desirable properties of transparency, toughness, flexibility, etc.
The invention consists in admixing r a s sociating, by the aid of a suitable solvent,-
with pyroxylin and wiarciiuios'eiesiersgf the acetic series, a halogenized fatty acid or derivative such as the methyl": p gpy le e atesilt ernule. l nt) :iri j fififieumtiv ie: A; n'ated fatty aci d. By a halogenized fat y a'cid ITn'ea'iT fatty acid, such as stearic, palmitid or myristic acid, in which a part of the hy; drogen is replaced by a halogen, such as fluorin,"ghlgri 1 i,f0r bromi ll1e compositibiiTiTa'ybe varied in'a'iiuinber of Ways to suit the special requirements of its use. For
instance, when great flexibility is required,
the proportion of the halogenized fatty acid or derivative may be increased until it exceeds the pyroxylin or cellulose ester. When it is desired to make more or less massive articles Where flexibility is not important, but where great toughness is desired, a smaller proportion of a halogenized fatty acid or derivative may be used, or if great toughness is not important, the Lhalogenizing of the fatty acid may be carried to such an extent as to resinize the same.- Stearic acid or palmitic acid, when chlorinated in the usual way for several days in a-heated condition (preferably with the aid of a.catalytic agent, such as i odi 1 r i i i t ip 1 orrv chlolid) passes through various stages, commencing with the solid fatty acid, thence to an oily liquid when cold, and finally through progressively increasing degrees of viscosity, as each additional atom of hydrogenis replaced by chlorin until a resinous solid results. The further this treatment is carried the higher will be the non-infiammability of the resulting compound. Such materials and many of its derivatives above referred Specification of.
L tters Patent latented June 28, 1910.
1906. Serial No. 319,465.
to, form a solid solvent of pyroxylin and cellulose esters when heated with the same with the aid of a common solvent. The presence of the halogenized fatty acid or fatty' acid derivative imparts decreased inflannnability to the product; in fact, when a halogenized fatty acid or fatty acid derivative is thus admixed in aryingproportions with pyrlylin or ;cellulose ,ester, the compound can be burned only with great difficulty. At the same time, a composition closely resembling celluloid can be obtained, since the halogenized solid solvent possesses the desirable A properties of camphor in celluloid without beingin the least volatile.
In manufacturing the improved celluloid composition, the halogenized solid solvent is added to the cellulose ester or yroxylin and with the aid of a common so vent, such as acetone, the composition may bemanufactured into rods, sheets, films or other articles by the well-known methods of manipulating celluloid.
Having now described my invention, Wha I claim as new and desire to secure by Let ters Patent is as follows 1. A celluloid composition, comprising pyroxylin or other cellulose ester, combined with a halogenized fatty acid or its derivative, substantially as set forth.
roxylin or other'cellulosemster, combined with af'chlorinated fatty acidcr its derivative, substantially as set forth.
3. A celluloid composition, comprising pyroxylin orother cellulose ester, combined with halo enized stearic acid, substantially as set fort 4, A celluloid composition, comprising pyroxylin or other cellulose ester, combined with chlorinated stearic acid, substantially as set forth.
5. A celluloid composition comprising an ester of cellulose of'the acetic series of fatty acids, combined with a halogenized fatty acid or its derivative, substantially as set forth.
6. A celluloid composition comprising an ester of cellulose of the acetic series of fatty acids, combined with a chlorinated fatty acid or its derivative, substantially as set forth. 7
7. A celluloid composition comprising an 2. A celluloid composition, comprising pyester of cellulose ofthe acetic series of fatty .;Th is specification signed and witnessed acigs, combine?l with lflalofienized stearic this 29th day of May 1906. Y aci ,substantia y as set ort 8. A celluloid composition, comprising an JGNAS AYLSWORTH 5 ester of cellulose of the acetic series of fatty Witnesses:
acids, combined with chlorinated stearic FRANK L. DYER, acid, substantially as set forth. ANNAR. KLEHM.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31946506A US962877A (en) | 1906-05-31 | 1906-05-31 | Celluloid composition. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31946506A US962877A (en) | 1906-05-31 | 1906-05-31 | Celluloid composition. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US962877A true US962877A (en) | 1910-06-28 |
Family
ID=3031275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US31946506A Expired - Lifetime US962877A (en) | 1906-05-31 | 1906-05-31 | Celluloid composition. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US962877A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305431A (en) * | 1960-02-15 | 1967-02-21 | Swift & Co | Flameproofing compositon, method and article containing same |
-
1906
- 1906-05-31 US US31946506A patent/US962877A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305431A (en) * | 1960-02-15 | 1967-02-21 | Swift & Co | Flameproofing compositon, method and article containing same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE701911C (en) | Capsule for medical purposes | |
| DE102014019214A1 (en) | Process for the production of molded parts | |
| US962877A (en) | Celluloid composition. | |
| DE755616C (en) | Plasticizer for mixed polyamides | |
| DE1164081B (en) | Process for the production of films made of polyvinyl chloride or its copolymers, stabilized against the effects of heat | |
| US1552795A (en) | Cellulose-ester composition | |
| US3277031A (en) | Plasticized compositions comprising a polyester of hydracrylic acid, and a cellulose ester | |
| US840251A (en) | Pattern-powder. | |
| US738533A (en) | Plastic composition. | |
| US1188797A (en) | Plastic composition. | |
| DE2064373C3 (en) | Meltable coating agents, in particular for food and pharmaceutical preparations | |
| US2019892A (en) | Cellulosic composition of matter containing a carbamate | |
| US552209A (en) | Pyroxyline compound | |
| US855556A (en) | Duplicate sound-record. | |
| USRE14530E (en) | Tebxaoixkt o office | |
| US2604413A (en) | Ethyl cellulose composition containing di-tertiary-octyl diphenyloxide | |
| US1617237A (en) | Cellulose-ester composition | |
| US774713A (en) | Cellulose acetate. | |
| US3068112A (en) | Polymeric derivatives of bicycloheptene as stabilizers for polymer compositions | |
| US543197A (en) | John h | |
| US2215601A (en) | Plastic composition | |
| US2245233A (en) | Cellulose derivative compositions containing butyl butoxyacetate | |
| USRE14531E (en) | Jonas w | |
| US1560542A (en) | Cellulose acetate composition | |
| US1226341A (en) | Process of making acetyl-cellulose plastic compounds. |