BE332695A - - Google Patents

Info

Publication number

BE332695A

BE332695A BE332695DA BE332695A BE 332695 A BE332695 A BE 332695A BE 332695D A BE332695D A BE 332695DA BE 332695 A BE332695 A BE 332695A

Authority

BE

Belgium

Prior art keywords

compounds

stilbene

cellulose acetate

yarns

products

Prior art date

Links

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• 150000001875 compounds Chemical class 0.000 claims description 24
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
• 239000000463 material Substances 0.000 claims description 22
• 229920002301 Cellulose acetate Polymers 0.000 claims description 21
• PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 18
• 238000004043 dyeing Methods 0.000 claims description 14
• 239000002253 acid Substances 0.000 claims description 13
• 238000004040 coloring Methods 0.000 claims description 10
• 239000004744 fabric Substances 0.000 claims description 9
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
• GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
• 239000000835 fiber Substances 0.000 claims description 6
• 238000000034 method Methods 0.000 claims description 5
• 235000021286 stilbenes Nutrition 0.000 claims description 5
• BIEFDNUEROKZRA-UHFFFAOYSA-N 2-(2-phenylethenyl)aniline Chemical class NC1=CC=CC=C1C=CC1=CC=CC=C1 BIEFDNUEROKZRA-UHFFFAOYSA-N 0.000 claims description 4
• 239000000084 colloidal system Substances 0.000 claims description 4
• 230000001808 coupling Effects 0.000 claims description 4
• 238000010168 coupling process Methods 0.000 claims description 4
• 238000005859 coupling reaction Methods 0.000 claims description 4
• 230000000694 effects Effects 0.000 claims description 4
• 239000003292 glue Substances 0.000 claims description 4
• -1 pax phenol Chemical class 0.000 claims description 4
• 230000001681 protective Effects 0.000 claims description 4
• 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 4
• 239000004375 Dextrin Substances 0.000 claims description 3
• 229920001353 Dextrin Polymers 0.000 claims description 3
• RGLYKWWBQGJZGM-UHFFFAOYSA-N Diethylstilbestrol Chemical compound C=1C=C(O)C=CC=1C(CC)=C(CC)C1=CC=C(O)C=C1 RGLYKWWBQGJZGM-UHFFFAOYSA-N 0.000 claims description 3
• 108010010803 Gelatin Proteins 0.000 claims description 3
• 101700014318 STIL Proteins 0.000 claims description 3
• 235000019425 dextrin Nutrition 0.000 claims description 3
• 229920000159 gelatin Polymers 0.000 claims description 3
• 239000008273 gelatin Substances 0.000 claims description 3
• 235000019322 gelatine Nutrition 0.000 claims description 3
• 235000011852 gelatine desserts Nutrition 0.000 claims description 3
• 101700044383 ssi Proteins 0.000 claims description 3
• 239000000725 suspension Substances 0.000 claims description 3
• QELUYTUMUWHWMC-UHFFFAOYSA-N Edaravone Chemical compound O=C1CC(C)=NN1C1=CC=CC=C1 QELUYTUMUWHWMC-UHFFFAOYSA-N 0.000 claims description 2
• 210000002268 Wool Anatomy 0.000 claims description 2
• 238000000227 grinding Methods 0.000 claims description 2
• 150000004780 naphthols Chemical class 0.000 claims description 2
• 239000003960 organic solvent Substances 0.000 claims description 2
• JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 claims description 2
• 229920003043 Cellulose fiber Polymers 0.000 claims 1
• 229920000742 Cotton Polymers 0.000 claims 1
• 241000268741 Pax Species 0.000 claims 1
• 238000004090 dissolution Methods 0.000 claims 1
• 125000001624 naphthyl group Chemical group 0.000 claims 1
• 150000002830 nitrogen compounds Chemical class 0.000 claims 1
• 150000004992 toluidines Chemical class 0.000 claims 1
• 239000000975 dye Substances 0.000 description 12
• 239000002904 solvent Substances 0.000 description 10
• 150000007513 acids Chemical class 0.000 description 9
• 239000000203 mixture Substances 0.000 description 8
• 150000003839 salts Chemical class 0.000 description 7
• 239000011780 sodium chloride Substances 0.000 description 7
• QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 6
• 238000009835 boiling Methods 0.000 description 6
• 229920002678 cellulose Polymers 0.000 description 6
• 235000010980 cellulose Nutrition 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• 239000001913 cellulose Substances 0.000 description 5
• 238000006193 diazotization reaction Methods 0.000 description 5
• UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
• ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 3
• VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• 235000014113 dietary fatty acids Nutrition 0.000 description 3
• 239000000194 fatty acid Substances 0.000 description 3
• 150000004665 fatty acids Chemical class 0.000 description 3
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
• 239000010931 gold Substances 0.000 description 3
• 229910052737 gold Inorganic materials 0.000 description 3
• 239000003921 oil Substances 0.000 description 3
• 235000019198 oils Nutrition 0.000 description 3
• TXVWTOBHDDIASC-UHFFFAOYSA-N 1,2-diphenylethene-1,2-diamine Chemical compound C=1C=CC=CC=1C(N)=C(N)C1=CC=CC=C1 TXVWTOBHDDIASC-UHFFFAOYSA-N 0.000 description 2
• RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-Naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
• LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
• CXWXQJXEFPUFDZ-UHFFFAOYSA-N Tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
• 125000003277 amino group Chemical group 0.000 description 2
• 125000003118 aryl group Chemical group 0.000 description 2
• UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
• 230000001264 neutralization Effects 0.000 description 2
• 239000004006 olive oil Substances 0.000 description 2
• 235000008390 olive oil Nutrition 0.000 description 2
• 239000002002 slurry Substances 0.000 description 2
• 239000000344 soap Substances 0.000 description 2
• 235000011121 sodium hydroxide Nutrition 0.000 description 2
• 239000008234 soft water Substances 0.000 description 2
• 239000000243 solution Substances 0.000 description 2
• QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-Tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 1
• ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-Chlorophenol Chemical class OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
• JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
• NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical class CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
• WVRFSLWCFASCIS-UHFFFAOYSA-N 3-(3-ethylcyclopentyl)propanoic acid Chemical class CCC1CCC(CCC(O)=O)C1 WVRFSLWCFASCIS-UHFFFAOYSA-N 0.000 description 1
• SRSXLGNVWSONIS-UHFFFAOYSA-N Benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
• CJCCRENXOGIKQN-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)(=O)O.S(=O)(=O)(O)C1=C(C=CC=C1)O Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)O.S(=O)(=O)(O)C1=C(C=CC=C1)O CJCCRENXOGIKQN-UHFFFAOYSA-N 0.000 description 1
• HPXRVTGHNJAIIH-UHFFFAOYSA-N Cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
• KZQYIMCESJLPQH-UHFFFAOYSA-N Demethylated antipyrine Chemical compound N1C(C)=CC(=O)N1C1=CC=CC=C1 KZQYIMCESJLPQH-UHFFFAOYSA-N 0.000 description 1
• OGBMKVWORPGQRR-UHFFFAOYSA-N Forteo Chemical compound C=1NC=NC=1CC(C(=O)NC(CC(C)C)C(=O)NC(CC(N)=O)C(=O)NC(CO)C(=O)NC(CCSC)C(=O)NC(CCC(O)=O)C(=O)NC(CCCNC(N)=N)C(=O)NC(C(C)C)C(=O)NC(CCC(O)=O)C(=O)NC(CC=1C2=CC=CC=C2NC=1)C(=O)NC(CC(C)C)C(=O)NC(CCCNC(N)=N)C(=O)NC(CCCCN)C(=O)NC(CCCCN)C(=O)NC(CC(C)C)C(=O)NC(CCC(N)=O)C(=O)NC(CC(O)=O)C(=O)NC(C(C)C)C(=O)NC(CC=1N=CNC=1)C(=O)NC(CC(N)=O)C(=O)NC(CC=1C=CC=CC=1)C(O)=O)NC(=O)C(CCCCN)NC(=O)CNC(=O)C(CC(C)C)NC(=O)C(CC(N)=O)NC(=O)C(NC(=O)C(CCSC)NC(=O)C(CC(C)C)NC(=O)C(CCC(N)=O)NC(=O)C(NC(=O)C(CCC(O)=O)NC(=O)C(CO)NC(=O)C(NC(=O)C(N)CO)C(C)C)C(C)CC)CC1=CNC=N1 OGBMKVWORPGQRR-UHFFFAOYSA-N 0.000 description 1
• 229940053641 Forteo Drugs 0.000 description 1
• WZCQRUWWHSTZEM-UHFFFAOYSA-N M-Phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
• 229940098465 Tincture Drugs 0.000 description 1
• 210000003462 Veins Anatomy 0.000 description 1
• ASCUXPQGEXGEMJ-GPLGTHOPSA-N [(2R,3S,4S,5R,6S)-3,4,5-triacetyloxy-6-[[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(4-methylanilino)oxan-2-yl]methoxy]oxan-2-yl]methyl acetate Chemical compound CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@H]1OC[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](NC=2C=CC(C)=CC=2)O1 ASCUXPQGEXGEMJ-GPLGTHOPSA-N 0.000 description 1
• 230000002378 acidificating Effects 0.000 description 1
• 150000001447 alkali salts Chemical class 0.000 description 1
• 125000000217 alkyl group Chemical group 0.000 description 1
• 125000002947 alkylene group Chemical group 0.000 description 1
• 150000003863 ammonium salts Chemical class 0.000 description 1
• 150000001454 anthracenes Chemical class 0.000 description 1
• 150000001491 aromatic compounds Chemical class 0.000 description 1
• 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
• 239000002585 base Substances 0.000 description 1
• 229950011260 betanaphthol Drugs 0.000 description 1
• 150000001717 carbocyclic compounds Chemical class 0.000 description 1
• 125000002837 carbocyclic group Chemical group 0.000 description 1
• 239000004359 castor oil Substances 0.000 description 1
• 235000019438 castor oil Nutrition 0.000 description 1
• 125000003636 chemical group Chemical group 0.000 description 1
• 238000006243 chemical reaction Methods 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• 239000003086 colorant Substances 0.000 description 1
• 150000001896 cresols Chemical class 0.000 description 1
• 125000004122 cyclic group Chemical group 0.000 description 1
• 125000000753 cycloalkyl group Chemical group 0.000 description 1
• VUSWCWPCANWBFG-UHFFFAOYSA-N cyclohex-3-ene-1-carboxylic acid Chemical compound OC(=O)C1CCC=CC1 VUSWCWPCANWBFG-UHFFFAOYSA-N 0.000 description 1
• XDTMQSROBMDMFD-UHFFFAOYSA-N cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
• 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
• RDJCIKZLXHKBPH-SEPHDYHBSA-L disodium;5-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]-2-[(E)-2-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NN=C3C=CC(=O)C=C3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NN=C1C=CC(=O)C=C1 RDJCIKZLXHKBPH-SEPHDYHBSA-L 0.000 description 1
• 239000012530 fluid Substances 0.000 description 1
• 150000004820 halides Chemical class 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 229940083761 high-ceiling diuretics Pyrazolone derivatives Drugs 0.000 description 1
• 230000002045 lasting Effects 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 150000005002 naphthylamines Chemical class 0.000 description 1
• 150000002989 phenols Chemical class 0.000 description 1
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
• 239000004576 sand Substances 0.000 description 1
• 239000008149 soap solution Substances 0.000 description 1
• KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
• 239000001632 sodium acetate Substances 0.000 description 1
• 235000017281 sodium acetate Nutrition 0.000 description 1
• 235000010288 sodium nitrite Nutrition 0.000 description 1
• 159000000000 sodium salts Chemical class 0.000 description 1
• 239000008117 stearic acid Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 150000003460 sulfonic acids Chemical class 0.000 description 1
• XSTXAVWGXDQKEL-UHFFFAOYSA-N triclene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1