AU720642B2 - A dehydrating process and a product dried thereby - Google Patents

Description

1 "A dehydrating process and a product dried thereby" Field of the Invention The present invention relates to a process for dehydrating a product, and in particular, though not limited thereto, to a process for dehydrating a biological product, preferably to a water content of 20% or less. The invention is also directed towards a dried product, and in particular, though not limited thereto, to a dried biological product in which the product.is dehydrated to a water content of 20% or less, when produced by the oe 10 process.

Background Art S" Many processes exist for drying products, such as various foods, fruits, vegetables, and other biological substances. For example 0 15 W089/08229 discloses a system and a method for drying granular material, in which the granular material is subjected to a drying agent, such as nitrogen.

It is also known to freeze-dry vegetables. Such a method is known S.to cause rupture of the cells and to increase the permeability of vegetables to water, see U.S. Patent Specification No. 4,788,072 at Column 2, Lines 15 to It is further known to dry fruit or vegetable slices by immersing said slices into a sugar-solution, see for example, European Patent Specification No. EP-A-0,339,175. When using a sugar solution with a high Dextrose equivalent (DE) value, for example, a DE value of 70, low molecular weight sugars are able to penetrate into thecells, whereby a higher sugarcontent exists.

Such dried products may not have a water activity lower than 0.4, andsome of the contents of the cell, such as flavour and odour constituents, may no longer be present in the interior of the cell.

When using a sugar solution with a low DE.value, for example, a DE value of 25, sugars are extracted from the product. This dried product also may not have a water activity lower than 0.4.

Furthermore, it is considered that due to the extraction of sugars, the taste and odour characteristics of the product may be altered.

The sugar osmotic drying is also considered as a pre-treatment, that is, a treatment for lowering-the water content of the product before a final drying treatment, such as frying. The water content of the osmotically dried product may thusnot be low enough to preclude spoilage of the product without additional measures, such as refrigeration, sterile packaging or the addition of preservatives. Due to the treatment of the product in a liquid *o sugar solution, sugar may completely fill the voids or spaces 15 situated between two adjacent cell membranes.

o:o• It is further known to dry grapes by spraying thembefore harvesting with a composition to facilitate removal of water from the grapes, see U.S. Patent Specification No. 5,068,988. The dried grapes retain a sufficiently high water content so as to 20 produce sufficient juice for making wine. The wines obtained by using such dried grapes have ahigh alcohol content.

It is also known to dry timber using a carefully regulated temperature and humidity regime during the drying process. The temperature and humidity regime is-species- and size-specific and i' 25 is selected to ensure that the drying operation does not cause warping of the product as a result of excessive moisture and temperature gradients within the material. The drying process results in a longer drying time than would result from drying without humidity regulation. Details of suchdrying processes are presented in a large number of standardworks, for example, in the 1991 ASHRAE Handbook, HVAC Applications.

It is generally accepted in the known art that "Based on the analysis of heat and masstransfer, the most efficient dehydration 3 systems will maintain the maximum vapour-pressure gradient and the maximum temperature gradient between the air and the interior parts of the product", see Introduction to Food Engineering, R.P.

Singh and D.R. Heldman, Academic Press (1993), at Page 422.

It is also generally accepted that in known drying processes the outer layer of the product becomes essentially impermeable to aroma compounds but still transmits some water vapour to allow drying to continue, see for example, "Food Dehydration", G.V.

Barbosa-Canovas and M.R. Oaks eds., A.I.Ch.E. Symposium Vol 89 (1993), Page 32.

U.S. Patent Specification No. 3,974,301 discloses a process for dehydrating banana to a moisture content below 20% by weight and having a water activity below about 0.6 in which the process requires slicing of the banana to form lengthwise peeled banana slices and blanching of the banana slices. French Patent Specification No. 2,661,224 discloses a dehydration apparatus in which air is conveyed into treatment tunnels in a dehydration process employing a first treatment cycle consisting of circulated S* air having a temperature below 40 0 C. The process is an 20 approximation of traditional open air drying of fruit. U.S.

Patent Specification No. 5,364,643 discloses a process for infusing dried fruits by coating the dried fruits with an edible humectant containing gel paste.

000 Finally, PCT Application Specification No. WO 94/13146 of one of the co-inventors of the present invention discloses a method and an apparatus for dehydrating biological products in which a closed system is used so as to ensure the retention of the essential flavour and fragrance of the natural product.

Definitions In this specification and in the claims, the following words and terms as used herein have the following meanings: Water content of an undried substance, in other words, a substance prior to being dried is:given as a percentage of the total weight of the undried substance.

Water content of a dried substance isgiven as a percentage of the total weight of dry matter only of the dried substance excluding all moisture.

A hygroscopic substance is one in which the water content tends to equilibrate with its surroundings.

Water activity of a hygroscopic substance is defined as the equilibrium relative humidity of a closed and thermally insulated system in which the substance has been placed. The measurement thereof should take place with a minimum head space and generally in conformity with recognised procedures for measurement of water activity. So in principle, the water activity is no different from equilibrium relative humidity except that it is expressed in terms ofa scale from 0-1, instead of on a scale of from 0-100%.

The water activity measures the degree of freedom of water, retained in various ways, in a hygroscopic substance.

"The water activity directly determines the physical, mechanical, chemical and microbiological properties of a hygroscopic substance, for example, interactions such as clumping, cohesion, electrostatic charge, and so on. In the food industry, the water activity is a highly: significant factor to be considered for the conservation of semifinished and finished products.

In particular, the water activity threshold for deteriorative mechanisms in a given hygroscopic food substance is defined as a level of water activity above which significant oxidation, enzymatic browning, microbiological organic activity and other deteriorative processes begin to take place to the detriment of the organoleptic and nutritional characteristics of that substance. For example, the proliferation of micro-organisms is generally considered to be suppressed at water activity levels below about 0.65. Other deteriorative processes become progressively less active as the water activity decreases toward a value between 0.2 and 0.25, that is, towards a level approximately corresponding to the monolayer water content.

Cellular structure of a substance means the structure of the cells of the substance, and also means the general arrangement of the cells, whereby intercellular spaces, channels or passageways are defined between the cells, andreference to damage to the cellular structure, in general, refers to damage caused to the cellular structure during a dehydrating process, it being understood that the cellsand cellular structure adjacent a face of the product may be damaged prior to the dehydrating process, as a result, for example, of cutting the substance or product into'slices orthe •0 15 like.

Cellular integrity of a substance refers to the degree to which the cellular structure of the substance is unaltered or-undamaged, and in particular, the degree to which the cell walls remain intact for retaining the organoleptic characteristics of the product. Reference to the maintenance of cellular integrity during a dehydrating process is defined as the maintenance -of the integrity of the cellular structure, which the substance had prior to being dried throughout the drying process so that at the end of the dehydrating process the dried product can-be rehydrated to 25 substantially its original form in substantially all respects.

Structural integrity of a substancerefers to the degree to which the structure of the substance is unaltered or undamaged, including its cellular structure. Reference to maintenance of structural integrity during a dryingprocess is defined as the maintenance of the integrity of the structure, which the-substance had prior to being dried throughout the dehydrating process so that.at the end of the dehydrating process, the dried product can be rehydrated to substantially its original formin substantially all respects. In other words, in a dehydrating process which maintains the structural integrity of the substance being dried, the dehydration process is essentially reversible. For substances having cells, the maintenance of structural integrity means also the maintenance of cellular integrity, in other words, keeping cell walls substantially intact and maintaining the intercellular spaces and passageways. The purpose of maintaining structural integrity during a drying process is to help retain the initial structural characteristics of the substance, and to facilitate the mass transfer of moisture from the substance. In food and health products, for example, the initial structural characteristics include organoleptic and nutritional properties, andother 0.00 qualities typical to each product in its initial form prior to being dried. It is assumed that only substances having a 15 relatively high degree of structural integrity are submitted to 00 the dehydrating process according to the invention, since otherwise, they could not be rehydrated to their original form.

Degradation temperature of a substance is defined as the o006 0o- temperature above which the-structural integrity of the substance and/or some of its chemical orbiochemical constituents may suffer irreversible thermal damage.

0 Organoleptic tests serve as a basis-for a sensory analysis of the internal and external quality of a material.. The external quality of a.material is judged accordingto its optical and physical 00 0 so 25 properties which are perceived by the visual.and tactile senses.

These properties have to do with the appearance:of the material, for example, colour,, size, shape, condition (uniformity, absence of defects and blemishes). -Of particular importance for- dried products are the hue (as it was before drying) and the lack of browning, -fading or other discolouration The internal quality of a material is judged according to its flavour and aroma, and texture. Flavour and aroma are caused by chemical properties and perceived mainly by the senses of taste.

and smell which are closely interlinked. Taste is due to the sensations felt on the tongue, while aromais perceived due to the stimulation of the olfactory senses with volatile organic compounds. For dried products, it is most desirable to retain the taste and aroma characteristic of that material inits initial state. The presence of foreign off-taste and off-aromas is most undesirable.

The chemical compounds that make up the aromatic properties of plant products need to be volatile by definition in order to be perceived at the temperature at which the product is going to be Sutilized. That is, they must be present in a gaseous or vapour state so that the molecules can reach the nasal passages of the personsperceiving the aromas. Generally, only a very small number of compounds impart the main characteristic aroma of a S 15 substance. Some volatile compounds may exist per se in the intact tissue, while others are formed enzymatically upon the rupture of the cells of the substance. One may measure precisely the concentration of compounds that impart the characteristic odour of a substance using gas chromatography equipment.

Texture is-most often expressed as an overall assessment of the feeling that food gives in the mouth. It is a combination of sensations derived from the lips, the tongue, the walls of the mouth, the teeth, and even the ears. It is desirable for dried products to maintain their textural integrity, not-to be too hard, S 25 too elastic or too brittle, during biting, chewing and swallowing.

Because the organoleptic properties of a substance are not generally equally subject to change, and are generally affected to a-different degree by different stimuli, it is appropriate to examine as many of the organoleptic properties as is practicable in order to evaluate substance degradation in the most thorough manner possible.

In food products, the amount of ascorbic acid present in the dried product is a good indicator of the degree of degradation which the product has undergone from its initial state.

This fol 1 ows from the fact that ascorbic acid is particularly volatile, that is vulnerable to depletion, especially at higher temperatures and over time (after harvesting, during storage). The losses of ascorbic acid are greater in fruits and vegetables having a higher pH.

Monolayer water content of a hygroscopic substance is defined as that amount of water which can be retained by the substance at maximum binding energy. This water content is estimated by fitting a theoretical expression such as the BET equation for moisture sorption to the measured moisture sorption isotherm for the substance. See for example, BET Monolayer values in Dehydrated Foods and Food Components, H.A. Iglesias and j. Chirife, Lebensm-Wiss. U.-Technol.

volume 9, (1976) at pages 107-113.

Summary of the Invention According to the invention there is provided a process for dehydrating a product by urging a gaseous drying medium into contact with the product in a chamber, wherein the temperature and relative humidity of the drying medium are controlled so that the rate of water removal from the product is such as to minimise damage to the cellular integrity of the product during the drying process, the relative humidity of the drying medium in the chamber is allowed to rise to a maximum value which lies within the range of 30% to 70%, and on the relative humidity of the drying medium in the chamber reaching the maximum value, the relative humidity of the drying medium in the chamber is maintained substantially constant at the maximum value, or is permitted to only gradually decrease by maintaining the relative humidity of the drying medium being delivered to the chamber substantially constant, until the relative humidity of the drying medium in the chamber commences to fall or commences to fall at an increasing rate.

MAW:NP:#27211.RS2 7 April 2000 The dried product produced by the process according to the invention has many advantages. It has a sufficiently low water activity to ensure long term resistance to degradation at typical storage temperatures of about 20'C to about A water activity in the range of 0.3 to 0.4 ensures long term resistance to degradation at such storage temperatures over a relatively long storage period. Depending on the product, at water activity levels up to 0.7, certain products are resistant to degradation and deterioration at typical storage temperatures of about 20°C to 30*c over relatively long storage periods.

In the case of fruits and vegetables, the product has improved organoleptic properties with respect to products dried by other know processes. This it is believed is due at least in part to the maintenance of the structural integrity, and in particular, the cellular integrity of the product. In general, it has been 1.RS2 7 April 2000 found that where the cellular integrity of at least 50% of the cells of the product is maintained, and in particular, 50% of the interior cells, the dried product can be rehydrated to have substantially all of the properties and characteristics which the product had prior to dehydration. Needless to say, when the cellular integrity of substantially all of the cells is maintained, the properties and characteristics of the rehydrated product even more closely approach those properties and characteristics of the product prior to being dehydrated. Where structural integrity has been maintained throughout the dehydration process, the properties and characteristics of the rehydrated product even still more closelyapproach those S properties and characteristics of the product prior to being dehydrated.

15 Preferably, the temperature and relative humidity of the- drying medium are controlled so that the cellular integrity of at least of the cells of the product not adjacent to a face of the product is maintained during the drying process, and ideally, the cellular integrity of substantially the entire product is maintained during the drying process.

In one aspect of the invention the rate of water removal from the product is such as to minimise damage to the structural integrity of the product during the drying process. Preferably, the see* structural integrity of at least 50% of the cells of the product 25- not adjacent to a face of the product is maintained during the drying process. Advantageously, the structural integrity of the product is substantially maintained during the drying process.

The dehydration process according to the invention establ.ishes a gentle drying regime which maintains the optimal conditions for the mass- transfer of moisture fromthe product being dried while substantially maintaining the structural integrity of substantially.the entire product during the drying process. By closely controlling the temperature and relative humidity of the V, (i 11 drying medium, the surface of the product being dried remains permeable to water, moisture and water vapour moving from the interior of the product into the drying medium.

Enhanced mass transfer of water from the product as a result of the gentle drying process of the invention results in a superior product as well as in an efficient drying process, due to the reduction in energy consumption.

The drying regime avoids subjecting the product and material being dried to thermal and pressure over-stresses,-hence maintaining the 10 structural and cellular integrity of -virtually the entire product during the drying process, while maintaining optimal conditions S° for heat and mass transfer.

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0* t."In one embodiment of the invention the relative humidity of the drying medium is controlled so that the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the product does not exceed 70% relative humidity. Preferably, the relative humidity of the drying medium is controlled so that the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the product does not exceed 60% relative humidity. Advantageously, the relative humidity of the drying medium is controlled so that the difference between the relative humidity of the drying medium *too and the equilibrium relative humidity of the product does not exceed 50% relative humidity.

Preferably, the maximum value of the relative humidity of the drying medium in the chamber lies in the range of 50% -to Advantageously, the maximum value of the relative humidity of the drying medium in the chamber lies in the range- of 50% to Preferably, the relative humidity of the drying medium in the chamber is permitted to fall off relatively rapidly after the fall in relative humidity of the drying medium has commenced or -the 12 rate of fall of the relative humidity of the drying medium has commenced to increase, until the water content of theproduct is approaching the desired water content and the rate of evaporation of water from the product becomes substantially independent of the drying medium.

In one aspect of the invention with the rate of evaporation of water from the product becoming substantially independent of the drying medium, the relative humidity of the drying medium is controlled to asymptotically approach a predetermined value of S 10 relative humidity which provides the product -dried to the desired water content.

In another aspect of the invention the predetermined value of relative humidity is lower than the equilibrium relative humidity of the product which corresponds to the desired water content, and the difference between the predetermined relative humidity of the drying medium and the equilibrium relative humidity of the product S. corresponding to the desired water content is in.the range of oto 40% relative humidity.

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••0 In general, the difference between the-predetermined value of S 20 relative humidity and the equilibrium relative humidity of the product corresponding to the desired water content is in -the range of 25% to 35% relative humidity, and in. many cases the difference @056 between the predetermined value of relative humidity and the equilibrium relative humidity of the product corresponding to the desired water content is approximately 30% relative humidity.

Depending on the product, the relative humidity of the drying medium may be maintained substantially at the predetermined value of relative humidity for a time period in the range -of 30 minutes to:120 minutes.

In another embodiment of the invention the drying medium is circulated through the chamber so that the speed of the drying 13 medium relative to the product lies in the range of 1 M per second to 3 M per second. Preferably the drying medium is circulated through the chamber so that the speed of the drying medium relative to the product lies in the range of 1.5 M per second to 2.5 M per second. Advantageously, the drying medium is circulated through the chamber so that the speed of the drying medium relative to the product is approximately 2 Mper second.

In general, it is preferably that during the period while the relative humidity of the drying medium in the chamber is- being S" 10 maintained substantially constant or is only gradually decreasing, the relative humidity of the drying medium in the chamber is not morethan 50% relative humidity lower than the equilibrium relative humidity of. the product, for minimising the damage to the cellular and structural integrity of the product. Preferably, S 15 during the period while the relative humidity of the drying-medium in the chamber is being maintained substantially constant or is only gradually decreasing, the relative humidity of the drying medium in the chamber is-not more than 40% relative humidity lower Q00 than the equilibrium relative humidity of the product, and is 20 preferably not more than 30% relative humidity lower than the equilibrium relative humidity of the product.

In another embodiment.of the invention during the period while the relative humidity of the drying ,medium in the chamber is falling relatively rapidly, the relative humidity-of the drying medium is S. 25 controlled so that the relative humidity of the drying medium in the chamber is not more than 70% relative humidity lower than the equilibrium relative humidity of the product,. for minimising the damage to the cellular and structural integrity of the product.

Preferably, during the period while the relative humidity of the drying medium in the chamber is -falling relatively rapidly, the relative humidity of the drying medium is controlled so that the relative humidity of the drying medium in the chamber-is not more than 60% relative humidity lower than the equilibrium relative humidity of the product, and advantageously, is not more than 14 relative humidity lower than the equilibrium relative humidity of the product.

Ideally, the drying medium is recirculated, and preferably, the relative humidity of the drying medium in the chamber is controlled by the introduction of fresh drying medium into the recirculating drying medium, and the rate at which the fresh drying medium is introduced does.not exceed 21% by weight of the mass flow rate of the drying medium.

-In one embodiment of theinvention the rate at which the fresh -o 10 drying medium is introduced does not exceed 15% by weight of the e g.

mass flow rate of the drying medium.

In another embodiment of the invention the rate at which the fresh drying medium is introduced does not exceed 10% by weight of the mass flow rate of the drying medium.

In a further embodiment of the invention the rate at which the fresh drying medium is introduced does not exceed 7% by weight of S the mass flow rate of the drying medium.

In a still furtherembodiment of the invention the rate at which the fresh drying medium is introduced does not exceed 4% by weight 20 of the mass flow rate of the drying medium.

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i In another embodiment of the invention fresh drying mediumis introduced at a substantially constant rate of. not more than 7% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity.

In another embodiment of the invention fresh drying medium is introduced at a substantially constant rate of not more than 5% by weight of the mass.flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity.

In a further embodiment of the invention fresh drying medium is introduced at a substantially constant rate of not more than 4% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity.

6SPIO S In a still further embodiment of the invention fresh drying medium is introduced at a substantially constant rate of not more than 3% byweight of the mass flow rate of the drying medium during the Coto period while the relative humidity of the drying medium in the 9e chamber is being maintained substantially constant at the maximum value of relative humidity.

In another embodiment of the invention fresh drying medium is introduced at a substantially constant rate of not more than 2% by o*0 I weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity.

SIn a further embodiment of the invention fresh -drying medium is introduced at a substantially constant rate of not more than 1% by weight of the mass flow rate of the drying medium during the .period while the relative humidity of the drying medium in the chamber- is being maintained substantially constant at the maximum value of relative humidity.

In another embodiment of the invention during theperiod while the relative humidity of the drying medium in the chamber is falling relatively rapidly, fresh drying medium is introduced at arate of not more than 21% by weight of the mass flow rate of the drying .b O

S

'e g

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0

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0 0 medium.

In general, the rate at which fresh drying medium is introduced is increased from the beginning of the period to the end of the period during which the relative humidity of the drying medium in the chamber is falling relatively rapidly.

In practice, no fresh drying medium is introduced into the recirculating drying medium until the relative humidity of the drying medium has reached its maximum value.

In another embodiment of the invention during the period while the relative humidity of the drying medium in the chamber is asymptotically approaching the predetermined value of relative humidity fresh drying medium is introduced at a rate of not more than 5% by weight of the mass flow rate of the drying medium.

In a further embodiment of the invention fresh drying medium is introduced through an inlet opening and exhaust drying medium is exhausted through an outlet opening, the size of the inlet and outlet openings being controlled as a function of the nominal exposed surface area of the product in accordance with a Modulation Index (MI) which is defined as: MI Kp x NSP (Sen Sex)/(Sen x Sex) where Sen is the cross-sectional area of the inlet opening for make-up fresh drying medium, Sex is the cross-sectional area of the outlet opening for exhaust drying medium, and NSP is the nominal exposed surface area of the product, and Kp is a constant whose value depends on the product being dried and the pressure/flow characteristics of the drying medium. During the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value, the value of the Modulation Index lies in the range of 1,000 to 10,000.

Preferably, during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value, the value of theModulation Index lies in the range of 2,000 to 8,000.

Preferably, the temperature of the drying medium is controlled not to rise to or above a degradation temperature which would cause irreversible thermal damage to the product.

In general, the temperature of the drying medium does not exceed 70 0

C.

0000 S 10 Typically, the drying medium is maintained at a temperature within the range 40 0 C to 70 0 C, but for preference the dryingmedium is maintained at a temperature within the range 55 0 C to 65 0

C.

0005 In one embodiment of the invention on reaching its maximum, the temperature of the drying medium is maintained substantially *s i15 constant thereafter.

The drying medium may be any suitable medium, however, a typical drying medium is air, or for example, the drying medium may.be nitrogen, and in some cases, the drying medium may be nitrogenenriched air.

By recirculating the drying medium, the process according to the Sinvention attains a relatively high.-degree of energy efficiency.

However, the.energy efficiency of the process according.to the invention also results from the enhanced-rate of water removal from theproduct which is made possible by virtue of the fact that the channels and passageways adjacent the faces of the product remain undamaged during the drying process, thus,- facilitating efficient water removal from the interior of the product.

Accordingly,: suitable control of the temperature and relative humidity of the drying medium results not only in superior product quality, but also in-reduced drying time and energy requirements.

By controlling the temperature and relative humidity of the drying medium in the chamber to provide a sufficiently high water vapour density in the chamber effectively regulates the rate at which water is liberated from the product by limiting the numerous gradients in temperature and humidity which occur in the removal of moisture from a hygroscopic substance. Proper regulation of these gradients serves to maintain structural integrityand in the case of biological material with cellular structure prevents the formation of an impermeable surface layer which has an adverse effect both on the dried product and also -on the removal of water from the interior of the product during the latter stages of the drying process.

Inaddition, the invention provides a process for preparing a dried product having the following characteristics, 15 a water content between 2% and 20%, andpreferably between 2% and 10%, and advantageously less than the level corresponding to the water activity threshold at which deterioration of the dried product commences, but not less than the lower limit for monolayer water content, "e 20 substantially all the cells not adjacent to an exposed face of the product still have a relatively high degree of structural integrity as demonstrated by a substantially undamaged cell membrane, and the product has a water activity lower than 0.7, preferably the *e 25 water activity is lower than 0.4, and.ideally is between 0.3 and 0.4, most preferably at a value which minimizes the effects of deteriorative mechanisms.

In general, cells of the product are-not ruptured by the drying process according to the invention. In particular, the cell membranes of the-product are not substantially damaged. As a result of this many organoleptic compounds and nutritional elements situated in or inside the cell membrane are retained. It seems even that many of the products of the.invention have membrane which is in such a state that organoleptic compounds are more perceptible than in the fresh state, that is can be more easily liberated in the mouth.

The dried product of the invention retains many of the organoleptic compounds of the product as they were prior to drying, including those comprising the bouquet and taste, and advantageously contains a substantial part of the flavour compounds in the lower boiling point fractions, typically lower than 40 0 C, contained in the product as they were prior to drying.

According to an embodiment of the product of the invention, said 10 product containing compounds which are able to be eluted at different temperatures, the weight ratio fraction of compounds eluted at a temperature between 150 0 C and 200 0 C to fraction of .compounds eluted at a temperature between 40 and 100 0 C is greater than 0.3, preferably greater than 0.5, for example between 0.6 and 2. The weight ratio fraction of compounds eluted at a temperature between 150 0 C and 200 0 C to fraction of compounds eluted up to 200 0 C is greater than 0.25, preferably greater than 0.3, for example 0.35-0.4.

Advantageously, a substantial proportion of the spaces or channels between cells adjacent to a face of the product is not filled with sugar and remains open. Preferably, a substantial proportion of the spaces or channels contains a gaseous medium, such as air, N 2 mixtures of N 2 02, oxygen-enriched air, water vapour, or some other. The gentle nature of the drying process of this invention minimizes cell wall degradation whereby both sugars and flavour constituents remain within the cells, rather than residing in spaces between the cells.

The dried product of the invention may be a fruit or vegetable food product such as pineapple, banana, papaya, mango, other tropical fruits, watermelon, carrots, cabbage, celery, peppers, spinach, beans, plums, apples, pears, mushrooms, grapes, oranges, __lemons, limes, and other fruits and vegetables, but can also be herbs, spices, tobacco, blood, sperm, bacteria, meat, seafood, tea leaves, seaweed, algae, coffee beans, cocoa beans, nuts, eggs and other food and other biological products.

The invention relates also to a process for dehydrating-other products and substahces, for example, products not containing cells, such as chemical compounds, pharmaceutical compounds or preparations, as well as non-biological products and substances.

In an alternative process according to the invention a gaseous drying medium is heated and urged into contact the product being i" 10 dried, the temperature of the drying medium contacting the product to be dehydrated being lower than the temperature of degradation of the product, the temperature of the product to be dehydrated being increased in a controlled manner during the drying process, "°"the process comprising at least one step in which the temperature of the drying medium is increased from a first temperature up to a temperature which may be adjacent the maximum dehydration temperature, but lower than thedegradation temperature. In one oaspect of the invention the said increase of temperature to the o drying medium is such that during said step a difference of temperature exists between the product and the drying medium, said difference being between 0.1°C and 5°C, preferably lower than 0 C, and more preferably lower than 1.5 0

C.

In another aspect of the invention, the temperature of.the drying 0 medium may be increased at a rate lower than Before this-step, the product may be submitted to another.

treatment, such-as a treatment which-does not damage cells of a product prepared according to the invention. For example, the drying medium may first be maintained at a temperature of about 0 C up to the moment a temperature of about 40°C is reached within the product, while thereafter the drying medium may be heated at such a rate that the difference of temperature existing _between-the product and the drying medium is less than about 5 0

C,

21 preferably less than 2.5°C. In general, a steady and continuous increase in temperature of the drying medium minimizes damage to the cell membranes so that a high percentage thereof remain intact while the moisture within the cells migrates therethrough and is removed by the drying medium. The gentle drying regime in which a controlled temperature difference between the drying medium and the product is maintained as mentioned above, results in a process in which colour and flavour constituents are not removed, but water is removed from the cells.

According to an alternative embodiment of the process according to the invention, when the water content of the product to be SO0 dehydrated is lowered to 10%, the drying medium is heated at such a rate that the difference of temperature existing between the product and the drying medium is less than about 2.5°C. In this t case, the product is pre-dried at a temperature of 40'C to until the product reaches a water content lower than preferably lower than In one alternative embodiment of the invention the rate of increase in the temperature of the drying- medium is such that the temperature of the drying medium reaches- the maximum dehydration temperature approximately at thesametime as the desired water content of the product has been attained.

In another alternative embodiment of the invention the rate of 0S 00 S *increase of the temperature of the drying medium is substantially constant.

Ideally, the maximum dehydration temperature is less than the temperature of degradation of the product.

In general, the maximum dehydration temperature does not exceed 0 C. Typically, the maximum dehydration temperature lies in the range 40 0 C to 50 0

C.

In one aspect of the invention the product is dried to a water content lower than In another aspect of the invention the product is dried to a water content of about Preferably, the drying medium is recycled. Preferably, during the end of the dehydration process less than 4% by volume of fresh drying medium is added to the drying medium. Advantageously, towards the end of the dehydration process not more than 1% of the humidity of the recirculated drying medium is condensed from the 10 drying medium as it is being recirculated.

In another embodiment of the invention the product is dried to a water content below about 10%, and the relative humidity of the *drying medium during the period while the water content of the product is being reduced below about 20% lies in the range between 10% and In a further embodiment of the invention the product is dried to a so.. water content of less than 7%.

Further, the invention provides a dried product dried according to the process according to the invention.

20 Brief Description of the Drawings The invention will be more clearly understood from the following descriptions of some- non-limiting examples and embodiments thereof which are given by way of example only with reference to the accompanying drawings in which: Fig. 1 is a schematic view of an apparatus suitable for carrying out a dehydrating process according to the invention, Figs. 2 to 5 are enlarged views of parts near the skin and.

parts in the interior of apple slices before drying and after drying, respectively using the process according to the invention and known processes, Fig. 6 shows plots of the relative humidity and the temperature of the drying medium,- and the equilibrium relative humidity of product against time during an example of the dehydrating process according to the invention, Fig. 7 shows plots of the relative humidity and the temperature of the drying medium against time during another example of the 0@@0 dehydrating process also according to the invention, and Figs. 8 to 60 show gas chromatograph traces of products before being dried and after being dried using the dehydratingprocess according to the invention, and also show gas chromatograph traces of all but one of the products after having been rehydrated subsequent to being dried using the dehydrating process according to the invention and other dehydrating processes.

Detailed Description of the Invention Before describing examples of the dehydration process according to S" the invention, a drying apparatus which is suitable for carrying out the-dehydration process will first be described with reference to Fig. 1. -It will of course be appreciated that the dehydration process is not limited to being carried out in the apparatus of 1, and many other different types of apparatus may be used.

The drying apparatus of Fig. 1 comprises an enclosed insulated drying chamber 1 having an access opening 2 which is closed by a door 3 for accommodatingtrays 4 on which products to be dehydrated are placed into the chamber 1. An inlet opening 5 is provided to the chamber 1 for introducing gaseous drying medium to the chamber 1, and an outlet opening 6 provides for removal of the drying medium from the chamber 1. A duct 7 extends from the outlet 6 to the inlet 5 for recirculating drying medium-back to the chamber 1. A fan 8 inthe duct 7 circulates drying medium through the duct 7 in the direction of the arrow A in said duct, and in turn through the drying chamber 1 also in the direction of the arrow A in said chamber. A heater 9 located in the duct 7 between the fan 8 and the inlet 5 heats the drying medium as it is being returned to the drying chamber 1. A condenser 10 which may be operated for condensing some of the waterout of the drying medium is located in the duct 7 between the fan 8 and the heater 9.

An inlet valve 11 for introducing fresh drying medium into the 000g 10 duct 7 is located upstream of the fan 8. The inlet valve 11 may communicate directly with ambient air for introducing fresh air eOg.

into the duct 7, or alternatively may introduce fresh drying medium from a drying medium source 12, for example, nitrogen contained in a gas bottle or other suitable container. An outlet valve 14 for exhausting part of the recirculated drying medium from the duct 7 is located between the condenser 10 and the heater 9.

control means, namely, a central programmable logic controller 15 which is computer controlled controls the apparatus in response 20 to signals received from sensors which are described below and which are located at appropriate locations in the.apparatus. A control link 16 activates and deactivates the fan 8 under the control of the central controller 15. The inlet valve 11 and the outlet valve 14 are controlled by the central controller 25 through control links. 17 and 18, respectively. Control links 19 and 20 control the heater 9 and the condenser 10, respectively.

A temperature sensor 22 located at the inlet 5 to the drying chamber 1 monitors the temperature of.the drying medium being introduced to the drying chamber Signals from the temperature -sensor 22 are relayed to the control1er 15 through a link 23. .A humidity sensor 25 is located in the.-drying chamber i, and in this case is provided by a psychrometric device for monitoring the relative humidity of the drying medium in the drying chamber 1.

The humidity sensor 25 is located in the drying chamber 1 remotely of the inlet 5 but adjacent the outlet 6. A link 26 relays signals from the humidity sensor 25 to the controller 15. A humidity sensor 27 is located in the duct 7 downstream of but adjacent the condenser 10 for monitoring the relative humidity of the drying medium as it exits the condenser 10. The humidity sensor 27 is also provided by a psychrometric device. A link 28 relays signals from-the humidity sensor 27.to the controller A product waterloss sensor 30 which is provided by a load cell device is located in the drying chamber 1 for monitoring the total S. i weight of the product being dried for determining the current water content of the product as the dehydration process proceeds.

In the examples described below the water loss sensor 30 was not :used. Rather, as will be discussed below, the equilibrium 15 relative humidity of the product was monitored, since water content is a function of equilibrium relative humidity. The product water loss sensor 30 is located in the drying chamber 1-so that the trays 4 with the product thereon are supported on the product water loss sensor 30. A link 31 relays signals from the 20 product water loss sensor 30 to the controller 15. During the dehydration process the weight of the product on the trays 4 changes, whereby the loss of water from the product can be estimated. As the dry matter content of the product can be see estimated by heating a sample of the product at a temperature of 25 about 100 0 C in a laboratory test fora time specified in a recognised test procedure, the water content of the.product can be determined from the weight of the product-which is monitored by the water loss sensor 30 as the drying process proceeds.

Accordingly, in response to signals received from the temperature sensor 22, the humidity sensors 25 and 27 and the product water loss sensor.30 the controller 15 controls the operation of the fan 8, the heater9 and the inlet and-outlet valves 11 and 14, respectively. Should it be desired to operate the condenser the condenser 10 is also controlled by the controller 15 in response to the signals received from these sensors.

In controlling the inlet and outlet valves, 11 and 14, respectively, the cross-sectional area of the opening presented to the fresh drying medium and the exhausted drying medium is controlled. The cross-sectional area is the area of the opening presented to the medium at right angles to the flow of medium.

The cross-sectional area of the opening defined by the inlet valve 11 is hereinafter represented by Sen, and the cross-sectional area of the opening defined by the outlet valve 14 is hereinafter 10 represented by Sex. In certain cases, the inlet and outlet valves 11 and 14, respectively, may remain closed during all or part of the process. The combination of the pressure drop across the fan 8, together with minute holes and cracks which, in general, would naturally occur in the duct 7 and the drying chamber 1, may 15 provide sufficient exchange of drying medium, namely, drying air with fresh air for efficient operation of the dehydration process in the drying apparatus of Fig. 1, without the need to open the inlet and outlet valves 11 and 14, respectively. The significant g2* ability of air to carry water vapour at elevated temperatures also 20 accounts for the ability to operate the apparatus to carry out a dehydration process according to the invention with little or no fresh air added, and little egress of moisture laden drying air from the apparatus.

Examples of.the dehydration process according to the invention for 25 drying fruit and vegetable products will now be described using the apparatus of Fig. 1. However, it will be readily apparent to those skilled in the art that the dehydration processes may be carried out on any other suitable apparatus. In the examples of the dehydration process, unless otherwise stated, the drying medium is air. The dehydration processes may be carried out at pressures lower or higher-than atmospheric pressure. However, it is preferable that the dehydration processes are carried out at substantially atmospheric pressure, or at a pressure just above atmospheric pressure, for example, up to 1.2 x 105 Pa. In the examples of the dehydration processes described herein, the pressure of the drying medium in the drying chamber 1 is maintained slightly above atmospheric pressure.

In a preferred dehydration process according to the invention the process proceeds sequentially through four phases, namely, Phase 1 a rising temperature phase, Phase 2 a high humidity phase, Phase 3 a declining humidity phase, and o :.Phase 4 an asymptotic phase.

S10 There is no sharp cut off point between the respective phases, OO..

rather, the phases merge gradually from one phase into the next.

For ease of understanding this dehydration process according to the invention, the four phases will now be described under separate headings, and with reference to Fig. 6. Fig. 6 illustrates the parameters, namely, temperature and relative *Oee humidity, of the drying medium which were monitored during a dehydration process according to the invention in which IDARED apples were dehydrated. Fig. 6 also illustrates the equilibrium i •.orelative humidity of the apples during the dehydration process.

Graph A is a plot of the temperature of the drying medium against time. Graph B is a plot of the relative humidity of the drying medium against time. Graph D is a plot of the equilibrium relative humidity of the apples against time. Graph A was plotted from the signals received from the temperature sensor 22 in the drying chamber 1. The relative humidity of the drying medium illustrated in Graph B was obtained from the humidity sensor 25 in thedrying chamber. The equilibrium relative humidity of the apples illustrated in Graph D was determined at half-hourly intervals during the drying process, At each half-hourly interval a sample of the apples was removed and its equilibrium relative humidity was determined. The IDARED apples were sliced into slices of approximately 3 mm thickness and loaded into the drying chamber 1 on the two trays 4 as illustrated in Fig. 1.

28 Phase 1 Rising temperature phase In Phase 1 the drying medium is circulated by the fan 8, and exchange of drying medium with the surrounding atmosphere is minimised. In other words, the inlet and outlet valves 11 and 14 are closed, and the only exchange of drying medium with the Surrounding -atmosphere takes place through cracks, and imperfections in the sealing of the duct 7 and the drying chamber 1. Heat is applied to the drying medium for raising the temperature of the drying medium to a first set point, which 10 although below, is relatively close to the maximum dehydration temperature at which the dehydration process is carried out. The maximum dehydration temperature should never exceed, and preferably should be less than the degradation temperature of the 0o. product being dried. Phase 1 essentially commences when the 15 product to be dried has been placed in the drying chamber 1 and the door 3 has been closed. The temperature difference between the drying medium and the product should not result in damage to the structural integrity of the product as a result of excessive thermal stress-.. Typically, the product is introduced into the 20 drying chamber 1 when the temperature of the drying medium is sees approximately 40 0 C. Phase 1 continues until the temperature -of the drying medium reaches the first set point, and the relative humidity of the drying medium reaches a first set point which will be the maximum value of relative humidity to which the drying medium -is allowed to rise. The first set pointsof the temperature and the relative humidity of the drying medium depend on the product being dried. The first set point temperature may range from 50'C to 70 0 C, andthefirst set point of the relative humidityof the drying medium may range from 30% to In the example illustrated in Fig. 6, thefirst temperature set point which isindicated by the letter E -is approximately 60 0 C and the first relative humidity set point which is indicated by the letter F is approximately 55%. Thus, on the temperature of the drying medium and the relative humidity of the drying medium reaching 60 0 C and 55% respectively the first phase ends, and the process moves into the second phase which will be described below.

During the first phase when the temperature of the drying medium reaches the first set point, the heater 9 is controlled for maintaining the temperature of the drying medium substantially at the first set point. Additionally, during the first phase the relative humidity of the drying medium may fluctuate. However, it is not permitted to exceed the first set point, and if necessary this may-be achieved by providing sufficient exchange of drying medium with the atmosphere through the inlet and outlet valves 11 10 and 14, respectively. On the temperature and relative humidity of the drying medium in the drying chamber 1 reaching the respective first set points, the heater 9 and the inlet and outlet valves 11 0••s and 14 are adjusted for maintaining the temperature and the relative humidity of the dryingmedium substantially at the first .set points as theprocess moves into the second phase. The value of the equilibrium relative-humidity of the product at the end of the first phase is indicated by the letter C on the Graph D of Fig. 6, which is approximately 93%.

As discussed above the pressure-of the drying medium in the drying 0 20 chamber 1 is maintained at a pressure slightly above atmospheric pressure, and should there beanytendency towards a build-up of over-pressure of drying medium.in the drying chamber 1 correction Sis made through the use of a pressure release valve (not shown).

The first phase of the drying process of the example illustrated in Fig. 6 took approximately30 minutes.

Phase 2 High humidity phase During the second phase, in general, the flow rate of the drying medium is maintained constant and similar to the flow rate during the first phase so that the speed of the drying medium over the exposed surface of the product is maintained at a similarspeed to that during the first phase. The temperature and relative humidity-of the drying medium are maintained substantially constant at the respective first set points. This is achieved by maintaining the heater 9 and the inlet and outlet valves 11 and 14, respectively, at their respective settings to which they were set at the end of the first phase. The second phase is completed when there is insufficient moisture available in the product to maintain the relative humidity of the drying medium substantially constant without altering the flow rate of the drying medium or the rate of exchange of drying medium with the atmosphere. The end of the second phase is determined as being the point in the 10 process at which the relative humidity of the drying medium oo0o commences to decrease rapidly, or if the relative humidity of the e: drying medium has commenced to decrease, the end of the second phase is the point at which the rateat which the relative humidity of the drying medium is decreasing commences to 15 significantly increase. In Graph B of Fig. 6 the end of the second phase is indicated by the point G. At this stage, the second phase is complete.

In general, theproduct being dried will contain a quantity of :free water, and the end of the second phase, in general, is determined when this free water has been exhausted. In general, it is at this stage that the evaporation rate of water from the product falls below the rate of vapour removal which had been substantially maintained during the second phase. The value of 0-the equilibrium relative humidity of the product at the end of the second phase is indicated by the point K on the Graph D of Fig. 6.

During the second phase, the relative humidity of the drying medium may not remain entirely constant. However, as can be seen in Fig. 6 the relative humidity during the second phase remains substantially constant for the initial part of the second phase and gradually begins to-decrease during the latter part of the second phase. However, in such cases, as discussed above, theend of the second phase is determined when the rate of decrease of relative humidity of the drying medium commences to increase significantly.

If desired, a number of points of both temperature and relative humidity may be set during the second phase, and when there is insufficient moisture available in the product to maintain the relative humidity of thedrying medium at the last of the set points, that is determined as being the point of completion of the second phase.

As discussed above the relative humidity of the drying medium is maintained substantially constant at about the maximum value of es, .relative humidity during the second phase, namely, the high humidity phase. This is achieved by setting the inlet and outlet valves 11 and 14 for controlling the exchange of drying medium withthe atmosphere at the end of the first phase. It has been see* found that a relationship exists between the area through which drying medium is exchanged with the atmosphere and the nominal exposed surface area of the product which is exposed to the drying medium in the drying chamber for maintaining the relative humidity substantially constant during the second phase. This relationship may be expressed in terms of a Modulation Index MI. The Modulation Index is equal to a constant multiplied by the nominal surface area of the product divided by the area S.

In the present case, assuming no leakages in theduct 7 and the drying chamber 1 the area S through which drying medium is exchanged with the atmosphere is equal to (Se, x Sex) Sx).

The Modulation Index can thus be expressed by the following formula: MI Kp x NSP/S =Kx NSP x S x xNSP .(S.en S ex) /Sen X Sex where Kp is a constant whose value depends on the particular type of product being dried and the pressure/flow characteristics of the drying medium, and of the fan8, NSP is the nominal surface area of product exposed to the drying medium.

The value of the Modulation Index during the second phase of the dehydration process is preferably maintained within the range 1,000 MI< 10,000 and more preferably is maintained within therange 2,000 MI 8,000.

The purpose of establishing control over the evaporation rate is to achieve the most rapid possible removal of water consistent with maintaining structural integrity, and achieving optimum retention of the. initial structural properties of the product being dried.

"The relative humidity of the drying medium being returned to the drying chamber 1 may be controlled, by controlling the exchange of .se. drying medium with fresh drying medium. But the relative humidity of the drying medium may also, or alternatively, be controlled by means of the condenser In the example of Fig. 6 the second phase took approximately seventy-five minutes.

Phase 3 Declining humidity phase The third phase of the dehydration process commences at the end of the second phase, in other words,-when the rate at which the relative humidity of the drying medium within the drying chamber commences to decrease significantly, while both the temperature of the drying medium in the drying chamber and the rate of drying medium exchange are held substantially constant. In the third phase the relative humidity of the drying medium in the drying chamber is allowed to continue to decrease. However, the rate at which the relative humidity is allowed to decrease is controlled so that the rate of evaporation of water from the product does not exceed a value which would result in damage to the structural integrity of the product. The rate at which the relative humidity of the drying medium is allowed to decrease during the third- phase is controlled by regulating the exchange of drying medium with atmosphere by the inlet and outlet valves 11 and 14, respectively.

Concurrently, in some cases the temperature of the drying medium may be varied during the third phase, provided it does not exceed the degradation temperature of the product being dried.

During the third phase the evaporation rate of moisture from the product is preferably modulated in order to maintain the gradients in temperature and relative humidity between the drying medium and the product within limits that will maximise the rate of-moisture .evaporation from the product, while at the same time avoiding damage to the structural integrity of the product. These limits vary from species to species, and also vary depending on the method of preparation of the product for drying, and the final 0*ee desired characteristics of the dried product. However, the limits are identifiable for each species. In general, the rate of introduction of fresh drying medium to the recirculating drying medium is increased as the third phase progresses.

.It is important that the temperature of the drying medium should be closely monitored during the third phase, since the evaporative soon cooling effect decreases as the dehydration process continues. In 20 order to prevent undesired temperature rises during the third phase, the heat provided to the drying medium, in general, is reduced, and the circulating rate of the drying medium may be S reduced.

0 o o 0 The third phase continues until the rate of water evaporation from the product decreases- virtually irrespective of the rate of drying medium exchange with fresh drying medium. In the example of Fig.

6 the end of the third phase is identified by the point H on the Graph B of relative humidity. The point I on the Graph D indicates the equilibrium relative humidity of the product at the end of the third phase.

The third phase of the example of Fig. 6 took approximately one and a half hours.

Phase 4 Asymptotic phase The fourth phase begins at the end of the third phase. During the fourth phase the relative humidity of the drying medium is allowed to asymptotically approach a predetermined value which is below the equilibrium relative humidity of the product which corresponds to the desired final water content of the product.

Typically, the difference between the value of predetermined relative humidity of the drying medium and the final equilibrium relative humidity of the product at the process temperature is in the order of.30% relative humidity,- although this value will vary *:from product to product, andwill also vary depending on the final water content to which the product is to be dried. The equilibrium relative humidity of the product during the fourth phase is increasingly dictated by the temperature of the drying 15 medium within the drying chamber, and the monolayer water content of the product, and is increasingly independent of the rate of exchange of drying medium with. atmosphere, The end of the fourth phase occurs when the equilibrium relative humidity of the product :,reaches the value which corresponds to the desired final value of S 20 water content of the product, provided the value of water content see* of the product isuniform throughout the product.

The fourth phase of theexample of Fig. 6- took approximately one and three quarter hours.

There is a minimum water content which may.be attained for products during the fourth phase; the level of which depends on factors which include the monolayer water content of the product being dried, the relative humidity of the drying medium entering the drying chamber 1, and thetemperature of the drying medium withn the drying chamber 1.

Even though the process of the invention may yield a lower rate of moisture removal from the-product in the initial portion of the dehydration cycle, the total drying time to reach a stated final moisture content is in most cases significantly shorter than for conventional forced flow warm air drying process. It has been found that the drying process of the invention may be completed in a time period which may be as short as one tenth of the time it takes to dry product by freeze-drying processes.

Dehydration processes according to the invention whereby the process comprises the above four phases have been carried out using the apparatus of Fig. 1. In all cases two trays 4 carrying respective loads of the product were introduced into the drying .so. chamber 1through the access opening 2 and the door 3 was securely closed. The fan 8 was activated to circulate the drying medium through the drying chamber 1 at a mass flow rate sufficient to urge the drying medium over the exposed surface of the product at speed of approximately 2 M per second. This speed was maintained during all four phases of the drying process. The inlet valve 11 .and the outlet valve 14 were closed to confine the drying medium within the duct. 7- and the drying chamber 1. The heater 7 was activated to raise the temperature of the drying S medium to the first set point temperature. The relative humidity of the drying medium in thedrying chamber 1 was allowed to rise to the first relative humidity set point. At this stage the first Om 0 phase was completed, and the second phase commenced. Immediately upon-commencement of the second phase the inlet valve 11 and outlet valve 14 were operated so as to maintain the relative humidity of the drying medium in the drying chamber 1 substantially constant at the first set point, and the heater was controlled to maintain the temperature of the drying medium in the drying chamber substantially constant for the durationof the second phase. The settings of the valves 11 and 14 were determined initially using the Modulation Index formula. Once the inlet and outlet valves 11 and 14, respectively were set at the beginning of the second phase, no further adjustment was necessary, and the relative humidity of the drying medium in the drying chamber tended to remain substantially constant.

The process moved from the second to the third phase when the relative humidity of the drying medium in the drying chamber 1 commenced to decrease, or commenced to decrease more rapidly than it had been decreasing during the latter part of the second phase.

During the third phase the inlet and outlet valves 11 and 14 were controlled for maintaining the relative humidity gradient between the drying medium in the drying chamber 1 and the product such that the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the product did not exceed a value which would result in damage to the structural S 10 integrity of the product as already described. This was achieved •by continuously varying the settings of the inlet and outlet valves 11 and 14 for increasing the rate at which fresh drying medium is added to the recirculating drying medium.

During the fourth phase as the relative humidity of the drying medium in the drying chamber commenced to asymptotically approach the predetermined value of relative humidity for the drying medium, the inlet and outlet valves 11 and 14, and the heater 9 were controlled and set for maintaining the rate at which fresh drying medium was added to the recirculating drying medium and at which heat was added to the drying medium, for maintaining the relative humidity of the drying medium substantially at the predetermined value. The relative humidity of the drying medium was maintained at the predetermined value for a sufficient period until the equilibrium relative humidity of the product being dried was at a value which corresponded with the desired final water content of the product.

Returning now to Fig. 6, this figure illustrates the parameters of the drying medium during the four phase drying process in which apple slices were dried to a final water content of approximately 5.5% by weight. The water activity of the dried apples was 0.272.

The apples which were dried in the process illustrated in Fig. 6 were of the IDARED variety, and had been removed from cold storage in which they had been for approximately six months. The apples were sliced into slices of approximately 3 mm thickness and were loaded into the drying chamber on the two trays 4. The total nominal surface area of the product exposed to the drying medium was 19 M 2 The loads of product on the two trays were arranged so that the length of the loads in the direction of air flow through the drying chamber 1, namely, in the direction of the arrow A was as short as possible for minimising the relative humidity gradient of the drying medium across the product. The drying medium was 10 circulated through the drying chamber 1 at -a mass flow rate sufficient to cause the drying medium to pass over the exposed surface area of the product at a speed of approximately 2 M per S .second.

,A more-detailed discussion of the dried apple slices is given below with reference to Table 1. Briefly, the temperature of the drying medium during the first phase of the drying process was allowed to rise to a first set point of approximately 60°C. The S* relative humidity of the drying medium was allowed to rise to a first set point of approximately 55%. At the end of the first phase the equilibrium relative humidity of the product was approximately 93%. During the second phase of the process, the temperature was maintained substantially-constant at the first set point, and for the greater part of the second phase the relative Shumidity of the drying medium was maintained substantially 25 constant at approximately 55%. .At the end of the second phase the relative humidity ofthe drying medium had fallen to approximately and the equilibrium relative humidity of the apples was approximately 84%. During the second phase, the drying medium was exchanged with the atmosphere and the rate at which fresh air was added to the drying medium was approximately 2% of the mass flow rate of the drying-medium. During the second phase, the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the product did not exceed relative humidity.

During the third phase of the drying process, the relative humidity of the drying medium was allowed to drop at a rate such that the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the apples did not exceed 47% relative humidity. In order to achieve this the rate of exchange of drying medium with the atmosphere was gradually increased during the third phase so that at the end of the third phase fresh air was being added to the drying medium at the rate of approximately 3.5% of the mass flow rate of drying medium.

During the third phase, the temperature of the drying medium remained substantially constant at approximately the value of the first set point, namely, approximately 60 0 C, and rose gradually towards the end of the third phase to a temperature of approximately 61 0 C. At the end of the third phase the relative S 15 humidity of the drying medium was approximately 13%, and the equilibrium relative humidity of the apple slices was approximately ,During the fourth phase the relative humidity of the drying medium was allowed to drop, .and to asymptotically approach a 0*00 predetermined value of 7% approximately. The relative humidity of the drying medium was retained substantially at the predetermined value of 7% for a period of approximately 40 minutes. This finally yielded dried apple slices with an equilibrium relative humidity value of approximately 38%-which corresponds.with the 25 desired final water content of approximately and a water activity of approximately 0.272. During the fourth.phase, the temperatureremained substantially constant at approximately 61'C.

The fall in temperature in the Graph A at the end of the fourth phase is as a result of the door 3 of the drying chamber 1 being opened- for the removal of the dried apples. At the end of the fourth phase, the difference the relative humidity of the drying medium and the equilibrium relative humidity of the product was approximately 30% relative humidity.

Fig. 7 illustrates two graphs, namely, the Graph A of temperature, and the Graph B of relative humidity of the drying medium of another example of the four phase dehydrating process according to the invention, in which apple slices (Cultivar Jonagold) of 3 mm thickness were dried. Although the apple slices dried in this embodiment of the invention are of a different variety to the IDARED apples which were dried in the example of the process according to the invention described with reference to Fig. 6, the general cell structure and other structural characteristics of the two types of apples are substantially similar. As can be seen S 10 from Fig. 7 the time period for the drying process according to this example of the invention was approximately 24 hours. This was significantly less than the approximately 5 hours taken by the process described with reference to Fig. 6. The reason for the I shorter drying time in the process of Fig. 7 is largely accounted 15 for by the fact that the rate of.exchange of drying medium with fresh drying medium was approximately doubled throughout the process. Another contributory factor to the reduced drying time was the fact that the temperature of the drying medium was allowed to rise gradually from 60 0 C to approximately 64 0 C during the 20 latter half of the third phase, and the fourth phase of the process. Because of the increase in drying medium exchange with fresh drying medium the relative humidity of the drying medium only reached a maximum value of approximately49%. Although the maximum value of relative humidity, at 49% is less than the *s 25 maximum value of approximately 55% of the process of Fig. 6 the lower value of maximum relative humidity was still sufficient to avoid damage to the cellular and structural integrity of the product, and also had the effect of accelerating the rate ofwater removal from the-product in both the second and third phases.

However, experiments which have been carried out indicate that any significant reduction of the maximum value of relative humidity much below 49% does not reduce the drying time of the process further. In fact, the drying time at lower maximum values of relative humidity may be either similar to that of Fig. 7, or may increase. Most significantly at values of maximum relative humidity much below 49%, damage to the cellular and structural integrity of the product will become increasingly apparent. This, it is believed, is caused by excessive differences between the relative humidity of the drying medium and the equilibrium relative humidity of the product. Thus, in general, it has been found advisable to carry out the processes according to the invention with a maximum value of relative humidity of the drying medium in the range of 50% to 60%, and preferably in the range of to In the example of the process described with reference to Fig. 7, 10 the equilibrium relative humidity of the apple slices was.not monitored. However, it-is believed that the curve of the equilibrium relative humidity of the product would substantially 00 .follow the curve of the product equilibrium relative humidity of Fig. 6, but modified appropriatelyto take account of the shorter drying time.

Graphs of the drying medium temperature and relative humidity and equilibrium relative humidity of the productduring drying processes on fruits and vegetables other than apples using the four phase dryingprocess according to the invention, although not 20 shown are substantially similar to those illustrated in Figs. 6 and 7. In general, the only differences are in the drying times, and the maximum values of temperature and relative humidity, which so are-dependent on the product being dried and on the treatment to which the products are subjected prior to drying, as well as the final desired water content of the product. However, in general, the maximum value of relative humidity of the.drying medium would lie within therange of 50% to 55%, and the initial.maximum value of the temperature of the drying medium,.would, in general, be in the range of 60 0 C to 70 0 C, and in the latter part of the drying cycle, typically, towards the end of the third phase, and during the fourth phase, the temperature may be allowed to rise to a maximum of approximately 65 0

C.

In order tomake a comparison between the product of the .invention 41 and other dried products, which were dried by other known techniques, the apple slices which were dried using the four phase process described with reference to Fig. 6 were compared with similar apple slices which had been dried by freeze-drying and conventional forced air drying.

Table 1 sets out the results of the analysis which have been carried out on the products dried by the three dehydration processes as follows: the water content of the apple product (W by weight), 10 the dry content of the apple product (including flavouring compound) (100 W *e aw..

the water activity ascorbic acid (vitamin C) content by weight, the results of a visual inspection of the cell structure of the product, the fraction of compounds eluted in a range of temperature from 0 to 200°C, the ratio (R 1 of compounds eluted between 0 to 40 0 C for an amount of dried product corresponding to 100g of dry matter, to compounds eluted between 0 to 40 0 C for an amount of the initial apple corresponding to lOOg of dry matter, the ratio (R 2 of compounds eluted between 100 and 150 0 C for an amount of dried product corresponding to lOOg of dry matter, to compounds eluted between 100 to 150°C for an amount of the initial apple corresponding to lOOg of dry matter, the ratio (R 3 of compounds eluted between 150 and 200 0 C for an amount of dried product corresponding to lOOg of dry compounds eluted between 150 and 200 0 C for an amount initial apple corresponding to lOOg of dry matter, matter, to of the 0 *obS

S

000 a 0 p 0 *0 *0 0U *C p the ratio of compounds other than water eluted between 0 to 200°C for an amount of dried product corresponding to lOOg of dry matter, to compounds other than water eluted between 0 to 2006C for an amount of the initial apple corresponding to 100g of dry matter, and the ratio R 3

/R.

10 Table 1 IDARED APPLES FROM STORAGE Fresh apples Invention dried Freeze dried Air drying product product not invention Water content 86 5.5 2.8 18.6

W%

(100-W) 15 94.5 97.2 81.4 Water activity 1.0 0.272 0.191 0.641 ascorbic acid 100 55 47 11 cells not damaged not damaged damaged damaged F 400C 1.3 4.8 1.8 F 40-100"C 94.0 53.9 70.3 F 100-150°C 2.5 6.8 13.8 F 150-200°C 2.1 34.5 14.1 F 150-200°C/F 40- 0.02 0.64 0.2 100°C R, 100 94.5 14.6

R

2 100 65.6

R

3 100 388 66.7 R 100 132 56 RJR, 1 4.1 4.6 It can be seen from Table 1 that the product dried in accordance with the invention retains a higher level of ascorbic acid (vitamin C) content and a higher content of low temperature eluted compounds. These low temperature eluted compounds, in general, are aromatic compounds. In addition as discussed below with r* o. a u 0 0' 41 reference to Figs. 2 to 5, little or no celldamage was detected in the product dried according to the invention, while cell damage was clearly visible in the products which were freeze-dried and forced air dried. The colour and texture of the product dried in accordance with the dehydration process of the invention matched more closely the colour and texture of the product prior to being dried, than did the colour and texture of the products dried using the other two drying processes.

Figs. 2 to 5 show on an enlarged scale the results of microscopic 10 analysis of the cells of the apple slices prior to drying and "after drying using thethree drying processes discussed with reference to Table 1. Figs. 2(a) and 2(b) illustrate portions of anapple slice prior to being dried. Fig. 2(a) illustrates the cellular structure at a skin area of the apple slice, while Fig.

2(b) illustrates the cellular structure of the flesh area of the apple slice, in other words, an interior portion of the apple °°slice. Figs. 3(a) and 3(b) illustrate portions of the apple slice at the skin area and the flesh area, respectively, after drying by the four phase drying process according to the invention. Figs.

3(c) and 3(d) illustrate portions of the skin area and flesh area, respectively, of apple slices which had beendried using the four -phase process according to the invention and had subsequently been .rehydrated. Figs. 4(a) and 4(b) illustrate portions of the skin area and flesh area, respectively, of apple slices which had been freeze-dried. Figs. 4(c) and 4(d) illustrate portions of the skin area and flesh area, respectively of apple slices, which had been freeze-dried, and subsequently rehydrated. Figs. 5(a) and illustrate portions of the skin area and flesh area, respectively, of apple slices which had been dried using the standard forced air drying process. Figs. 5(c) and 5(d) illustrate portions of the skin area and flesh area, respectively, of appleslices which had been dried by the standard forced air drying process and subsequently rehydrated. All the microscopic analysis on the skin area of the apple slices were carried out at a magnification factor of 280X. All the microscopic analysis on the flesh area of the apple slices were carried out at a magnification factor of 140X. It should be noted that the analyses were carried out on different slices. However, a valid comparison between the slices can still be made.

By comparing the skin area of the apple slices before and after drying using the process according to the invention, namely, the illustrations of Figs. 2(a) and it can be seen that little or no-cell damage occurred to the cellular structure of the apple slices in the skin area during the drying process according to the 10 invention. Furthermore, by comparing the skin area of the apple 0 slice as illustrated in Fig. 3(c) which had been dried by the .".process according to the invention and subsequently rehydrated, it can be seen that the cellular structure after rehydration returns substantially to its structure prior to being dried. The cell walls have a substantially normal convex shape, and the cell ;membrane of each cell in general, is in its normal position adjacent the cell wall. Moreover, a waxy layer at the skin 0000 surface and colour components visible within several of the cells adjacent the skin are substantially undisturbed, while significant disturbance can be detected inthe corresponding areas of product dried by the air-flow and freeze-drying processes.

The continuous lines in the Figs. 2 to 5 illustrate the walls of the cells, and the partly broken lines illustrate the membrane of each cell. In Figs. 2(a) and only the cell walls illustrated by the continuous line are visible. The reason for this is thatthemembrane in any fresh product, or a product prior to dehydration, in general will be adjacent the cell wall. Thus, in the portions of the apple slices illustrated in Figs. 2(a) and themembrane being adjacent the cell wall is not visible in these two illustrations. Ideally if a product is to be rehydrated to its form prior to being dried, the membrane and cell wall of each cell should coincide.

While part of the membrane of some of the cells of the skin area of the rehydrated apple slices of Fig. 3(c) have not entirely returned to the cell wall, in general, the membrane and the cell wall in the majority of cells do coincide.

Similarly, much the same conclusion can be drawn from a comparison between Figs. 3(b) and In Fig. it can be seen that little or no damage has occurred to the cellular structure of *ee the flesh area of the apple slice after the slice had been dried 0O*o according to the invention, and after rehydration, the flesh area Ow:.

of the apple slice substantially returns to normal. In general, S• 10 in the majority of cells virtually the entire membrane returns to 0 the cell walls.

@0 A comparison between Figs. 2(a) and 2(b) on the one hand, and Figs. 4(a) to 4(d) on the other hand shows that as-a result of freeze-drying significant damage occurs to the cells both in the 15 skin area and the flesh area as a result of freeze-drying. Not :::only are the cells damaged, but the membranes of the cells are also dislocated during freeze drying. The extent of the damage can clearly be seen in Figs. 4(c) and 4(d) where after rehydration the cells in the skin area fail to return to normal. In Fig.

it can be seen that while some of the cell walls partly take up the convex shape which they had prior to being freeze-dried, in virtually all cells the membrane fails to return to normal, and remains substantially shrivelled up within the cell. In addition, the intercellular spaces are generally enlarged in the freeze dried material as a consequence of the freezing process.

Comparisons between Figs. 2(a) and 2(b) on the one hand, and Figs.

to 5(d) on the other handshow a somewhat similar result as that from a-comparison of Figs. 2 and 4. As can be seen from Fig.

a substantial amount of damage has occurred to the cells in the skin area of the apple slice as a result of the standard forced air drying process. Broken cell walls are clearly visible in several locations of the forced air dried product. This is further emphasised in Fig. 5(c) after rehydration where the cells in the skin area of the apple slice have failed to return to normal, and furthermore, in all cases the membrane has failed to return to the cell wall, and remains substantially shrivelled up within the cell. In Fig. 5(b) cell damage to the flesh area of the apple slice after the standard forced air drying process is less evident. However, after rehydration of the flesh area the cells in the apple slice failed to return to normal, since as can see be seen in Fig. 5(d) in virtually all cases the membrane fails to S.o.

return to the cell wall, and furthermore, the cell walls fail to regain their normal convex shape. This failure of the cells to 0*oe: reassume their original convex shape shows that the turgor of the fresh product has been irreversibly damaged.

Dried tropical fruit materials obtained using three technologies were tested. The dried tropical fruits which were dried in accordance with the invention were dried using a four phase dehydration process, which is substantially similar to that S"described with reference to Fig. 6. The other two drying technologies were freeze-drying and conventional air-flow drying which is identical to the standard forced air drying process to which the apple slices referred to in Table 1 were subjected. The freeze-drying process is also identical to the freeze-drying o process to which the apple slices referred to in Table 1 were subjected. Dried materials including banana, mango, pineapple, kiwi, papaya, and ginger were prepared according to the four phase dehydration process of the invention, air-flow dried material prepared in ISK (Institute of Pomology and Floriculture)of Skierniewice, Poland, and freeze-dried material produced in ISK.

The dried products were subjected to organoleptic and physical and chemical analyses.

A sensory analysis was carried out of the slices of fresh fruits, and dried fruits dried according to the invention, dried-by conventional air-flow drying and freeze-drying, and of rehydrated slices of the fruits with the use of a scaling method. The method for the tests an unstructured linear scale (a segment on a 0000 0 0Oee

S

*000

S

000e *5 5 0O@S 6 5005 0 506O OS 55 0 0 47 straight line, of length 100 mm, with the proper descriptions at the edges, defining unequivocally the subject of the evaluation).

The persons performing the test marked onto the scale their ratings, correspondingly to the sensation experienced; next, the results of the test were converted to numeric values, assuming the whole range of thescale to be 10 imaginary units. Tables 2a 2f show the results obtained based upon averages for 10 persons, each of whom received samples coded in a different order.

Table 2a 10 Banana a summary of average organoleptic ratings Banana Characteristics 1 2 3 4 5 6 7 8 Fresh fruit 7.98 0.18 0.46 3.44 3.16 8.27 0.55 8.40 Invention dried in a dry 4.03 1.56 0.37 7.16 1.98 3.88 2.21 4.00 material condition following 1.99 4.65 7.90 1.44 1.09 4.16 1.17 hydration 1 15 Air-flow dried fruit in a dry 3.98 1.52 3.97 7.77 6.25 3.91 1.61 4.32 (not invention) condition following 1.84 4.87 6.46 2.02 1.19 3.19 1.36 hydration Freeze-dried in a dry 3.05 2.44 0.78 5.51 8.13 5.80 1.42 5.15 material condition following 1.96 3.13 6.79 1.19 0.90 3.36 1.20 hydration Quality characteristics:

S

0 1. Banana smell 2. Foreign smell 3. Hue degree of 4. Hardness Brittleness 6. Banana taste 7. Foreign taste 8. General impress (0-imperceptible, (0-imperceptible, brown (0-light, no brown hue, (0-soft, (0-elastic, (0-imperceptible, (0-imperceptible, iion (0-low quality 10-high quality) 48 Table 2b Mango a summary of average organoleptic ratings 0e e 6 00eO 6000 0 See.

*500 @5 Mango Characteristics 1 2 3 4 5 6 7 8 Fresh fruit 7.38 0.16 0.46 3.68 3.73 8.64 0.27 8.51 Invention dried in a dry 3.28 0.87 1.76 7.42 1.25 4.10 0.39 4.29 material condition following 1.63 1.95 1.39 0.49 1.96 1.71 2.23 hydration Air-flow dried fruit in a dry 4.62 0.33 0.67 7.69 4.83 0.34 5.11 (not invention) condition following 1.94 2.88 0.95 1.52 1.86 2.60 2.04 hydration Freeze-dried in a dry 3.04 0.75 0.50 6.02 8.16 5.08 0.38 5.92 material condition following 0.98 4.89 0.59 0.84 0.62 3.42 1.20 hydration -0 gee.

0050 -SO 56 6 0 000

S

0@ 00 5 6 Quality characteristics: 1. Mango smell 2. Foreign smell 3. Hue degree of brown 4. Hardness Brittleness 6. Mango taste 7. Foreign taste 8. General impression (0-imperceptible, (O-imperceptible, (0-light, no brown hue, (0-soft, (0-elastic, (0-imperceptible, (0-imperceptible, (0-low quality 10-high quality) 49 Table 2c Pineapple a summary of organoleptic ratings 0@S* a aese 0 0 0 S Pineapple Characteristics 1 2 3 4 5 6 7 8 Fresh fruit 7.89 0.95 0.99 3.43 2.43 8.78 0.25 7.66 Invention dried in a dry 6.41 0.24 2.91 7.42 2.27 5.30 0.33 4.82 material condition following 0.65 3.48 1.04 3.44 0.86 3.42 1.20 hydration Air-flow dried fruit in a dry 4.29 0.55 3.35 7.02 6.51 5.21 0.53 5.79 (not invention) condition following 1.10 3.46 0.46 4.59 0.43 3.16 1.13 hydration Freeze-dried in a dry 3.33 0.66 0.05 4.51 9.46 5.29 0.72 6.78 material condition following 0.66 5.83 0.61 3.34 0.32 5.08 0.83 hydration 0 Quality characteristics: 1. Pineapple smell (0-imperceptible, 2. Foreign smell (0-imperceptible, 3. Hue degree of brown (0-light, no brown hue, 4. Hardness (0-soft, 5. Brittleness (0-elastic, 6. Pineapple taste (0-imperceptible, 7. Foreign taste (0-imperceptible, 8. General impression (O-low quality 10-high quality) Table 2d Kiwi a summary of average organoleptic ratings 4 0, as 4 s 4** Kiwi Characteristics 1 2 3 4 5 6 7 8 Fresh fruit 7.96 0.25 5.05 3.06 3.42 8.26 0.48 8.39 Invention dried in a dry 4.38 1.33 8.12 8.13 3.26 5.01 1.05 4.60 material condition following 3.50 2.14 6.70 0.71 2.57 2.49 2.60 hydration.

Air-flow dried fruit in a dry 3.82 0.56 5.96 7.43 3.76 5.12 1.07 5.35 (not invention) condition following 3.55 1.73 4.77 1.03 2.87 1.63 3.59 hydration Freeze-dried in a dry 4.30 0.83 0.35 4.79 8.37 6.35 0.76 6.50 material condition following 3.19 2.71 3.24 0.42 2.09 2.89 2.15 hydration a

I,

C

0 Quality characteristics: 1. Kiwi smell (0-imperceptible, 2. Foreign smell (0-imperceptible, 3. Hue degree of brown (0-light, no brown hue, 4. Hardness (0-soft, 5. Brittleness (0-elastic, 6. Kiwi taste (0-imperceptible, 7. Foreign taste (O-imperceptible, 8. General impression (0-low quality 10-high quality) Table 2e Papaya a summary of average organoleptic ratings iJa

S

Saia 07 a 0 eg.

S

55*O Papaya Characteristics _1234_5 67 8 Fresh fruit 5.96 1.27 1.43 1.88 2.62 7.02 1.37 6.14 Invention dried in a dry 4.31 1.72 1.96 7.17 4.98 4.74 0.57 4.64 material condition following 5.00 1.39 2.00 1.51 2.49 1.44 2.67 hydration Air-flow dried fruit in a dry 3.97 1.08 1.30 6.93 3.62 4.89 0.98 4.91 (not invention) condition following 3.40 2.31 1.36 1.81 2.20 1.93 2.09 hydration Freeze-dried in a dry 2.33 3.49 0.47 3.92 8.81 5.21 1.29 5.90 material condition following 2.11 4.84 2.48 0.82 1.44 2.41 1.73 hydration O 0 *a Quality characteristics: 1. Papaya smell 2. Foreign smell 3. Hue degree of brown 4. Hardness Brittleness 6. Papaya taste 7. Foreign taste 8. General impression (0-imperceptible, (0-imperceptible, (0-light, no brown hue, (0-soft, (0-elastic, (0-imperceptible, (0-imperceptible, (0-low quality 10-high quality) Table 2f Ginger a summary of average organoleptic ratings 0 @060 0o*S 0 *0@S

S@

S. 0 6000 Ginger Characteristics 1 2 3 4 Fresh fruit 8.25 1.30 2.80 3.88 7.12 Invention dried in a dry 8.50 0.58 8.10 8.40 6.44 material condition following 6.41 1.45 3.04 4.71 hydration Air-flow dried fruit in a dry 8.15 0.78 7.10 8.20 6.89 (not invention) condition following 6.55 1.53 2.60 4.55 hydration Freeze-dried in a dry 8.26 0.40 2.25 9.54 8.09 material condition following 6.21 1.49 2.38 4.53 hydration

S

0 0000 @6 00 5 Quality characteristics: 1. Ginger smell 2. Foreign smell 3. Hue degree of brown 15 4. Brittleness 5. General impression (0-imperceptible, (0-imperceptible, (0-light, no brown hue, (0-elastic, (0-low quality 10-high quality) 0 0*@e 0O 00

S

Note: Because the ginger is spicy, the organoleptic ratings of ginger taste and foreign taste were not determined.

A numerical comparison of the level of chromatographic traces for volatile compounds produced by the above six fruits and tubers, and maracuja (passion fruit), in the temperature ranges indicated is shown in Table 3a. The data is given in integrated units per lOOg of tested material and per litre of air. The results are an average taken from three measurements. This analysis was performed on gas chromatography HP equipment with an FID sensor.

Tabl e 3a

S

0 6SSS 0

S

0

*SSO

0e S S *555 Species of M.aterial for testing Integration units/i 00 g. of material/i litre of air fruits up to 40 0 C 40-100 0 C I100-150 0 C I150-200 0 C Sum Banana Fresh fruit 26748 859268 104988 1800 992803 Invention dry 6790 536595 30498 1604 575487 dried material rehydrated 32627 210861 37764 1882 283133 Air-flow dry 9651 166922 16646 1251 194470 dried fruit (not rehydrated 37002 169846 19130 2201 228179 invention) Freeze- dry 10791 175815 2561870 214072 dried material rhdte536 1954 23627 278478 Mang o Fresh fruit 30409 2187960 67388 11173 2297230 Invention dry 24853 1115610 36929 2612 1.180031 dried material rehydrated 15652 486410 18351 17608 538021 Air-flow dry 10092 389620 18861 1214 419788 dried fruit (not rhdae 00 808 282 247 591 invention) rhdae 00 808 282 247 591 Freeze- dy11647 83841 19425 1329 11642 dried material rehydrated 221021 813584 17517 31151 1083544 Pineapple Fresh fruit 2652388 1409435 13954 988 4076765 Invention dry 35784 266918 29059 962 332724 dried material rehydrated 37455 167733 12814 3404 221406 Air-flow dry 4324 77395. 241.19 1483 107321 dried fruit (not rhdae invention) rhdae Freeze- dry 12382 223756 49863 1875 287876 dried material rehydrated 845643 1225238 23128 23005 12117014 0 *050

S

55 00 0

*S

05**

S

0000 S. SO @0 0 0 Table 3a (cont.)

C

0

S.

S

0005

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S

OS @0

S

S

0 0@*e @5 @0

S

0 Species of Material for testing Integration units/100 g. of material/1 litre of air fruits up to 40 0 C 40-100 0 C 100-150°C 150-200°C Sum Papaya Fresh fruit 44241 115873 9723 10668 180505 Invention dry 65224 1225642 117337 116037 1524240 dried material rehydrated 37984 236664 66855 27728 369231 Air-flow dry 91344 389998 26840 44398 552580 dried fruit (not rehydrated 20834 309857 22098 26266 379055 invention) Freeze- dry 210815 1292847 101984 188652 1794298 dried material rehydrated 40767 873458 71271 100297 1085793 Kiwi Fresh fruit 26177 522458 78669 36821 664125 Invention dry 41937 838027 84701 48206 1012871 dried material rehydrated 20994 302139 86783 80773 490689 Air-flow dry 7166 133374 39127 31099 210766 dried fruit (not rehydrated 17637 190287 37391 16393 261708 invention) Freeze- dry 65379 809322 172824 60241 1107766 dried material rehydrated 33167 380260 98544 90943 602914 Ginger Fresh fruit 81457 2868454 186263 143744 3279918 Invention dry 35410 6415635 547090 130020 7128155 dried material rehydrated 22259 2382750 328543 87831 2821383 Air-flow dry 35797 981063 83339 74943 1175142 dried fruit (not rehydrated 25714 1424850 160946 18462 1629972 invention) Freeze- dry 38034 1753864 203369 161739 2157006 dried material rehydrated 28157 1551262 190494 72531 1842444 Maracuja Fresh fruit 60421 4039152 126841 29330 4255744 Invention dry 30273 908475 83137 22088 1043973 dried material rehydrated 8543 104654 36850 21001 171048 Air-flow dry 29449 155702 40386 27165 252702 dried fruit (not rehydrated 11751 144101 37612 9248 202712 invention) Freeze- dry 60623 1560407 138764 69129 1828923 dried materi al rehydrated 94142 1325725 91805 39018 1550690 0S@*

S

S

SS

5 S Another numerical comparison of the level of chromatographic traces for volatile compounds produced by the same materials is shown in Table 3b. The data in integration units per 100g of tested material per litre of air passed through has been recalculated in terms of 100g of dry mass of the tested material.

The results are averages for three measurements.

Table 3b Species of Material for testing Integration units/100 g. of material/1 litre of air fruits upto 40C 40-100°C 100-1500C 150-200 0 C Sum LO Banana Fresh fruit. 108731 3492957 426781 7316 4035785 Invention dry 7320 578477 32879 1729 620405 dried material rehydrated 315236 2037302 364869 18179 2735586 Air-flow dry 10210 176599 17611 1324 205744 dried fruit (not rehydrated 227563 1044564 117650 13539 1403316 invention) Freeze- dry 11086 180619 26295 1921 219921 dried material rehydrated 340312 1240714 180777 14202 1776005 Mango Fresh fruit 160896 11576507 356551 60703 12154657 Invention dry 26678 1197552 39641 2801 1266675 dried material rehydrated 178273 5539982 309008 200544 6127807 Air-flow dry 415861 70131 1296 448060 dried fruit (not rehydrated 305898 7132463 321795 315097 8075253 invention) Freeze- dry 12242 88124 20417 1397 122180 dried material rehydrated 3139509 11560122 248822 442190 15391243 Pineapple Fresh fruit 20402988 10841808 338105 7596 31590497 Invention dry 38239 285230 31053 1028 355550 dried material rehydrated 692321 3100427 236853 62928 4092529 Air-flow dry 4548 81418 25373 1560 112899 dried fruit (not rehydrated 522149 4240161 369343 388692 5520345 invention) Freeze- dry 13086 236478 52698 1982 304244 dried material rehydrated 15047029 21801390 411524 409343 37669292

*SS@

S

S

S

S

@0@5

SC

5 Table 3b (cont.) 0**O 000@ 0

S

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e.g.

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OeOe 0 0000 S@ Ce @0 0 6 *5*S 0 S. SO 56 0

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Species of Material for testing Integration units/i00 g. of material/i litre of air fruits up to 401C 40-100 0 C 100-150 0 C 150-200 0 C Sum Papaya Fresh fruit 456560 1195797 100342 110098 1862797 Invention dry 70627 1327170 127057 125649 1650503 dried material rehydrated 703408 4382660 1238057 513475 6387600 Air-flow dry 97704 417154 28709 47490 591057 dried fruit (not rehydrated 481145 7156053 510350 606602 8754150 invention) Freeze- dry 222028 1361608 107408 198685 1889729 dried material rehydrated 779481 16700926 1362733 1917725 20760865 Kiwi Fresh fruit 118287 2360859 355488 166386 3001020 Invention dry 45415 907544 91727 52205 1096891 dried material rehydrated 168628 2426819 697051 648776 3941274 Air-flow dry 7635 142099 41686 33133 224553 dried fruit (not rehydrated 158321 1708139 335644 147158 2349262 invention) Freeze- dry 67800 839284 179223 62471 1148778 dried material rehydrated 270093 3096582 802476 740576 4909727 Ginger Fresh fruit 276031 9720277 631185 487101 11114594 Invention dry 37479 6790469 579053 137616 7544617 dried rehydrated 108582 11623169 1602646 428442 13762839 Air-flow dry 38434 1053320 89477 80463 1261694 dried fruit (not rehydrated 133370 7390301 834784 95757 8454212 invention) Freeze- dry 39365 1815219 210483 167397 2232464 dried material rehydrated 165436 9114347 1119234 426153 10825170 Maracuja Fresh fruit 273027 18251931 573165 132533 19230656 Invention dry 32863 986186 90248 23977 1133274 dried material rehydrated 46454 565394 199082 113460 924390 Air-flow dry 31067 164260 42606 28658 266591 dried fruit (not rehydrated 59197 725948 189479 46590 1021214 invention) Freeze- dry 63975 1646694 146438 72951 1930058 dried material rehydrated 383627 5402303 374101 158997 6319028 Gas chromatographic (GG)-traces illustrated in Figs. 8 to 11 were prepared of banana slices prior to and after drying using the three drying processes discussed with reference to Table 1. Gas chromatographic traces illustrated in Figs. 12 to 14 were also prepared of the banana slices after they had been subsequently rehydrated. The gas chromatographic traces were prepared on a HP gas chrornatograph with an FID sensor in the range of temperature from room temperature up to 200 0 C. The time period of each test for preparing the corresponding trace is plotted on the x-axis in 000 10 units of minutes. During the test period the temperatures of the sample slices were raised in a controlled manner from room fee: temperature to 200 0 C. The y-axis is a measure of the 0 chromatographic response measured by the gas chromatograph. The Os.. scale of this response is in machine units, and the scale is adjusted for each test to accommodate the most prominent peak measured. The numbers associated with the peaks in the traces are the retention times in minutes for the release of the respective volatile compounds. These retention times in conjunction with the 0.00.0temperature profile used for the tests make it possible to *fe* 20 associate each peak unambiguously with a specific molecular vol atil1e compound.

Fig. 8 illustrates the gas chromatographic trace for a banana slice prior to dehydration. Fig. 9 illustrates the gas chromatographic trace for a banana slice having been dried by the 25 four phase process according to the invention. Fig. illustrates the gas chromatographic trace for a banana slice which has been dried by the conventional air-flow process. Fig. 11 illustrates the gas chromatographic trace for a banana slice which has been dried by the freeze drying process. Fig. 12 illustrates the gas chromatographic trace of a banana slice which has been rehydrated after having been dried by the four phase process according to the invention. Fig..13 illustrates the gas chromatographic trace for a banana slice which has been rehydrated after having been dried by the conventional air-flow drying process. Fig. 14 illustrates the gas chromatographic trace for a banana slice which has been rehydrated after having been dried by the freeze drying process.

The flavour and bouquet or characteristic aroma of foods eaten in their raw state are dominated by volatile compounds which are eluted, namely, liberated or activated at temperatures up to 400C0, in other words, up to normal body temperature. Accordingly, the similarity between the elution chromatographic signature of a fresh fruit or vegetable, in other words, a fruit or vegetable which has not been dried, and the dried product is a strong indication of how well the fresh fruit taste and aroma is retained during a drying process. A comparison between the gas -chromatographic trace of Fig. 8, namely, the trace of the fresh banana with the gas chromatographic trace of Fig. 9 of the banana m dried by the process of the invention illustrates that the banana dried by the process according to the invention retains substantially all of the compounds which are eluted at temperatures of up to 40 0 C. Furthermore, it can be seen from the -trace of Fig. 12 that the rehydrated banana which had been dried by the process according to the invention also retains substantially all of the compounds which are eluted at temperatures up to 400C. On the other hand, a comparison of the traces of Figs. 10 and 11 which illustrate the traces of the banana which had been dried by the conventional air-flow drying S.process and the freeze-drying process, respectively, and the trace S 25 of Fig. 8, shows that after conventional air-flow drying and freeze-drying a significant number of the compounds which are eluted at temperatures of up to 40'C which were present in the banana prior to being dried are absent in the product after drying. Similarly, a comparison between the trace of Fig. 8, and Figs. 13 and 14 which illustrate the banana having been rehydrated after conventional air-flow drying and freeze drying, respectively, shows a somewhat similar result to that of the comparison of the traces of Fig. 8 on the one hand, and Figs. and 11 on the other hand.

Additionally, it can be seen from the trace of Fig. 9 that the dried banana which was dried by the process according to the invention has prominent gas chromatographic peaks at 6.110 and 7.374 minutes retention times.

The main fraction of volatile compounds were compounds evaporating in the range of temperatures of 40 0 C to 100 0 C. In the fresh fruits, this fraction contained predominantly: butanoic acid methyl ester an unidentified compound with RT=10.2; butanoic acid propyl ester (RT=11.9); 2-methyl butanol and/or 3methyl butanol (RT=14.8); ethanoic acid hexyl ester (RT=16.5).

*e Hexanol (RT=19.3) was the main constituent of the 100 0 C to 150 0

C

fraction. In the dried banana which were dried by all three drying processes, the main constituents of the 40°C to 100°C fraction were: ethanol butanoic acid methyl ester and 2methyl butanol and/or 3-methyl butanol. In the dried banana which was dried by the drying process of the invention the main components of the above mentioned fraction were a compound with RT=11.0 (probably isobutanoic acid isobutyl ester) and an unidentified compound with RT=17.6. In the dried banana which was dried by the freeze-drying process, in the 40 0 C to 100 0 C fraction butanoic acid methyl ester (RT=7.3) and an unidentified compound with RT=10.5 dominated. Following rehydration of the banana which had been dried by all three drying processes, a drop in the level of ethanol in the aroma was detected, the dominating compound was 25 still the butanoic acid methyl ester Overall, the proportion of the low-boiling fraction (up to 40 0 C) rose in the aroma of both the rehydrated banana which had been both dried by the process according to the invention and the freeze-drying process.

Figs. 15 to 18 illustrate gas chromatographic traces of the IDARED apple slices which were prepared in similar fashion to those of Figs. 8 to 11. Fig. 15 is a gas chromatographic trace of an apple slice prior to being dried. Fig. 16 is a gas chromatographic trace of an apple slice having been dried by the four phase process according to the invention. Fig. 17 is a gas chromatographic trace of an apple slice having been dried by the conventional air-flow drying process, and Fig. 18 is a gas chromatographic trace of an apple slice having been dried by the freeze-drying process. A comparison between the four traces of Figs. 15 to 18 indicate that as in the case of the banana slices, the apple which was dried by the process according to the invention retains a substantial amount of thevolatile compounds which are eluted at temperatures up to 40 0 C, while the apples 10 which were conventionally air-flow dried and freeze-dried do not ,-retain the same amount of such compounds. However, a significant Oct* 9 feature which can be seen by a comparison between the traces of See...

Figs. 15 and 18 is the fact that the apple which was dried by the 0000 freeze-drying process shows the development of significant peaks ,15 in the higher temperature range, in other words, temperature ranges towards 200 0 C which, in general, tend to be associated with the development of off tastes. Such peaks are not present in the trace of the apple dried by the process according to the *rGo invention.

SODA

•a B *Ga.- 1D It can also be seen from the trace of Fig. 16 that the apple dried by the process according to the invention has prominent gas chromatographic peaks at 6.101, 10.186 and 11.834 minutes retention times.

OSUA

Figs. 19 to 25 are gas chromatographic traces for mango slices which correspond to the gas chromatographic traces of the banana slices of Figs. 8 to 14. In other words, Fig. 19 is a gas chromatographic trace of mango prior to drying, Fig. 20 is a trace of the mango dried by the four phase process according to the invention, Fig. 21 is a trace of the mango dried by the conventional air-flow drying process, Fig. 22 is a trace of the mango dried by the freeze-drying process, Fig. 23 is a trace of the mangowhich was rehydrated subsequent to being dried by the process according to the invention, Fig. 24 is a trace of the mango having been rehydrated subsequent to being dried by the 61 conventional air-flow drying process, and Fig. 25 is a trace of the mango having been rehydrated subsequent to being dried by the freeze-drying process. Comparisons between the traces of Figs. 19 to 23 yield substantially similar conclusions to those drawn from the comparisons made between Figs. 8 to 14 of the banana as already discussed. In addition, it can be seen from Fig. 20 that the dried mango which was dried by the process according to the invention has prominent gas chromatographic peaks at 6.181 and 12.771.

S 10 The main fraction of volatile compounds in the mango are compounds evaporating in the 40 0 C to 100 0 C range of temperatures. The dominant compounds to be found in this fraction for the fresh fruit are: unidentified compounds with RT=12.5, RT=12.8 (probably butanol), RT=13.1, RT=14.2 and RT=17.0. The compound with RT=12.7 remains the main compound emitted by the dried mango which were dried by all three drying processes. However, in the aromas from the dried mango which was dried by the process according to the invention there is also a large quantity of ethanol (RT-6.81).

e* Following rehydration of the mango dried by the process of the invention, three compounds dominate, one with RT=9.2 (probably propanol), two others with RT=12.5 and RT-16.6. Following rehydration of the mango which had been dried by the conventional air-flow drying process butanol (RT=12.8) additionally dominates.

After rehydration of the mango which had been dried by the freeze- 25 drying process, the rehydrated mango becomes very aromatic, with a large participation of a compound with RT=4.0 (ethanoic acid methyl ester) in the fraction up to 40 0 C. This rehydrated mango also displays compounds with RT=5.1 (methanol), RT=9.2 (propanol), RT=12.3 and RT=16.5 in the 40 0 C to 100 0 C fraction, and compounds with RT=27.6 and RT=29.9 in the 150 0 C to 200 0 C fraction.

Figs. 26 to 32 illustrate gas chromatographic traces for papaya which also correspond to the gas chromatographic traces of Figs. 8 to 14. In other words, Fig. 26 is a trace of papaya prior to being dried, Figs. 27 to 29 are traces of papaya having been dried 62 by the process according to the invention, the conventional airflow drying process and the freeze-drying process, respectively, and Figs. 30 to 32 are traces of papaya having been rehydrated subsequent to being dried by the drying process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively. A comparison between the traces of Figs. 26 to 32 yields substantially similar conclusions as those drawn from the comparison between the traces of Figs. 8 to 14 in connection with banana. Additionally, the dried papaya 10 dried by the process according to the invention has prominent gas chromatographic peaks at 6.254, 7.941 and 9.323 minutes retention 0 times.

gFigs. 33 to 39 illustrate gas chromatographic traces for kiwi slices which also correspond to Figs. 8 to 14. In other words, Fig. 33 is a trace of the kiwi prior to being dried, Figs. 34 to 36 are traces of the kiwi having been dried by the process of the invention, the conventional air-flow drying process and the freeze-drying process, respectively, and Figs. 37 to 39 are traces of the kiwi having been rehydrated subsequent to beingdried by the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively. A comparison between the traces of Figs. 33 to 39 yields substantially similar conclusions to those drawn from the results "of the comparison of the traces of Figs. 8 to 14 for banana. In 25 addition, it can be seen from Fig. 34 that the dried kiwi which was dried by the process according to the invention has prominent gas chromatographic peaks at 6.344, 7.946, 8.649 and 9.336 minutes retention times.

Figs. 40 to 46 illustrate gas chromatographic traces of ginger which correspond to the traces of Figs. 8 to 14. In other words, Fig. 40 illustrates a trace of the ginger prior to drying, Figs.

41 to 43 illustrate traces of the ginger having been dried by the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively, and Figs. 44 to 46 illustrate traces of the ginger having been rehydrated subsequent to being dried by the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively. Comparisons between the traces of Figs. 40 to 46 yield substantially similar conclusions as those drawn from the comparison of the traces of Figs. 8 to 14 for banana. Additionally, it can be seen from Fig. 41 that the dried ginger which had been dried by the process according to the invention has prominent gas chromatographic peaks at 5.741, 6.356, 10 7.996, 8.496, 9.407, 10.006 and 11.213 minutes retention times.

Figs. 47 to 53 illustrate gas chromatographic traces of pineapple, s which correspond to the gas chromatographic traces of Figs. 8 to 0o*S 14. In other words, the traces of Fig. 47 is of pineapple prior "to drying. The trace of Figs. 48 to 50 are of pineapple which has been driedby the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively, and the traces of Figs. 51 to 53 are of pineapple which has been rehydrated, prior to having been dried by the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively. A S. comparison between the traces of Figs. 48 to 53 yields similar conclusions to those drawn from the comparison between the traces of Figs. 8 to 14 in respect of banana, and furthermore, it can be seen from Fig. 49 that the pineapple dried by the process 25 according to the invention has a prominent gas chromatographic peak at 6.104 minutes retention time.

In the pineapple prior to being dried, the most intense was the fraction up to 40 0 C, with the compound RT=4.9 (ethyl ethanoate) dominating. In the 40'C to 100'C fraction the predominant compounds were RT=7.4 (butanoic acid methyl ester), RT=8.1 (2methylbutanoic acid methyl ester) and RT=14.0 (hexanoic acid methyl ester). In the dried pineapple which had been dried by the conventional air-flow drying process, the main component was an unidentified compound with RT=12.6, and in the dried pineapple 64 which had been dried by the process according to the invention the main component was ethanol The dried pineapple which had been dried by the freeze-drying process contained mainly the compounds with RT=12.6. Following rehydration of the dried product which had been dried by the conventional air-flow drying process and the freeze-drying process, there was an increase in the proportion of compounds belonging to the up to 40 0 C fraction.

In the case of the rehydrated pineapple which had previously been conventionally air-flow dried, the main compounds were 10 unidentified compounds with RT=9.2 and RT=16.5. Additionally, in °the rehydrated pineapple which had been dried by the conventional s air-flow drying process there were unidentified compounds belonging to the 150 0 C to 200 0 C fraction which were characterised by RT=27.6 and RT=29.8. The main compounds in the rehydrated 15 material which had previously been dried by the freeze-drying process were compounds with RT=2.8, RT=3.8 (ethanoic acid methyl ester), RT=5.0 (ethyl ethanoate), RT=6.1 (ethanol), RT=11.2 and RT=14.9 (3-methylbutanol).

Figs. 54 to 60 illustrate gas chromatographic traces of maracuja slices, which correspond to the gas chromatographic traces of Figs. 8 to 14. In other words, Fig. 54 illustrates a trace of the maracuja prior to being dried, Figs. 55 to 57 illustrate traces of the maracuja dried by the process according to the invention, the conventional air-flow drying process and the freeze-drying 25 process, respectively, and Figs. 58 to 60 illustrate traces of the maracuja having been rehydrated subsequent to being dried by the process according to the invention, the conventional air-flow drying process and the freeze-drying process, respectively. A comparison process between the traces of Figs. 55 to 60 yields substantially similar conclusions to those drawn from the comparison of the traces of Figs. 8 to 14 for banana.

Additionally, it can be seen from Fig. 55 that the dried maracuja which was dried by the process according to the invention displays prominent gas chromatographic peaks at 6.367, 7.983, 8.682 and 9.375 minutes retention times.

In the above analysis which has been made with reference to Figs.

8 to 60 it should be noted that the various compounds which have been identified, have been identified on the basis of the comparison of retention times with reference times, and by relying upon data which is available in theliterature. The compound with the retention time of 27.0 which is visible on the gas chromatograph is an octanoic acid ethyl ester, which is used as a reference substance. Additionally, it should be noted that the abbreviation "RT" in the above discussion with reference to Figs.

S 10 8 to 60 indicates "retention time".

0eOO The results of the analysis of the volatile compounds using gas a 000 chromatography give evidence of the influence of the drying technology on the composition of the level of aromatic compounds 0 in the dried materials. The main fraction of volatile compounds consists of compounds evaporating in the 40 0 C to 100 0 C range of temperature. In all the dried materials because of the technological processing, a fall in the level of aromatic *6"substances occurs. However, the dried fruits and vegetables which 6 were dried by the process according to the invention have the highest level of aromatic compounds for each of the species of S fruits and vegetables. Following rehydration an increase in the content of volatile compounds occurs in the case of mango and pineapple. This is greatest in the case of the mango and 0@00 pineapple which had been dried by the freeze drying process. An 25 increase in the content of volatile compounds in the rehydrated banana also occurs, and this increase is greatest in the case of the rehydrated banana which had previously been dried by the process according to the invention. At the same time, in the organoleptic rating, the highest level of foreign smell for banana has been observed in rehydrated banana, while in thecase of mango and pineapple, the highest level of foreign smell has been found in rehydrated mango and banana which had been previously dried by the freeze drying process.

An assessment of hue conducted on each fruit and tuber tested, ee~g.

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Table 4 [Variety of Material for testing Hue according to Hunter Lab I fruit11 L' a. I b* Banana Fresh fruit .80.57 4.07 26.39 Invention dried dry 62.48 5.89 27.15 material 49.37 6.21 20.20 Air-flow dried fruit dr y 68.98 5.78 28.04 (not invention) 54.03 5.81 18.79 Freeze-dried dry 86.11 2.95 14.24 material rehydrated 51.95 6.71 16.01 Mango Fresh fruit 69.64 15.83 60.30 Invention dried dry 65.89 20.90 62.33 material rehydrated 60.74 16.88 66.91 Air-flow dried fruit dry 77.95 16.57 67.85 (not invention) 68.39 15.14 67.89 Freeze-dried dry 83.64 10.97 43.47 material _________rehydrated 72.48 1 13.01 1 60.37 Pineapple Fresh fruit 84.52 1.51 26.63 Invention dried dry 81.50 3.88 32.67 material 78.57 0.55 31.78 Air-flow dried fruit dry 78.38 3.63 33.05 (not invention) 79.01 0.67 29.43 Freeze-dried dry 92.44 -0.14 18.02 material rehydrated 85.78 1 -0.75 17.90 67 Table 4 (cont.) .me), 0064 Variety of Maera for testing Hu According to Hunter Lab fruit Maera I .a Papaya Fresh fruit .63.0 25.0 36.3 Invention dried dry 66.6 20.? 40.7 material rehydrated 46.0 26.3 36.4 Air-flow dried fruit dry 68.8 21.5 45.1 (not invention) 51.9 24.1 44.0 Freeze-dried dry 78.5 12.9 24.5 material______ rehydrated 69.0 16.7 36.7 Kiwi Fresh fruit 47.2 -1.9 20.5 Invention dried dry 51.0 5.9 29.7 material 47.4 3.1 25.6 Air-flow dried fruit dry 57.9 3.7 27.7 (not invention) 55.2 0.7 24.2 Freeze-dried dry 84.4 -1.8 19.1 material______ rehydrated -63.9 0.0 25.7 Maracuja Fresh fruit 44.2 7.6 30.7 Invention dried dry 44.3 13.2 36.4 material rehydrated 43.7 7.5 30.0 Air-flow dried fruit dry 30.5 8.6 13.2 (not invention) rehydrated 34.5 9.5 30.9 Freeze-dried dry 72.1 11.9 46.7 material_____ rehydrated 49.7 7.1 34.3 Ginger Fresh fruit 66.9 1.3 33.4 Invention dried dry 56.2 3.0 18.6 material rehydrated 63.4 3.9 32.0 Air-flow dried fruit dry 69.9 1.1 19.0 (not invention) 62.3 4.8 33.3 Freeze-dried dry 83.3 -2.0 22.0 material_____ rehydrated 1 67.3 1 3.5 -1 34.1 4eeO a 0S CU ~3 a C a S

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68 The dry mass content of each fruit and tuber tested was evaluated by desiccating samples to substantially total dryness. The results are shown in Table 5. The table shows that for the majority of fruits tested, the products dried by the four phase process of the invention could be rehydrated to a water content closer to the water content of the product prior to being dried, than could product dried by the other two drying processes. The ability of a dried product to be rehydrated to a state approaching that of the product prior to being dried is an indication of the 10 retention of the properties of that product which it had prior to being dried.

Table Variety of fruit Material for testing Dry substance Banana Fresh fruit 24.60 Invention dried material dry 92.76 rehydrated 10.35 Air-flow dried fruit (not dry 94.52 invention) rehydrated 16.26 Freeze-dried material dry 95.80 Srehydrated 15.46 15 Mango Fresh fruit 18.90 Invention dried material dry 93.16 rehydrated 8.78 Air-flow dried fruit (not dry 93.69 invention) rehydrated 6.80 Freeze-dried material dry 95.14 rehydrated 7.94 Pineapple Fresh fruit 13.00 Invention dried material dry 93.58 rehydrated 5.41 Air-flow dried fruit (not dry 95.06 invention) rehydrated 5.34 Freeze-dried material dry 94.62 Srehydrated 5.62 S S OeOS 00 @5 5* 0 0 69 Table 5 (cont.) 0*OS 0 000@ 0

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*0 0 0 [Variety of fruit (Material for testing Dry substanc[% Papaya Fresh fruit 9.69 Invention dried material dry 92.35 rehydrated 5.40 Air-flow dried fruit (not dry 93.49 invention) rehydrated 4.33 Freeze-dried material dry 94.95 rehydrated 5.23 Kiwi Fresh fruit 16.75 Invention dried material dry 92.34 rehydrated 12.45 Air-flow dried fruit (not dry 93.86 invention) rehydrated 11.14 Freeze-dried material dry 96.43 12.28 Maracuja Fresh fruit 22.13 Invention dried materialI dry 92.12 18.51 Air-flow dried fruit (not dry 94.79 invention) rehydrated 19.85 Freeze-dried material dry 94.76 rehydrated 24.54 Ginger Fresh fruit 29.51 Invention dried material dry 94.48 rehydrated 20.50 Air-flow dried fruit (not dry 93.14 invention) rehydrated 19.28 Freeze-dried material dry 96.62_ rehydrated 117.02 Measurements of water activity of the above dried fruits and tubers have been taken and the results are presented in Table 6.

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activity meter AW-THERM 40 with automatic temperature compensation.

Table 6 Variety of fruit Materials for test Water activity Banana Invention dried material 0.392 Air-flow dried fruit (not invention) 0.374 Freeze-dried material 0.223 Mango Invention dried material 0.410 Air-flow dried fruit (not invention) 0.355 Freeze-dried material 0.237 Pineapple Invention dried material 0.362 Air-flow dried fruit (not invention) 0.337 Freeze-dried material 0.306 Papaya Invention dried material 0.347 Air-flow dried fruit (not invention) 0.301 Freeze-dried material 0.267 Kiwi Invention dried material 0.330 Air-flow dried fruit (not invention) 0.294 Freeze-dried material 0.144 Maracuja Invention dried material 0.333 Air-flow dried fruit (not invention) 0.309 Freeze-dried material 0.169 Ginger Invention dried material 0.298 Air-flow dried fruit (not invention) 0.345 Freeze-dried material 0.099 0000

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0 Ascorbic acid content of the above dried is presented in Table 7.

fruits and tubers tested The ascorbic acid presence was tested using the HPLC method, Supelco LC 18 column, with the solvent 1% KHPO 4 pH=3, the rate of flow 0.8 ml/min. The detection was conducted at a wavelength of 243 nm.

71 A representative sample of the material was taken, which was homogenized in 6% metaphosphoric acid, and then filtered. From the solution that was obtained, phenol compounds were removed on the C-18 column and then the solution was subjected to the HPLC chromatography analysis. The retention time of ascorbic acid was equal to 6.31 min. In the tested range of ascorbic acid content, (from 0.2 to 1.5 mg of ascorbic acid in 100 ml of solution prepared for injection) the square of the correlation of the content of ascorbic acid in the reference solutions and the 10 surface areas of the peak equalled to 0.9998.

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Table 7 Variety of fruit Material for testing Ascorbic acid content [mg/100g] [mg/100g dry Banana Fresh fruit 5.8 23.6 100.0 Invention dried material 3.2 3.4 14.4 Air-flow dried fruit (not 0.5 0.5 0.2 invention) Freeze-dried material 3.0 3.2 13.5 Mango Fresh fruit 21.3 112.7 100.0 Invention dried material 103.3 110.9 98.4 Air-flow dried fruit (not 93.8 98.6 87.5 invention) Freeze-dried material 87.7 90.2 80.0 Pineapple Fresh fruit 32.7 251.6 100.0 Invention dried material 217.6. 232.5 92.4 Air-flow dried fruit (not 198.9 210.2 83.5 invention) Freeze-dried material 239.2 246.5 97.9 Papaya Fresh fruit 44.6 460.0 100.0 Invention dried material 392.1 413.7 89.9 Air-flow dried fruit (not 405.2 433.4 94.2 invention) Freeze-dried material 41?.8 435.8 94.7 Kiwi Fresh fruit 104.4 623.1 100.0 Invention dried material 574.0 621.6 99.8 Air-flow dried fruit (not 459.9 499.1 80.1 invention) Freeze-dried material 549.1 569.5 91.4 Maracuja Fresh fruit 13.0 58.7 100.0 Invention dried material 38.9 42.2 72.0 Air-flow dried fruit (not 2.5 2.6 4.4 invention) Freeze-dried material 46.4 50.5 86.0 Of the above fruits and tubers, a comparison has been made of the content of b-carotene and carotenoids, and the level of nitrates and nitrites for banana, mango and pineapple. The result of the comparison are shown in Table 8. The analytical methods used were as follows: carotenoids and b-carotene method described by Czapski and Saniewski, Experimentia, 39, 1373-1374, 1983; nitrates potentiometric method, using the ORION apparatus; nitrites standard spectrophotometry method, according to Polish PN-92 A-75112.

Table 8 0S*@

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6 0 0 0 Variety of Material for testing b-carotene sum of all nitrates nitrates fruits carotenoids [mg/100g D.W.] Banana Fresh fruit 275 393 350 <100 Invention dried material 255 487 330 Air-flow dried fruit 389 645 310 (not invention) Freeze-dried material 383 547 270 Mango Fresh fruit 330 875 105 <100 Invention dried material 371 734 110 Air-flow dried fruit 402 .927 100 (not invention) Freeze-dried material 418 981 105 Pineapple Fresh fruit 326 131 145 <100 Invention dried material 364 645 140 Air-flow dried fruit 291 558 150 (not invention) Freeze-dried material 300 594 140 Table 9 shows the results of texture tests on the slices of the above fruits and tubers, with the exception of maracuja (passion fruit). Each result is an average of at least 20 measurements.

The measurements of the penetration force and the Young's modulus were performed using the structural solidity meter Instron 4303 with a sensor having a radius of 3.7 mm. To make the measurements, the perforation of a slice of a given material was placed between two plates with holes having a radius of 16.7 mm.

As can be seen from Table 9, most of the products dried by the *6@S 6 6000 6@@S

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Table 9 Variety of fruit Material for testing Penetration Apparent Young's Force modulus [MPa] Banana Fresh fruit 0.31 0.031 Invention dried material 9.79 0.138 Air-flow dried fruit (not invention) 12.49 0.238 Freeze-dried material 7.14 0.367 Mango Fresh fruit 0.54 1.004 Invention dried material 10.95 0.175 Air-flow dried fruit (not invention) 1 2.32 0.231 Freeze-dried material 10.00 0.311 Pineapple Fresh fruit 1.80 0.013 Invention dried material 11.94 0.119 Air-flow dried fruit (not invention) 7.90 0.106 Freeze-dried material 8.74 0.235 Papaya Fresh fruit 0.395 0.0095 Invention dried material 7.392 0.2239 Air-flow dried fruit (not invention) 7.171 0.1382 Freeze-dried material 5.207 0.2970 Kiwi Fresh fruit 0.624 0.0045 Invention dried material 10.280 0.1265 Air-flow dried fruit (not invention) 9.782 0.0953 Freeze-dried material 11.075 0.2534 Ginger Fresh fruit 12.130 0.0875 Invention dried material 17.570 1.0240 Air-flow dried fruit (not invention) 20.100 0.5468 Freeze-dried material 9.077 0.3866 Evaluation of the orqanoleotic test results Banana The banana slices dried by the four phase process of the invention and the conventional air-flow dried slices received similar ratings, both higher than the ratings for the freeze-dried banana slices, for the presence of typical banana flavour and the absence of off-flavour. The slightly different overall rating for the conventional air-flow dried material is the result of its greater hardness, caused by its having been dried to a water content level of 5.5% 7.2% for the material dried in accordance with the invention). Banana slices dried in accordance with the invention were much less brittle than the other dried products tested. In addition, the hue of the banana slices dried in accordance with S 10 the invention was closer than the hue of the freeze-dried banana slices to the hue of the banana slices prior to drying.

0000 Following rehydration, because of a comparable water-absorption *Goo capacity (cf. Table the materials dried in accordance with the invention and conventional air-flow dried material reached a °o6° similar level of hardness. At the same time, the freeze-dried and the conventional air-flow dried materials were characterised by a high degree of browness and a strongly perceptible foreign smell *and taste after rehydration. They were rated as unpalatable, with an unnatural hue and smell. The hue ratings are confirmed in the 0000 colour parameter measurements according to the Hunter scale (Table 4).

Mango The conventional air-flow dried material received the highest :0.'4rating for mangosmell with the lowest level of foreign smell, slightly higher than the rating for material dried in accordance with the invention. Like thefreeze-dried material, the conventional air-flow dried material was characterised by a low degree of browness, comparable to that of the mango prior to drying. The conventional air-flow dried material and the material dried in accordance with the invention received similar hardness ratings, reflecting the nearly equal water content and 6.8% respectively). The product dried in accordance with the invention had a much lower degree of brittleness.

Following rehydration, the differences between the various dried materials became more noticeable. Thus, the material dried using conventional air-flow drying had a higher level of foreign smell and taste after rehydration, in addition to being harder and lighter in colour than the material dried in accordance with the invention. The rehydrated freeze-dried material, while retaining a light hue comparable to that of the mango prior to drying, was characterised by a particularly high level of foreign smell and taste.

0n*s0 10 Pineappl e _Of the dried pineapples tested, the pineapple dried in accordance with the invention was characterised by the highest organoleptic o ratings (Table 2c). In particular, it had an exceptionally strong pineapple smell, similar to that for pineapple prior to drying, with almost no foreign smell. In addition, it was characterised by low brittleness.

Slices of rehydrated pineapple which had been dried in accordance r r with the invention were characterised by a hardness close to that of the slices of pineapple prior to drying. This feature is 0 0 6 20 important in the use of dried fruit for the production of breakfast mixtures to which liquids, for example, milk are normally added. Also in those slices of pineapple which were o0 rehydrated after being dried in accordance with the invention, the a 0 most intense pineapple aroma was recorded. The highest level of foreign smell, as in the case of mango, was noticed in the rehydrate obtained from the freeze-dried material. These results are in line with those acquired from the analysis of volatile compounds as shown in Figs. 9 and 12.

Kiwi Kiwi slices dried in accordance with the invention had low brittleness and a high level of kiwi flavour retention. The freeze-dried material also had a high level of kiwi flavour retention, but was otherwise light in colour and brittle.

After rehydration, the structure became too soft and a strong offflavour and odour developed in the freeze-dried and conventionally air-flow dried materials. The kiwi dried in accordance with the invention was superior to all others tested in colour retention and was rated substantially better than the others in flavour and odour after rehydration.

Papaya The papaya slices dried by conventional air-flow drying received generally average rankings, while after rehydration it received 10 low rankings. Papaya dried in accordance with the invention displayed higher intensity of taste-flavour compounds typical for papaya prior to drying, and the lowest presence of foreign taste

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and off-flavour. The freeze-dried material received higher A rankings in general in the dry state, compared to conventional air-flow dried material, while after rehydration the density of compounds responsible for undesirable taste and odour significantly increased. All papaya fruit products, both in dry •form and after rehydration, displayed fair colour with no indication of browning. The rehydrated papaya which had been dried in accordance with the invention received substantially higher rankings than the papaya dried using the other processes.

Ginger The freeze-dried ginger slices displayed fair colour and a high degree of brittleness. The highest level of ginger flavour with almost no foreign smell was observed in material dried in accordance with the invention. Relatively good quality was displayed by the conventional air-flow dried material except for significant browning which was reflected in the hue evaluation and the general quality ranking. In all dried products, the density of volatile compounds giving the typical ginger fragrance decreased after rehydration, while the intensity of foreign odour returned to the level typical for ginger prior to drying. The rehydrated ginger which had been dried in accordance with the invention received a slightly higher overall rating compared to the rehydrated ginger which had been dried according to the other techniques.

Hue Table 4 presents the colour coordinates determined in the Hunter L*a*b* apparatus for various materials before and after drying.

The materials dried in accordance with the invention exhibited superior colour retention and colour stability after rehydration in all cases.

•Other Observations S...r 10 Capacity for rehydration •..The highest capacity for water absorption (rehydration) was shown by the dried papaya and ginger dried in accordance with the invention. In the case of the kiwi, the conventionally air-flow dried material had a slightly higher rehydration capacity than the material dried in accordance with the invention. The freeze-dried material of the various fruits and tubers tested indicated the lowest levels of rehydration capacity compared to the others.

Water activity S- The water activity measurements (Table 6) indicate that all the tested dried materials were completely protected against microbiological deterioration. Thus, these materials would not require any additional treatment to ensure preservation, other than packaging because of their high hygroscopicity. The pineapple dried in accordance with the invention had the highest water activity value, which is in line with the dry mass measurements and the organoleptic assessments. The water activity value for all of the tested materials dried in accordance with the invention were less than 0.41, which indicates that they were completely protected against microbiological decomposition.

Ascorbic acid content The results of tests for the presence of ascorbic acid in the materials before and after drying can be found in Table 7. For the mango and the pineapple dried in accordance with the invention, there were only insignificant losses of vitamin C during processing. Thus, the mango dried in accordance with the invention retained approximately 98% of the vitamin C content of the mango prior to drying. Similarly, the pineapple dried in accordance with the invention retained 92%. The mango and pineapple slices dried by conventional air-flow drying exhibited greater losses of vitamin C, 20% for the mango and 16% for the pineapple. A comparison of the vitamin C losses in the materials 10 dried in accordance with the invention and freeze-dried materials allows one to conclude that the proportion of vitamin C preserved in the former is exceptionally high.

Goes "e Because bananas contain a very high level of native enzymes from the group of oxidases, drying brought about a very strong fall in the content of ascorbic acid. The highest preservation rate of ascorbic acid (about 15%) was found in thebananas dried in accordance with the invention. For the freeze-dried bananas, the *0ee preservation rate was about 14%. The conventionally air-flow dried bananas had a vitamin C loss in the range of 98%, meaning that there was nearly complete destruction of the vitamin C in that material.

The kiwi dried in accordance with the invention had practically no ascorbic acid losses. In the freeze-dried kiwi, 80% of the vitamin C was preserved.

Presence of carotenoids and of beta-carotene The results of the tests, given in Table 8, indicate that all species of materials tested retain a similar high level of bcarotene and carotenoids. Thus, each of the drying processes results in a small loss of these elements. Pineapple dried in accordance with the invention demonstrated superior results in the retention of b-carotene.

Level of nitrates and nitrites The level of nitrates and nitrites in the fresh and dried materials tested is below the accepted maximum value given by FAO/World Health Organisation and the Polish National Hygiene Office. With respect to the presence of the above mentioned compounds in these materials, they can be consideredcompletely acceptable for consumption by adults and children.

Composite products using materials dried in accordance with the invention 10 Materials dried in accordance with the invention can be added to oooo o composite food preparations. For example, dried apple or banana "slices may be added to a mixture to be baked for making a cake.

Dried fruit slices as such or dried fruits in powder form may also be advantageously used as additives to sugar syrup, jams, marmalades, yogurt, sauces, for example, salad dressing, gelatinous products, for example, a mixture of dry gelatine and dried particles of fruits or herbs, and so on.

After drying, herbs, spices, vegetables and the like are advantageouslycut into small particles and are possibly mixed 20 with salts or other seasoning materials.

Use of the inventive processes as a pre-treatment Tests made on various dried materials, for example, apple slices, have shown that the product of the invention had a higher vitamin C content than freeze-dried apple slices. Because of this high retention of vitamin C content, the process of the invention can be used as a prior treatment so as to increase the concentration of the structural components of the material being dried, including vitamin C content, and to increase the efficiency of another process for which the material is to be used, without significant degradation of those components. The process of the invention can therefore be used, for example, for the drying of a culture medium containing microorganisms so as to have dried material with a higher concentration of the component sought in 81the process.

Processes according to other embodiments of the invention can also be carried out by means of the-apparatus shown in Fig. 1, and this will be readily apparent to those skilled in the art.

While the apparatus of Fig. 1 which has been described for carrying out the dehydration process according to the invention, provides for carrying out the dehydration processes of the invention as batch processes, it will be readily apparent to those skilled in the art that other suitable apparatus may be provided Sosog so that the processes according to the invention may be carried 0066out as continuous processes.

*It is also envisaged that it is not essential that the same drying medium, subject to the addition of fresh drying medium be used in the complete drying process. For example, it is envisaged that the SOSO 15. product may be conveyed on a production line through a number of go..different drying chambers in which different drying media would be 06used. However, in such cases, the temperature and relative humidity of the drying media in general would be regulated in the various drying chambers so that the change in drying medium temperature and relative humidity to which the product is subjected in the transition from one drying chamber to another would be gradual, and would be substantially similar to that .0already described with reference to Figs. 6 and 7. Furthermore, it is envisaged that where the product is transferred from one drying chamber to another in a drying process, the drying medium may be circulated a number of times through the respective drying compartments, and then may subsequently be circulated to-the next drying chamber in sequence.

It will of course be appreciated that the dehydrating processes for dehydrating various fruits and tubers which have been described above may be varied without departing from the scope of the invention. The examples of the inventive drying process 82 described have been given-purely for the purpose of describing the best method known for carrying out the process according to the invention.

see* .5*00 .00 00 0000 0000 0.00.

Claims (42)

1. A process for dehydrating a product by urging a gaseous drying medium into contact with the product in a chamber, wherein the temperature and relative humidity of the drying medium are controlled so that the rate of water removal from the product is such as to minimise damage to the cellular integrity of the product during the drying process, the relative humidity of the drying medium in the chamber is allowed to rise to a maximum value which lies within the range of 30% to 70% and 10 on the value of relative humidity of the drying medium reaching the maximum value, the relative humidity of the drying medium in the chamber is maintained substantially constant at the maximum °value, or is permitted to only gradually decrease by maintaining the relative humidity of the drying medium being delivered to the 15 chamber substantially constant, until the relative humidity of the drying medium in the chamber commences to fall or commences to fall at an increasing rate. A process as claimed in Claim 1 in which the temperature and relative humidity of the drying medium are.controlled so that the cellular integrity of at least 50% of the cells of the product not adjacent to a face of the product is maintained during the drying process. see*

3. A process as claimed in Claim 2 in which the temperature and *""relative humidity of the drying medium are controlled so that the cellular integrity of the product is substantially maintained during the drying process.

4. A process as claimed in any one of the preceding.claims in which the rate of water removal from the product is such as to minimise damage to the structural integrity of the product during the drying process. A process as claimed in any one of the preceding claims in which the structural integrity of at least 50% of the cells of the 84 product not adjacent to a face of the product is maintained during the drying process.

6. A process as claimed in Claim 5 in which the structural integrity of the product is substantially maintained during the drying process.

7. A process as claimed in any one of the preceding claims in which the relative humidity of the drying medium is controlled so that the difference between the relative humidity of the drying medium and the equilibrium relative humidity of the product does not exceed 70% relative humidity. *foe 4 a ese. 0000 a 660 **so *000 Go** 0O a. a 0 0 009 0 S S@ Se 0 S

8. A process as claimed in humidity of the drying medium between the relative humidity equilibrium relative humidity relative humidity.

9. A process as claimed in humidity of the drying medium between the relative humidity equilibrium relative humidity 20 relative humidity. Claim 7 in which the relative is controlled so that the difference of the drying medium and the of the product does not exceed Claim 8 in which the relative is controlled so that the difference of the drying medium and the of the product does not exceed A process as claimed in any one of the preceding claims in which the maximum value of medium in the chamber lies the relative humidity ofthe drying in the range of 50% to

11. A process as claimed in Claim 10 in which the maximum value of the relative humidity of the drying medium in the chamber lies in the range of 50% to

12. A process as claimed in any one of the preceding claims in which the relative humidity of the drying medium in the chamber is permitted to fall off relatively rapidly after the fall in relative humidity of the drying medium has commenced or the rate of fall of the relative humidity of the drying medium has commenced to increase, until the water content of the product is approaching the desired water content and the rate of evaporation of water from the product becomes substantially independent of the drying medium.

13. A process as claimed Claim 12 in which on the rate of evaporation of water from the product becoming substantially *00 G independent of the drying medium, the relative humidity of the 10 drying medium is controlled to asymptotically approach a 000: predetermined value of relative humidity which provides the product dried to the desired water content. S 14. A process as claimed in Claim 13 in which the predetermined value of relative humidity is lower than the equilibrium relative humidity of the product which corresponds to the. desired water content, and the difference between the predetermined relative 0humidity of the drying medium and the equilibrium relative 1 "humidity of the product corresponding to the desired water content is in the range of 20% to 40% relative humidity.

15. A process as claimed in Claim 14 in which the difference between the predetermined value of relative humidity and the *SaP eo, equilibrium relative humidity of the product corresponding to the desired water content is in the range of 25% to 35% relative humidity.

16. A process as claimed in Claim 15 in which the difference between the predetermined value of relative humidity and the equilibrium relative humidity of the product corresponding to the desired water content is approximately 30% relative humidity.

17. A process as claimed in any one of Claims 13 to 16 in which the relative humidity of the drying medium is maintained substantially at the predetermined value of relative humidity for a time period in the range of 30 minutes to 120 minutes.

18. A process as claimed in any one of the preceding claims in which the drying medium is circulated through the chamber so that the speed of the drying medium relative to the product lies in the range of 1 M per second to 3 M per second.

19. A process as claimed in Claim 18 in which the drying medium is circulated through the chamber so that the speed of the drying ,-medium relative to the product lies in the range of 1.5 M per second to 2.5 M per second. 09.0..

20. A process as claimed in Claim 19 in which the drying medium is circulated through the.chamber so that -the speed of the drying medium relative to the product lies in the range of approximately 2 M per second.

21. A process as claimed in any one of the preceding claims in 15 which during the period-while the relative humidity-of the drying medium in the chamber is being maintained substantially constant or is only gradually decreasing, the relative humidity of the Sdrying medium in the chamber is not more than humidity lower than the equilibrium relative humidity of the product. *00* A process as claimed in Claim 21 in which during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant or is only gradually decreasing, the relative humidity of the drying medium in the chamber is not more than 40% relative humidity lower than the equilibrium relative humidity of the product.

23. A process as claimed in Claim 22 in which during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant or is only gradually decreasing, the relative humidity of the drying medium in the chamber is not more than 30% relative humidity lower than the equilibrium relative humidity of the product.

24. A process as claimed in any one of Claims 12 to 23 in which during the period while the relative humidity of the drying medium in the chamber is falling relatively rapidly, the relative humidity of the drying medium is controlled so that the relative humidity of the drying medium in the chamber is not more than relative humidity lower than the equilibrium relative humidity of i the product. nee •0M 10 25. A process as claimed in Claim 24 in which during the period 0while the relative humidity of the drying medium in the chamber is S falling relatively rapidly, the relative humidity of the drying medium is controlled so that the relative humidity of the drying medium in the chamber is not more than 60% relative humidity lower than the equilibrium relative humidity of the product. 0* f'

26. A process as claimed in Claim 25 in which during the period ,•while the relative humidity of the drying medium in the chamber is S falling relatively rapidly, the relative humidity of the drying medium is controlled so that the relative humidity of the drying medium in the chamber is not more than 50% relative humidity lower than the equilibrium relative humidity of the product. 00*5

27. A process as claimed in any one of the preceding claims in which the drying medium is recirculated.

28. A process as claimed in Claim 1 in which the relative humidity of the drying medium in the chamber is controlled by the introduction of fresh drying medium into the recirculating drying medium, and the rate at which the fresh drying medium is introduced does not exceed 21% by weight of the mass flow rate of the drying medium.

29. A process as claimed in Claim 28 in which the rate at which the fresh drying medium is introduced does not exceed 15% by weight of the mass flow rate of the drying medium. A process as claimed in Claim 29 in which the rate at which the fresh drying medium is introduced does not exceed 10% by weight of the mass flow rate of the drying medium.

31. A process as claimed in Claim 30 in which the rate at which the fresh drying medium is introduced does not exceed 7% by weight of the mass flow rate of the drying medium. S32. A process as claimed in Claim 31 in which the rate at which *OOOS 10 the fresh drying medium is introduced does not exceed 4% by weight S•,o of themass flow rate of the drying medium.

33. A process as claimed in any one of the preceding claims in which fresh drying medium is introduced at a substantially constant rate of not more than 7% by weight of the mass flow rate 15 of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity. So°° o o. 0

34. A.process as claimed in Claim 33 in which fresh drying medium is introduced at a substantially constant rate of not more 20 than 5% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity. A process as claimed in Claim 34 in which fresh drying medium is introduced at a substantially constant rate of not more than 4% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity. 89

36. A process as claimed in Claim 35 in which fresh drying medium is introduced at a substantially constant rate of not more than 3% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value of relative humidity.

37. A process as claimed in Claim 36 in which fresh drying medium is introduced at a substantially constant rate of not more than 2% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium 0600 in the chamber is being maintained substantially constant at the S maximum value of relative humidity. 0:o 38. A process as claimed in Claim 37 in which fresh drying medium is introduced at a substantially constant rate of not more than 1% by weight of the mass flow rate of the drying medium during the period while the relative humidity of the drying medium see* in the chamber is being maintained substantially constant at the •6 maximum value of relative humidity.

39. A process as claimed in any one of Claims 12 to 38 in which during the period while the relative humidity of the drying medium in thechamber is falling relatively rapidly, fresh drying medium is introduced at a rate of not more than 21% by weight of the mass •flow rate of the drying medium. A process as claimed in Claim 39 in which the rate at which fresh drying medium is introduced is increased from the beginning of the period to the end of the period during which the relative humidity of the drying medium in the chamber is falling relatively rapidly.

41. A process as claimed in any one of Claims 27 to 40 in which no fresh drying medium is introduced into the recirculating drying medium until the relative humidity of the drying medium has reached its maximum value.

42. A process as claimed in any one of Claims 27 to 41 in which during the period while therelative humidity of the drying medium in the chamber is asymptotically approaching the predetermined value of relative humidity fresh drying medium is introduced at a rate of not more than 5% by weight of the mass flow rate of the drying medium.

43. A process as claimed in any one of Claims 27 to 41 in which fresh dryingmedium is introduced through an inlet opening and Of: 10 exhaust drying medium is exhausted through an outlet opening, the size of the inlet and outlet openings being controlled as a Sfunction of the nominal exposed surface area of the product in accordance with a Modulation Index (MI) which is defined as: MI Kp x-NSP (Sen Se)/(Sen x Sex) where Sen is the cross-sectional area of the inlet opening for make-up fresh drying medium, *0@0 Sex is the cross-sectional area of the outlet opening for exhaust drying medium, and fees NSP is the nominal exposed surface area of the 20 product, and Kp is a constant whose value depends onthe product being dried and the pressure/flow characteristics of the drying S medium, and during the period while the relative humidity of the S drying medium in the chamber is being maintained substantially constant at the maximum value, the value of the Modulation Index lies in the range of 1,000 to 10,000.

44. A process as claimed in Claim-43 in which during the period while the relative humidity of the drying medium in the chamber is being maintained substantially constant at the maximum value, the value of the Modulation Index lies in the range of 2,000 to 8,000. A process as claimed in any one of the preceding claims in which the temperature of the drying medium is controlled not to rise to or above a degradation temperature which would cause irreversible thermal damage to the product.

46. A process as claimed in any one of the preceding claims in which the temperature of the drying medium does not exceed

47. A process as claimed in Claim 46 in which the drying medium is maintained at a temperature within the range to 70 0 C.

48. A process as claimed in Claim 47 in which the drying medium is maintained at a temperature within the range to

49. A process as claimed in any one of the preceding claims in which initially the temperature of the drying medium rises to a maximum value.

50. A process as claimed in claim 49 in which on reaching its maximum, the temperature of the drying medium is maintained substantially constant thereafter.

51. A process as claimed in any one of the preceding claims in which the drying medium is air.

52. A process as claimed in any one of the preceding claims in which the drying medium is nitrogen.

53. A process as claimed in any one of the preceding claims in which the drying medium is nitrogen-enriched air.

54. A process according to any one of claims 1 to 53 substantially as hereinbefore described with reference to the examples and Figure 1 of the accompanying drawings. 7 April 2000 A dried product dried by the process substantially as hereinbefore described with the examples and to the accompanying drawings. of claim 1 reference to DATED: 7 April 2000 CARTER SMITH BEADLE Patent Attorneys for the Applicant: DTL S.A. MAW:NP:#27211.RS2 7 April 2000