AU692507B2 - Method and cleaning agent composition for cleaning the barrel of a gun - Google Patents

Method and cleaning agent composition for cleaning the barrel of a gun Download PDF

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Publication number
AU692507B2
AU692507B2 AU13879/95A AU1387995A AU692507B2 AU 692507 B2 AU692507 B2 AU 692507B2 AU 13879/95 A AU13879/95 A AU 13879/95A AU 1387995 A AU1387995 A AU 1387995A AU 692507 B2 AU692507 B2 AU 692507B2
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AU
Australia
Prior art keywords
cleaning method
barrel
document
foam
cleaning
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Ceased
Application number
AU13879/95A
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AU1387995A (en
Inventor
Markku Paananen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milfoam Oy
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Milfoam Oy
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Filing date
Publication date
Application filed by Milfoam Oy filed Critical Milfoam Oy
Publication of AU1387995A publication Critical patent/AU1387995A/en
Application granted granted Critical
Publication of AU692507B2 publication Critical patent/AU692507B2/en
Assigned to MILFOAM OY reassignment MILFOAM OY Alteration of Name(s) in Register under S187 Assignors: KOIVULUOMA, MARJA
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • C11D3/048Nitrates or nitrites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41AFUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
    • F41A29/00Cleaning or lubricating arrangements
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/16Metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Coin-Freed Apparatuses For Hiring Articles (AREA)

Abstract

The invention relates to a method for cleaning the barrel of a firearm, whereby a foam containing an agent that removes bullet residue is applied into the firearm barrel to be cleaned, the foam is allowed to act for 0.1 - 30 minutes, whereupon the foam is removed from the barrel.

Description

I I 7 I I WO 96/21837 PCT/F]95/00006 la0 Method and cleaning agent composition for cleaning the barrel of a gun.
The prefent invention relates to a method for cleaning the barrel of a firearm as presented in claim i.
The barrel of a firearm has to be cleaned at regular intervals to remove the remnants of bullets and combustion residue such as soot, powder and burnt grease, accumulated in the barrel. In this context, bullet remnants means the metal residue left in the barrel from bullets, such as, in the case of commonly used bullets containing copper, residue of copper, possible copper compounds and other alloyed metals, e.g. copper and zinc residue and, in the case of lead bullets, lead residue.
Various methods and cleaning agents for the cleaning of a gun barrel are known. However, current cleaning methods often involve mechanical cleaning by scrubbing the barrel with a hard brush, such as a bronze brush. For example, in a commonly used cleaning method the cleaning agent contains aluminium particles which scrub off impurities from the barrel surface during mechanical cleaning.
Mechanical scrubbing is a laborious and timeconsuming operation. Naturally it also causes wear of the barrel surface, thus shortening the service life of the firearm.
To remove the copper residue left in the barrel from copper bullets, cleaning agents acting chemically on copper have also been tried. This type of cleaning agents usually contain ammonia, and the problem has been that ammonia is very volatile, i.e. the cleaning agent quickly becomes ineffective as the active component evaporates. Furthermore, when such cleaning agents are used, the barrel must nevertheless be cleaned mechanically as well, so they do not eliminate the drawbacks associated with mechanical clea- -L i, I II I~--II I WO 96/21837 PCT/FI95/00006 ning. Moreover, the evaporating gases are detrimental and undesirable. EP specification 75 113 presents a composition of substances that contains ammonia or amine compounds mixed in a gel to prevent evaporation.
In addition, the commonest cleaning agents currently used are relatively expensive.
The object of the present invention is to eliminate the drawbacks referred to above.
A special object of the invention is to produce an effective cleaning method of a new type that reduces the need for mechanical cleaning and thus significantly extends the serv; life of the barrel.
A further object o. the invention is to produce a new type of cleaning method that is faster and more user- friendly than earlier methods.
As for the features characteristic of the invention, reference is made to the claims.
The invention is based on the unexpected observation made during investigations that bullet residue can be removed by using a foam that, in the case of bullets containing copper, contains an alkaloamine and, in the case of bullets containing lead, a nitrate salt. Thanks to the invention, a method has now been discovered that makes it possible to effectively and quickly remove the metal residue left by bullets in a barrel, without damaging the steel of thebarrel.
In the method of the invention, ammonia can also be used for the cleaning of a barrel because the foam prevents evaporation of ammonia, so the cleaning agent does not lose any of its effectiveness.
For the first time, the present invention produces a firearm cleaning method that uses a foam containing substances that remove bullet residue. The foam to be used can be produced by using a tenside.
The tenside may be any commonly used, foam-producing surface-active substance, such as coconut diethanolamide.
I I I II I WO 96/21837 PCT/FI95/I006 3 Further, nitrate salt has now been used for the first time as a material that chemically removes bullet residue. It was observed during investigations carried out that lead residue in a barrel reacts due to nitrate salt in a way that allows the lead to be removed from the barrel surface without mechanical scrubbing. The nitric salt used is preferably an inorganic nitrate, such as alkaline nitrate, alkaline earth nitrate or ammonium nitrate, especially sodium nitrate. In the method of the invention, the cleaning can be performed by using any substance that forms a foam, preferably a consistent foam, that contains e.g.
exclusively nitrate salt, in which case it is applicable for the cleaning of firearms using lead bullets.
The pH of the nitrate salt solution is preferably adjusted to an alkalic value if necessary. However, e.g.
in the case of sodium nitrate, no pH adjustment is needed. There is no indication that, when used in the manner described, nitrates cause wear of the steel material of the barrel. The reaction product is removed automatically from the barrel surface, or it can be removed by using only a soft felt plug, i.e. without actual mechanical scrubbing. Thus, when the method of the invention is used, bullet residue can be effectively removed from the barrel by wiping it with a material or plug commonly used for the cleaning of firearms, without damaging the steel material of the barrel.
In an embodiment of the method of the invention, preferably a consistent foam containing an alkanolamine and/or a nitrate salt is used, in which case the method is applicable for the cleaning of both firearms using lead bullets and firearms using copper/copper compound bullets. In addition to its primary purpose in the method of the invention, the alkanolamine can also be used for the adjustment of the pH of the solution to an alkalic value in connection with
M
WO 96/21837 PCT/FI95/00006 4 solutions containing a nitrate salt. The alkanolamine is preferably monoethanolamine or diethanolamine or a compound of these, especially monoethanolamine.
In the cleaning method of the invention, a foam is used that contains about 1 80 preferably about 20 70 nitrate salt, such as sodium nitrate, and/or about 1 70 preferably about 1 e.g. 2 25 alkanolamine, such as monoethanolamine or diethanolamine.
In the method of the invention, a foam is used that preferably additionally contains an organic solvent for the removal of combustion residue such as soot, gunpowder remnants and/or burnt grease. For this purpose, any solvent or solvents, especially a watersoluble/mixable solvent, may be used. In an especially advantageous case, the composition contains under e.g. 1 15 methylpyrrolidone and/or under e.g. 1 15 butoxyethanol, which have proved to be effective in removing combustion residue.
The amount of tenside used in the cleaning method is e.g. under 50 e.g. about 0.1 25 w-% of the composition, depending on the intended application.
The foam used in the cleaning method may further contain about 1 90 added water. By varying the amount of water, it is possible e.g. to adjust the concentrations of the active substances as desired. The amount of water added may be e.g. 5 In a preferable embodiment, an amount of under 15 e.g. about 0.1 3 of sodium salt of m-nitrobenzenesulfonic acid has been added to a composition containing alkanolamine to assist in removing from the barrel surface the reaction products formed by residue from bullets containing copper.
The composition used in the method of the invention may additionally contain an amount of about I' I WO 96/21837 PCT/FI95/00006 0.1 30 e.g. 1 10 of a barrel protecting substance, such as commonly known arms oil or preferably so-called cutting lubricant, which may be of semisynthetic or synthetic type and which prevents copper from sticking to the barrel. The agent used for barrel treatment may be a water-mixable substance or it can be emulsified in water using e.g. a tenside and/or solvent, such as butoxyethanol.
The composition of substances used in the method of the invention can be implemented in any suitable form. Preferably the composition is in the form of a foaming liquid or, suitably, in the form of a spray sprayable as a foam, in which case it is packed in a container equipped to produce a spray, together with propellants if required. The composition may also contain an agent that increases viscosity.
In the following, the invention is described in greater detail by the aid of examples, which are only intended to illustrate the invention without limiting it.
ExamDle 1: Producing a composition of substances for use in the cleaning method of the invention.
A cleaning solution composed according to one of the following alternatives is prepared: prefer- composition Components red A B C D E coconut diethanolamide 0.1-50 4 25 2 3 monoethanolamine 0-70 1-30 25 2 15 sodium nitrate 0-70 20-70 40 20 70 methylpyrrolidone 0-30 1-15 5 15 5 10 1-butoxyethanol 0-30 1-15 5 15 5 10 sodium salt of m-nitrobenzenesulfonic acid 0-30 0.1-3 1 3 2 I r 111 1 WO 96/21837 PCT/FI95/00006 6 semi-synthetic cutting lubricant 0-30 1-10 10 10 10 water added 0-60 1-30 10 10 12 When compounding the components, the sodium nitrate is solved in the water added. It can also be added to other components in the form of a rich water solution. Instead of monoethanolamine, other alkanolamines can also be used, such as diethanolamine. When the composition is produced in the form of a foaming liquid, the formulation is performed by using a tenside in an amount of e.g. about 0.1 30 When the composition is produced in the form of a .spray, the amount of tenside used is e.g. 0.1 4 The concentrations of active components are selected e.g. on the basis of the length of time the cleaning agent is to be allowed to act in the barrel. This action time may vary e.g. between 0.1 30 min., whereupon the composition is removed by using a plug of a medium, e.g. a felt plug.
The finished composition has an alkalic pH value. The cleaning method of the invention is less hazardous to the user and the environment than earlier methods and the composition emits no toxic gases as compared with previous compositions. Moreover, consisting of cheap components, it is advantageous in respect of cost. The composition used does not suffer any loss of efficiency during storage or use. Furthermore, the composition used in the method protects the barrel, and the addition of cutting oil has the effect that a smaller amount of bullet residue, such as copper, sticks to the barrel surface.
Generally, the cleaning method of the invention is applicable for the cleaning of the barrel part of a firearm of any type and any size.
-r 111 WO 96/21837 PCT/F195/00006 7 Example 2: An experiment was carried out to test the effectiveness and applicability of a cleaning method as provided the invention, designed for firearms using copper/copper compound bullets.
Composition of the foam used in the method Components w-% monoethanolamine methylpyrrolidone ca. l-butoxyethanol ca. sodium salt of m-nitrobenzenesulfonic acid ca. 1 coconut diethanolamide ca. 4 water added ca. semi-synthetic cutting lubricant ca. The composition was prepared in the form of a spray. To clean a firearm, the foaming alkalic composition was sprayed into the barrel and allowed to act for ca. 10 min., whereupon it was removed by pushing a felt plug through the barrel.
The firearm cleaning method was tested in field conditions during half a year. It was established that the cleaning method worked in -cold and hot weather. Moreover, the method was found to be effective and easy to use.
In comparing a barrel cleaned by Lhe method of the invention was compared with a barrel cleaned by the traditional mechanical method, the barrels were inspected using an endoscope and it was established that the barrel treated by the method of the invention was in a considerably better condition, i.e. it showed less wear and burn damage, than the reference barrel.
It is estimated that, by using the cleaning method of I 'r WO 96/2 1837 PCT/F95/020006 the invention, the service life of a firearm is extended by about 50

Claims (13)

  1. 2. Cleaning method as defined in claim 1, characterized in that the agent is allowed to be acti- ve in the barrel for 1 20 minutes.
  2. 3. Cleaning method as defined in claim 1 or 2, characterized in that the foaming agent used is a tenside.
  3. 4. Cleaning method as defined in any one of claims 1 3, characterized in that the foaming agent used is coconut diethanolamide. Cleaning method as defined in any one of claims 1 4, characterized in that the proportion of foam material is under 50 e.g. 0.1 25 of the whole amount of the composition.
  4. 6. Cleaning method as defined in any one of claims 1 5, characterized in that the foam material is introduced into the firearm barrel in liguid state and foamed by drawing a plug of a medium through the barrel.
  5. 7. Cleaning method as defined in any one of claims 1 6, characterized in that the foam is spray- ed into the firearm barrel from a spray bottle.
  6. 8. Cleaning method as defined in claim 7, characterized in that the foam is sprayed from a spray bottle through an elastic sealing fitted on the end of the barrel.
  7. 9. Cleaning method as defined in any one of claims 1 8, characterized in that the substance used for removing bullet residue is an alkanolamine and/or an inorganic nitrate. 71 r -1 II~IIBLII WO 96/21837 PCT/FI95/00006 Cleaning method as defined in any one of claims 1 9, characterized in that the alkanolamine used is monoethanolamine and/or diethanolamine.
  8. 11. Cleaning method as defined in any one of claims 1 10, characterized in that the nitrate salt used is an inorganic nitrate, such as sodium nitrate.
  9. 12. Cleaning method as defined in any one of claims 1 11, characterized in that the method invol- ves the use of a foam containing a solvent designed to remove combustion residue.
  10. 13. Cleaning method as defined in any one of claims 1 12, characterized in that it involves the use of a foam that contains under 50 preferably 1 15 methylpyrrolidone and/or under 50 prefe- rably 1 15 butoxyethanol.
  11. 14. Cleaning method as defined in any one of claims 1 13, characterized in that it involves the use of a foam that contains about 0 90 water ad- ded. Cleaning method as defined in any one of claims 1 14, characterized in that it involves the use of a foam that, in conjunction with the alkanola- mine, contains under 5 sodium salt of m- nitrobenzenesulfonic acid.
  12. 16. Cleaning method as defined in any one of claims 1 15, characterized in that it involves the use of a foam that contains a substance lubricating and protecting the firearm barrel, such as semi- synthetic or synthetic cutting lubricant or arms oil.
  13. 17. Composition of cleaning agents for the cleaning of the barrel of a firearm, said composition containing a substance removing bullet residue, cha- racterized in that the composition contains a tenside, and that the substance removing bullet residue is an alkanolamine and/or a nitrate salt, and that the com- -Y~C~I WO 96/21837 PCTLFJ95/00006 position is in the form of a foam according to any one of claims 1 16. 1 1N'ERNATIONAL SEARCIH REPO WI' nternational application No. PCT/FI 95/00006 A. CLASSIFICATION OF SUBJECT MATTER IPC6: F41A 29/00 According to International Patent Classification (IPC) or to both national classification and IPC B. FIELDS SEARCHED Minimum documentation searched (classification system followed by classiication symbols) IPC6: B08B, C11D, F41A Documentation searched other than minimum documentation to the extent that such documents are included in the fields searched SE,DK,FI,NO classes as above Electronic data base consulted during the international search (name of data base and, where practicable, search terms used) DIALOG C. DOCUMENTS CONSIDERED TO BE RELEVANT Category* Citation of document, with indication, where appropriate, of the relevant passages Relevant to claim No. A US 4482469 A PLoTZE), 13 November 1984 1 (13.11.84) A US 3037887 A BRENNER ET AL), 5 June 1962 1 (05.06.62) E,A WO 9507328 Al (CIOFFE, 16 March 1995 1 (16.03.95), page 4, line 5 line 32 S Further documents arc listed in the continuation of Box C. See patent family annex. Special categones of cited documents: T" later document published after the ittemational filing date or pnonty date and not L conflict with the application but cited to understand document defining the general state of the art which s not considered the pnnciple or theory underlying the invention to be of particular relevance erlier document but published on or after the international filing date document of particular relevance: the claimed invention cannot be considered novel or cannot be considered to involve an inventive document whi :h may throw doubts on priority claim(s) or which is step when the document is taken alone cited to establish the publication date of another citation or other special reason (as specified) document of particular relevance: the claimed invention cannot be document referring to an oral disclosure, use, exhibition or other considered to Involve an inventive step when the document is means combined with one or more other such documents, such combination document published prior to the international filing date bit later than being obvious to a person skilled in the art the priority date claimed document member of the same patent family Date of the actual completion of the international search Date of mailing of the international search report 2 3 -08- 1995 9 August 1995 Name and mailing address of the ISA/ Authorized officer Swedish Patent Office Box 5055, S-102 42 STOCKHOLM Jonas Lbfgren Facsimile No. 46 8 666 02 86 Telephone No. 46 8 782 25 00 Form PCT/ISA/210 (second sheet) (July 1992) e. INTERNAIONAL SEARCH REPOwR Information on patent family members International application No, 10/07/95 PCT/FI 95/00006 Patent document cited in search report US-A- 4482469 Publication Patent family member(s) 13/11/84 AU-A- DE-A- EP-A- 8791382 3135153 0075113 Dlublication date 10/03/83 24/03/83 30/03/83 US-A- 3037887 05/06/62 FR-A- 1268482 00/00/00 GB-A- 923281 00/00/00 WO-Al- 9507328 16/03/95 NONE Form PCT/ISA/210 (patent family annex) (July 1992) I
AU13879/95A 1995-01-10 1995-01-10 Method and cleaning agent composition for cleaning the barrel of a gun Ceased AU692507B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI1995/000006 WO1996021837A1 (en) 1995-01-10 1995-01-10 Method and cleaning agent composition for cleaning the barrel of a gun

Publications (2)

Publication Number Publication Date
AU1387995A AU1387995A (en) 1996-07-31
AU692507B2 true AU692507B2 (en) 1998-06-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
AU13879/95A Ceased AU692507B2 (en) 1995-01-10 1995-01-10 Method and cleaning agent composition for cleaning the barrel of a gun

Country Status (7)

Country Link
EP (1) EP0843806B1 (en)
AT (1) ATE217959T1 (en)
AU (1) AU692507B2 (en)
DE (2) DE69526806T2 (en)
ES (1) ES2177626T3 (en)
RU (1) RU2128319C1 (en)
WO (1) WO1996021837A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2544420C2 (en) * 2013-05-14 2015-03-20 Борис Васильевич Потапов Method of protection of bore of artillery system against soil particles getting into it
RU2702513C1 (en) * 2018-06-01 2019-10-08 Пётр Петрович Паринов Weapon cleaning composition
RU2719526C1 (en) * 2019-02-20 2020-04-21 Федеральное государственное казенное военное образовательное учреждение высшего образования "Рязанское гвардейское высшее воздушно-десантное ордена Суворова дважды Краснознаменное командное училище имени генерала армии В.Ф. Маргелова" Министерства обороны Российской Федерации Method of servicing small-calibre gun barrel channel

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3037887A (en) * 1959-05-04 1962-06-05 Dow Chemical Co Foam cleaning of surfaces
US4482469A (en) * 1981-09-04 1984-11-13 Ploetze Bodo Cleaning agent for fire-arm barrels
WO1995007328A1 (en) * 1993-09-10 1995-03-16 Anthony Cioffe Material and method for cleaning firearms and other metal ordnance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3037887A (en) * 1959-05-04 1962-06-05 Dow Chemical Co Foam cleaning of surfaces
US4482469A (en) * 1981-09-04 1984-11-13 Ploetze Bodo Cleaning agent for fire-arm barrels
WO1995007328A1 (en) * 1993-09-10 1995-03-16 Anthony Cioffe Material and method for cleaning firearms and other metal ordnance

Also Published As

Publication number Publication date
DE843806T1 (en) 1999-06-02
AU1387995A (en) 1996-07-31
WO1996021837A1 (en) 1996-07-18
EP0843806B1 (en) 2002-05-22
DE69526806D1 (en) 2002-06-27
DE69526806T2 (en) 2002-11-07
RU2128319C1 (en) 1999-03-27
EP0843806A1 (en) 1998-05-27
ATE217959T1 (en) 2002-06-15
ES2177626T3 (en) 2002-12-16

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