AU670556B2 - Printing on plastic films - Google Patents

Description

OPI DATE 19/07/93 APPLN. ID AOJP DATE 16/09/93 PCT NUMBER 30905/3092905 PCT/GB92/02266 I 11 111 AU9230905 (51) International Patent Classification 5 (II) International Publication Number: WO 93/11946 B41M 1/30, 5/03, 5/025 Al B41M 7/02, 3/14 (43) International Publication Date: 24 June 1993 (24.06.93) (21) International Application Number: PCT/GB92/02266 Published With international search report.

(22) International Filing Date: 7 December 1992 (07.12.92) Priority data: 9126048.9 7 December 1991 (07.12.91) GB (71)72) Applicant and Inventor: JENNINGS, Mark [GB/GB1; 0 9 Farnborough Rd, Birkdale, Southport PR8 3DF (GB).

(74)Agent: W.P. THOMPSON CO.; Coopers Building, Church Street, Liverpool LI 3AB (GB).

(81) Designated States: AT, AU BB, BG, BR, CA, CH, CS, DE, DK, ES, Fl, GB, HU, JP, KP, KR, LK, LU, MG, MN, MW, NL, NO, NZ, PL, PT, RO, RU, SD, SE, US, European patent (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE), OAPI patent (BF, BJ, CF, CG, CI, CM, GA, GN, ML, MR, SN, TD, TG).

(54)Title: PRINTING ON PLASTIC FILMS (57) Abstract By using particulate material to take up an ink, the ink can be transferred to a plastics film at a high level of fidelity. The plastics film can then be laminated with another plastics film for security purposes to give a security document. Humidity and laminating temperature can be varied to produce a document which does not bleed or which bleeds after a certain length of time, WO 93/11946 PCi/GB92/02266 -1- PRINTING ON PLASTIC FILMS

PRINTING

The present invention relates to printing and more particularly, though not exclusively, to the printing of plastics to produce documents which are harder to copy; it also relates to the construction of the document produced, intermediate products made, and their methods of manufacture.

With improvements in photocopying, documents can be more easily re-produced. Thus, the forging of documents is becoming a major problem. The range of documents being forged is vast. The production of security cards, money, tickets and membership cards are just some examples of the areas in which forging and copying is proving difficult to control.

Since paper documents also wear quickly there has been a desire to produce plastics documents of, for example, the type described. However, to date, the attempts to make plastics documents, which meet the needs of the user or operator, have not proved satisfactory.

One of the problems with printing onto plastics derives from the colourants used. Firstly, the colourants used can be removed from plastics by the use of solvents such as acetone, thereby leaving the documents open to alteration. To overcome this WO 93/11946 PC/G92/02266 -2problem attempts have been made to bond a further plastics layer over the printed layer thereby enclosing the ink. Two major problems have, however, become apparent. Firstly, it has been found that plastics, for example, PVC or polyester/polyethylene film will not fully bond to itself or each other where one or the other has been coloured wi.h an ink or dye stuff. It has also been found that printing directly onto plastics and then bonding a further plastic film thereto, thereby encapsulating the ink or dye, proves unsatisfactory since the ink or dye tends to run/bleed immediately or within a short time, resulting in a blurred print. Whilst this problem can be diminished by drying the ink using high powered infra-red or ultra-violet light, the process is time consuming and expensive.

It is an object of the invention to improve upon the known products and to devise a method for doing so. The present invention can be used to provide products which substantially do not bleed or which bleed at controlled rates.

In accordance with one aspect of the present invention there is provided a process for printing a plastics film comprising: printing a colourant onto a layer of material (preferably inorganic) of a particulate nature, which WO 93/11946 PCT/GB92/02266 -3material is releasably bound by a binder to a backing; transferring the colourant onto a first plastics film by placing the first plastic film over the printed layer and subjecting it to a substantially constant heat; removing the backing; and optionally bonding a second plastics film to the first plastics film, thereby encapsulating the colourant in the plastics.

By producing a document in this way, avoidance of bleeding of the inks used can be achieved, if desired, and, furthermore, if a second layer of plastics is bonded to the printed plastics layer it will bond even where colour has taken. This is thought to be because the ink plus the particulate material becomes bonded within the polyethylene. Also, by bonding a second layer thereto it becomes difficult or impossible to tamper with the first printed layer since the inks are enclosed within the plastics.

Preferably, the plastics film is a polyester film coated with polyethylene, such as that purchased from Morane (Banbury, under the trade name Morafast.

Other plastics, such as, for example, polyvinylchloride may be used, but the ink can be removed with acetone. However, the bonding properties of polyethylene make it preferred and the ink is, after bonding, unaffected by acetone. Thus, where a WO 93/11946 PCT/GB92/02266 -4polyethylene coated polyester film is used, it is preferred that the ink or dye is transferred to the polyethylene coated surface.

The colourant used may be any ink or dye but the following are preferred: diethylene glycol based ink using food dyes as colourants.

These inks are particularly favoured when used with polyethylene since they are cheap to use and print well.

The material of a particulate or colloidal nature is preferably silica, a sand, silicon, clay or chalk.

Silica is most preferred and is referred to throughout the remainder of the specification, although the above alternatives can be used also.

Preferably the particles are provided in a coating with latex PVA) or starch.

Preferably the backing is a dense paper exceeding per square metre to avoid tearing when the paper is removed, although other materials could be used.

Preferably, the paper has a low level of loose fibres c no loose fibres. Parchment paper is preferred and i: produced by dipping paper in conc. H 2

SO

4 and then washing.

The colourant or ink can be applied by hand, or by machine. Suitable machines include, for example, computer controlled printers, dot matrix, laser and WO 93/11946 PCT/GB92/2266 ink jet printers or printing plates etc, but ink jet printers are preferred.

The ink can be transferred to the plastics film by bringing the plastics film into contact with the surface of the material having a particulate nature, which material has been printed over, and subjecting it to a constant heat. This can be done by passing the two layers through a standard laminator. The temperature required will depend on the plastics used and the thickness of the sheets.

The backing layer, usually paper, can then be peeled off, with washing and scrubbing if necessary, to leave a printed plastics sheet which has absorbed the ink. Consequently, it is more difficult to remove the inks by the use of solvents than with conventionally printed plastics.

As pointed out above, printed plastics can also be bonded to a further plastic sheet to encapsulate the ink or dye making the product "tamper proof".

This is of particular importance in documents of a security nature.

According to a further aspect of the invention there is also provided a plastics sheet comprising thereon a layer of silica.

Preferably the particle size of most or substantially all the particles is from 5 microns to WO 93/11946 PCT/GB92/02266 -6- 0.006 microns in diameter, more preferably from 1pm to 0.006 pm.

The particle size can be determined by passing particles through a graded series of sieves and determining which sieves the particles will or will not pass through.

The plastics film used may be formed from any of the plastics hereinbefore mentioned, but the preferred plastics film is a polyester/polyethylene laminate.

Preferably the layer of particles is formed on the polyethylene side of the laminate.

Without wishing to be bound by theory it is believed that the improved printing quality derives from the colourant.being transferred to the plastics from the particles in a "dry state".

By using different loadings of silica, different types of document can be produced loadings of 4 to 8 g/m 2 (preferably 5-7 g/m) give transparent documents.

Loadings of 8-20g/m 2 (preferably 10 to 15 g/m 2 give opaque documents.

In order to produce documents which substantially do not bleed when the backing is removed, the layer of particulate or colloidal material preferably should not be exposed to an atmosphere of above 40% humidity for any lengthy period of time not for longer than 20 minutes). Desirably, the second plastics film WO 93/11946 PCT/GB92/02266 -7should then be laminated to the first plastics film at a temperature of at or above 350 0 F. This also applies to the silica, plastics layers and/or paper prior to being used for a product intended not to bleed.

In order to produce documents having printing which is initially legible but which later begins to bleed, the said layer preferably should be exposed to an atmosphere of above 40% humidity 40 to humidity). Also, the first plastics film can be subjected to a very fine water mist. Desirably the layer takes in no further moisture from the atmosphere. The second plastics film then desirably is laminated to the first at a temperature at or below 350 0

F.

Having printed onto the plastics, further additional steps can be taken to improve security, depending on the type of document being produced.

For a laminated document, for example, money, tickets etc. a mark akin to a "water mark" can be introduced. The mark, as it is hereafter referred may be produced as follows: A sheet of paper preferably with a weight in excess of 80 gms, but lower weights can be used, and having coated thereon fine particles of silica has a design embossed thereon using a metal ie or other means for embossing paper. Preferably, the impression WO 93/11946 PCr/GB92/02266 -8is made on the co--ed side so that the coated side is depressed, although it will work, though less effectively, the other way round. The embossed sheet, is then placed, particle side down over a first plastics sheet and the two sheets are passed through a laminator in the same way as has been described with reference to the transfer of inks from the coated sheet. The backing paper is then removed, and when a second plastics film is bonded to the first film, a mark is visible which mark contains no inks and does not appear to the hand to be raised or lowered in the end product.

Features of the invention will now be described, by way of example only, with reference to the following specific embodiments.

To produce a printed plastics document which also comprises a "watermark" the following procedure can be followed: A sheet comprising a parchment paper backing and having thereon a layer of silica, has a design printed on the silica layer. Th inks or dyes used are standard printing dyes and the design is applied by a computer controlled printer, printing plate or other means.

At another place along the sheet, preferably a place which has not been printed, a part of the coated WO 93/11946 PCT/GB92/02266 -9surface is raised by embossing the paper with a metal die having a raised design thereon.

The printed sheet is then covered, for example, with a 100 microns thick polyester plastics sheet with a 16 micron thick polyethylene coat on at least one side, so that the polyethylene coat faces the silica coated surface of the printed sheet. The two are heated to a temperature at which the polyethylene melts sufficiently to take up ink. For the sheet of the given ex.amples this temperature will desirably be between 32°C (90F) and 60 0 C (140 0 preferably about 38°C (about 100 0 and can be achieved by passing the respective sheets through, for example, a pouch or role laminator. It should be appreciated that the leatures exemplified above are not limiting. The polyester sheet is preferably above 30, e.g. up to 500 microns thick and the polyethylene coat is preferably from 12, up to 20 microns thick. It is desirable that the heat applied is constant and that sufficient pressure is exerted to expel any air from between the sheets.

The bac.ing paper is then removed. Generally it can be peeled off, but if it is well stuck down it can be soaked and scrubbed as necessary.

Where the paper was embossed, the raised parts caused the polyethylene to be "pushed out" as the PCr/GB92/02266 WO 93/11946 paper was laminated to the plastics. When another plastics layer is placed into contact with the sheet, the paper having been removed, and laminated a distinctive mark is left. The amount of heat used in lamination affects the clarity of the mark. The hotter the lamination the less clear the resulting mark. Generally a lamination temperature of greater than 49°C (120 0 F) is used.

Where lamination is used to encapsulate the ink it is possible, to incorporate other items between the sheets being laminated. Thus, for example, signature strips or electronic chips can be introduced and incorporated within the final product. In the laminate, desirably, the silica layer is sandwiched between two polyethylene layers.

The results given in Table 1 below show how the present invention can be used to produce documents of different bleed times: The Examples illustrated by the Table were performed using parchment paper and a diethylene glycol ink comprising a food dye. The ink was prepared by treating yellow food dye obtainable under the trade mark "GOLD SEAL" (from Clayton Jowett Ltd, Runcorn, England) until its volume was reduced by due to evaporation, 100 mls of the remaining liquid was then mixed with diethylene glycol to give a WO 93/11946 PCT/GB92/02266 -11level of 20% u/v glycol in the final ink. The paper was loaded with an even layer of silica at a particle size of 0.010 microns and at a level of 10 g silica/m 2 and was then printed with the dye. The printed layer was then placed against a polyester (150 microns thick) /polyethylene (16 microns thick) plastics film and heated at a temperature sufficient to transfer the printed layer to the plastics film polyethylene layer and the parchment paper was then removed. The resultant product comprising the plastics film and the printed layer was then left at the humidity level and exposure time given in the Table before finally laminating a second layer of the plastics material to the first layer at the temperature given in the Table.

The length of time taken for the ink used to bleed for the printing to become blurred to the naked eye) was determined by regular inspection and is given in the Table.

Bleeding could be effected with other ink jet inks provided that after removing the backing paper the layer of silica is exposed to an atmosphere of at least 40% humidity and the temperature at final lamination was below 177 0 C (350 0

F).

Yellow, magenta and cyan food dyes are obtainable under the trade mark "GOLD SEAL" and can be used to form ink jet inks as aforesaid, (except that WO 93/1'946 PCr/GB92/02266 -12rather than 50% of the volume of the dye is evaporated). By mixing these dyes in appropriate proportions different colours can be produced, as desired.

TABLE 1 Length of Temp.to Length Temp.

Time to Transfer Humidity of time at final Example Bleed Print Exposed Lamination 1 1 year 100*F 40 15 mins 325 0 F max.

2 6 months 100-200 0 F 75 30 mins. 325 0

F

3 1 month 100-200 0 F 75 60 mins. 325OF 4 2 weeks 100-200 0 F 40-50 60 mins. 3256F 1 week 100-200OF 75 3 hours 325"F It is desirable in certain circumstances for bleeding to occur after a given time. This is the case, for example, where a ticket or card is intended to be valid for a limited period only, the expiry of this period being indicated by bleeding of the ink.

By appropriate variation of humidity, temperature at final lamination and ink used, the time can be varied at which bleeding occurs.

By appropriate variation of these parameters cards can be produced which will normally only bleed after several months (see e.g. Example However, bleeding can be accelerated by puncturing or tearing the card to expose the silica to the atmosphere. One application of this is for consumer products having WO 93/11946 PCT/GB2/02266 -13labels. The label can be formed with a line or point of weakness to which it is attached via a tag, to the consumer product. When the label is removed from the tag, tearing along the line of weakness exposes the silica to accelerate bleeding.

Even if the label is somehow reattached to the clothing, bleeding can still occur. This is advantageous in avoiding fraud by indicating to shopkeepers when a label has been removed from the consumer product. In the case of clothing, this label, after being pierced, will then attract moisture from the body. If the label shows signs of slight bleeding where it was pierced, this will show the garment has just been "tried on". If the article is worn for more than two hours the whole of the label will have bled (given the label is 1" x However, the ink dues not come out of the label. A further refinement of this technique is for the tag of the label to be attached to the consumer product via adhesive which coats a removable holographic image on the tag. Thus, if it is attempted to remove the label by pulling at the tag and avoiding the line or point of weakness the label and tag can be removed together, but this destroys the holographic image. A label comprising the removable holographic image and adhesive is also within the scope of the present invention.

WO 93/11946 PCT/GB192/02266 -14- It has also been found that if a hologram printed on polyester and placed, e.g. in the centre of a number of various other sheets of printed laminate, then the special effects can be made which to date noone has been able to photocopy, or even copy using a scanning unit.

It has been found that anything printed above the hologram (which is itself transparent) if tilted to the light appears to become embedded within that hologram. Also, any part of the top-most layer, if the item is tilted accordingly, is all that can be viewed, so that in the case of a credit card, this top part could be printed with the name, signature and account number of an authorised user.

In one embodiment a hybrid document can be produced i.e. one embodying the printed plastics described with an insert of printed paper or a material which can be marked when pressure is applied thereto. Since the printed material used will eventually fade in time, it is preferred in some embodiments to coat the plastics'with a material which reflects ultra-violet light or to use an ultra-violet resistant polyester, which light is responsible for the fading.

In other embodiments, however, the fading of the ink due to exposure to U.V. light can be used PC1'/GB92/02266 WO 93/11946 advantageously. For example, tickets such as concert or football tickets may have certain information printed in an ink which on exposure to a high dosage of u.tra-violet light will be destroyed.

Furthermore, the following additional features can be included: 1. Only one part of an image or pattern may be applied to a document. The other part of the pattern is held by the person receiving the tickets at the entrance to the establishment (theatre, football ground, Wimbledon etc.). That person can then quickly place the transparent ticket over the template he holds and if the pattern/image is complete then that ticket is "passed". Also a fingerprint can be applied, and because of the transparent nature of the document this can be placed over a recorded fingerprint fozr verification.

2. A heat sensitive material or chemical may be used on the ticket so that a pre-defined number/pattern or image etc. shows up under certain conditions.

3. Fibre optics may be incorporated into a document.

They can be applied so that either: a) One or more fibres which have been etched via a laser or other means with either words or a design, are affixed on or between the laminate sheets so that when a light is applied to the edge of the card, where WO 93/11946 PC/G B9c2/02266 -16viewed from the front of the card. It has also been found that if the amount of light is measured at the start of the fibres, the amount of light received at the other end will depend on the amount and size of the words or design etched onto the fibres due to light being diverted through the design. Therefore the amount of light received at the end can be anticipated and measured and if the light does not reach or is over a certain level, then, the card/document will be suspect.

b) A number of fibres are set in such a way that light transmitted onto one edge of the card is received at another edge. Light sensors can then be used to detect the received light and to read it at an angle which is oblique to the direction in which light enters the card, and if the correct message is not received then the card is considered "suspect".

c) The fibres can be arranged in such a way that they can be read as a number i.e. using the same principle as a bar code. Each card can have its own unique number or bar code.

d) A fluorescent fibre can be also used whereby light is transmitted via the surface of the fibre to the fibre ends. These too can be etched and read by a light sensor/reader.

WO 93/11946 iPcr/GB2/02266 -17- If in the case of a credit card, for example, fibre optics are placed across the whole of the card information such as A/C number, name, etc., plus any other information, can be etched in and read by an automatic reader by moving the card relative to the reader.

Using this method a wealth of untamperable information can be held within the card so that a magnetic strip is no longer required. A magnetic strip can, however, be fixed/sprayed onto or into a product of the present invention if desired.

Generally, a person will read the transparent document against a plain background. If the document is placed against,'for example, a white background the details of the document will show up clearly.

In the case of a document that may be used where there is no suitable background to hand, a plain hinged back can be affixed to the document. The person inspecting the card can both see the card clearly, and by raising the flap can see that no changes or insertions have been made.

It has also been found that if a number of printed films are laminated together, the colour is enhanced. Also "3D" images can be made by the fact that for example: mountains and sky can be printed on a first film, trees and bushes on a second etc. If, as has been found, clear film is inserted between WO 93/11946 111CF/GB92)/02266 -18these printed films, an effective 3D effect can be made or at least some depth of field achieved.

Another addition to the security aspect includes printing a document so small, that it cannot be read by the naked eye, but can be read with the use of a magnifying glass.

In another embodiment security can be enhanced by applying a prism effect.

In this embodiment the plastics incorporates a number of prisms some running in one direction and some running in another. To read a document a correcting card is required or the card can be tilted to a certain angle to be able to read it.

In another embodiment, security can be enhanced by the addition of a foil, preferably metal which has been embossed with lettering or design. This foil is encapsulated between the sheets of plastics material.

Also, this foil can be encapsulated in a plane state so that with credit cards, if the card is stamped with round letters and/or numbers these can be easily read by the naked eye.

If an electrically conductive ink/dye/paint within the card is used, the card can be used as part of an electrical circuit or a switch to cause a short circuit to, say, light up a bulb or open a door (i.e.

as a key card).

WO 93/11946 PCr/GB2/02266 -19- Another embodiment of the invention is to print either some or all of the document with white ink/dye etc. This will stop photocopying, as no photocopier can print white.

Two other ways of printing in white are:- 1. To cut out shapes/letters/numbers etc. from the paper that has more than 10 microns of silica and to transfer this silica to the laminate, by the normal means of this invention, then on final lamination, this white print will remain.

2. To have a design/words/numbers etc. placed in the coating or rather on the coating of the paper at the time of manufacture, i.e. the first coating of less than 5 microns is applied, then, when dry, a second coating is applied using rollers that will leave the design required etc. proud of the first coating. This second coating will have to be thick enough to give a total thickness (of the two coats) of microns or more.

2a. Using method 1, a coloured design, printed around this resulting white design can then be used with the intention that the colour bleeds into the design within a given period.

It has been found that the "watermark" cannot be photocopied either.

If an overhead transparency is made by photocopying one of the invention's documents given WO 93/11946 PCT'/GB92/02266 that any white print or "watermark" will not be present and then placed on an overhead projector, the image will show on the screen. None of the invention's prints will show up clearly on the screen; so this too could be used as a security check.

It has also been found that if two layers of plastic are printed with the same details, but adhered together, slightly off-set, that a blurred print results, but if the card is tilted to one side, the prints line up and can be easily read.

Going further with this, two identical prints can be made and laminated off-set, so that when viewed straight on, the whole print appears as a black card, until the card is viewed at an angle.

Claims (16)

1. A process for printing a plastics film, comprising printing a colourant onto a layer of particulate or colloidal material, which material is releasably bound to a backing; transferring the colourant onto a first plastics film by placing the first plastics film over the printed layer and subjecting the plastics film and printed layer to a substantially constant heat, and removing the backing characterised in that the particulate or colloidal material has a particle size of from 5 to 0.006 microns.

2. A process according to claim 1, wherein a second plastics film is bonded to the first plastics film to encapsulate the colourant and the particulate or colloidal material.

3. A process according to claim 1 or 2, wherein the particulate or colloidal material is silica.

4. A process according to any preceding claim, wherein the backing is :i 15 parchment paper.

5. A process according to any preceding claim, wherein the layer comprises 4 to 8 g/m 2 or 8 to 20 g/m 2 of particulate or colloidal material.

6. The process according to any preceding claim for producing a 20 document having a colourant which substantially does not bleed, comprising printing the colourant onto a layer of particulate or colloidal material, which layer is releasably bound to a backing; transferring the colourant onto a first plastics film by placing the plastics film over the printed layer and subjecting the plastics film and printed layer to a substantially constant heat; removing the backing and laminating a second plastics film to the first plastics film at a temperature at or above 1770C (350 0 F).

7. A process according to any of claims 1 to 5, for producing a document having a colourant which bleeds after a period of time, comprising printing the colourant onto a layer of particulate or colloidal material, which layer is releasably bound to a backing; Z kA) C4 transferring the colourant onto a first plastics film by placing the plastics film over the printed layer and subjecting the plastics film and printed layer to a substantially constant heat; removing the backing and exposing the layer of particulate or colloidal material to an atmosphere of above 40% humidity; and laminating a secc-d plastics film to the first plastics film at a temperature below 177o0c (350 0 F).

8. A process according to any one of claims 2 to 7, wherein a U.V. sensitive or U.V. reflective material is inserted between first and second laminated plastics film.

9. A process according to any one of claims 2 to 8, wherein one or more fibre optic fibres are inserted between the first and second plastics films. A printed -lastics document comprising a first plastics film and a 15 layer of particulate or colloidal material thereon onto which a colourant has been printed, wherein the layer of particulate or colloidal material onto which a colourant has been printed has been transferred to the plastics film by subjecting it to a constant heat, characterised in that the particulate or colloidal material has a particle size of from 5 to 0,006 microns. ;t

11. A document as claimed in claim 10 in which the particulate or I• colloidal material is silica. 12, A document according to claim 10 or 11, wherein the first plastics film is laminated to a second plastics film to encapsulate the colourant and the :t layer of particulate or colloidal material,

13. A document according to claim 12, wherein a UV, sensitive material, U.V, reflective material and/or one or more fibre optic fibres are encapsulated between the first and second plastics films, 14, A document according to claim 13, wherein the one or more fibre optics are etched. A', A document according to any of claims 12, 13 or 14, wherein at least one of the plastics films comprises an embossed portion.

16. A document according to any of claims 12 to 15, wherein the document is a label and comprises a portion having a removable hologram and an adhesive overlying the hologram.

17. A document according to any of claims 11 to 16, wherein the document comprises at least one region of weakness where the document can be manually torn to expose the silica to the atmosphere.

18. A document as claimed in any of claims 10 to 17 which further comprises a mark akin to a watermark.

19. A process for printing a plastics film according to claim 1, substantially as hereinbefore described. Dated this 29th day of May 1996 15 MARK JENNINGS By his Patent Attorneys COLLISON CO *e C C o *oe o *,Q I INTERNATIONAL SEARCH REPORT International Application No PCT/GB 92/02266 1. CLASSIFICATION OF SUBJECT MATTER (if several classification symbols apply, indicate all) 6 According to International Patent Ciassifcation (IPC) or ito both National Classification and iPC Int.Cl. 5 B41M1/30; B41M5/03; B41M5/025; B41M7/02 B41M3/14 UI. FIELDS SEARCHED Minimum Documentation Serlid CIAsi. tion System Classification Symbols Int.Cl. 5 B41M Documentation Searced other than Minimum Documentation to the Extent that such Documaents are Included In the Fields Sezrchedl il. DOCUMENTS CONSIDERED TO BE RELEVANT 9 Category 0 Citatinit of Document, 11 with Indication, where appropriate, of the relevant passages 12] Relevant to Claim No. t3 PATENT ABSTRACTS OF JAPAN vol. 008, no. 069 (M-286)31 March 1984 JP,A,58 215 392 SANYO DENKI KK 14 December 1983 see abstract DATABASE WPI Section Ch, Week 7316, April 1973 Derwent Publications Ltd., London, GB; Class A03, AN 73-22509U JP,A,48 011 408 (KYODO PRINTING CO LTD) 1973 see abstract EP A,0 208 573 (ARJOMARI-PRIOJX SA) 14 January 1987 ee claims; figures 1,3,4,6, 11 1 1Special categories of died documents: 10 document defining the general st of the ait which Is not considered to be of panlasir relevance IE earlier document but published on or alter the International filing date IV document which may throw doubts on priority claim(s) or which Is cited to establish the publication late of another citation or tither special reason (as specified) 0' document ref erring to an oral disclosure, use, exhibition or other means 'r document published pridr to the international fling date but later than the priority date claimed I' Ilt document published after the International filing date ,or priority date and not in conflict with the application but cited to understand the princile or theory unaderlying the Invention W document of particular rtlevance; the claimed Invention cannot be considered novel or cannot be considered to Involve an inventive step I' document of paricular relevance; shl claime Invention cannot be consdered to Involve an Inventive step when the document Is combined with one or more other such docu- ments, such combination being obvious to a person skilled in the art W document Member Of the same patent faMIly IV. CERTMFCATION Date of the Actual Completdon of the International Search Date of Milling of tis j toastoSearch Report MARCH 1993 22" International Searching Authority Signature of Authorized Officer EUROPEAN PATENT OFFICE HILLEBRECHT D.A. To PCTIISAzto toe$"m Aw~ml ljowerf t"3) internaional Application No P CT/GB 92/02266

111. DOCUMENTS CONSIDERED TO BE RELEVANT (CONTINUED FROM TILE SECOND SHEET) Category Citation of Document, with Indication, where appropriate, of the reeat passages Relevant to Claim No. A EPAO 419 241 (MINNESOTA MINING AND 1-16 MANUFACTURING COMPANY) 27 M1-rch 199]. see claims; figures I -I Fena PCTj=2SAjZIOr (ailwa II Ijaamiy INS) ANNEX TO THE INTERNATIONAL SEARCH REPORT ON INTERNATIONAL PATENT APPLICATION NO. GB 9202266 SA 67357 This annex lists the patent family members relating to the patent documents cited in the above-mentioned international mearch report. The members inr- as contrined in the European Patent Office EDP file on The Eutopean Patent Office is in no way liable for these particulars vthich art merely given for the purpose of information. 05/03/93 Patent document Pbcation Patent family Publication cited in search report dte mnes)dat EP-A-0208573 14-01-87 FR-A- AU-B- AU-A- CA-A- JP-A- US-A- 2583794 577512 5917686 1261062 61297193 4710614 26-12-86 22-09-88 08-01-87 26-09-89 27-12-86 0 1-12-87 EP-A-0419241 27-03-91 US-A- 5060981 29-10-91 AU-B- 626445 30-07-92- AU-A- 6120990 11-04-91 CA-A- 2023569 20-03-91 JP-A- 3156436 04-07-91 SFor morm details about this annex -sev Official Journal of the European Patent Office, No. 121B2