AU640478B2 - High heat styrenic copolymer blends having improved tensile properties - Google Patents
High heat styrenic copolymer blends having improved tensile propertiesInfo
- Publication number
- AU640478B2 AU640478B2 AU76955/91A AU7695591A AU640478B2 AU 640478 B2 AU640478 B2 AU 640478B2 AU 76955/91 A AU76955/91 A AU 76955/91A AU 7695591 A AU7695591 A AU 7695591A AU 640478 B2 AU640478 B2 AU 640478B2
- Authority
- AU
- Australia
- Prior art keywords
- rubber
- composition
- weight percent
- particles
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 title claims description 126
- 229920006249 styrenic copolymer Polymers 0.000 title description 2
- 239000002245 particle Substances 0.000 claims description 161
- 229920001971 elastomer Polymers 0.000 claims description 136
- 239000005060 rubber Substances 0.000 claims description 130
- 239000000178 monomer Substances 0.000 claims description 83
- 229920000642 polymer Polymers 0.000 claims description 55
- 239000000839 emulsion Substances 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 40
- 229920000578 graft copolymer Polymers 0.000 claims description 36
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 24
- 150000002825 nitriles Chemical class 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 17
- 229920001577 copolymer Polymers 0.000 claims description 16
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 13
- 230000002902 bimodal effect Effects 0.000 claims description 13
- 238000009826 distribution Methods 0.000 claims description 9
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000012662 bulk polymerization Methods 0.000 claims description 3
- 238000004945 emulsification Methods 0.000 claims description 3
- -1 vinyl aromatic compound Chemical class 0.000 description 31
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 27
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- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 5
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- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
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- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
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- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
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- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical class ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
- VJDVKNLYGQTELS-UHFFFAOYSA-N 1,3-dichloro-2-ethenyl-5-methylbenzene Chemical compound CC1=CC(Cl)=C(C=C)C(Cl)=C1 VJDVKNLYGQTELS-UHFFFAOYSA-N 0.000 description 1
- SSZOCHFYWWVSAI-UHFFFAOYSA-N 1-bromo-2-ethenylbenzene Chemical compound BrC1=CC=CC=C1C=C SSZOCHFYWWVSAI-UHFFFAOYSA-N 0.000 description 1
- VTPNYMSKBPZSTF-UHFFFAOYSA-N 1-ethenyl-2-ethylbenzene Chemical compound CCC1=CC=CC=C1C=C VTPNYMSKBPZSTF-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
- UVHXEHGUEKARKZ-UHFFFAOYSA-N 1-ethenylanthracene Chemical compound C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 UVHXEHGUEKARKZ-UHFFFAOYSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 1
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- 125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 description 1
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- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB909007702A GB9007702D0 (en) | 1990-04-05 | 1990-04-05 | High heat styrenic copolymer blends having improved tensile properties |
| GB9007702 | 1990-04-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU7695591A AU7695591A (en) | 1991-10-30 |
| AU640478B2 true AU640478B2 (en) | 1993-08-26 |
Family
ID=10673934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU76955/91A Ceased AU640478B2 (en) | 1990-04-05 | 1991-04-03 | High heat styrenic copolymer blends having improved tensile properties |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0523161A4 (enrdf_load_stackoverflow) |
| JP (1) | JPH05506051A (enrdf_load_stackoverflow) |
| AU (1) | AU640478B2 (enrdf_load_stackoverflow) |
| CA (1) | CA2078337A1 (enrdf_load_stackoverflow) |
| GB (1) | GB9007702D0 (enrdf_load_stackoverflow) |
| MX (1) | MX174589B (enrdf_load_stackoverflow) |
| TW (1) | TW205562B (enrdf_load_stackoverflow) |
| WO (1) | WO1991015544A1 (enrdf_load_stackoverflow) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5270387A (en) * | 1990-01-02 | 1993-12-14 | The Dow Chemical Company | High heat styrenic copolymer blends having improved tensile properties |
| DE19649255A1 (de) * | 1996-11-28 | 1998-06-04 | Bayer Ag | Thermoplastische Hochglanz-Formmassen vom ABS-Typ |
| DE19649249A1 (de) * | 1996-11-28 | 1998-06-04 | Bayer Ag | Verbesserte thermoplastische Formmassen vom ABS-Typ |
| KR100364232B1 (ko) * | 1997-12-22 | 2003-02-19 | 제일모직주식회사 | 내충격성 및 저광택성이 우수한 열가소성 수지의 제조방법 |
| DE19858731A1 (de) * | 1998-12-18 | 2000-06-21 | Bayer Ag | Hochschlagzähe ABS-Formmassen |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3652721A (en) * | 1970-07-24 | 1972-03-28 | Monsanto Co | Novel graft copolymer blends with two different particle sizes and method of making same |
| US4567233A (en) * | 1983-06-15 | 1986-01-28 | Mitsubishi Monsanto Chemical Company | Heat and impact resistant resin composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3509238A (en) * | 1966-03-21 | 1970-04-28 | Monsanto Co | Abs graft polyblends containing two graft polymers with different degrees of grafting |
| DE3135252A1 (de) * | 1981-09-05 | 1983-03-17 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
| EP0293490B1 (en) * | 1986-12-11 | 1992-08-05 | Monsanto Kasei Company | Heat and impact resistant resin composition |
| DE3802614A1 (de) * | 1988-01-29 | 1989-08-03 | Basf Ag | Formmasse und deren verwendung |
-
1990
- 1990-04-05 GB GB909007702A patent/GB9007702D0/en active Pending
-
1991
- 1991-04-03 EP EP19910907833 patent/EP0523161A4/en not_active Ceased
- 1991-04-03 JP JP91507757A patent/JPH05506051A/ja active Pending
- 1991-04-03 CA CA 2078337 patent/CA2078337A1/en not_active Abandoned
- 1991-04-03 WO PCT/US1991/002276 patent/WO1991015544A1/en not_active Application Discontinuation
- 1991-04-03 AU AU76955/91A patent/AU640478B2/en not_active Ceased
- 1991-04-05 MX MX2524691A patent/MX174589B/es unknown
- 1991-04-10 TW TW80102743A patent/TW205562B/zh active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3652721A (en) * | 1970-07-24 | 1972-03-28 | Monsanto Co | Novel graft copolymer blends with two different particle sizes and method of making same |
| US4567233A (en) * | 1983-06-15 | 1986-01-28 | Mitsubishi Monsanto Chemical Company | Heat and impact resistant resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1991015544A1 (en) | 1991-10-17 |
| CA2078337A1 (en) | 1991-10-06 |
| GB9007702D0 (en) | 1990-06-06 |
| AU7695591A (en) | 1991-10-30 |
| JPH05506051A (ja) | 1993-09-02 |
| EP0523161A4 (en) | 1993-07-07 |
| TW205562B (enrdf_load_stackoverflow) | 1993-05-11 |
| MX174589B (es) | 1994-05-27 |
| EP0523161A1 (en) | 1993-01-20 |
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