AU624016B2 - Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process - Google Patents

Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process

Info

Publication number
AU624016B2
AU624016B2 AU61039/90A AU6103990A AU624016B2 AU 624016 B2 AU624016 B2 AU 624016B2 AU 61039/90 A AU61039/90 A AU 61039/90A AU 6103990 A AU6103990 A AU 6103990A AU 624016 B2 AU624016 B2 AU 624016B2
Authority
AU
Australia
Prior art keywords
carbon dioxide
gas
power plant
turbine power
steam turbine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU61039/90A
Other versions
AU6103990A (en
Inventor
Guenther Haupt
Rainer Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of AU6103990A publication Critical patent/AU6103990A/en
Application granted granted Critical
Publication of AU624016B2 publication Critical patent/AU624016B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
    • F01K23/068—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification in combination with an oxygen producing plant, e.g. an air separation plant
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
    • F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/045—Purification by catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
    • F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
    • F02B2043/106—Hydrogen obtained by electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/32—Direct CO2 mitigation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/30—Use of alternative fuels, e.g. biofuels

Abstract

In plants with fossil combustion, carbon dioxide and, if appropriate, water are ultimately formed as a combustion product. These two products are as a rule released as waste gases into the atmosphere. The carbon dioxide produced then impedes the heat emission from our Earth and causes the so-called greenhouse effect. The invention is based on the object of largely suppressing the release of carbon dioxide from a gas-and-steam power plant into the atmosphere. In a gas-and-steam turbine power plant with a gasifier (18, 238) upstream of the combustion chamber (14, 234), it is provided according to the invention that the raw gas (RG) from the gasifier (18, 238) is dedusted, cooled, purified and enriched with water and shift-converted. The carbon dioxide (CO2) and, if appropriate, the sulphur compounds are separated off by a scrubbing agent. The carbon dioxide is disposed of, for example passed into a dry ice plant (66, 290) or otherwise industrially utilised. The pure gas (GG) largely free of carbon dioxide and containing essentially hydrogen is fed as fuel to the combustion chamber (14, 234) of the gas turbine. The invention is applicable especially to gas-and-steam turbine power plants, but can also be used in pure gas turbine power plants. <IMAGE>
AU61039/90A 1989-08-16 1990-08-15 Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process Ceased AU624016B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3926964 1989-08-16
DE3926964A DE3926964A1 (en) 1989-08-16 1989-08-16 METHOD FOR REDUCING THE CARBON DIOXIDE CONTENT OF THE EXHAUST GAS FROM A GAS AND STEAM TURBINE POWER PLANT AND POST-WORKING POWER PLANT

Publications (2)

Publication Number Publication Date
AU6103990A AU6103990A (en) 1991-02-21
AU624016B2 true AU624016B2 (en) 1992-05-28

Family

ID=6387179

Family Applications (1)

Application Number Title Priority Date Filing Date
AU61039/90A Ceased AU624016B2 (en) 1989-08-16 1990-08-15 Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process

Country Status (9)

Country Link
EP (1) EP0413199B1 (en)
AT (1) ATE82009T1 (en)
AU (1) AU624016B2 (en)
DD (1) DD297078A5 (en)
DE (2) DE3926964A1 (en)
DK (1) DK0413199T3 (en)
ES (1) ES2036080T3 (en)
FI (1) FI904059A0 (en)
GR (1) GR3006989T3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007047270A1 (en) * 2005-10-12 2007-04-26 Praxair Technology, Inc. Igcc wobbe index maintenance method

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4117192C2 (en) * 1991-05-25 1994-06-23 Saarbergwerke Ag Process for generating energy in a combined gas-steam power plant and plant for carrying out the process
DE4117191C2 (en) * 1991-05-25 1994-11-24 Saarbergwerke Ag Combined gas-steam power plant to generate energy
JPH0565237A (en) * 1991-09-10 1993-03-19 Mitsubishi Heavy Ind Ltd Energy supply method using methanol as medium
US6170264B1 (en) * 1997-09-22 2001-01-09 Clean Energy Systems, Inc. Hydrocarbon combustion power generation system with CO2 sequestration
DE19531842A1 (en) * 1995-08-29 1997-04-30 Messer Griesheim Gmbh Process for reducing flue gas in combustion processes
SE9702830D0 (en) * 1997-07-31 1997-07-31 Nonox Eng Ab Environment friendly high efficiency power generation method based on gaseous fuels and a combined cycle with a nitrogen free gas turbine and a conventional steam turbine
WO1999041188A1 (en) * 1998-02-13 1999-08-19 Norsk Hydro Asa Process for producing electrical power and steam
DE19832293A1 (en) * 1998-07-17 1999-10-21 Siemens Ag Gas-and-steam turbine plant with integrated fossil fuel gasification
AU2001276823A1 (en) 2000-05-12 2001-12-03 Clean Energy Systems, Inc. Semi-closed brayton cycle gas turbine power systems
WO2005100754A2 (en) 2004-04-16 2005-10-27 Clean Energy Systems, Inc. Zero emissions closed rankine cycle power system
DE102005026534B4 (en) * 2005-06-08 2012-04-19 Man Diesel & Turbo Se Steam generating plant
DE102006034712A1 (en) * 2006-07-27 2008-01-31 Steag Saar Energie Ag Method for reducing the CO2 emission of fossil-fired power plants
EP1944268A1 (en) 2006-12-18 2008-07-16 BP Alternative Energy Holdings Limited Process
DE102007022168A1 (en) 2007-05-11 2008-11-13 Siemens Ag Process for generating motor energy from fossil fuels with removal of pure carbon dioxide
US8951314B2 (en) 2007-10-26 2015-02-10 General Electric Company Fuel feed system for a gasifier
PL2100869T3 (en) * 2008-03-10 2020-07-13 Edgar Harzfeld Method for producing methanol by recovering carbon dioxide from exhaust gases of energy generation facilities powered by fossil fuels
EP2105189A1 (en) 2008-03-27 2009-09-30 Siemens Aktiengesellschaft Method and device for separating carbon dioxide from an exhaust gas of a fossil fuel-powered power plant
EP2133308A1 (en) * 2008-06-12 2009-12-16 Siemens Aktiengesellschaft Pure gas pre-heating device and method for pre-heating pure gas
JP5412171B2 (en) * 2009-04-30 2014-02-12 三菱重工業株式会社 Method and apparatus for separating acidic gas from synthesis gas
DE102010024465A1 (en) * 2010-06-21 2011-12-22 Siemens Aktiengesellschaft Method for utilizing waste electrical energy of e.g. coal fired power plant, involves liquefying gas with assistance of electrical power, storing liquefied gas, and cooling process medium of power station with assistance of liquefied gas
DE102015003680A1 (en) * 2015-03-24 2016-09-29 Peter Paul Smolka Fuel production plant for power plants
DE102015218502A1 (en) 2015-09-25 2017-03-30 Siemens Aktiengesellschaft Steam turbine power plant with hydrogen combustion with the involvement of a gasification device
DE112016007162A5 (en) 2016-09-25 2019-05-16 Peter Paul Smolka Fuel production plant for power plants
DE102017000590A1 (en) 2017-01-12 2018-07-12 Peter Paul Smolka Fuel Production Plant for Power Plants B

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EP0207620A2 (en) * 1985-06-04 1987-01-07 Imperial Chemical Industries Plc Energy recovery
EP0217505A2 (en) * 1985-08-07 1987-04-08 Imperial Chemical Industries Plc Production of a gas containing hydrogen
EP0259114A1 (en) * 1986-08-29 1988-03-09 Humphreys &amp; Glasgow Limited Clean electric power generation

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
EP0207620A2 (en) * 1985-06-04 1987-01-07 Imperial Chemical Industries Plc Energy recovery
EP0217505A2 (en) * 1985-08-07 1987-04-08 Imperial Chemical Industries Plc Production of a gas containing hydrogen
EP0259114A1 (en) * 1986-08-29 1988-03-09 Humphreys &amp; Glasgow Limited Clean electric power generation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007047270A1 (en) * 2005-10-12 2007-04-26 Praxair Technology, Inc. Igcc wobbe index maintenance method

Also Published As

Publication number Publication date
DK0413199T3 (en) 1993-03-01
EP0413199B1 (en) 1992-11-04
ATE82009T1 (en) 1992-11-15
GR3006989T3 (en) 1993-06-30
EP0413199A1 (en) 1991-02-20
AU6103990A (en) 1991-02-21
DE59000430D1 (en) 1992-12-10
DE3926964A1 (en) 1991-02-21
ES2036080T3 (en) 1993-05-01
DD297078A5 (en) 1992-01-02
FI904059A0 (en) 1990-08-16

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