AU6103990A - Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process - Google Patents
Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the processInfo
- Publication number
- AU6103990A AU6103990A AU61039/90A AU6103990A AU6103990A AU 6103990 A AU6103990 A AU 6103990A AU 61039/90 A AU61039/90 A AU 61039/90A AU 6103990 A AU6103990 A AU 6103990A AU 6103990 A AU6103990 A AU 6103990A
- Authority
- AU
- Australia
- Prior art keywords
- carbon dioxide
- gas
- power plant
- turbine power
- steam turbine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
- F01K23/068—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification in combination with an oxygen producing plant, e.g. an air separation plant
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/045—Purification by catalytic desulfurisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
- F02B2043/106—Hydrogen obtained by electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
In plants with fossil combustion, carbon dioxide and, if appropriate, water are ultimately formed as a combustion product. These two products are as a rule released as waste gases into the atmosphere. The carbon dioxide produced then impedes the heat emission from our Earth and causes the so-called greenhouse effect. The invention is based on the object of largely suppressing the release of carbon dioxide from a gas-and-steam power plant into the atmosphere. In a gas-and-steam turbine power plant with a gasifier (18, 238) upstream of the combustion chamber (14, 234), it is provided according to the invention that the raw gas (RG) from the gasifier (18, 238) is dedusted, cooled, purified and enriched with water and shift-converted. The carbon dioxide (CO2) and, if appropriate, the sulphur compounds are separated off by a scrubbing agent. The carbon dioxide is disposed of, for example passed into a dry ice plant (66, 290) or otherwise industrially utilised. The pure gas (GG) largely free of carbon dioxide and containing essentially hydrogen is fed as fuel to the combustion chamber (14, 234) of the gas turbine. The invention is applicable especially to gas-and-steam turbine power plants, but can also be used in pure gas turbine power plants. <IMAGE>
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3926964 | 1989-08-16 | ||
DE3926964A DE3926964A1 (en) | 1989-08-16 | 1989-08-16 | METHOD FOR REDUCING THE CARBON DIOXIDE CONTENT OF THE EXHAUST GAS FROM A GAS AND STEAM TURBINE POWER PLANT AND POST-WORKING POWER PLANT |
Publications (2)
Publication Number | Publication Date |
---|---|
AU6103990A true AU6103990A (en) | 1991-02-21 |
AU624016B2 AU624016B2 (en) | 1992-05-28 |
Family
ID=6387179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU61039/90A Ceased AU624016B2 (en) | 1989-08-16 | 1990-08-15 | Process for reducing the carbon dioxide content of the exhaust gas of a gas and steam turbine power plant and power plant operating according to the process |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0413199B1 (en) |
AT (1) | ATE82009T1 (en) |
AU (1) | AU624016B2 (en) |
DD (1) | DD297078A5 (en) |
DE (2) | DE3926964A1 (en) |
DK (1) | DK0413199T3 (en) |
ES (1) | ES2036080T3 (en) |
FI (1) | FI904059A0 (en) |
GR (1) | GR3006989T3 (en) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4117192C2 (en) * | 1991-05-25 | 1994-06-23 | Saarbergwerke Ag | Process for generating energy in a combined gas-steam power plant and plant for carrying out the process |
DE4117191C2 (en) * | 1991-05-25 | 1994-11-24 | Saarbergwerke Ag | Combined gas-steam power plant to generate energy |
JPH0565237A (en) * | 1991-09-10 | 1993-03-19 | Mitsubishi Heavy Ind Ltd | Energy supply method using methanol as medium |
US6170264B1 (en) * | 1997-09-22 | 2001-01-09 | Clean Energy Systems, Inc. | Hydrocarbon combustion power generation system with CO2 sequestration |
DE19531842A1 (en) * | 1995-08-29 | 1997-04-30 | Messer Griesheim Gmbh | Process for reducing flue gas in combustion processes |
SE9702830D0 (en) * | 1997-07-31 | 1997-07-31 | Nonox Eng Ab | Environment friendly high efficiency power generation method based on gaseous fuels and a combined cycle with a nitrogen free gas turbine and a conventional steam turbine |
AU6719898A (en) * | 1998-02-13 | 1999-08-30 | Norsk Hydro Asa | Process for producing electrical power and steam |
DE19832293A1 (en) * | 1998-07-17 | 1999-10-21 | Siemens Ag | Gas-and-steam turbine plant with integrated fossil fuel gasification |
AU2001276823A1 (en) | 2000-05-12 | 2001-12-03 | Clean Energy Systems, Inc. | Semi-closed brayton cycle gas turbine power systems |
US20050241311A1 (en) | 2004-04-16 | 2005-11-03 | Pronske Keith L | Zero emissions closed rankine cycle power system |
DE102005026534B4 (en) * | 2005-06-08 | 2012-04-19 | Man Diesel & Turbo Se | Steam generating plant |
US7690204B2 (en) * | 2005-10-12 | 2010-04-06 | Praxair Technology, Inc. | Method of maintaining a fuel Wobbe index in an IGCC installation |
DE102006034712A1 (en) * | 2006-07-27 | 2008-01-31 | Steag Saar Energie Ag | Method for reducing the CO2 emission of fossil-fired power plants |
EP1944268A1 (en) | 2006-12-18 | 2008-07-16 | BP Alternative Energy Holdings Limited | Process |
DE102007022168A1 (en) | 2007-05-11 | 2008-11-13 | Siemens Ag | Process for generating motor energy from fossil fuels with removal of pure carbon dioxide |
US8951314B2 (en) | 2007-10-26 | 2015-02-10 | General Electric Company | Fuel feed system for a gasifier |
PL2100869T3 (en) * | 2008-03-10 | 2020-07-13 | Edgar Harzfeld | Method for producing methanol by recovering carbon dioxide from exhaust gases of energy generation facilities powered by fossil fuels |
EP2105189A1 (en) | 2008-03-27 | 2009-09-30 | Siemens Aktiengesellschaft | Method and device for separating carbon dioxide from an exhaust gas of a fossil fuel-powered power plant |
EP2133308A1 (en) * | 2008-06-12 | 2009-12-16 | Siemens Aktiengesellschaft | Pure gas pre-heating device and method for pre-heating pure gas |
JP5412171B2 (en) * | 2009-04-30 | 2014-02-12 | 三菱重工業株式会社 | Method and apparatus for separating acidic gas from synthesis gas |
DE102010024465A1 (en) * | 2010-06-21 | 2011-12-22 | Siemens Aktiengesellschaft | Method for utilizing waste electrical energy of e.g. coal fired power plant, involves liquefying gas with assistance of electrical power, storing liquefied gas, and cooling process medium of power station with assistance of liquefied gas |
DE102015003680A1 (en) * | 2015-03-24 | 2016-09-29 | Peter Paul Smolka | Fuel production plant for power plants |
DE102015218502A1 (en) | 2015-09-25 | 2017-03-30 | Siemens Aktiengesellschaft | Steam turbine power plant with hydrogen combustion with the involvement of a gasification device |
DE112016007162A5 (en) | 2016-09-25 | 2019-05-16 | Peter Paul Smolka | Fuel production plant for power plants |
DE102017000590A1 (en) | 2017-01-12 | 2018-07-12 | Peter Paul Smolka | Fuel Production Plant for Power Plants B |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8519821D0 (en) * | 1985-08-07 | 1985-09-11 | Ici Plc | Hydrogen streams |
EP0207620B1 (en) * | 1985-06-04 | 1990-07-11 | Imperial Chemical Industries Plc | Energy recovery |
GB2196016B (en) * | 1986-08-29 | 1991-05-15 | Humphreys & Glasgow Ltd | Clean electric power generation process |
-
1989
- 1989-08-16 DE DE3926964A patent/DE3926964A1/en not_active Withdrawn
-
1990
- 1990-08-01 DE DE9090114779T patent/DE59000430D1/en not_active Expired - Lifetime
- 1990-08-01 EP EP90114779A patent/EP0413199B1/en not_active Expired - Lifetime
- 1990-08-01 DK DK90114779.3T patent/DK0413199T3/en active
- 1990-08-01 ES ES199090114779T patent/ES2036080T3/en not_active Expired - Lifetime
- 1990-08-01 AT AT90114779T patent/ATE82009T1/en not_active IP Right Cessation
- 1990-08-14 DD DD90343446A patent/DD297078A5/en not_active IP Right Cessation
- 1990-08-15 AU AU61039/90A patent/AU624016B2/en not_active Ceased
- 1990-08-16 FI FI904059A patent/FI904059A0/en not_active IP Right Cessation
-
1993
- 1993-02-05 GR GR920402440T patent/GR3006989T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
FI904059A0 (en) | 1990-08-16 |
DD297078A5 (en) | 1992-01-02 |
EP0413199A1 (en) | 1991-02-20 |
ATE82009T1 (en) | 1992-11-15 |
GR3006989T3 (en) | 1993-06-30 |
AU624016B2 (en) | 1992-05-28 |
DE3926964A1 (en) | 1991-02-21 |
DE59000430D1 (en) | 1992-12-10 |
ES2036080T3 (en) | 1993-05-01 |
EP0413199B1 (en) | 1992-11-04 |
DK0413199T3 (en) | 1993-03-01 |
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