AU594988B2

AU594988B2 - Continuous pickling method and apparatus

Info

Publication number: AU594988B2
Application number: AU65501/86A
Authority: AU
Inventors: Yuuji Furuzawa; Toshio Taguchi; Kenichi Yanagi
Original assignee: Mitsubishi Heavy Industries Ltd
Current assignee: Mitsubishi Heavy Industries Ltd
Priority date: 1985-12-06
Filing date: 1986-11-18
Publication date: 1990-03-22
Anticipated expiration: 2006-11-18
Also published as: BR8605681A; AU6550186A; DE3669898D1; EP0225273B1; EP0225273A1; KR870006236A

Description

LL 1L ^IF- arm~rrr=clirnn AUiKALlA PATENTS ACT 1952 COMPLETE

SPECIFICATION

(ORIGINAL)

FOR OFFICE USE: Application Number: Lodged: 6sso506.

Class Int. Class Complete Specification Lodged: Accepted: Published: 594988 Priority: i i ii r !1 r iii., i I i j Related Art: ii

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ii ir LU-,LII~-UU~ilr~rUUf:tliZ iYSlld ii Name of Applicant(s): r f Applicant(s): 4drlrss of Applicant(s): 0 MITSUBISHI JUKOGYO KABUSHIKI KAISHA 5-1, Marunouchi 2-Chome, Chiyoda-ku, TOKYO, JAPAN o 0* Actual inventor(s): Kenichi YANAGI Toshio TAGUCHI Yuuji FURUZAWA Address for Service: Kelvin Lord Co., 4 Douro Place,' WEST PERTH, Western Australia 6005.

Complete Specification for the invention entitled: "CONTINUOUS PICKLING METHOD AND APPARATUS" S The following statement is a full description ofthis invention, including the best method of performing it known to me us

SPECIFICATION

1. TITLE OF THE INVENTION Continuous Pickling Method and Apparatus 2. BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a continuous pickling o method and apparatus for metallic materials, especially 0 0 0 So steel plates.

S0 ooa t (ii) Description of the Prior Art ,'q0 One embodiment of a conventional continuous pickling apparatus is shown in Fig. 10. In this drawing, reference I numeral 101 is a steel strip, numeral 102 is an acid tank, 0 1 103 is an acid liquid, and 104a, 104b, 104c, 104d and 104e 0 00 are guide rolls.

ooo The steel strip 101 having ordinary temperature is o o unwound from a payoff reel not shown, and is then caused to 0°o0 run through the acid liquid 103 in the acid tank 102, while 0 a scale formed on the surfaces of the steel strip 4 is pickled out with the acid liquid 103. Afterward, the scale-free steel strip 101 is taken out from the acid tank 102 and is then fed to a subsequent process not shown.

In the continuous pickling apparatus, it is necessary that the steel strip surfaces are in contact with the acid laliquid for a certain period of time, and for the sake of this requirement, when the running speed of the steel strip therethrough is high, the elongated acid tank is correspondingly needful.

In recent years, however, it is strongly desired to shorten the acid tank from the viewpoints of equipment cost, installation space and the like. As means for shortening this acid tank, there are a manner of causing the steel strip to pass through a mechanical scale breaker prior to immersing it into the acid tank, in order to form fine cracks in the scale on the surfaces of the steel strip and to thereby accelerate the removal of the scale, and a manner ,ii i of jetting the acid liquid against the steel strip in the acid tank so as to shorten a reaction time, and these manners can obtain expected results. Nevertheless, with regard to the acid tank, a length of no less than 50 to 100 ti j m is required, and in the case of such a long acid tank, the high equipment cost and the extensive installation space are 04 0' 0 necessary. For this reason, it is strongly needed to o shorten the acid tank, 3. OBJECT AND SUMMARY OF THE INVENTION i An object of the present invention is to provide a continuous pickling method and apparatus by which a period of time necessary for a pickling operation is curtailed, so 2 ~L L I -d 1 3that a used acid tank is shortened.

In the present invention, a first means for achieving the above object is to heat a material to be pickled up to a high temperature. That is, the present invention is directed to a continuous pickling method for continuously pickling a metallic material to be pickled, said method being characterized by heating said material to a temperature higher than the boiling point of an acid liquid under atmospheric pressure, and then pickling said material in said acid liquid, said acid liquid in which said material is pickled being at a temperature lower than its boiling point.

In accordance with one aspect of the present invention, there is provided a heating device for heating a steel strip which is a material to be pickled that is provided in front of an acid tank, and in the heating device, the steel strip is then heated up to a temperature higher than a boiling point of an acid liquid under atmospheric pressure. Afterward, the steel strip is introduced into 20 the acid tank in order to be subjected to a pickling treatment.

0 According to the present invention, at the moment when the steel strip is immersed into the acid liquid, the steel strip having a temperature higher than the boiling point of the acid liquid is brought into contact with the acid liquid having a temperature lower than the boiling point.

At this time, the acid liquid penetrates into fine cracks in a scale on the surface of the steel strip, and it boils to generate vapor. As a result, a gas is expanded

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I -4 abruptly, so that pieces of the scale are peeled off and new cracks occur. In this way, the pickling time is curtailed.

Further, a second means for achieving the above object is to jet an acid liquid against a previously highly heated material to be pickled. That is, the present invention is directed to a continuous pickling method for continuously pickling a metallic material to be pickled, said method being charcterized by heating said material to a temperature higher than the boiling point of an acid liquid under atmospheric pressure, and then jetting said acid liquid against said material to thereby pickle said material, without immersing said material into said acod liquid, said acid liquid being at a temperature lower than its boiling point.

In accordance with another aspect of the present invention there is provided a heating device for heating a steel strip and is provided above the acid tank, and the steel D a strip is heated up to a temperature higher than the boiling oao c point of the acid liquid under atmospheric pressure by the heating device. Afterward, the steel strip is introduced gOo into the acid tank, and the acid liquid is jetted against the steel strip material to pickle the latter, without immersing the steel strip material into the acid liquid.

According to the present invention, at the moment when the acid liquid is jetted against the steel strip, the steel strip having a temperature higher than the boiling point of \A4 0<Y d) Tc~ _I ~C~-PYI~ the acid liquid is brought into contact with the acid liquid having a temperature lower than the boiling point. At this time, the acid liquid penetrates into fine cracks in a scale on the surfaces of the steel strip, and it boils to generate vapor. As a result, a gas is expanded abruptly, so that pieces of the scale are peeled off and new cracks occur In addition, the jetted acid liquid washes out the pieces of the scale, or the reacted acid liquid is replaced with the new acid liquid to accelerate the reaction, whereby the time *s 0 necessary for the pickling treatment is curtailed.

As compared with a conventional jet manner in the acid liquid, the jet method of the present invention has a greater jet effect because of the vigor of the jet being maintained, and an advantage of decreasing a necessary amount of the acid liquid owing to immersing no steel strip into the acid liquid.

Moreover, the present invention provides an apparatus r1 for practicing the above mentioned method.

also LtSe,5 The- ~pre present lnvention ±ck a pretreating apparatus for continuous pickling which comprises a tank for receiving herein hot water having a temperature higher than its boiling point under atmospheric a pressure, a heating device for heating the hot water, and seal rolls disposed at an outlet and an inlet of the tank and a material to be pickled.

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*rr::tn 4 09 4 00 The object, characteristics and benefits of the present invention will be more clarified by the undermentioned description in reference to the accompanying drawings.

4. BRIEF DESCRIPTION OF THE DRAWINGS Figs. 1 to 4 show schematic sectional view of embodiments of an apparatus suitable for a pickling method with regard to the present invention, and of these drawings, Fig. 1 shows the apparatus in which a heating device is provided above an acid tank, Fig. 2 shows the apparatus in which a heating water tank is provided as a heating device, Fig. 3 shows the same apparatus as in Fig. 1 with the exception that a high pressure is retained in the acid 15 tank, and Fig. 4 shows the apparatus in which the heating water tank is used and the high pressure is retained in the acid tank; Fig. 5 shows a relation between a temperature of a steel plate and a ratio of a pickling time; Figs. 6 to 9 show schematic sectional view of other embodiments of the apparatus suitable for the pickling method with regard to the present invention, and of these drawings, Fig. 6 shows the apparatus in which the heating device is provided above the acid tank, Fig. 7 shows the apparatus in which the heating water tank is proviaed as the heating -6nc~-I device, Fig. 8 shows the apparatus having the acid tank portion in which shield plates are disposed confronting the upper and the lower surfaces of the steel strip, and Fig. 9 shows the apparatus having acid tank portions of box shield structures which are constituted so as to surround the steel strip; and Fig. 10 is a schematic sectional view of a conventional pickling apparatus.

5. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENIT In the first place, embodiments of the present invention for practicing the above mentioned first means are shown in Figs. i, 2, 3 and 4. In the embodiment in Fig. i, a heating device is provided above an acid tank, and reference numeral 1 is a steel strip, numeral 2 is an acid 42 tank, 3 is an acid liquid, 4a, 4b, 4c, 4d and 4e are guide rolls, and 6a and 6b are electric type, hot air type or 0° oiother type heating devices. The steel strip 1 is heated up 4:0.0 to a temperature higher than a boiling point of the acid liquid at atmospheric pressure by the heating devices 6a, 6b, and it is then immersed into the acid liquid 3 in the acid tank 2 to pickle the steel strip i.

Fig. 2 exhibits the other embodiment in which a heating water tank 7 is equipped as the heating device. The heating water tank 7 in Fig. 2 is of a sealing type, and pairs of -7seal rolls 9a, 9b and 9c, 9d are disposed at an outlet and an inlet, respectively, of the steel strip 1 in the heating water tank 7, whereby an opening space between the interior j of the heating water tank 7 and the outside is minimized, and the steel strip 1 is allowed to run continuously through the heating tank 7, while a high pressure is retained in the tank 7. A pressurizing water 8 having a high temperature is placed in the heating water tank 7. Numerals 10a, 10b and S 10c are guide rolls.

1 0 In'idetF-YA ),the pressurizing water 8 is heated by, for example, a disposed heating device 41 so as to provide the water 8 with a high temperature.

i Fig. 3 shows the other embodiment. In this embodiment, i t the heating devices 6a and 6b are disposed in front of the ji 15 acid tank as in the case of Fig. 1, but the acid tank 12 is l m ia -sealed by the seal rolls 5a, 5b and 5c, 5d in order to maintain the interior of the acid tank 12 at a high pressure and to maintain the acid liquid 3 at a temperature i higher than its boiling point at atmospheric pressure. In 20 this embodiment, the steel strip at the outlet of the S heating device 6a, 6b has a higher temperature than the acid V liquid 3. In Fig. 3, 14a, 14b and 14c are guide rolls.

-i Fig. 4 is the further other embodiment of the present invention. The apparatus in Fig. 4 is equipped with the same acid tank 12 as in Fig. 3, but the same heating water 8 c Y~.

tank 7 as in Fig. 2 is provided as the heating device above the acid tank. That is, numeral 8 is a pressurizing water having a high temperature, 9a, 9b, 9c and 9d are seal rolls, V and 10a, 10b and 10c are guide rolls.

V 5 According to the pickling means of each embodiment just described, the steel strip is first heated up to a temperature higher than the boiling point of the acid liquid at atmospheric pressure and is then immersed into the acid j liquid. Therefore, at the moment when the steel strip is immersed into the acid liquid, the latter penetrates into I fine cracks in a scale on the surfaces of the steel strip, and it boils to generage vapor, which fact leads to the abrupt expansion of a gas. As a result, pieces of the scale are peeled off and new cracks occur, so that a time necessary for the pickling operation is curtailed. According to experiments made by the inventors of the present application, the higher the temperature of the steel plate is, the S" shorter the time necessary for the pickling operation is, as o shown in Fig. 5. For example, when the pickling time 02 necessary for the steel plate of 80'C is regarded as 100%, 0 0 the pickling time for the steel plate of 2000C is 50% or less. In the case that a temperature of the acid liquid in the acid tank is higher than the boiling point thereof at atmospheric pressure, the similar effect can be obtained by heating the steel plate up to a level higher than the 9 .1 liquid temperature.

Embodiments of the present invention which can practice the above mentioned second means are shown in Figs. 6 and 7.

In the embodiment in Fig. 6, a heating device is provided above an acid tank, and reference numeral 1 is a steel strip, numeral 22 is an acid tank, 3 is an acid liquid, 24a, 24b, 24c and 24d are guide rolls. Numerals 6a and 6b are electric type, hot air type or other type heating devices, as shown in Fig. 3. The steel strip 1 is heated up to a St temperature higher than a boiling point of the acid liquid 4 I at atmospheric pressure by the heating devices 6a, 6b, and is then introduced into the acid tank 22. Afterward, the steel strip 1 is subjected to a pickling treatment by jetting the acid liquid, fed by a pump not shown, against both the surfaces of the steel strip 1 through nozzles 11a, 11b, 11c, and 11k, while supported by the guide rolls 24a, 24b, 24c and 24d, without being immersed into the acid liquid 3.

oo Fig. 7 shows the other embodiment of the present invention, and in this embodiment, the same heating water tank 7 as in Fig. 4 is equipped.

Figs. 8 and 9 show other embodiments of an acid tank portion regarding the present invention. The embodiment in Fig. 8 has shield plates 12a, 12b, 12c, and 12Z which closely confront the upper and lower surfaces of the steel 10 strip 1 so as to define a flow path for the acid liquid between these shield plates and the steel strip 1. In this construction, the acid liquid jetted through nozzles 11a, 11b, 11c, and 11k flows through the aforesaid flow path, so that a contact time between the acid liquid and the steel strip 1 is prolonged, and a velocity of the acid liquid along the steel strip 1 is kept up, thereby assuring an effective pickling reaction.

The embodiment in Fig. 9 has box shields 1 3 a, 13b,.

o 10 which are shaped so as to surround the steel strip 1, and in this case, a flow path is defined between the box shields re and the steel strip 1. As compared with the embodiment in t Fig. 8, the acid liquid does not flow out in a cross direction of the steel strip, so that an effect of the acid 15 liquid increases additionally.

In the present invention, the material to be pickled, o after heated up to a high temperature, is pickled, as described in detail above. Therefore, at the momenc when oOo the steel strip is immersed into the acid liquid, the latter oo2O penetrates into fine cracks in a scale on the surface of the steel strip, and it boils to generage vapor, which fact leads to the abrupt expansion of a gas. As a result, pieces of the scale are peeled off and new cracks occur, so that a time necessary for the pickling operation can be curtailed.

Further, in consequence, the acid tank can be shortened.

11 t j-2 ifi i This is an effect of the present invention.

In addition, according to the present invention, the steel strip is heated as described above, and the acid liquid is then jetted against the heated steel strip, instead of being immersed into the acid liquid. Therefore, if at the moment when the acid liquid is jetted against the steel strip, the acid liquid penetrates into fine cracks in a scale on the surface of the steel strip, and it boils to generage vapor, which fact leads to the abrupt expansion of Ii a gas. As a result, pieces of the scale are peeled off and new cracks occur, and the jet of the acid liquid washes out the peices of the scale, so that a time necessary for the pickling operation is curtailed. According to experiments made by the present inventors, the time necessary for the pickling treatment in the present invention is about 1/3 of that of the conventional pickling treatment in which neither heating nor jetting are carried out.

SFurthermore, according to the pickling pretreating 4 44 apparatus, the material to be pickled, for example, the .o 0 steel strip can be heated up to the temperature higher than the boiling point of the acid liquid at atmospheric pressure. Therefore, the method of the present invention can surely be practiced as described above, thereby curtailing t:he pickling time and shortening the acid tank.

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Claims

1. A continuous pickling method for continuously pickling a metallic material to be pickled, said method being characterized by heating said material to a temperature higher than the boiling point of an acid liquid under atmospheric pressure, and the pickling said material in said acid liquid, said acid liquid in which said material is pickled being at a temperature lower than its boiling point.

2. A continuous pickling method accoridng to Claim 1 wherein said heating treatment prior to pickling is carried out by means of an electric type or a hot air type heating device, or a heating water tank.

3. A continuous pickling method for continuously pickling a metallic material to be pickled, said method being charcterized by heating said material to a temperature higher than the boiling point of an acid liquid inder Satmospheric pressure, and then jetting said acid liquid against said material to thereby pickle said material, without immersing said material into said acid liquid, said acid liquid being at a temperature lower than its boiling a o point.

4. A continuous pickling method according to Claim 3 wherein said heating treatment prior to pickling is carried out by means of an electric type or a hot air type heating device, or a heating water tank.

A continuous pickling method according to Claim 3, wherein said material has upper and lower surfaces such A tthan in jetting said acid liquid against said material to 14 be pickled, shield plates are disposed substantially near said upper and lower surfaces of said material.

6. A continouus pickling method according to Claim 3 wherein in jetting said acid liquid against said material 5 to be pickled, said material is surrounded by a box shield.

7. A continuous pickling method according to any one of the preceding claims, wherein said heating treatment prior to pickling is carried out by a pre-treatment apparatus, which comprises: a pressure-sealed tank for retaining therein hot water having a temperatre higher than the Sboiling point under atmospheric pressure of an acid liquid ,i to be used in said pickling method, said tank having an inlet and an outlet through which metallic material to be Hi pickled, in use, passes; a heating device for heating said i 15 hot water; and, seal rolls disposed at said inlet and |i outlet. i i8. A continuous pickling method substantially as herinbefore described wih reference to any one of Figures 1 to 9 of the accompanying drawings. 20 9. A continuous pre-treating and pickling apparatus substantially as hereinbefore descirbed with reference to o, Oany one of Figures 1 to 9 of the accompanying drawings. DATED DECEMBER 29, 1989 MITSUBISHI JUGOGYO KADUSHIKI KAISHA By His Patent Attorneys KELVIN LORD AND COMPANY PERTH, WESTERN AUSTRALIA