AU4469796A - Low sludging composition and process for treating aluminum and its alloys - Google Patents
Low sludging composition and process for treating aluminum and its alloysInfo
- Publication number
- AU4469796A AU4469796A AU44697/96A AU4469796A AU4469796A AU 4469796 A AU4469796 A AU 4469796A AU 44697/96 A AU44697/96 A AU 44697/96A AU 4469796 A AU4469796 A AU 4469796A AU 4469796 A AU4469796 A AU 4469796A
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- AU
- Australia
- Prior art keywords
- composition according
- aqueous liquid
- liquid composition
- component
- ppm
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- Abandoned
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/361—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing titanium, zirconium or hafnium compounds
Description
Description SLUDGING COMPOSITION AND PROCESS FOR TREATING ALUMINUM
AND ITS ALLOYS
Technical Field
This invention relates to a surface treatment composition and process that form a conversion coating on the surface of aluminiferous metals that imparts an excellent corrosion resistance and paint adherence to such surfaces prior to their painting. The aqueous solutions of this composition are transparent solutions that resist the production of a precipitating solid even when they contain eluted aluminum. The present invention is applied with particularly good effect to the surface treatment of drawn-and-ironed aluminum cans (hereinafter usually abbreviated as "aluminum Dl cans"). Sludge adhesion to the equipment is inhibited and an excellent corrosion resistance and paint adherence are imparted to the substrate surface when aluminum Dl cans fabricated by the drawing and ironing of aluminum alloy sheets are subjected, prior to their being painted and/or printed, to surface treatment with a surface treatment bath according to the present invention. Background Art
The outside bottom surface of aluminum Dl cans is subjected to high-tem¬ perature sterilization without being painted. If this region has a low corrosion resistance, the aluminum is oxidized and blackened during this step, and its appearance is thereby impaired. This phenomenon is generally known as "blackening". As a result, the (unpainted) conversion coating produced by sur¬ face treatment desirably should have an intrinsically high corrosion resistance. At the present time, the surface treatment of aluminum Dl cans is carried out mainly using Cr(VI)-containing phosphoric acid-chromate treatments and zirconium-type nonchromate treatments. These treatments are applied to the surfaces of the cans as aqueous liquid compositions, which hereinafter are us¬ ually called "baths" for brevity, even though they are more often applied by spray¬ ing the "bath" liquid onto cans than by immersion of the cans in the baths.
A typical example of nonchromate surface treatment baths is disclosed in
Japanese Patent Publication Number Sho 56-33468 [33,468/1981]. This surface treatment bath is an acidic (pH 1.5 to 4.0) water-based coating solution that contains phosphate, fluoride, and zirconium or titanium or a mixture thereof. The characteristic features of this acidic nonchromate treatment bath are s that it contains effective fluoride and does not contain a solid-producing com¬ ponent that is prone to precipitation. Since this nonchromate treatment bath does not contain toxic hexavalent chromium, it has come to be widely used at the present time as a surface treatment agent for aluminum Dl cans. However, this bath in actuality also suffers from major drawbacks as described in the following. o When the prior art surface treatment baths are used on can manufacturing lines, they are ordinarily sprayed on the aluminum Dl cans for about 15 to 30 seconds. When an object shaped like aluminum Dl cans is subjected to spray treatment for such a brief period of time, the resulting coating may not be uniform, because of differences that occur between different regions of the can s in the bath flow rate and in the contact conditions between the bath and the surface of the substrate. This creates variations or instabilities in the anticor- rosion performance.
If, however, the production of a large conversion coating weight on the outside bottom surface of the can is pursued in order to stabilize the anticorro- o sion performance, too much conversion coating will be produced on the necking or flange regions that are processed after painting. This causes the problem of paint delamination after painting.
This variation in coating weight among the aforementioned regions is even more substantial in the case of aged surface treatment baths where the ac- 5 cumulated concentration of eluted aluminum in the solution has reached high values.
When the aforementioned prior art surface treatment bath is used industri¬ ally, avoiding unacceptable paint delamination results in the major drawback of requiring the use of an effective fluoride concentration, which essentially must be
30 maintained at a constant value during use of the bath, that is somewhat smaller than that which would be most desirable for avoiding blackening and avoiding the formation of precipitates.
Due to this, when aluminum ions actually do elute and enter the bath, pre¬ cipitation occurs even for the above-described surface treatment bath with its distinguishing feature of not containing a highly precipitation-prone solid-pro¬ ducing component. Even with this bath, then, problems such as equipment soiling, nozzle clogging, and the like, do in fact occur. Disclosure of the Invention
Problems to Be Solved bv the Invention The present invention seeks to solve the problems described above for the prior art. In specific terms, the present invention introduces a bath and a pro- cess using said bath that not only are able to produce a highly corrosion-re¬ sistant, strongly paint-adherent conversion coating on the surfaces of alumin¬ iferous metal substrates, but which also exhibit excellent properties in terms of conversion coating uniformity, sludging inhibition, and process stability.
Summary of the Invention It has been discovered that:
(i) a treatment bath that maintains a transparent appearance can be obtained when an oxidizing agent and a hydrogen fluoride-generating compound that produces a particular value for the HF concentration are also present in a surface treatment bath that contains a phosphoric acid compound and zirconium compound and has a pH of 1.5 to 4.0;
(ii) an excellent corrosion resistance and good paint adherence can be imparted to the surface of aluminiferous metal substrates by the formation thereon of a conversion coating by contacting the surface of the aluminiferous metal with the aforesaid conversion bath for 0.5 to 60 seconds; and (hi) the conversion coating thereby formed is very uniform, while at the same time an excellent sludging inhibition is obtained.
The highly sludging-inhibited composition according to the present inven¬ tion for treating the surface of aluminiferous metals is a waterborne surface treatment bath that forms a conversion coating on the surface of aluminiferous metals and is characterized in that it has a pH of 1.5 to 4.0 and comprises, pref¬ erably consists essentially of, or more preferably consists of water and the fol¬ lowing components:
(A) at least one phosphoric acid compound,
(B) at least one zirconium compound,
(C) at least one oxidizing agent, and
(D) at least one compound that is a source of hydrogen fluoride, in a quantity s that produces a total concentration of hydrogen fluoride in the aqueous solution in the range from 0.0001 to 0.2 grams per liter (hereinafter us¬ ually abbreviated as "g/L"). Detailed Description of the Invention and Preferred Embodiments Thereof The aforesaid hydrogen fluoride-generating compound in the surface o treatment composition according to the present invention is preferably selected from hydrofluoric acid and ammonium fluoride.
The aforesaid oxidizing agent in the surface treatment composition accor¬ ding to the present invention preferably consists of at least one selection from hydrogen peroxide, nitrous acid, organoperoxides, and salts of the preceding, s The aforesaid zirconium compound(s) are preferably present in a surface treatment composition according to the present invention at a total concentration of 0.005 to 0.5 g/L as zirconium.
The aforesaid phosphoric acid compound(s) is preferably present in a sur¬ face treatment composition according to the present invention at a concentration 0 of 0.005 to 0.4 g/L as PO4 "3 ions. The total stoichiometric equivalent as P04 '3 ions of all orthophosphoric acid (i.e., H3PO4), metaphosphoric acids (i.e., [HPO-Jx, where x is a positive integer with a value of at least 3), and condensed phosphoric acids (i.e.,
where n is a positive integer with a value of at least 2) and any anionic products formed by dissociation of any of these acids, 5 including such anions added to the composition in the form of salts, is to be understood as constituting the P04 "3 ions content for the definition of this concentration, irrespective of the actual extent of ionization, dissociation, and/or association that may occur in the surface treatment composition.
The aforesaid oxidizing agent is preferably present in the surface o treatment composition according to the present invention at a concentration of 0.01 to 5.0 g/L.
A highly sludging-inhibited process according to the present invention for
treating the surface of aluminiferous metal substrates is characterized by the formation of a conversion coating on the surface of aluminiferous metal by con¬ tacting said surface for 0.5 to 60 seconds with a treatment bath containing any surface treatment composition as described directly above and thereafter, optionally, subjecting said surface to a water rinse and drying.
When prior art surface treatment agents with their relatively slow reaction rates are sprayed on an article shaped like aluminum Dl cans, the resulting conversion coating usually will not be uniform, because of differences in bath flow rate and surface/bath contact conditions that occur between different regions. The conversion coating may therefore exhibit an uneven performance. In the specific case of aged surface treatment solutions in which the aluminum ions concentration in the solution has reached high levels, fluorine is consumed from the fluorocomplex of zirconium and it becomes necessary to add additional fluorine source in order to keep the zirconium stably dissolved in the bath, i.e., to keep the treatment bath transparent. This causes an even more pronounced variation in coating weight among the various regions of the can.
The inventors discovered that the rate of the conversion coating formation reactions and the uniformity of the conversion coating can be improved through the presence of HF — in addition to zirconium, phosphoric acid, and oxidizing agent — for the purpose of stabilizing the quality by eliminating the variations in coating weight between the regions of such a shaped article that would otherwise arise from differences in reaction rate.
It was also discovered that managing the HF concentration to 0.0001 to 0.2 g/L in order to inhibit precipitation of the zirconium in the treatment bath leads to an improved inhibition of sludge formation even in the case of aged treatment baths having high aluminum ion concentrations.
Coating formation is believed to occur during treatment with a zirconium- containing treatment bath because of an increase in pH at the interface between the metal substrate and the treatment bath. On the other hand, with regard to the hydrofluoric acid and aluminum fluorocomplexes present in conversion treatment baths, it is known that the structures of these compounds change as a function of the pH of the treatment bath. Free fluoride (F), hydrofluoric acid
(HF), and various aluminum fluorocomplexes may be present in an acidic aqueous solution containing aluminum and fluorine. Their proportions vary with variations in the pH of the aqueous solution. Conversion coating formation reactions are believed to occur due to the decline in the HF concentration in the vicinity of the interface. Therefore, control of the HF concentration in the treatment bath becomes necessary in order to maintain a high conversion activity and a transparent appearance on the part of the treatment bath.
The HF concentration is measured in the present invention as follows. A commercially available fluoride ion reference solution is first diluted with a com- mercially available solution for adjusting the pH/ionic strength, in order to prepare three reference solutions with the following F" concentrations: P = 1 mg/L, F- = 10 mg/L, and F- = 100 mg/L. These are then equilibrated at the specified temperature and used to calibrate the measurement values of a fluoride ion meter. A sample of the surface treatment solution is then equilibrated at the specified temperature, and its F concentration is obtained using the calibrated fluorine ion meter and converted to the molar concentration, designated as "[F"]". The pH of the treatment bath is also measured and the molar H* concentration, designated as "[H*]". is derived from this. The molar concentration of HF, designated as "[HF]", is then calculated from the known dissociation constant for HF according to the following equation: [HF] = {[H+] • [F"]/10"317}. The [HF] value thus obtained is converted to g/L by multiplying by the gram molecular weight of HF.
The following concentrations are preferred for the surface treatment composition according to the present invention: for the zirconium compound, 0.005 to 0.5 g/L as zirconium; for the phosphoric acid compound, 0.005 to 0.4 g/L as P04 ions; for the oxidizing agent, 0.01 to 5 g/L.
With regard to the concentrations of the phosphoric acid compound, zir¬ conium compound, and oxidizing agent in the surface treatment composition ac¬ cording to the present invention, if any of these falls below the above-specified lower limits, the resulting treatment bath will have an inadequate conversion coating formation activity and may not be able to lay down a conversion coating of sufficient thickness. No additional increases in effect are obtained when these
concentrations exceed the above-specified upper limits, and such concentrations therefore serve merely to raise the cost.
Zirconium-containing sludge is readily produced when the concentration of the hydrogen fluoride-source compound in the surface treatment composition according to the present invention falls below 0.0001 g/L as HF (hydrogen fluoride). An excessive etch, which impedes the formation of a conversion coating, occurs when this value exceeds 0.2 g/L.
A surface treatment process according to the present invention comprises the formation of a conversion coating by bringing the target surface of the aluminiferous metal substrate into contact with a treatment bath containing treat¬ ment composition as described above and then, optionally but preferably, exe¬ cuting thereon a water rinse and drying. Said contact between the treatment bath and metal surface may be implemented, using spray or immersion tech¬ nology, as a continuous one-step process or as an intermittent multi-step pro- cess. The total contact time preferably should be from 0.5 to 60 seconds. Because the specific component composition of the treatment bath is able to in¬ hibit sludge adhesion to the equipment, the described process according to the present invention can achieve an excellent operating stability and a high treat¬ ment efficiency. The surface treatment bath according to the present invention is an acidic treatment bath that contains phosphate ions, a zirconium compound, fluoride, and oxidizing agent as its essential components. The source of the phosphate ions in this treatment bath preferably is phosphoric acid, ammonium phosphate, and/or an alkali metal salt of phosphoric acid, with phosphoric acid and ammonium phosphate more preferred, taking into consideration sludging inhibition. The content is preferably 0.005 to 0.4 g/L as phosphate (P04) ions, while the range of 0.01 to 0.20 g/L as phosphate ion is even more preferred. Phosphate ion concentrations below 0.005 g/L result in a poor reactivity, which makes it very difficult to form satisfactory coatings. At the other extreme, no - additional benefits are obtained at concentrations in excess of 0.4 g/L, which therefore serve merely to raise the cost of the treatment bath and thus are eco¬ nomically undesirable.
The presence of a zirconium compound in treatment baths according to the present invention is most advantageously brought about through the use of water-soluble compounds of zirconium, more preferably water-soluble fluorozir- conium complexes and still more preferably fluozirconic acid (H.ZrFβ) and its salts. With regard to the use of the oxide, hydroxide, nitrate, or phosphate of zir¬ conium, this should be accompanied by the simultaneous addition of fluoride that furnishes hydrogen fluoride in sufficient quantity to transform the zirconium into a water-soluble fluorocomplex and thereby prevent production of a precipitate. The zirconium compound content is preferably 0.005 to 0.5 g/L as zirconium and is more preferably 0.01 to 0.1 g/L as zirconium. Adequate film formation may not occur at a zirconium content below 0.005 g/L. No additional benefits are obtained at concentrations in excess of 0.5 g/L, which therefore serve merely to raise the cost of the treatment bath and thus are economically undesirable.
The presence of hydrogen fluoride in the treatment bath according to the present invention is most advantageously brought about by adding hydrofluoric acid or ammonium fluoride. The preferred HF content falls in the range of 0.0001 to 0.2 g/L and more preferably falls in the range of 0.01 to 0.1 g/L.
The oxidizing agent present in the treatment bath according to the present invention is exemplified by hydrogen peroxide, nitrous acid and its salts, and or- ganoperoxides. The use of hydrogen peroxide is most preferred, based on a consideration of the ease of treating the waste water produced by the process according to the present invention. The oxidizing agent functions to accelerate the rate of the reactions that produce the zirconium coating. The oxidizing agent content is preferably 0.01 to 5 g/L and more preferably 0.1 to 1.0 g/L. The reaction-accelerating activity may be unsatisfactory at oxidizing agent concentrations below 0.01 g/L. No problems are associated with concentrations in excess of 5 g/L, but such concentrations do not provide any additional benefit, and thus merely drive up the costs and are therefore economically undesirable.
The pH of the treatment bath should be adjusted to 1.5 to 4.0. The extent of etching becomes excessive at pH values below 1.5 and impedes conversion coating formation. The etch becomes too weak at pH values in excess of 4.0 and makes it difficult to form a highly corrosion-resistant coating. The preferred
pH range is 2.3 to 3.0. The pH can be adjusted through the use of an acid such as phosphoric acid, nitric acid, or hydrochloric acid, or through the use of an alkali such as ammonium hydroxide, ammonium carbonate, or sodium hydroxide. Phosphoric acid and nitric acid are the preferred acids for adjusting the pH, while basic ammonium compounds are preferred as the alkali.
The stability of the treatment bath can be substantially impaired by metal ions, such as those of copper, manganese, and the like, that are produced when an alloying component is eluted from the surface of the aluminiferous metal substrate. This can result in such problems as sludge production, precipitate formation, and the adhesion of sludge and/or precipitate to the equipment and the like. In order to prevent this from happening, an organic acid or salt thereof, for example, gluconic acid, oxalic acid, and their salts, may be added in order to chelate such components and stabilize the bath.
A water-soluble fluorocomplex of, for example, titanium, silicon, and the like, may also be added to the surface treatment bath according to the present invention along with the zirconium compound, for example, a water-soluble fluorozirconium complex.
An example of the surface treatment process according to the present invention for an aluminiferous metal substrate includes the following steps: (1) surface cleaning: degreasing (acidic, alkaline, or solvent-based degreasers may be used)
(2) water rinse
(3) conversion coating treatment (surface treatment using a treatment bath according to the present invention) (4) water rinse
(5) rinse with deionized water
(6) drying
The treatment temperature with the surface treatment bath according to the present invention is not crucial, and, for example, a temperature range from room temperature to 90 °C can be used. However, taking into consideration the stability, operating behavior, and productivity characteristics of the treatment bath, the bath is preferably used at from 25 °C to 50 °C. The treatment time is
also not crucial, but treatment times of, for example, 0.5 to 60 seconds are preferred and the range of 5 to 30 seconds is even more preferred. A full reaction is not usually obtained in less than 5 seconds; this would prevent the formation of a highly corrosion-resistant coating. At the other end of the range, no additional increase in performance has been observed at times above 60 seconds.
The surface treatment bath and process according to the present inven¬ tion will be illustrated through the working examples provided below.
Examples The following samples and performance evaluation tests were used in the working and comparative examples. (1 . Samples
The materials were aluminum alloy (A3004) sheets and aluminum Dl cans fabricated from this type of aluminum alloy sheet. These were each cleaned, prior to surface treatment according to this invention, with a hot aqueous solution of an acidic degreaser (PALKLIN™ 500, a product of Nihon Parkerizing Company, Limited, Tokyo). 12) Evaluation methods (a. Corrosion resistance and coating uniformity The corrosion resistance and coating uniformity were evaluated on the aluminum Dl cans based on the resistance to blackening by boiling water. The resistance to blackening by boiling water was tested as follows. After surface treatment, the aluminum Dl cans were immersed in boiling tap water for 30 min¬ utes. This was followed by a visual determination of the degree of discoloration (blackening) thereby produced at the elevations (regions where the bath flow rate was fast) and depression (region where the bath flow rate was slow) of the aluminum Dl cans. Said elevations correspond to the rib and exterior sidewall regions of actual aluminum Dl cans, while the depression corresponds to the dome region. The corrosion resistance was evaluated by scoring the test results on the following scale:
+ = no blackening
9595 PCI7US95/16231
@ = blackening over part of the surface x = blackening over the entire surface. The coating uniformity was rated as follows based on the resulting loca¬ tion-specific evaluation of the resistance to blackening by boiling water: a score of "uniform" was rendered when both locations were free of blackening, while a score of "nonuniform" was rendered when blackening occurred at only one location.
(b) Paint adherence
After the aluminum alloy (A3004) sheet had been subjected to the surface treatment, it was coated with a can-grade epoxy-urea paint to give a paint film thickness of 5 to 7 micrometers. This was followed by baking and drying to give a painted panel. A test panel was then prepared by bending the painted panel in a bending tester, and this test panel was subjected to a peel test using cellophane tape. The test results were scored as follows: + = peeling did not occur x = peeling occurred.
(c) Bath transparency
The treatment bath which had been used in the particular example or comparative example was held at 40 °C for 15 days. The amount of zirconium in the bath was measured both before and after this holding period, and the presence/absence of precipitate was determined from the difference in these values. A "+" indicates that precipitate was not produced, while "x" indicates that precipitate was produced.
(d) Confirming test for sludoe adhesion The treatment bath which had been used in the particular example or comparative example was supplied continuously for 16 hours to spray treatment using a small-scale sprayer held at 40 °C. During this time, the development of sludge at the nozzle of the device was inspected visually. A "+" indicates no sludge adhesion, while "x" indicates that sludge adhesion occurred. Example 1
The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 20 seconds with surface treatment bath (1) (composition given
below) heated to 40 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence. The aluminum nitrate was used as an aluminum source for the purpose of artificially aging the treatment bath.
Surface treatment bath (1 . phosphoric acid 30 ppm as P04 ions fluozirconic acid 30 ppm as Zr hydrogen peroxide 100 ppm as H202 aluminum nitrate 100 ppm as Al pH = 3.0 (adjusted with aqueous ammonia) concentration of HF = 11 ppm (adjusted with hydrofluoric acid).
Example 2 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 40 seconds with surface treatment bath (2) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rins¬ ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath 12) phosphoric acid 20 ppm as P04 ions fluozirconic acid 10 ppm as Zr hydrogen peroxide 300 ppm as H202 aluminum nitrate 50 ppm as Al pH = 2.7 (adjusted with aqueous ammonia) concentration of HF = 9 ppm (adjusted with hydrofluoric acid)
Example 3
The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 15 seconds with surface treatment bath (3) (composition given below) heated to 40 βC. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying
oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (3) phosphoric acid 40 ppm as P04 ions fluozirconic acid 40 ppm as Zr hydrogen peroxide 200 ppm as H202 aluminum nitrate 200 ppm as Al pH = 2.3 (adjusted with aqueous ammonia) concentration of HF = 15 ppm (adjusted with hydrofluoric acid) Example 4
The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were immersed for 10 seconds in surface treatment bath (4) (composition given below) heated to 30 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (4) phosphoric acid 150 ppm as P04 ions fluozirconic acid 100 ppm as Zr hydrogen peroxide 400 ppm as H202 aluminum nitrate 300 ppm as Al pH = 2.5 (adjusted with aqueous ammonia) concentration of HF = 70 ppm (adjusted with hydrofluoric acid)
Example 5 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 5 seconds with surface treatment bath (5) (composition given below) heated to 30 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (5. phosphoric acid 400 ppm as P04 ions ammonium fluozirconate 200 ppm as Zr hydrogen peroxide 500 ppm as H202 aluminum nitrate 500 ppm as Al pH = 2.5 (adjusted with aqueous ammonia) concentration of HF = 100 ppm (adjusted with hydrofluoric acid).
Example 6 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 15 seconds with surface treatment bath (6) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rins¬ ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence, Surface treatment bath (6) phosphoric acid 50 ppm as PO4 ions zirconium oxide 30 ppm as Zr hydrogen peroxide 200 ppm as H202 aluminum nitrate 200 ppm as AI pH = 2.3 (adjusted with aqueous ammonia) concentration of HF = 13 ppm (adjusted with hydrofluoric acid)
Example 7 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 15 seconds with surface treatment bath (7) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rins¬ ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath 17) phosphoric acid 50 ppm as P04 ions zirconium oxide 30 ppm as Zr hydrogen peroxide 200 ppm as H202
aluminum nitrate 100 ppm as Al pH = 3.5 (adjusted with aqueous ammonia) concentration of HF = 7 ppm (adjusted with hydrofluoric acid).
Comparative Example 1 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 10 seconds with surface treatment bath (8) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (8. (no oxidizing agent. phosphoric acid 30 ppm as P04 ions fluozirconic acid 30 ppm as Zr aluminum nitrate 200 ppm as Al pH = 3.0 (adjusted with aqueous ammonia) concentration of HF = 15 ppm (adjusted with hydrofluoric acid).
Comparative Example 2 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 10 seconds with surface treatment bath (9) (composition given below) heated to 50 °C. This was followed by rinsing with tap water, spray rins¬ ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (9) (no zirconium compound. phosphoric acid 50 ppm as P04 ions hydrofluoric acid 220 ppm as F hydrogen peroxide 500 ppm as H202 aluminum nitrate 100 ppm as Al pH = 2.5 (adjusted with aqueous ammonia) concentration of HF = 10 ppm (adjusted with hydrofluoric acid)
Comparative Example 3 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were
sprayed for 20 seconds with surface treatment bath (10) (composition given below) heated to 35 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (10. fluozirconic acid 40 ppm as Zr hydrogen peroxide 500 ppm as H202 aluminum nitrate 200 ppm as Al pH = 3.0 (adjusted with aqueous ammonia) concentration of HF = 50 ppm (adjusted with hydrofluoric acid).
Comparative Example 4 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 15 seconds with surface treatment bath (11) (composition given below) heated to 40 βC. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (11) phosphoric acid 50 ppm as P04 ions fluozirconic acid 50 ppm as Zr hydrogen peroxide 300 ppm as H202 aluminum nitrate 200 ppm as Al pH = 2.7 (adjusted with aqueous ammonia) concnetration of HF = 0.05 ppm (adjusted with hydrofluoric acid).
Comparative Example 5 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 10 seconds with surface treatment bath (12) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rins- ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (12) phosphoric acid 40 ppm as P04 ions zirconium oxide 40 ppm as Zr hydrogen peroxide 300 ppm as H202 aluminum nitrate 200 ppm as Al pH = 2.8 (adjusted with aqueous ammonia) concentration of HF = 0.01 ppm (adjusted with hydrofluoric acid).
Comparative Example 6 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 15 seconds with surface treatment bath (13) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rinsing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence, Surface treatment bath (13) phosphoric acid 40 ppm as P04 ions fluozirconic acid 40 ppm as Zr aluminum nitrate 300 ppm as Al pH = 3.0 (adjusted with aqueous ammonia) concentration of HF = 15 ppm (adjusted with hydrofluoric acid).
Comparative Example 7 The cleaned aluminum Dl cans and cleaned aluminum alloy sheets were sprayed for 30 seconds with surface treatment bath (14) (composition given below) heated to 40 °C. This was followed by rinsing with tap water, spray rins- ing for 10 seconds with deionized water, and then drying in a hot-air drying oven. The samples thus obtained were evaluated for their corrosion resistance, coating uniformity, and paint adherence.
Surface treatment bath (14) phosphoric acid 100 ppm as P04 ions fluozirconic acid 100 ppm as Zr aluminum nitrate 300 ppm as Al pH = 3.0 (adjusted with aqueous ammonia)
concentration of HF = 20 ppm (adjusted with hydrofluoric acid).
Test results from all the Examples and Comparative examples are report¬ ed in Table 1.
Examples 1 to 7 used surface treatment baths and surface treatment pro- cesses according to the present invention, and Table 1 confirms the following results for these examples: the obtained conversion coatings exhibited an excellent corrosion resistance and paint adherence; the obtained conversion coatings were very uniform; the surface treatment baths maintained their trans¬ parency; and sludge adhesion was thoroughly inhibited. In contrast, Com- parative Examples 1 to 7 — which used surface treatment baths outside the scope of the invention — in each case gave an unsatisfactory overall perform¬ ance because each was found to be deficient in at least one aspect (corrosion resistance, paint adherence, conversion coating uniformity, treatment bath transparency, and inhibition of sludge adhesion). The surface treatment composition and surface treatment process accord¬ ing to the present invention impart an excellent corrosion resistance and ex¬ cellent paint adherence to the surface of aluminiferous metal substrates prior to the painting thereof. Other desirable effects demonstrated by this composition and process are a very uniform conversion coating, excellent treatment bath transparency, and an excellent inhibition of sludge adhesion.
These characteristics confer a high degree of practical utility on the bath and process according to the present invention for treating the surface of alumin¬ iferous metal substrates.
TABLE 1
Example Corrosion Resistance and Uniformity Paint Bath Inhibition or Com¬ Adher¬ Trans¬ of Sludge parison Elevations Depressions Uniformity ence parency Adhesion Example
Ex l + + uniform + + +
Ex 2 + + uniform + + +
Ex 3 + + uniform + + +
Ex 4 + + uniform + + +
Ex 5 + + uniform + + +
Ex 6 + + uniform + + +
Ex 7 + + uniform + + +
CE 1 x x - + + +
CE 2 x X - + + +
CE 3 x X - + + +
CE 4 + + uniform + X X
CE 5 x @ nonuniform + X X
CE 6 x + nonuniform + + +
CE 7 @ + nonuniform X + +
Abbreviations for Table 1 "Ex" = "Example"; "CE" = "Comparative Example".
Claims (19)
1. A highly sludging-inhibited aqueous liquid composition for treating the sur¬ face of aluminiferous metals, said composition having a pH of 1.5 to 4.0 and comprising water and: s (A) at least one phosphoric acid compound,
(B) at least one zirconium compound,
(C) at least one oxidizing agent, and
(D) at least one compound that is a source of hydrogen fluoride, in a quantity that produces a total concentration of hydrogen fluoride in the aqueous o composition in the range from 0.0001 to 0.2 g/L.
2. An aqueous liquid composition according to claim 1 , in which component (D) is selected from the group consisting of hydrofluoric acid, ammonium fluoride, and mixtures thereof.
3. An aqueous liquid composition according to claim 2, in which component s (C) is selected from the group consisting of hydrogen peroxide, nitrous acid and its salts, organoperoxides, and mixtures of any two or more of the preceding.
4. An aqueous liquid composition according to claim 1 , in which component (C) is selected from the group consisting of hydrogen peroxide, nitrous acid and its salts, organoperoxides, and mixtures of any two or more of the preceding. 0 5. An aqueous liquid composition according to claim 4, in which the concen¬ tration of component (B) is from 0.005 to 0.
5 g/L, measured as zirconium.
6. An aqueous liquid composition according to claim 3, in which the con¬ centration of component (B) is from 0.005 to 0.5 g/L, measured as zirconium.
7. An aqueous liquid composition according to claim 2, in which the con- 5 centration of component (B) is from 0.005 to 0.5 g/L, measured as zirconium.
8. An aqueous liquid composition according to claim 1 , in which the concen¬ tration of component (B) is from 0.005 to 0.5 g/L, measured as zirconium.
9. An aqueous liquid composition according to claim 8, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as PO4 ions. 0
10. An aqueous liquid composition according to claim 7, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as P04 ions.
11. An aqueous liquid composition according to claim 6, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as P04 ions.
12. An aqueous liquid composition according to claim 5, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as PO4 ions.
13. An aqueous liquid composition according to claim 4, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as P04 ions.
14. An aqueous liquid composition according to claim 3, in which the concen- tration of component (A) is from 0.005 to 0.4 g/L as P04 ions.
15. An aqueous liquid composition according to claim 2, in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as PO4 ions.
16. An aqueous liquid composition according to claim 1 , in which the concen¬ tration of component (A) is from 0.005 to 0.4 g/L as P04 ions.
17. An aqueous liquid composition according to any one of claims 1 through 16, in which the concentration of component (C) is 0.01 to 5.0 g/L.
18. A process of forming a protective conversion coating on an aluminiferous substrate surface, said process comprising contacting the substrate surface with an aqueous liquid composition according to claim 17 for from 0.5 to 60 seconds, and, optionally, thereafter subjecting said substrate surface to a water rinse and drying.
19. A process of forming a protective conversion coating on an aluminiferous substrate surface, said process comprising contacting the substrate surface with an aqueous liquid composition according to any one of claims 1 through 16 for from 0.5 to 60 seconds, and, optionally, thereafter subjecting said substrate surface to a water rinse and drying.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32054594A JP3349851B2 (en) | 1994-12-22 | 1994-12-22 | Surface treatment composition for aluminum-containing metal material excellent in sludge suppression property and surface treatment method |
| JP6-320545 | 1994-12-22 | ||
| PCT/US1995/016231 WO1996019595A1 (en) | 1994-12-22 | 1995-12-22 | Low sludging composition and process for treating aluminum and its alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU4469796A true AU4469796A (en) | 1996-07-10 |
Family
ID=18122634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU44697/96A Abandoned AU4469796A (en) | 1994-12-22 | 1995-12-22 | Low sludging composition and process for treating aluminum and its alloys |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0799326A4 (en) |
| JP (1) | JP3349851B2 (en) |
| AR (1) | AR000514A1 (en) |
| AU (1) | AU4469796A (en) |
| BR (1) | BR9510243A (en) |
| CA (1) | CA2208459A1 (en) |
| TR (1) | TR199501662A2 (en) |
| WO (1) | WO1996019595A1 (en) |
| ZA (1) | ZA9510615B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU757539B2 (en) | 1997-08-21 | 2003-02-27 | Henkel Kommanditgesellschaft Auf Aktien | Process for coating and/or touching up coatings on metal surfaces |
| ATE217363T1 (en) * | 1997-09-17 | 2002-05-15 | Chemetall Plc | METHOD AND COMPOSITION FOR CORROSION PROTECTION OF METAL SURFACES |
| US6432603B1 (en) * | 1998-11-27 | 2002-08-13 | Canon Kabushiki Kaisha | Process for producing electrophotographic photosensitive member |
| US6168868B1 (en) * | 1999-05-11 | 2001-01-02 | Ppg Industries Ohio, Inc. | Process for applying a lead-free coating to untreated metal substrates via electrodeposition |
| DE19933189A1 (en) * | 1999-07-15 | 2001-01-18 | Henkel Kgaa | Process for the protection against corrosion or aftertreatment of metal surfaces |
| JP2001342578A (en) * | 2000-05-31 | 2001-12-14 | Honda Motor Co Ltd | Surface treatment agent for metal |
| JP4707258B2 (en) * | 2001-05-07 | 2011-06-22 | 日本ペイント株式会社 | Acid cleaning agent for chemical film and treatment method |
| JP5111701B2 (en) * | 2001-09-11 | 2013-01-09 | 日本ペイント株式会社 | Surface treatment method for aluminum or aluminum alloy |
| US6761933B2 (en) | 2002-10-24 | 2004-07-13 | Ppg Industries Ohio, Inc. | Process for coating untreated metal substrates |
| CA2454029A1 (en) * | 2002-12-24 | 2004-06-24 | Nippon Paint Co., Ltd. | Chemical conversion coating agent and surface-treated metal |
| WO2006098359A1 (en) | 2005-03-16 | 2006-09-21 | Nihon Parkerizing Co., Ltd. | Surface-treated metallic material |
| US7815751B2 (en) | 2005-09-28 | 2010-10-19 | Coral Chemical Company | Zirconium-vanadium conversion coating compositions for ferrous metals and a method for providing conversion coatings |
| US7980000B2 (en) * | 2006-12-29 | 2011-07-19 | Applied Materials, Inc. | Vapor dryer having hydrophilic end effector |
| US8673091B2 (en) | 2007-08-03 | 2014-03-18 | Ppg Industries Ohio, Inc | Pretreatment compositions and methods for coating a metal substrate |
| US9574093B2 (en) | 2007-09-28 | 2017-02-21 | Ppg Industries Ohio, Inc. | Methods for coating a metal substrate and related coated metal substrates |
| JP5215043B2 (en) * | 2008-06-02 | 2013-06-19 | 日本パーカライジング株式会社 | Metal surface treatment liquid and surface treatment method |
| US8282801B2 (en) | 2008-12-18 | 2012-10-09 | Ppg Industries Ohio, Inc. | Methods for passivating a metal substrate and related coated metal substrates |
| US9273399B2 (en) | 2013-03-15 | 2016-03-01 | Ppg Industries Ohio, Inc. | Pretreatment compositions and methods for coating a battery electrode |
| EP3031951B1 (en) * | 2014-12-12 | 2017-10-04 | Henkel AG & Co. KGaA | Optimized process control in the pretreatment of metals to protect against corrosion on the basis of baths containing fluoride |
| FR3044329A1 (en) * | 2015-11-27 | 2017-06-02 | Constellium Neuf-Brisach | METHOD FOR ELECTROLYTIC DEPOSITION OF AN ALTERNATING CURRENT CONVERSION LAYER |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3539403A (en) * | 1966-12-07 | 1970-11-10 | Collardin Gmbh Gerhard | Solutions for the deposition of protective layers on zinc surfaces and process therefor |
| JPS5424232A (en) * | 1977-07-26 | 1979-02-23 | Nippon Packaging Kk | Surface treating method of aluminum |
| CA1333043C (en) * | 1988-02-15 | 1994-11-15 | Nippon Paint Co., Ltd. | Surface treatment chemical and bath for aluminium and its alloy |
| JPH0364484A (en) * | 1989-08-01 | 1991-03-19 | Nippon Paint Co Ltd | Surface treating agent and treating bath for aluminum or aluminum alloy |
| US5139586A (en) * | 1991-02-11 | 1992-08-18 | Coral International, Inc. | Coating composition and method for the treatment of formed metal surfaces |
| GB2259920A (en) * | 1991-09-10 | 1993-03-31 | Gibson Chem Ltd | Surface conversion coating solution based on molybdenum and phosphate compounds |
| US5143562A (en) * | 1991-11-01 | 1992-09-01 | Henkel Corporation | Broadly applicable phosphate conversion coating composition and process |
| JPH0748677A (en) * | 1993-07-05 | 1995-02-21 | Nippon Parkerizing Co Ltd | Aluminum di can and common surface treatment solution and process for tin di can |
| JP2828409B2 (en) * | 1994-03-24 | 1998-11-25 | 日本パーカライジング株式会社 | Surface treatment composition for aluminum-containing metal material and surface treatment method |
-
1994
- 1994-12-22 JP JP32054594A patent/JP3349851B2/en not_active Ceased
-
1995
- 1995-12-13 ZA ZA9510615A patent/ZA9510615B/en unknown
- 1995-12-15 AR AR33464295A patent/AR000514A1/en unknown
- 1995-12-22 CA CA 2208459 patent/CA2208459A1/en not_active Abandoned
- 1995-12-22 AU AU44697/96A patent/AU4469796A/en not_active Abandoned
- 1995-12-22 WO PCT/US1995/016231 patent/WO1996019595A1/en not_active Application Discontinuation
- 1995-12-22 BR BR9510243A patent/BR9510243A/en not_active Application Discontinuation
- 1995-12-22 TR TR95/01662A patent/TR199501662A2/en unknown
- 1995-12-22 EP EP95943426A patent/EP0799326A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP3349851B2 (en) | 2002-11-25 |
| EP0799326A1 (en) | 1997-10-08 |
| CA2208459A1 (en) | 1996-06-27 |
| ZA9510615B (en) | 1996-07-03 |
| BR9510243A (en) | 1997-11-04 |
| TR199501662A2 (en) | 1996-07-21 |
| WO1996019595A1 (en) | 1996-06-27 |
| AR000514A1 (en) | 1997-07-10 |
| JPH08176841A (en) | 1996-07-09 |
| EP0799326A4 (en) | 1997-12-10 |
| MX9704518A (en) | 1997-10-31 |
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