AU3939993A - Acidic activated bleaching compositon - Google Patents
Acidic activated bleaching compositonInfo
- Publication number
- AU3939993A AU3939993A AU39399/93A AU3939993A AU3939993A AU 3939993 A AU3939993 A AU 3939993A AU 39399/93 A AU39399/93 A AU 39399/93A AU 3939993 A AU3939993 A AU 3939993A AU 3939993 A AU3939993 A AU 3939993A
- Authority
- AU
- Australia
- Prior art keywords
- composition according
- hydrogen peroxide
- organic peracid
- composition
- peracid precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/391—Oxygen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
Acidic activated bleaching composition
Technical field
The present invention relates to bleaching compositions, mainly for use in laundry applications. The compositions according to the present invention, which comprise hydrogen peroxide as well as peracid precursors, are stable upon storage.
Background
Bleaching compositions using hydrogen peroxide have been extensively described in the art. Such hydrogen peroxide bleaches have an advantage over chlorine bleaches in that they are environmentally more compatible. Another advantage is that they are "milder" bleaches. This latter advantage is especially
significant in laundry applications as hydrogen peroxide bleaches are safer to fabrics.
A major drawback of hydrogen peroxide bleaches is that they are less active than chlorine bleaches at low temperatures which are often encountered in modern laundering applications. Thus, hydrogen peroxide bleach activators have been developed and have been extensively described in the art. These activators are mainly transition metals or peracid precursors. Peracid precursors react with hydrogen peroxide to yield peracids. Peracids are the "activated" bleaching compounds which are efficient at low temperatures.
A problem which occurs in the formulation of such "activated" hydrogen peroxide bleaching compositions is the difficulty to obtain a composition which is both chemically and physically stable. Indeed, such compositions of the prior art are either turbid suspensions of insoluble activators with good chemical stability, or clear compositions with poor chemical stability which causes significant and undesired oxygen release.
It has now been found that this problem could be addressed by formulating a bleaching composition comprising hydrogen peroxide, an organic peracid precursor selected from a specific class, e.g. glycol and glycerin esters, and by formulating said composition in a narrow, acidic pH range. The mildly acidic pH range allows for adequate chemical stability of both the hydrogen peroxide and the organic peracid precursor. The activation of hydrogen peroxide trough the formation of a peracid is enhanced by the pH raise
which occurs upon dilution in the wash water, especially when a detergent composition bringing further alkalinity is also present in the wash water.
Glycol esters have been often described as solvents in detergent and bleaching compositions. Such compositions are described for instance in US 3 956 159. These compositions have a pH of 6.5 and above.
J 62252500 (abstract) discloses bleaching compositions which comprise a bleach activator, including triacetin. These compositions are formulated at neutral or weakly basic pH.
Bleaching compositions for various applications, comprising triacetin are also disclosed in J62001792, J62001794 J 62001796, and J61Q42600 (abstracts).
Summary of the invention
The compositions according to the present invention are clear aqueous bleaching compositions comprising hydrogen peroxide as well as an organic peracid precursor, characterized in that the compositions have a pH in the range of from about 3.5 to about 6, and that the organic peracid precursor is a compound according to the formula:
wherein x is 0 or 1, R1# R2, R3 are independently selected from -H, -OH, -C-0-R4 or -0-C-R4 where RΛ is
II II *
0 O c l~ 4 alkyl, with the proviso that at least two of R^, R2 or R3 are -0-C-R4; or mixtures thereof.
O
Detailed description of the invention
The compositions according to the present invention are clear aqueous liquid compositions which comprise hydrogen peroxide. Preferably, the compositions according to the present invention comprise from about 0.5 % to about 20 % by weight of the total composition of hydrogen peroxide, more preferably from about 2 % to about 15 %, most preferably from about 4 % to about 9%.
The compositions according to the present invention further comprise a specific organic peracid precursor according to the formula:
wherein x is 0 or 1, R^, R , R3 are independently selected from -H, -OH, -C-0-R4 or -0-C-R4 where R4 is
11 11 o o
C1-C alkyl, with the proviso that at least two of R^, R2 or R3 are -0-C-R4; or mixtures thereof. All these
0
compounds are well known chemicals which are commercially available or can be synthesized according to the chemical literature.
Preferred such peracid precursors for use in the compositions according to the present invention are selected from ethylene glycol diesters, triacetin and diacetin, or mixtures thereof. Particularly preferred compounds are triacetin and ethylene glycol diacetate. Tributyrin also displays excellent stability in the compositions according to the present invention but is less preferred because it is less soluble in the compositions according to the present invention.
The compositions according to the present invention typically comprise from about 1 % to about 15 % by weight of the total composition of such an organic peracid precursor, or mixtures thereof. The desired amount of organic peracid precursor can also be defined in relation to the amount of hydrogen peroxide in the composition. Accordingly, the compositions according to the present invention preferably comprise from about 0.1 to about 2 moles of organic peracid precursor per mole of hydrogen peroxide.
The compositions according to the present invention have a pH in the range of from about 3.5 to about 6, most preferably from about 3.5 to about 5, most preferably about 4. The pH of the composition can be adjusted and buffered with such chemicals as organic and inorganic acids which are stable to oxidation, citric acid, sulphuric acid, sodium hydroxide, ammonia and amines. Preferred buffer for use in the
compositions according to the present invention is citric acid. It is essential that the pH of the composition remains within the above range as said range is critical to ensure adequate chemical stability of the hydrogen peroxide and of the specific organic peracid precursors used in the compositions according to the present invention.
The compositions according to the present invention may comprise surfactants. Preferred surfactants for use herein are well known anionic surfactants such as alkyl benzene sulphonates and alkyl sulfates, and/or nonionic surfactants such as ethoxylated aήd/or propoxylated alcohols. All surfactants for use herein must be resistant to oxidation by peracids and hydrogen peroxide, and are preferably water-soluble. The compositions according to the present invention can comprise from 0% to about 30% by weight of the total composition of surfactants, preferably from about 0.5 % to about 15 %, most preferably from about 2 % to 8 %.
The compositions according to the present invention may further comprise peroxide stabilizers such as stannates, 8-hydroxyquinoline, pyrophosphates and phosphonates. Chelating agents may also be useful in the context of the present invention; suitable chelants include EDTA, NTA and DETPA, picolinic and dipicolinic acids and amino polyphosphonates, although some of these are poorly environmentally compatible. Radical scavengers can also be used herein, such as butylated hydroxy toluene and other hindered hydroxy benzenes, or sodium benzoate. Butylated hydroxy toluene is a highly preferred ingredient as it has been observed that it
stabilizes the peracid precursors according to the present invention, as well as hydrogen peroxide.
The compositions according to the present invention can also comprise such optional ingredients as whitening agents, dyes, builders, thickeners, hydrotropes, perfumes, all of which need to be compatible with the mildly acidic pH and the oxidizing environment of the compositions according to the present invention.
The compositions according to the present invention are further illustrated in the following examples.
Examples
The following compositions are made by mixing together the listed ingredients in the listed proportions.
pH 4
Ingredients: % by weight:
V VI VII VIII
Hydrogen peroxide 6.0 8.0 3.5 5.0 Na alkyl sulphate 2.8 2.0 4.0 3.5 Triacetin 3.0 5.0 Ethylene glycol diacetate 4.0 5.0 Citric acid 1.0 1.0 1.0 1.0 Na stannate 0.0015 0.0015 0.0010 0.0015 Na hydroxide pH 4 pH 4 pH 4 pH 4 Water & minors up to 100 %
Claims (11)
1. An aqueous bleaching composition comprising hydrogen peroxide and an organic peracid precursor, characterized in that the compositions have a pH in the range of from about 3.5 to about 6, and that the organic peracid precursor is a compound according to the formula:
wherein x is 0 or 1, Rlf R2, R3 are independently selected from -H, -OH, -C-0-R4 or -0-C-R4 where R4
II 4 l( 4 4 0 O is C1-C4 alkyl, with the proviso that at least two of Rl' R2 or R3 are -0-C-R4; or mixtures thereof.
2. A composition according to claim 1 which has a pH in the range of from about 3.5 to about 5.
3. A composition according to claim 2 which has a pH of about 4.
A composition according to any of the preceding claims wherein the organic peracid precursor is selected from ethylene glycol diesters, triacetin, diacetin, or mixtures thereof.
5. A composition according to claim 4 wherein the organic peracid precursor is selected from triacetin and ethylene glycol diacetate.
6. A composition according to any of the preceding claims which comprises from about 0.5 % to about 20 % by weight of the total composition of hydrogen peroxide.
7. A composition according to any of the preceding claims which comprises from about 1 % to about 15 % by weight of the total composition of said organic peracid precursor.
8. A composition according to claim 6 which comprises from about 0.1 to about 2 moles of said organic peracid precursor per mole of hydrogen peroxide.
9. A composition according to any of the preceding claims which comprises from about 0.5 % to about 15 % by weight of the total composition of a surfactant.
10.A composition according to any of the preceding claims which comprises citric acid.
11.A composition according to any of the preceding claims which comprises butylated hydroxy toluene.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92200961 | 1992-04-03 | ||
EP19920200961 EP0563460B1 (en) | 1992-04-03 | 1992-04-03 | Acidic activated bleaching composition |
PCT/US1993/002944 WO1993020167A1 (en) | 1992-04-03 | 1993-03-29 | Acidic activated bleaching compositon |
Publications (2)
Publication Number | Publication Date |
---|---|
AU3939993A true AU3939993A (en) | 1993-11-08 |
AU668936B2 AU668936B2 (en) | 1996-05-23 |
Family
ID=8210529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU39399/93A Ceased AU668936B2 (en) | 1992-04-03 | 1993-03-29 | Acidic activated bleaching compositon |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0563460B1 (en) |
JP (1) | JPH07505437A (en) |
CN (1) | CN1078254A (en) |
AU (1) | AU668936B2 (en) |
BR (1) | BR9306183A (en) |
DE (1) | DE69226072T2 (en) |
ES (1) | ES2118105T3 (en) |
IE (1) | IE930263A1 (en) |
TW (1) | TW299351B (en) |
WO (1) | WO1993020167A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU688356B2 (en) * | 1993-08-03 | 1998-03-12 | Procter & Gamble Company, The | A process of cleaning carpets using active oxygen compounds in an acidic aqueous medium |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5753138A (en) * | 1993-06-24 | 1998-05-19 | The Procter & Gamble Company | Bleaching detergent compositions comprising bleach activators effective at low perhydroxyl concentrations |
GB9600159D0 (en) * | 1996-01-05 | 1996-03-06 | Warwick Int Group | Process for bleaching or disinfecting a substrate |
US5879409A (en) * | 1996-02-23 | 1999-03-09 | The Procter & Gamble Company | Bleach additive and bleaching compositions having glycine anhydride activators |
US6221341B1 (en) * | 1997-11-19 | 2001-04-24 | Oraceutical Llc | Tooth whitening compositions |
WO2004089089A1 (en) | 2003-04-02 | 2004-10-21 | Kao Corporation | Composition for bactericide production and process for producing organic peracid |
EP1496104B1 (en) * | 2003-07-08 | 2008-05-07 | The Procter & Gamble Company | Liquid activator composition |
WO2010030769A1 (en) * | 2008-09-10 | 2010-03-18 | Danisco Us Inc. | Enzymatic textile bleaching compositions and methods of use thereof |
US8546449B2 (en) | 2011-03-24 | 2013-10-01 | Enviro Tech Chemical Services, Inc. | Methods and compositions for the generation of peracetic acid on site at the point-of-use |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3956159A (en) * | 1974-11-25 | 1976-05-11 | The Procter & Gamble Company | Stable concentrated liquid peroxygen bleach composition |
EP0125781B1 (en) * | 1983-04-14 | 1987-08-12 | Interox Chemicals Limited | Peroxygen compounds |
JPS6142600A (en) * | 1984-08-06 | 1986-03-01 | 花王株式会社 | Fungicidal composition |
JPS621796A (en) * | 1985-06-28 | 1987-01-07 | 花王株式会社 | Bleaching composition |
JPS621792A (en) * | 1985-06-28 | 1987-01-07 | 花王株式会社 | Bleaching composition |
JPS621794A (en) * | 1985-06-28 | 1987-01-07 | 花王株式会社 | Bleaching composition |
JPS62252500A (en) * | 1986-04-25 | 1987-11-04 | 花王株式会社 | Bleaching composition |
US4800038A (en) * | 1988-01-21 | 1989-01-24 | Colgate-Palmolive Company | Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners |
US5047168A (en) * | 1988-01-21 | 1991-09-10 | Colgate-Palmolive Co. | Sugar ethers as bleach stable detergency boosters |
US5151212A (en) * | 1990-03-21 | 1992-09-29 | The Belzak Corporation | Peroxygen compound activation |
-
1992
- 1992-04-03 DE DE1992626072 patent/DE69226072T2/en not_active Expired - Fee Related
- 1992-04-03 ES ES92200961T patent/ES2118105T3/en not_active Expired - Lifetime
- 1992-04-03 EP EP19920200961 patent/EP0563460B1/en not_active Expired - Lifetime
-
1993
- 1993-03-29 BR BR9306183A patent/BR9306183A/en not_active Application Discontinuation
- 1993-03-29 JP JP5517617A patent/JPH07505437A/en active Pending
- 1993-03-29 AU AU39399/93A patent/AU668936B2/en not_active Ceased
- 1993-03-29 WO PCT/US1993/002944 patent/WO1993020167A1/en active Application Filing
- 1993-04-02 IE IE930263A patent/IE930263A1/en not_active IP Right Cessation
- 1993-04-03 CN CN 93105485 patent/CN1078254A/en active Pending
- 1993-05-03 TW TW82103446A patent/TW299351B/zh active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU688356B2 (en) * | 1993-08-03 | 1998-03-12 | Procter & Gamble Company, The | A process of cleaning carpets using active oxygen compounds in an acidic aqueous medium |
Also Published As
Publication number | Publication date |
---|---|
BR9306183A (en) | 1998-06-23 |
EP0563460A1 (en) | 1993-10-06 |
CN1078254A (en) | 1993-11-10 |
DE69226072T2 (en) | 1999-02-25 |
JPH07505437A (en) | 1995-06-15 |
ES2118105T3 (en) | 1998-09-16 |
DE69226072D1 (en) | 1998-08-06 |
AU668936B2 (en) | 1996-05-23 |
IE930263A1 (en) | 1993-10-06 |
TW299351B (en) | 1997-03-01 |
WO1993020167A1 (en) | 1993-10-14 |
EP0563460B1 (en) | 1998-07-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA1319077C (en) | Liquid detergent containing solid peroxygen bleach | |
FI90786C (en) | Liquid detergent composition containing perborate bleach | |
US4772290A (en) | Liquid hydrogen peroxide/peracid precursor bleach: acidic aqueous medium containing solid peracid precursor activator | |
EP0598694B1 (en) | Stable compositions with persulfate salts | |
JPH0781158B2 (en) | Flowable sulfone peroxycarboxylic acid composition | |
US5904734A (en) | Method for bleaching a hard surface using tungsten activated peroxide | |
CA2667647A1 (en) | Liquid detergent formulation with hydrogen peroxide | |
JPH073293A (en) | Bleaching composition in form of translucent isotropic aqueous solution | |
JPH041298A (en) | Liquid detergent composition containing enzyme and enzyme-stabilizing system | |
JPH03200899A (en) | Liquid detergent compound containing stabilized bleach- ing agent | |
US3951840A (en) | Stable bleaching composition | |
CA2007380C (en) | Liquid detergent composition containing enzyme and stabilization system | |
EP0563460B1 (en) | Acidic activated bleaching composition | |
JPH03210399A (en) | Chlorine-free liquid compound for automatic dish washer | |
JP2662712B2 (en) | Concentrated acidic liquid composition with amine fluorescent whitening agent useful as bleach vehicle | |
JPS601920B2 (en) | Bleaching and cleaning compositions | |
US5250212A (en) | Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol | |
US4824592A (en) | Suspending system for insoluble peroxy acid bleach | |
US5380456A (en) | Stabilization of aqueous persalt solutions | |
US2362401A (en) | Detergent compositions | |
EP1038947A2 (en) | Cleaning formulation | |
US5047577A (en) | Quaternary ammonium compounds | |
JPH02132196A (en) | Bleaching agent and bleaching cleansing agent composition | |
JP2994035B2 (en) | Stabilized bleach-containing liquid detergent composition | |
JP2000511217A (en) | Alkaline peroxide liquid detergent composition |