AU2013267517B2 - An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof - Google Patents

An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof Download PDF

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Publication number
AU2013267517B2
AU2013267517B2 AU2013267517A AU2013267517A AU2013267517B2 AU 2013267517 B2 AU2013267517 B2 AU 2013267517B2 AU 2013267517 A AU2013267517 A AU 2013267517A AU 2013267517 A AU2013267517 A AU 2013267517A AU 2013267517 B2 AU2013267517 B2 AU 2013267517B2
Authority
AU
Australia
Prior art keywords
absorbent composition
range
acid
hindered amine
sterically hindered
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2013267517A
Other languages
English (en)
Other versions
AU2013267517A1 (en
Inventor
James Edward CRITCHFIELD
Diego Patricio VALENZUELA
Loren Clark WILSON
Jingjun Zhou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Huntsman Petrochemical LLC
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Huntsman Petrochemical LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV, Huntsman Petrochemical LLC filed Critical SHELL INT RESEARCH
Publication of AU2013267517A1 publication Critical patent/AU2013267517A1/en
Application granted granted Critical
Publication of AU2013267517B2 publication Critical patent/AU2013267517B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0408—Pretreatment of the hydrogen sulfide containing gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/16—Hydrogen sulfides
    • C01B17/167—Separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/50—Inorganic acids
    • B01D2251/502—Hydrochloric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/50—Inorganic acids
    • B01D2251/504—Nitric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/50—Inorganic acids
    • B01D2251/506—Sulfuric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B01D2252/2023—Glycols, diols or their derivatives
    • B01D2252/2026—Polyethylene glycol, ethers or esters thereof, e.g. Selexol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056—Sulfur compounds, e.g. Sulfolane, thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Gas Separation By Absorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treating Waste Gases (AREA)
AU2013267517A 2012-05-31 2013-05-29 An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof Ceased AU2013267517B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261653920P 2012-05-31 2012-05-31
US61/653,920 2012-05-31
PCT/US2013/043105 WO2013181245A1 (en) 2012-05-31 2013-05-29 An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof

Publications (2)

Publication Number Publication Date
AU2013267517A1 AU2013267517A1 (en) 2014-12-11
AU2013267517B2 true AU2013267517B2 (en) 2015-11-26

Family

ID=48670778

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2013267517A Ceased AU2013267517B2 (en) 2012-05-31 2013-05-29 An absorbent composition for the selective absorption of hydrogen sulfide and a process of use thereof

Country Status (12)

Country Link
US (1) US20150093314A1 (enExample)
EP (1) EP2854995A1 (enExample)
JP (1) JP6490578B2 (enExample)
KR (1) KR20150044856A (enExample)
CN (1) CN104619397A (enExample)
AU (1) AU2013267517B2 (enExample)
BR (1) BR112014029666A2 (enExample)
CA (1) CA2874730A1 (enExample)
EA (1) EA029106B1 (enExample)
IN (1) IN2014DN10047A (enExample)
MX (1) MX2014014374A (enExample)
WO (1) WO2013181245A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9364773B2 (en) 2013-02-22 2016-06-14 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US11440815B2 (en) 2013-02-22 2022-09-13 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US9708196B2 (en) 2013-02-22 2017-07-18 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
CN104289093A (zh) * 2014-09-26 2015-01-21 中国石油化工股份有限公司 一种湿法硫化氢废气净化装置及其方法
MX2018004013A (es) * 2015-09-29 2018-05-23 Basf Se Agente de absorcion y un metodo para remover selectivamente sulfuro de hidrogeno.
CN110650785B (zh) 2017-05-15 2022-05-24 巴斯夫欧洲公司 用于选择性脱除硫化氢的吸收剂和方法
JP7101759B2 (ja) 2017-09-04 2022-07-15 ビーエーエスエフ ソシエタス・ヨーロピア 硫化水素を選択的に除去するための吸収剤および方法
CN109529541B (zh) 2017-09-21 2022-07-22 株式会社东芝 二氧化碳吸收剂及二氧化碳分离回收装置
CN114173908B (zh) 2019-09-10 2025-04-01 巴斯夫欧洲公司 从流体料流中移除酸性气体的方法
WO2022010874A1 (en) * 2020-07-07 2022-01-13 Exxonmobil Research And Engineering Company Acid gas scrubbing methods featuring amine phase separation for hydrogen sulfide capture

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4961873A (en) * 1987-10-13 1990-10-09 Exxon Research And Engineering Company Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H2 S

Family Cites Families (13)

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US3347621A (en) 1964-11-02 1967-10-17 Shell Oil Co Method of separating acidic gases from gaseous mixtures
US3965244A (en) 1974-11-27 1976-06-22 Shell Oil Company Selective removal of sulfur compounds from acid gas mixtures containing significant quantities of carbonyl sulfide
US3989811A (en) 1975-01-30 1976-11-02 Shell Oil Company Process for recovering sulfur from fuel gases containing hydrogen sulfide, carbon dioxide, and carbonyl sulfide
AU506199B2 (en) 1975-06-26 1979-12-20 Exxon Research And Engineering Company Absorbtion of co2 from gaseous feeds
US4152353A (en) 1977-08-29 1979-05-01 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
US4618481A (en) 1985-08-30 1986-10-21 Exxon Research And Engineering Co. Absorbent composition containing a severely hindered amino compound and an amine salt and process for the absorption of H2 S using the same
US4894178A (en) 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S
US4892674A (en) 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
DE19742911A1 (de) 1997-09-29 1999-04-01 Basf Ag Verfahren zur Herstellung von Aminen
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
BR0306705B1 (pt) * 2002-01-14 2011-10-04 processo para a remoção de dióxido de carbono e opcionalmente de sulfeto de hidrogênio e/ou sulfeto de carbonila de uma corrente gasosa, e, lìquido absorvente.
JP5271708B2 (ja) * 2005-08-09 2013-08-21 エクソンモービル リサーチ アンド エンジニアリング カンパニー 酸性ガス洗浄プロセスのためのアルキルアミノアルキルオキシ（アルコール）モノアルキルエーテル
MX371466B (es) * 2010-12-01 2020-01-28 Huntsman Petrochemical Llc Aminas inhibidas estericamente y metodos asociados.

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4961873A (en) * 1987-10-13 1990-10-09 Exxon Research And Engineering Company Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H2 S

Also Published As

Publication number Publication date
KR20150044856A (ko) 2015-04-27
EA201401328A1 (ru) 2015-04-30
CN104619397A (zh) 2015-05-13
CA2874730A1 (en) 2013-12-05
US20150093314A1 (en) 2015-04-02
EA029106B1 (ru) 2018-02-28
MX2014014374A (es) 2015-06-23
BR112014029666A2 (pt) 2017-08-22
AU2013267517A1 (en) 2014-12-11
WO2013181245A1 (en) 2013-12-05
IN2014DN10047A (enExample) 2015-08-21
EP2854995A1 (en) 2015-04-08
JP6490578B2 (ja) 2019-03-27
JP2015523203A (ja) 2015-08-13

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FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired