AU2013223200B2 - Reformed coal production equipment - Google Patents

Reformed coal production equipment

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Publication number
AU2013223200B2
AU2013223200B2 AU2013223200A AU2013223200A AU2013223200B2 AU 2013223200 B2 AU2013223200 B2 AU 2013223200B2 AU 2013223200 A AU2013223200 A AU 2013223200A AU 2013223200 A AU2013223200 A AU 2013223200A AU 2013223200 B2 AU2013223200 B2 AU 2013223200B2
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AU
Australia
Prior art keywords
gas
pyrolysis
pipe
coal
heating
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Ceased
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AU2013223200A
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AU2013223200A1 (en
Inventor
Keiichi Nakagawa
Setsuo Omoto
Fumiaki Sato
Jun Satou
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Mitsubishi Heavy Industries Ltd
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Mitsubishi Heavy Industries Ltd
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Publication of AU2013223200A1 publication Critical patent/AU2013223200A1/en
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Publication of AU2013223200B2 publication Critical patent/AU2013223200B2/en
Ceased legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28Other processes
    • C10B47/30Other processes in rotary ovens or retorts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/26After-treatment of the shaped fuels, e.g. briquettes
    • C10L5/28Heating the shaped fuels, e.g. briquettes; Coking the binders
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Coke Industry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The purpose of the present invention is to provide reformed coal production equipment whereby it is possible to efficiently remove tar without lowering the production amount of reformed coal. Reformed coal production equipment provided with: a combustion furnace (124) for generating heated gas (11); a dry distillation gas supply pipe (101) for supplying dry distillation gas (14) that was generated at a dry distillation device to the combustion furnace; a vapor generator (125) to which a portion of the heated gas generated at the combustion furnace is supplied and which generates waste heat gas (13) by subjecting the heated gas to heat exchange; and a discharge pipe (52), a waste heat gas delivery pipe (54), a mixed gas delivery pipe (55), a blower (126), a mixed gas supply pipe (56), a mixed gas branching pipe (102), a flow rate adjustment valve (103), and a mixed gas communication pipe (104) which supply, to the dry distillation gas supply pipe, the waste heat gas and low-temperature heated gas (12) formed by indirectly heating dried coal by means of the heated gas at the dry distillation device (121).

Description

H:\sbt\lnterwovm\NRPortbl\DCC\SBTR79896541.docx-30/06/2015 REFORMED COAL PRODUCTION EQUIPMENT [0001] The present invention relates to upgraded coal production equipment, and is particularly useful when used to upgrade coal of low rank (low-rank coal) , such as brown coal or subbituminous coal, which is porous and has a high water content. [0 0 02] Coal of low rank (low-rank coal), such as brown coal or subbituminous coal, which is porous and has a high water content generates a low amount of heat per unit weight, and is therefore dried through a heating treatment to have improved amount of heat generation per unit weight. [0003] As upgraded coal production equipment configured to perform such upgrade of low-rank coal, there is, for example, equipment comprising: an indirect-heating pyrolysis device which performs pyrolysis on low-rank coal by heating the low-rank coal indirectly by use of a heating gas; and a combustion furnace which generates the heating gas by combusting a pyrolysis gas generated in the pyrolysis device and supplied to the combustion furnace through a pyrolysis gas supply pipe. [0004] The pyrolysis gas described above is composed of a low-boiling component. However, since the low-rank coal is processed under a relatively high temperature, the pyrolysis gas is accompanied by tar (pyrolysis oil) which is a H:\sbt\lnerwoven\NRPorbl\DCC\SBI\6592245_ .DOC- l/08/2014 high-boiling component. When the pyrolysis gas is cooled, the tar is attached to a wall surface of a duct or the like through which the pyrolysis gas flows. When a large amount of tar is attached, a problem might occur, such as clogging the duct. Hence, various techniques have been developed to remove the tar. [0005] For example, Patent Document 1 given below discloses a decoking method for combusting and removing coke attached to the inside of a pipe by use of a gas which is obtained by adjusting air to have an oxygen concentration of 3 vol% to 21 vol% through dilution with water vapor or an inert gas, and which is also adjusted to have a temperature of 350 0 C to 500 0 C. [0006] Patent Document 2 given below discloses a method for performing a pyrolysis treatment on a processed object by using an eternal heating kiln. In this method, an oxygen-containing gas is supplied into an inner cylinder of the external heating kiln to combust a carbide of organic matter in the processed object and/or a combustible gas, which are produced by pyrolysis. Thereby, the temperature of a pyrolysis gas increases, so that liquefaction or solidification is prevented. PRIOR ART DOCUMENTS PATENT DOCUMENTS [0007] Patent Document 1: Japanese Patent Application Publication No. Hei 7-16552 (see, e.g., paragraph [0013], [0017], and the like) Patent Document 2: Japanese Patent Application Publication No. 2004-3738 (see, e.g., paragraphs [0011], [0014], [0015], and the like) 2 H:\sblntrwovm,,\NRPortbl\DCC\SB'I7989654_1.dox-30/06/2015 -3 [00081 To apply the decoking method described in Patent Document 1 to the upgraded coal production equipment described earlier, the decoking has to be performed with the pyrolysis device itself being stopped. Alternatively, two systems of ducts through which the pyrolysis device supplies the combustion furnace with a pyrolysis gas are provided, and the decoking has to be performed while stopping one of the systems. This entails decrease in operating rate of the equipment, size increase, and the like, causing increase in costs for producing upgraded coal. In other words, the tar cannot be removed efficiently. [00091 By directly supplying the oxygen-concentration adjusted gas adjusted for its oxygen concentration to the pyrolysis gas supply pipe described earlier, tar produced during operation is combusted, so that attachment of the tar to the pyrolysis gas supply pipe can be suppressed. However, generating the oxygen-concentration adjusted gas from air or from an inert gas (nitrogen or water vapor) requires an apparatus specialized for that, and this increases costs for producing upgraded coal. Moreover, the oxygen-concentration adjusted gas has to be increased in temperature in advance in order for it to react with the tar. Thus, additional energy is needed. In sum, the tar cannot be removed efficiently. [0010] In the method for performing a pyrolysis treatment on a processed object by using an external heating kiln described in Patent Document 2, the carbide itself of organic matter in the processed object produced by the pyrolysis is combusted. Thus, when this method is applied to the pyrolysis device of the upgraded coal production equipment, the production volume of the upgraded coal is lowered.
H:\sb\lnwoven\NRPortb\DCC\SBT\7989654_ .docx-30/06/2015 -4 [00111 The invention provides an upgraded coal production equipment comprising: drying means for drying coal; indirect-heating pyrolysis means for performing pyrolysis on the dried coal by indirectly heating the dried coal by use of a heating gas; cooling means for cooling the coal subjected to the pyrolysis; heating gas generation means for generating the heating gas; pyrolysis gas supply means for supplying the heating gas generation means with a pyrolysis gas generated in the indirect-heating pyrolysis means; waste-heat gas generation means for receiving supply of part of the heating gas generated in the heating gas generation means and generating a waste-heat gas by subjecting the heating gas to heat exchange; and mixed gas supply means for supplying the pyrolysis gas supply means with the waste-heat gas and a low-temperature heating gas generated when the heating gas heats the coal indirectly in the indirect-heating pyrolysis means. [0012] Preferred embodiments of the invention provide upgraded coal production equipment capable of efficient tar removal without lowering the production volume of upgraded coal. [0013] In the upgraded coal production equipment according to a preferred embodiment of the invention, further comprises gas temperature measurement means, provided at the pyrolysis gas supply means, for measuring a gas temperature, and the mixed gas supply means comprises gas flow rate adjustment means for adjusting a flow rate of the waste-heat gas and the low temperature heating gas supplied to the pyrolysis gas supply means, and control means for controlling the gas flow H:\sht\Intenvovi\NRPortb\DCC\SBT\7989654_I.docm-30/06/2015 -5 rate adjustment means such that the flow rate of the waste-heat gas and the low-temperature heating gas is increased when the gas temperature measured by the gas temperature measurement means is equal to or higher than 400 0 C, and that the flow rate of the waste-heat gas and the low-temperature heating gas is decreased when the gas temperature measured by the gas temperature measurement means exceeds 5500C. [0014] According to the upgraded coal production equipment of the preferred embodiments of the present invention, the low temperature heating gas and the waste-heat gas can be supplied to the pyrolysis gas supply means. Thereby, even if the pyrolysis gas is cooled in the pyrolysis gas supply means to face possible liquefaction or solidification of tar (pyrolysis oil), the low temperature heating gas and the waste-heat gas make the oxygen concentration about 1 to 2 %, and thereby the tar is oxidatively decomposed. As a result, the tar becomes light in weight and is thereby prevented from being attached to a wall surface of a duct or the like forming the pyrolysis gas supply means. Further, since a light gas generated when the tar becomes light in weight is combusted, the temperature of the pyrolysis gas rises, which can prevent attachment of tar to a wall surface of the duct or the like forming the pyrolysis gas supply means. The oxidative decomposition of the tar can be performed without stopping the device, and therefore the operating rate of the equipment can be improved compared to equipment which has to stop the device in order for the tar to be oxidatively decomposed. In other words, tar can be removed efficiently. Since the pyrolysis gas has almost the same temperature as the low-temperature heating gas and the waste-heat gas, preheating of the low-temperature heating gas and the waste-heat gas is unnecessary, which is energy-saving. [0015] The invention will now be described, by way of non limiting example only, with reference to the accompanying drawings, which are briefly described below.
H:\sht\ltenvven\NRPortbl\DCC\SB /989654_l-dox-30/06/2015 -6 [Fig. 1] Fig. 1 is a schematic diagram showing the overall configuration of a main embodiment of upgraded coal production equipment according to the present invention. [00161 An embodiment of upgraded coal production equipment according to the present invention is described. [0017] MAIN EMBODIMENT Based on Fig. 1, a main embodiment of upgraded coal production equipment according to the present invention is described. [0018] First, as shown in Fig. 1, low-rank coal 1 such as brown coal or subbituminous coal is supplied to a drying device 111 by a hopper or the like (not shown) , the drying device 111 being drying means for drying the low-rank coal 1. An outlet opening of the drying device 111 communicates with an inlet opening 122a of a pyrolysis device 121 configured to perform pyrolysis on dried coal 2. An outlet opening 122b of the pyrolysis device 121 communicates with an inlet opening of a cooling device 131 being cooling means for cooling pyrolysis coal 3. [0019] The pyrolysis device 121 has an inner cylinder 122 and an outer cylinder 123 surrounding the inner cylinder 122. The outer cylinder 123 is supplied with a heating gas 11 to be described later. Thereby, the dried coal 2 supplied into the inner cylinder 122 is indirectly heated and is subjected to pyrolysis, to generate the pyrolysis coal 3. In other words, the pyrolysis device 121 is an indirect-heating device, such as, e.g., an external heating kiln, in which a hot gas (heating gas) being a heat source does not come into direct contact with the low-rank coal 1. The pyrolysis device 121 forms indirect-heating pyrolysis means. [0020] A gas exhaust port of the inner cylinder 122 of the pyrolysis device 121 communicates with a gas intake port of a combustion furnace 124 via a pyrolysis gas supply pipe 101. Thereby, a pyrolysis gas 14 containing gaseous tar (pyrolysis oil) generated by the pyrolysis is supplied to the gas intake port of the combustion furnace 124. The gas intake port of the combustion furnace 124 is also supplied with a fuel (not shown) such as a natural gas. The combustion furnace 124 generates the heating gas 11 by combusting the pyrolysis gas 14 and the fuel such as a natural gas. In other words, the combustion furnace 124 forms heating gas generation means. A gas exhaust port of the combustion furnace 124 communicates with a gas intake port of the outer cylinder 123 of the pyrolysis device 7 121 via a heating gas feed pipe 51. [0021] The heating gas feed pipe 51 communicates with a gas intake port of a steam generator 125 via a heating gas branch pipe 53. The steam generator 125 forms waste-heat gas generation means for generating a waste-heat gas 13 through heat exchange between the heating gas 11 and water to thereby generate steam. A gas exhaust port of the steam generator 125 communicates with an exhaust pipe 52 to be described later via a waste-heat gas feed pipe 54. [0022] A gas exhaust port of the outer cylinder 123 of the pyrolysis device 121 communicates with a gas intake port of an exhaust-gas treatment device 127 via the exhaust pipe 52, the exhaust-gas treatment device 127 being exhaust-gas purification means for purifying the waste-heat gas 13 and a low-temperature heating gas 12 which is generated when the heating gas 11 heats the inner cylinder 122. The low-temperature heating gas 12 and the waste-heat gas 13 are discharged to the outside of the system after undergoing the purification treatment in the exhaust-gas treatment device 127. [0023] The exhaust pipe 52 communicates with a gas intake port of a blower 126 via a mixed gas feed pipe 55. A gas exhaust port of the blower 126 communicates with a gas intake port of the combustion furnace 124 via a mixed gas supply pipe 56. The mixed gas supply pipe 56 communicates with a mixed gas branch pipe 102. The mixed gas branch pipe 102 communicates with a mixed gas communication pipe 104 via a flow rate adjustment valve 103. The mixed gas communication pipe 104 communicates 8 with the pyrolysis gas supply pipe 101. [0024] The pyrolysis gas supply pipe 101 is provided with a gas temperature measurement instrument 105 which is gas temperature measurement means for measuring the temperature of a gas inside the pipe. The gas temperature measurement instrument 105 is connected to a control device 106 such that the measured gas temperature can be sent to the control device 106, the control device 106 being control means for controlling the valve position of the flow rate adjustment valve 103. [0025] The exhaust pipe 52, the waste-heat gas feed pipe 54, the mixed gas feed pipe 55, the blower 126, the mixed gas supply pipe 56, the mixed gas branch pipe 102, the flow rate adjustment valve 103, the mixed gas communication pipe 104, and the like form mixed gas supply means. [0026] In the upgraded coal production equipment according to this embodiment thus configured, when the low-rank coal 1 is charged into the hopper, the hopper supplies the low-rank coal 1 at a room temperature to the drying device 111 a predetermined amount at a time. The low-rank coal 1 supplied to the drying device 111 is removed of water and becomes the dried coal 2 by being heated up to about 200 'C by a drying combustion gas (about 150 to 300 0 C) from a drying combustor (not shown) . Then, the dried coal 2 is transferred into the inner cylinder 122 of the pyrolysis device 121. The dried coal 2 transferred to the pyrolysis device 121 is subjected to pyrolysis by being indirectly heated by the heating gas 11 (gas temperature: about 1050 'C, oxygen concentration: about 2 to 3 %) from the 9 combustion furnace 124. Thereby, the dried coal 2 becomes the pyrolysis coal 3 as a result of removal of components such as the pyrolysis gas 14 containing gaseous tar, and the pyrolysis coal 3 is fed to the cooling device 131. The pyrolysis coal 3 fed to the cooling device 131 becomes upgraded coal 4 by being cooled down to about 50 'C. [0027] Meanwhile, the heating gas 11 (gas temperature: about 1050 0 C, oxygen concentration: about 2 to 3 %) generated in the combustion furnace 124 is fed to the outer cylinder 123 of the pyrolysis device 121 via the heating gas feed pipe 51. The heating gas 11 used inside the outer cylinder 123 to heat the inner cylinder 122 becomes the low-temperature heating gas 12 (gas temperature: about 350 *C, oxygen concentration: about 2 to 3 %). The low-temperature heating gas 12 is fed to the exhaust pipe 52. Meanwhile, the heating gas 11 is also fed to the steam generator 125 via the heating gas feed pipe 51 and the heating gas branch pipe 53. The heating gas 11 used in the steam generator 125 for generation of water vapor becomes the waste-heat gas 13 (gas temperature: about 350 0 C, oxygen concentration: about 2 to 3 %). The waste-heat gas 13 is fed to the exhaust pipe 52 via the waste-heat gas feed pipe 54. [0028] Part of the low-temperature heating gas 12 and the waste-heat gas 13 is supplied to the exhaust-gas treatment device 127. The low-temperature heating gas 12 and the waste-heat gas 13 undergo the purification treatment in the exhaust-gas treatment device 127 and are then discharged to the outside of the system. The rest of the low-temperature heating gas 12 and the waste-heat gas 13 (gas temperature: about 350 10 'C, oxygen concentration: about 2 to 3 %) is fed to the blower 126 via the mixed gas feed pipe 55. [0029] Part of the low-temperature heating gas 12 and the waste-heat gas 13 fed to the blower 126 is supplied to the combustion furnace 124 via the mixed gas supply pipe 56. The rest of the low-temperature heating gas 12 and the waste-heat gas 13 (gas temperature: about 350 0C, oxygen concentration: about 2 to 3 %) fed to the blower 126 is supplied to the pyrolysis gas supply pipe 101 via the mixed gas branch pipe 102, the flow rate adjustment valve 103, and the mixed gas communication pipe 104. [0030] The valve position of the flow rate adjustment valve 103 is controlled by the control device 106 based on the gas temperature measured by the gas temperature measurement instrument 105. For example, the control device 106 adjusts the flow rate adjustment valve 103 by opening it to increase the aperture when the gas temperature measured by the gas temperature measurement instrument 105 is equal to or higher than 400 0C, and adjusts the flow rate adjustment valve 103 by narrowing it when the gas temperature exceeds 550 *C. Thereby, the low-temperature heating gas 12 and the waste-heat gas 13 (oxygen concentration: about 2 to 3 %) are mixed with the pyrolysis gas 14 (gas temperature: about 400 *C, oxygen concentration: about 0 %), and this mixed gas has an oxygen concentration adjusted to about 1 to 2 %. As a result, gaseous tar (pyrolysis oil) is oxidatively decomposed (decoking) to become light in weight, and thereby attachment of the tar to the pyrolysis gas supply pipe 101 can be prevented. The tar 11 is reduced in weight to become a light gas, and this light gas is combusted. Thus, decrease in the gas temperature is prevented. Thereby, attachment of the tar to the pyrolysis gas supply pipe 101 can be prevented. Specifically, the decoking is performed just when the tar is about to be attached to the inner wall surface of the pyrolysis gas supply pipe 101 by adjustment of the amount of the low-temperature heating gas 12 and the waste-heat gas 13 supplied to the pyrolysis gas supply pipe 101 based on the gas temperature inside the pyrolysis gas supply pipe 101. Hence, the tar can be efficiently removed. [0031] Thus, according to the upgraded coal production equipment according to this embodiment, by supplying the low-temperature heating gas 12 and the waste-heat gas 13 into the pyrolysis gas supply pipe 101, the oxygen concentration of the gases 12, 13, 14 in the pyrolysis gas supply pipe 101 is adjusted to about 1 to 2 %, so that tar contained in the pyrolysis gas 14 (pyrolysis oil) is oxidatively decomposed (decoking) to become light in weight. Thereby, attachment of the tar to the pyrolysis gas supply pipe 101 can be prevented. [0032] Moreover, since a light gas generated when the tar becomes light in weight is combusted, the temperature of the pyrolysis gas 14 rises, which can prevent attachment of the pyrolysis oil to a wall surface of the pyrolysis gas supply pipe 101 and the like. Since the pyrolysis gas 14 has almost the same temperature as the low-temperature heating gas 12 and the waste-heat gas 13, preheating of the low-temperature heating gas 12 and the waste-heat gas 13 is unnecessary, which is energy-saving. Furthermore, since decoking can be performed 12 to remove tar without stopping the device, the operating rate of the equipment can be improved compared to equipment which has to stop the device to decoke the device for tar removal. In other words, tar can be removed efficiently. INDUSTRIAL APPLICABILITY [0033] The upgraded coal production equipment according to the present invention can remove tar efficiently without lowering the production volume of upgraded coal, and can therefore be utilized significantly beneficially in various industries. EXPLANATION OF REFERENCE NUMERALS [00341 1 low-rank coal 2 dried coal 3 pyrolysis coal 4 upgraded coal 11 heating gas 12 low-temperature heating gas 13 waste-heat gas 14 pyrolysis gas 51 heating gas feed pipe 52 exhaust pipe 53 heating gas branch pipe 54 waste-heat gas feed pipe 55 mixed gas feed pipe 56 mixed gas supply pipe 101 pyrolysis gas supply pipe 102 mixed gas branch pipe 103 flow rate adjustment valve 104 mixed gas communication pipe 13 H:\sbt\lnterwovmNRPortbl\DCC\SBT\7989654_I.dmx-30/06/2015 - 14 105 gas temperature measurement instrument 106 control device 111 drying device 121 pyrolysis device 122 inner cylinder 123 outer cylinder 124 combustion furnace 125 steam generator 126 blower 127 exhaust-gas treatment device 131 cooling device [0035] While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only, and not by way of limitation. It will be apparent to a person skilled in the relevant art that various changes in form and detail can be made therein without departing from the spirit and scope of the invention. Thus, the present invention should not be limited by any of the above described exemplary embodiments. [0036] Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" and "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps. [0037] The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.
AU2013223200A 2012-02-24 2013-02-21 Reformed coal production equipment Ceased AU2013223200B2 (en)

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JP2012-038514 2012-02-24
JP2012038514A JP5804971B2 (en) 2012-02-24 2012-02-24 Modified coal production facility
PCT/JP2013/054251 WO2013125608A1 (en) 2012-02-24 2013-02-21 Reformed coal production equipment

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AU2013223200B2 true AU2013223200B2 (en) 2015-07-16

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JP5971652B2 (en) 2012-10-09 2016-08-17 三菱重工業株式会社 Coal deactivation processing equipment
JP5536247B1 (en) 2013-03-04 2014-07-02 三菱重工業株式会社 Coal deactivation processing equipment
DE102017125297B4 (en) * 2017-10-27 2021-03-04 ARCUS Technologie GmbH & Co GTL Projekt KG Process for the production of coke and / or pyrolysis gas in a rotary kiln

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WO2013125608A1 (en) 2013-08-29
CN104066823A (en) 2014-09-24
JP2013173831A (en) 2013-09-05
JP5804971B2 (en) 2015-11-04
AU2013223200A1 (en) 2014-08-14

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