AU2012213597A8 - Alkaline liquid detergent compositions - Google Patents

Alkaline liquid detergent compositions

Info

Publication number
AU2012213597A8
AU2012213597A8 AU2012213597A AU2012213597A AU2012213597A8 AU 2012213597 A8 AU2012213597 A8 AU 2012213597A8 AU 2012213597 A AU2012213597 A AU 2012213597A AU 2012213597 A AU2012213597 A AU 2012213597A AU 2012213597 A8 AU2012213597 A8 AU 2012213597A8
Authority
AU
Australia
Prior art keywords
midblock
polymer
composition
motif
reversed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU2012213597A
Other versions
AU2012213597B2 (en
AU2012213597A1 (en
Inventor
Robert John Carswell
Martin Charles Crossman
Adam Peter Jarvis
Alyn James Parry
Susan Henning Rogers
John Francis Wells
Jeremy Nicholas Winter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Publication of AU2012213597A1 publication Critical patent/AU2012213597A1/en
Publication of AU2012213597A8 publication Critical patent/AU2012213597A8/en
Application granted granted Critical
Publication of AU2012213597B2 publication Critical patent/AU2012213597B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines or polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0036Soil deposition preventing compositions; Antiredeposition agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715Polyesters or polycarbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

An aqueous alkaline isotropic concentrated detergent liquid composition with an undiluted pH of at least 7.8 and at most 9 comprising: a)10 to 60 wt% non-soap surfactant, b) 0 to 20 wt% hydrotrope, c) 0 to 4 wt% soap, d) 0 to 10 wt% nonionic EPEI, e) at least 1 wt% triethanolamine, characterised in that dissolved in the alkaline isotropic liquid there is: f) at least 1 wt%, preferably at least 1.5 wt% of a polyester substantive nonionic soil release polymer of the type E-M-L-E, where the midblock M is connected to a generally hydrophilic end block E and blocks E each comprise capped oligomers of polyethylene glycol remote from the midblock, with at least 10 EO repeat units, the end blocks being free from ester bonds, either directly or via linking moiety L which comprises the motif: B-Ar-B where B is selected from urethane, amide and ester moieties and Ar is,4 phenylene, and midblock M comprises the motif: wherein R1 and R2 may be the same or different selected from C1-C4 alkyl, C1-C4 alkoxy and Hydrogen, provided that R1 and R2 may not both be hydrogen, n is at least 2, preferably more than 5, the ester bonds may by 2 formed the other way around (not shown), if they are so reversed then all of them will be so reversed, G3107 (C) CPL -78- wherein the composition comprising the polymer provides soil release less than a ΔE of 5 with DMO on woven polyester after storage of the polymer in the detergent composition at 60°C for 8 days at a pH >7.5.
AU2012213597A 2011-01-31 2012-01-23 Alkaline liquid detergent compositions Ceased AU2012213597B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11152787.5 2011-01-31
EP11152787 2011-01-31
PCT/EP2012/050945 WO2012104159A1 (en) 2011-01-31 2012-01-23 Alkaline liquid detergent compositions

Publications (3)

Publication Number Publication Date
AU2012213597A1 AU2012213597A1 (en) 2013-07-25
AU2012213597A8 true AU2012213597A8 (en) 2014-08-14
AU2012213597B2 AU2012213597B2 (en) 2014-08-28

Family

ID=44168218

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2012213597A Ceased AU2012213597B2 (en) 2011-01-31 2012-01-23 Alkaline liquid detergent compositions

Country Status (10)

Country Link
EP (1) EP2670788B1 (en)
CN (1) CN103347928B (en)
AU (1) AU2012213597B2 (en)
BR (1) BR112013019386B1 (en)
CL (1) CL2013002181A1 (en)
ES (1) ES2538997T3 (en)
MY (1) MY163351A (en)
PL (1) PL2670788T3 (en)
WO (1) WO2012104159A1 (en)
ZA (1) ZA201305194B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9365806B2 (en) * 2012-07-31 2016-06-14 Conopco Inc. Alkaline liquid laundry detergent compositions comprising polyesters
BR112015002039A2 (en) * 2012-07-31 2017-07-04 Clariant Finance Bvi Ltd polyesters
EP2692842B1 (en) * 2012-07-31 2014-07-30 Unilever PLC Concentrated liquid detergent compositions
WO2014019658A1 (en) * 2012-07-31 2014-02-06 Clariant International Ltd Polyesters
BR112016003054B1 (en) 2013-08-16 2022-02-15 Chemsenti Limited BLEACHING FORMULATION, PARTICLE, METHOD AND USE OF A PARTICLE
EP3167033B1 (en) 2014-07-09 2020-04-29 Unilever Plc. Process for making a laundry liquid composition
WO2016075179A1 (en) * 2014-11-11 2016-05-19 Clariant International Ltd Laundry detergents containing soil release polymers
ES2694703T3 (en) * 2015-07-30 2018-12-26 The Procter & Gamble Company Water soluble unit dose item
WO2017133879A1 (en) 2016-02-04 2017-08-10 Unilever Plc Detergent liquid
WO2017202923A1 (en) * 2016-05-27 2017-11-30 Unilever Plc Laundry composition
EP3469130A1 (en) 2016-06-09 2019-04-17 Unilever PLC Laundry products
US20190136162A1 (en) 2016-06-09 2019-05-09 Conopco, Inc., D/B/A Unilever Laundry products
US10081783B2 (en) 2016-06-09 2018-09-25 The Procter & Gamble Company Cleaning compositions having an enzyme system
WO2018028933A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028934A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028935A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
WO2018028936A1 (en) * 2016-08-08 2018-02-15 Henkel Ag & Co. Kgaa Stable liquid detergent comprising soil release polymer
CN106833932A (en) * 2016-12-28 2017-06-13 于文 Gym suit cleaning agent and preparation method thereof
CN111164192B (en) 2017-09-29 2022-08-26 联合利华知识产权控股有限公司 Laundry products
WO2019068473A1 (en) 2017-10-05 2019-04-11 Unilever Plc Laundry products
US10808206B2 (en) 2017-11-14 2020-10-20 Henkel IP & Holding GmbH Detergent boosters, detergent systems that include a detergent booster, and methods of laundering fabric
WO2019096942A1 (en) * 2017-11-17 2019-05-23 Unilever Plc Soil release polymers and laundry detergent compositions containing them
BR112022020079A2 (en) * 2020-05-20 2022-11-29 Clariant Int Ltd DIRT RELEASE POLYESTERS FOR USE IN DETERGENT COMPOSITIONS
BR112023001773A2 (en) * 2020-08-28 2023-03-28 Unilever Ip Holdings B V DETERGENT COMPOSITION AND METHOD

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135931A1 (en) * 2008-06-16 2009-12-23 The Procter and Gamble Company Use of soil release polymer in fabric treatment compositions

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US857A (en) 1838-07-26 of greene
US4702A (en) 1846-08-20 Comte de fontainemoeeatt
US2182306A (en) 1935-05-10 1939-12-05 Ig Farbenindustrie Ag Polymerization of ethylene imines
US2208095A (en) 1937-01-05 1940-07-16 Ig Farbenindustrie Ag Process of producing insoluble condensation products containing sulphur and nitrogen
US2553696A (en) 1944-01-12 1951-05-22 Union Carbide & Carbon Corp Method for making water-soluble polymers of lower alkylene imines
US2806839A (en) 1953-02-24 1957-09-17 Arnold Hoffman & Co Inc Preparation of polyimines from 2-oxazolidone
BE615597A (en) 1958-06-19
GB1296839A (en) 1969-05-29 1972-11-22
GB1372034A (en) 1970-12-31 1974-10-30 Unilever Ltd Detergent compositions
DK187280A (en) 1980-04-30 1981-10-31 Novo Industri As RUIT REDUCING AGENT FOR A COMPLETE LAUNDRY
DE3585505D1 (en) * 1984-12-21 1992-04-09 Procter & Gamble BLOCK POLYESTER AND SIMILAR COMPOUNDS, USED AS A DETOIL REMOVER IN DETERGENT COMPOSITIONS.
EP0218272B1 (en) 1985-08-09 1992-03-18 Gist-Brocades N.V. Novel lipolytic enzymes and their use in detergent compositions
US4711730A (en) 1986-04-15 1987-12-08 The Procter & Gamble Company Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
JPS6356289A (en) 1986-07-30 1988-03-10 Res Dev Corp Of Japan Beta-mannanase and production thereof
JPS6336775A (en) 1986-07-31 1988-02-17 Res Dev Corp Of Japan Novel alkalophilic strain of bacillus genus capable of producing beta-mannanase and beta-mannosidase and use thereof
DE3750450T2 (en) 1986-08-29 1995-01-05 Novo Industri As Enzyme-based detergent additive.
NZ221627A (en) 1986-09-09 1993-04-28 Genencor Inc Preparation of enzymes, modifications, catalytic triads to alter ratios or transesterification/hydrolysis ratios
EP0305216B1 (en) 1987-08-28 1995-08-02 Novo Nordisk A/S Recombinant Humicola lipase and process for the production of recombinant humicola lipases
JPS6474992A (en) 1987-09-16 1989-03-20 Fuji Oil Co Ltd Dna sequence, plasmid and production of lipase
JP3079276B2 (en) 1988-02-28 2000-08-21 天野製薬株式会社 Recombinant DNA, Pseudomonas sp. Containing the same, and method for producing lipase using the same
JP2728531B2 (en) 1988-03-24 1998-03-18 ノボ ノルディスク アクティーゼルスカブ Cellulase preparation
US5648263A (en) 1988-03-24 1997-07-15 Novo Nordisk A/S Methods for reducing the harshness of a cotton-containing fabric
GB8915658D0 (en) 1989-07-07 1989-08-23 Unilever Plc Enzymes,their production and use
JPH0347076A (en) 1989-08-25 1991-02-28 Res Dev Corp Of Japan Beta-mannase and production thereof
US5256168A (en) * 1989-10-31 1993-10-26 The Procter & Gamble Company Sulfobenzoyl end-capped ester oligomers useful as soil release agents in granular detergent compositions
JP3112937B2 (en) 1990-04-14 2000-11-27 カリ―ヒエミー アクチエンゲゼルシヤフト Alkaline Bacillus lipase, DNA sequence encoding the same and Bacillus producing this lipase
AU8060091A (en) 1990-05-29 1991-12-31 Chemgen Corporation Hemicellulase active at extremes of ph and temperature and the means for the production thereof
ATE169671T1 (en) 1990-09-13 1998-08-15 Novo Nordisk As LIPASE VARIANTS
EP0511456A1 (en) 1991-04-30 1992-11-04 The Procter & Gamble Company Liquid detergents with aromatic borate ester to inhibit proteolytic enzyme
ATE136055T1 (en) 1991-04-30 1996-04-15 Procter & Gamble LIQUID DETERGENTS CONTAINING BRACKETS WITH BORIC ACID-POLYOL COMPLEX FOR PTOTEOLYTIC ENZYMIN INHIBITION
ES2079138T3 (en) * 1991-06-14 1996-01-01 Procter & Gamble SELF-THICKENING CLEANING COMPOSITIONS.
JP2626662B2 (en) 1991-10-09 1997-07-02 科学技術振興事業団 Novel β-mannanase and method for producing the same
FI931193A0 (en) 1992-05-22 1993-03-17 Valtion Teknillinen MANNANASENZYMER, GENER SOM KODAR FOER DEM OCH FOERFARANDEN FOER ISOLERINGAV GENERNA SAMT FOERFARANDE FOER BLEKNING AV LIGNOCELLULOSAHALTIG MASSA
DK72992D0 (en) 1992-06-01 1992-06-01 Novo Nordisk As ENZYME
DK88892D0 (en) 1992-07-06 1992-07-06 Novo Nordisk As CONNECTION
CA2138519C (en) 1993-04-27 2007-06-12 Jan Metske Van Der Laan New lipase variants for use in detergent applications
DK48693D0 (en) 1993-04-30 1993-04-30 Novo Nordisk As ENZYME
JP2859520B2 (en) 1993-08-30 1999-02-17 ノボ ノルディスク アクティーゼルスカブ Lipase, microorganism producing the same, method for producing lipase, and detergent composition containing lipase
CA2173946A1 (en) 1993-10-13 1995-04-20 Anders Hjelholt Pedersen H2o2-stable peroxidase variants
JPH07143883A (en) 1993-11-24 1995-06-06 Showa Denko Kk Lipase gene and mutant lipase
ATE222604T1 (en) 1994-02-22 2002-09-15 Novozymes As METHOD FOR PRODUCING A VARIANT OF A LIPOLYTIC ENZYME
US5824531A (en) 1994-03-29 1998-10-20 Novid Nordisk Alkaline bacilus amylase
JP3851656B2 (en) 1994-05-04 2006-11-29 ジェネンコア インターナショナル インコーポレーテッド Lipase with improved surfactant resistance
AU2884595A (en) 1994-06-20 1996-01-15 Unilever Plc Modified pseudomonas lipases and their use
WO1996000292A1 (en) 1994-06-23 1996-01-04 Unilever N.V. Modified pseudomonas lipases and their use
BE1008998A3 (en) 1994-10-14 1996-10-01 Solvay Lipase, microorganism producing the preparation process for the lipase and uses thereof.
EP0785994A1 (en) 1994-10-26 1997-07-30 Novo Nordisk A/S An enzyme with lipolytic activity
JPH08228778A (en) 1995-02-27 1996-09-10 Showa Denko Kk New lipase gene and production of lipase using the same
CN102080070B (en) 1995-03-17 2016-01-20 诺沃奇梅兹有限公司 new endoglucanase
EP0839186B1 (en) 1995-07-14 2004-11-10 Novozymes A/S A modified enzyme with lipolytic activity
DE69632538T2 (en) 1995-08-11 2005-05-19 Novozymes A/S NOVEL LIPOLYTIC ENZYMES
DE69628656D1 (en) 1995-09-20 2003-07-17 Genencor Int MANNASE OF BACILLUS AMYLOLIQUEFACIENS AND METHOD FOR YOUR PREPARATION
AU2892897A (en) 1996-06-19 1998-01-07 Unilever Plc Bleach activation
CN101085985B (en) 1996-09-17 2012-05-16 诺沃奇梅兹有限公司 Cellulase variants
DE69718351T2 (en) 1996-10-08 2003-11-20 Novozymes As DIAMINOBIC ACID DERIVATIVES AS DYE PRECURSORS
ZA981883B (en) 1997-03-07 1998-09-01 Univ Kansas Catalysts and methods for catalytic oxidation
ID22981A (en) 1997-03-07 1999-12-23 Procter & Gamble RACING COMPOSITION
WO1999027083A1 (en) 1997-11-24 1999-06-03 Novo Nordisk A/S PECTIN DEGRADING ENZYMES FROM $i(BACILLUS LICHENIFORMIS)
CN1244695C (en) 1997-11-24 2006-03-08 诺沃奇梅兹有限公司 Novel pectate lyases
US6124127A (en) 1997-11-24 2000-09-26 Novo Nordisk A/S Pectate lyase
KR20010052736A (en) 1998-06-10 2001-06-25 피아 스타르 Novel mannanases
JP2002530481A (en) 1998-11-13 2002-09-17 ザ、プロクター、エンド、ギャンブル、カンパニー Bleach composition
BR0008715A (en) 1999-03-02 2002-01-02 Procter & Gamble Bleach stabilized compositions
JP4745503B2 (en) 1999-03-31 2011-08-10 ノボザイムス アクティーゼルスカブ Polypeptides having alkaline α-amylase activity and nucleic acids encoding them
WO2000060045A1 (en) 1999-04-01 2000-10-12 The Procter & Gamble Company Transition metal bleaching agents
AU2001281736A1 (en) 2000-07-19 2002-01-30 Novozymes A/S Cell-wall degrading enzyme variants
GB0030673D0 (en) 2000-12-15 2001-01-31 Unilever Plc Ligand and complex for catalytically bleaching a substrate
US6897188B2 (en) * 2001-07-17 2005-05-24 Ecolab, Inc. Liquid conditioner and method for washing textiles
ES2281002T3 (en) 2003-08-06 2007-09-16 Ciba Specialty Chemicals Holding Inc. COMPOSITIONS TO FORM TONES.
ES2404533T3 (en) 2004-08-30 2013-05-28 Basf Se Matting Process
US7686892B2 (en) 2004-11-19 2010-03-30 The Procter & Gamble Company Whiteness perception compositions
DE102004056785A1 (en) 2004-11-24 2006-06-01 Sasol Germany Gmbh Flowable, amphiphilic and nonionic oligoesters
US7597766B2 (en) * 2007-08-03 2009-10-06 American Sterilizer Company Biodegradable detergent concentrate for medical instruments and equipment
EP2300586B1 (en) 2008-06-16 2015-04-08 Unilever PLC Improvements relating to fabric cleaning

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135931A1 (en) * 2008-06-16 2009-12-23 The Procter and Gamble Company Use of soil release polymer in fabric treatment compositions

Also Published As

Publication number Publication date
EP2670788A1 (en) 2013-12-11
BR112013019386B1 (en) 2021-04-06
CL2013002181A1 (en) 2014-06-27
ES2538997T3 (en) 2015-06-25
BR112013019386A2 (en) 2020-10-27
CN103347928B (en) 2016-10-12
ZA201305194B (en) 2014-09-25
WO2012104159A1 (en) 2012-08-09
PL2670788T3 (en) 2015-08-31
AU2012213597B2 (en) 2014-08-28
CN103347928A (en) 2013-10-09
MY163351A (en) 2017-09-15
EP2670788B1 (en) 2015-03-11
AU2012213597A1 (en) 2013-07-25

Similar Documents

Publication Publication Date Title
AU2012213597A8 (en) Alkaline liquid detergent compositions
IN2015MN00104A (en)
MX2010006373A (en) Alkaline cleaning compositions.
CN102643724B (en) Liquid laundry detergent containing tea saponin and method for preparing liquid laundry detergent
CA2561307A1 (en) Antibacterial cleaning wipe
AR080507A1 (en) COMPOSITIONS OF LIQUID DETERGENTS THAT INCLUDE A DIAMID GELIFIER AND PROCESSES TO PREPARE THEM
NZ591299A (en) Naturally based heavy duty cleaning composition for removing soil and stains
CN103740489A (en) Pipeline cleaning agent
WO2008137798A3 (en) Cleaning compositions with water insoluble conversion agents and methods of making and using them
WO2009024747A3 (en) Environmentally acceptable hard surface treatment compositions
EP2576721A4 (en) Surfactant-less alkaline-polymer formulations for recovering reactive crude oil
CN104031755A (en) Oil stain cleaning agent and preparation method thereof
TW200632092A (en) Thickened bleach compositions
EP1842572A3 (en) Hair cleansing composition
WO2009027456A3 (en) Esterified alkyl alkoxylates as solid low-foam wetting agents
CN103469237A (en) Metal oil contamination cleaner
CN104480482A (en) Special cleaning solution for slightly alkaline chemical equipment
WO2011015858A3 (en) Composition
MX2012001489A (en) Composition.
WO2004039331A3 (en) Cleaner compositions
MX2011013763A (en) Concentrated shampoo.
CN103981043A (en) Stain-removal antifogging detergent for glass
CN102373119A (en) Machine cleaning agent
CN103361665A (en) Novel environmental-friendly stainless steel cleaner
EP4259762B1 (en) Composition

Legal Events

Date Code Title Description
TH Corrigenda

Free format text: IN VOL 27 , NO 28 , PAGE(S) 4230 UNDER THE HEADING PCT APPLICATIONS THAT HAVE ENTERED THE NATIONAL PHASE - NAME INDEX UNDER THE NAME UNILEVER PLC, APPLICATION NO.2012213597, UNDER INID (72) CORRECT THE CO-INVENTOR TO PARRY, ALYN JAMES

FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired