AU2011328557A1

AU2011328557A1 - Floor casting nozzle for arrangement in the floor of a metallurgical container

Info

Publication number: AU2011328557A1
Application number: AU2011328557A
Authority: AU
Inventors: Martin Kendall
Original assignee: RHI AG
Current assignee: RHI AG
Priority date: 2010-11-11
Filing date: 2011-10-25
Publication date: 2013-05-02
Anticipated expiration: 2031-10-25
Also published as: DE102010050936A1; UA107409C2; US20130233899A1; MX2013005164A; CN103228382A; JP2013542856A; BE1019916A5; WO2012062414A1; EP2637814A1; AU2011328557B2; CA2754323C; RU2013121151A; CA2754323A1; ZA201303150B; BR112013011578A2; JP5572266B2; KR20130100160A

Abstract

The invention relates to a floor casting nozzle for arrangement in or on the floor of a metallurgical container, having an upper end, preferably for connection to a metallurgical container or to a slide valve of a metallurgical container, and having a lower end, wherein a flow channel is arranged between the two ends, having at least one lower casting opening arranged on the lower end, wherein the wall of the flow channel pointing radially outward is enclosed by a gas-tight housing and wherein the housing encloses the lower end having the at least one casting opening in a gas-tight manner. The invention further relates to a method for operating a floor casting nozzle.

Description

RFPI01312-WO Refractory Intelectual Property GmbH & Co KG Discharge nozzle for installation inside the base of a metalurgic vessel The invention relates to a discharge nozzle for installation inside or at the base (bottom) of a metallurgic vessel with an upper end, preferably for the connection to a metallurgic vessel or to a sliding valve of a metallurgic vessel and a lower end, wherein a flow-through channel with at least one discharge opening at its lower end is arranged between the two ends, wherein the radially to the outside pointing wallof the flow-through channel is surrounded by a gas-proof casing (envelope). Furthermore, the invention relates to a technique for the operation of the bottom discharge nozzle. Especially when steel is melted, the liquid metal is ultimately poured from a metallurgic vessel into a casting mould. Such a metallurgic vessel can especially be a casting ladle or a so called tundish (also called intermediate vessel). The liquid metal is poured from the ladle into the tundish and from the tundish into the casting mould of a strand casting apparatus. In doing so, it flows through a discharge nozzle which is located in the base of the ladle, or respectively in the base of the tundish. The adherence of materials to the wall of the discharge nozzle, which accumulates while flowing through, is disadvantageous. Thereby the cross-section of the opening is reduced so that the stream properties and hence the quality of the steel are negatively affected, inter alia through turbulences. The accumulated material can break off and cause enclosures, which affect the quality of the steel.

RFP101312-WO Refractory intellectual Property GmbH & Co KG 2 in order to prevent the adherence of material to the wall a noble gas like argon is often fed into the flow-through channel. Too large quantities of gas can also negatively affect the quality of the steel though, for example by the formation of hollow enclosures in the steel, which lead to damage on the surface when the steel is rolled out (milled), A material for the discharge nozzle is described for example in WO 2004/035249 Al. A discharge nozzle within a metallurgic vessel is disclosed in KR 2003-0017154 A or in US 2003/0116893 Al. In the latter publication the use of noble gases is displayed with the target of reducing the adherence of materials to the inner wall of the discharge nozzle (so called clogging), similar to the way as described in JP 2187239. A mechanism with a gas supply control is known relatively detailed from WO 01/56725 AL According to the Japanese publication JP 8290250 nitrogen is supplied. JP 3193250 discloses a technique to monitor the adherence of materials w th theaid of multiple temperature sensors which are arranged in series alongside the discharge nozzle, The supply of noble gas into the inner space of the discharge nozzle is further known from JP 2002210545, JP61206559, JP 58061954 and JP 7290422. From some of these publications it is also known, additionally to the supply of noble gas, to prevent oxygen from entering by instaing cases around a part of the discharge nozzle. To some extent, for example in JP 8290250, a noble gas high pressure is created inside such a casing. To prevent the entrance of oxygen a case around the sliding-gate of the discharge nozzle is disclosed in JP 11170033, According to the previously mentioned publications the flow of metal melt along the discharge nozzle is controlled by sliding-gates. These sliders glide perpendicular to the direction of flow of the metal melt and can hence close the discharge nozzle, Another method to regulate the flow is a so called stopper rod, for example as known from JP 2002143994.

RFPI013i2-WO Refractory Intellectual Property GmbH & Co KG The installation of an additional case around the valve of a discharge nozzle is described in the Korean publication KR 1020030054769 A. The gas that is within the case is extracted by suction via a vacuum pump JP 4270042 describes a similar case. In this case a non-oxidising atmosphere is created within the case, as described in other aforementioned publications. The casing features an opening, through which the noble gas can be supplied A further arrangement,.wherein gas is extracted by suction from the casing that partially surrounds the discharge nozzle in order to create a vacuum inside the casing is known from JP 61003653 Further discharge nozzles are for example known from DE 10 2004 057381. Here it is attempted to avoid the problem of adherence with the aid of a controlled noble gas supply or with the aid of an almost complete sealing of the whole coating-area of the discharge nozzle and the associated prevention of oxygen entering through the wall of the discharge nozzle into the steel melt The object of the present invention is to further improve the present technologies in order to minimize the adhesion of material inside the nozzle of a discharge device in a simple and reliable way without affecting the quality of the metal melt or the solidified metal respectively. This task is solved by the characteristics of the independentlaimfs. Preferred embodiments are disclosed in the sub-claims. Surprisingly it has been found that good resultsfor a discharge nozzle for the arrangement in the base (bottom) of a metallurgic vessel with an upper end, preferably for the connection to a metallurgic vessel or to a slide valve of a metallurgic vessel, and an low,,er end, wherein a flow-through channel with at least one PR101312-WO Refractory Intellectual Property GmbH & o KG 4 discharge opening at its lower end is arranged between the two ends, wherein the radially to the outside pointing (fireproof) wall of the flow-through channel is surrounded by a gas-proof casing (envelope), can be achieved by the fact that not only the circumference of the discharge nozzle, te. the radially to the outside pointing wall of the flow-through channel being surrounded by a gas-proof case, but by the fact that the casing of the discharge nozzles also encloses the lower end with the at least one discharge opening. The term gas-proof is not to be understood as absolute leakage-free, but rather that the entering of gas, especially atmospheric oxygen and nitrogen, is general prevented or stopped respectively, For an skilled person it is clearly understandable that the discharge nozzle, the sliding gate valve (or a stopper rod closure) and a further upper nozzle, which is surrounded by a case and arranged in the base of the metallurgic vessel above the sliding valve, are connected in a gas-tight manner and in this way represent a system of a completely sealed nozzle-arrangement. A method according to the invention for the operation of a discharge nozzle, for example by using the discharge nozzle according to the invention as described above, is characterized by the fact that the discharge nozzle is arranged at a sliding gate (valve) or a stopper rod closure of a metalurgic vessel and that before the opening of the sliding gate or the stopper rod closure respectively either a vacuum is created or a noble gas flushing with a subsequent creation of a noble gas excess or high pressure taking place in the discharge nozzle and that the sliding gate valve or the stopper rod closure is opened afterwards For the noble gas, argon can preferably be used, In doing so, oxygen is at least partially removed from the discharge nozzle, so an oxygen deficit or low partial pressure of oxygen is created. The high pressure or rather the vacuum (low pressure) exists in the whole volume within the gas-proof case. The term in the discharge RFP I 312-VO Refractory Intellectual Property GmbH & Co KG 5 nozzle" therefore means the space within the casing (envelope) or the outer-wall respectively and includes the internal volume and the pores of the whole discharge channel, Before the entry of the steel melt this low or high pressure also exists in the flow through channel. At the entry of the steel melt into the discharge nozzle, or rather into its flow-through channel, after the opening of the slide valve or the stopper rod closure, the casing melts when it comes into contact with the steel melt in the area of the at least one discharge opening, so that the steel melt can flow into the vessel which is located underneath. After the opening the discharge nozzle can be run either under a vacuum or under noble gases. One type of discharge nozzle is the so called submerged entry nozzle, called SEN or SES (Submerged Entry Nozzle or Submerged Entry Shroud) among experts With its lower end, it dips (penetrates) into the steel melt which is inside the subjacent metallurgic vessel, whereby the case (casing) melts when it comes into contact with the liquid steel, so that a free flow-through is possible. It is advantageous that the case features multiple case parts that are connected with each other in a gas-proof manner and preferably arranged above each other. The case is preferably made of metal, ike steel, so that it is resistant enough but also melts when it comes into contact with the steel melt. The metal of the case is depending on its purpose chosen in such a way that it melts by the metal inside the melt-receving container, It can also be advantageous that the case features a lower case part made of steel which surr ounds at least the lower end with the at least one discharge opening in a gas-proof manner and that above that a gas-proof case part designed as an integral REP101312-WQ Refractory Intellectual Property GmbH & Co KG 6 part of the wall, being arranged, so that the discharge opening is enclosed by a kind of cap, while the circumferencial wall of the discharge nozzle arranged above features a gas-proof layer, especially surface, which - according to the invention -is considered as part of the case. It can also be advantageous that the case features a lower case part made of steel which is implemented in a gas-proof manner into the lower end with the at least one discharge opening and that a gas-proof case part designed as an integral part of the wall is arranged above, so that the discharge opening is closed by a kind of plug, whereby the outer circumference of the discharge nozzle, including the plug, features a gas-proof layer, especially surface, which, induding the plug, may be considered in accordance with the invention - as part of the casing. Furthermore it can be advantageous to install a layer of a dividing (separating) material, like a paper coating, which is known to the skied person in order to prevent the adhesion of slag or scoria, which are typically present at the surface of the area of the metallic case which is to be dipped into, in order to accelerate the melting of this casing. It is appropriate to arrange a getter material within the casing, preferably selected from at least one metal of the group comprising silicon, calcium, titanium, aluminium, magnesium or zirconium. By this remaining free oxygen in the casing can be bound The fireproof (refractory) material of the wall can feature a low porosity of 2 to 13%, preferably smaller than 10%. Such material, for example carbon impregnated alumina-graphite-material, can - in terms of the invention- Create a sufficient impermeability (sealing). Standard fireproof material has a porosity of more than 16%.

RFP101312-WO Refractory Intellectual Property GmbH & Co KG 7 It is furthermore advantageous that a heating is arranged inside the wall of the flow through channel in order to be able to pre-heat the discharge nozzle before use in order to prevent or minimise temperature shocks. Preferably, a layer of a dividing (separating) material, like papers arranged around the outer surface of the discharge nozzle. Furthermore is can be advantageous that the outer surface of the wall is surrounded by an insulating cement seal at its upper end, below the gas-proof case, whereby the cement seal preferably contains a castable heat-proof cement preferably with at least one of the group alumina (A203) , aluminium-silicate, magnesia (MgC). Furthermore it is prefered that the outer circumference of the wall is surrounded by an isolating material at its lower end, below (under) the gas-proof case, especially a ceramic paper or a woven fabric of ceramic fibres. The insulating material can be arranged directly below (underneath) the cement seal. It is also preferred that gas channels are arranged in the lengthwise direction of the nozzle, underneath the gas-proof casing, especially between the gas-proof casing and the wall. A sliding gate valve, according to the invention, for use with a discharge nozzle and especially for use with a discharge nozzle as defined above which comprises an outer gas-proof case, is characterized by the fact that the gas -proof case includes at least one gas inlet and at least one gas outlet The at least one gas inlet can be used to pump noble gases like argon into the case and the at least one gas outlet can be used to create a vacuum within the case.

RFP101312-WO Refractory intellectual Property GmbH & Co KG 8 A method is advantageous whereby after the opening of the slide valve or the stopper rod closure respectively a) a noble gas high pressure is created if a low pressure (negative pressure) was present before said opening or b) a low pressure is created if a high pressure (excess pressure) was present before said opening, It is especially advantageous that the low pressure is I to 1013 mbar, especialy 150 to 1013 mbar, and the high pressure is 1013 to 1500 mbar or more, i.e. high pressure being above atmospheric pressure, Especially at a discharge nozzle of a casting ladle a vacuum (low pressure) can be created first and later, after the opening, a noble gas high pressure. At the discharge of a tundish it is advantageous to create a noble gas high pressure first and a vacuum after the opening. In the following, the invention is explained in an exemplified manner with the aid of a drawing. In the drawing Fig. 1 shows a discharge nozzle for a tundish Fig, 2 shows a further discharge nozzle for a tundish Fig. 3 shows a third variation of a discharge nozzle for a tundish Fig. 4 shows a discharge nozzle for a casting ladle Fig. 5 shows a further discharge nozzle for a casting ladle Fig. 6 shows the arrangement of a discharge nozzle at a tundish and Fig, 7 shows the arrangement of a discharge nozzle at a casting ladle.

RFP101312-WO Refractory Inteflectual Property GmbH & Co KG 9 The discharge nozzle displayedin Fig. 1 features a flow-through channel I with multiple lateral discharge openings 2 The wall 3 of the flow-through channel I is generally made out of a mixture of alumina and graphite. At its upper end a mounting sleeve 4 is arranged for the alignment to a sliding gate valve, which represents the main part of the completely sealed system. The outer circumference of the wall 3 is surrounded by an insulating cement seat 5 at its upper end; below an insulating material 6, for example a ceramic paper or a fibre mat of ceramic fibres being arranged. On top of the cement seal 5 and the isolating material 6 a gas-proof case 7 is arranged. This encloses the whole discharge nozzle up to the mounting sleeve 4 and solely provides one opening 8 for feeding in a noble gas (Argon). The noble gas can be fed into a gap between the gas-proof case 7 and the insulating material 6 for the flushing action. A so called scoria belt (scoria layer) 9 made of zirconium-graphite is arranged above the discharge openings 2, The discharge openings 2 are closed by the case 7. A similar discharge nozzle is displayed in Fig. 2. It features a cap 10, for example made out of steel, at its lower end, which closes (encloses) the discharge openings 2. At least the outer surface of the wall 3 is gas-proof at least above said cap 10, thus forming a gas-proof part of the case. Along the outer surface of the cap 10 a layer of a separating material 10', like for example paper, is arranged. This dividing layer 10 can also cover the whole outer surface of the discharge nozzle, Fig. 3 shows a similar arrangement to Fig, 1, whereby a circumferential slit 27 within the wall 3 is connected to the opening 8, By this means Argon can be fed into the wall and an Argon high pressure can be achieved RFP1I1312-WO Refractory Intelectual Property GmbH &.Co KG 10 The discharge nozzle for a casting ladle (Fig. 4) is, in principle, designed in a similar way, however it features a persistently straight flow-through channel V and a discharge opening 2' which is located centrically at the lower end. A similar arrangement is displayed in Fig. 5, wherein the discharge opening Z is closed by a gas-proof plug 28 and wherein at least the outer surface of the wall 3 is designed in a gas-proof manner, The plug 28 can be melted, burned or dissolved by the influence of the metal melt in the metalurgic vessel in order to clear the discharge opening 2" It can for example consist of a metal like steel, stainless steel or copper. In Fig. 6 the arrangement of a discharge nozzle as a lower nozzle 11 at a tundish 12 is displayed, The tundish 12 features a multilayered lining 13, which protects the tundish wall 14, An upper nozzle 15 in which electrodes 16 are embedded and which outer periphery 29 being gas-proof is arranged in the base of the tundish 12. At the upper end the upper nozzle 15 is surrounded by a wel nozzle 17 for its protection. At the lower face of the upper nozzle 15, below the base of the tundish 12, a sliding gate valve 18 is arranged, surrounded by a gas-proof slider-case 19. which is connected in a gas proof manner at its upper end with the outside 29 of the upper nozzle 15 and with the gas-proof case 7 at its lower end. Inside the slider-case 19 an inlet 20 for noble gas and a connection 21 for a vacuum pump are provided. Fig, 7 shows the arrangement of a discharge nozzle at a casting ladle 22 as wel as the tundish 12 which is arranged underneath. The tundish comprises, besides its outlet opening 23. so called impact pads 24 which are supposed to calm the steel melt mechanically, so to prevent turbulences that are too large, At the casting ladle opening (sliding valve) 25, the discharge nozzle displayed in Fig. 4 is arranged. The inlet for noble gas as well as the connection for a vacuum pump are, for reasons of simplicity, not displayed in Fig. 7. It is obvious for the skilled person that the general structural arrangement of the described components of the invention to pass the RFP10131>WO Refractoiy Intelectual Property GmbH & Co KG metal melt from the casting ladle into the tundish and from there into the casting mould is very similar and features a common design and function The casting ladle 22 itself features a multilayered lining 26 along its inside. Before the casting process starts, the sliding valve 25 is closed and a vacuum is created in the flow-through channel 1', Fig. 4, of a casting ladle in order to remove any oxygen. Thereby a vacuum is also created in the flow-through channel 1', in the wall of the discharge nozzle, so between the inside wall surrounding the flow-through channel 1and the outer case as well as inside the sliding valve 25 a low pressure (vacuum) is created. Upon flowing in of the steel melt into the flow-through channel the gas-proof case 7 melts in the area of the discharge opening 2'when it comes into contact with the steel melt, so that the steel melt can flow into the subjacent container (tundish 12), The low pressure was, in an example, regulated within the area of 700 to 800 mbar, and the subsequent high pressure was adjusted to a maximum of 1500mbar. At the discharge of the tundish, a discharge nozzle is also located. Initially a high pressure with an argon pressure of a maximum. of 1500 mbar is created inside said nozzle, At the flowing in of the steel melt into the flow-through channel 1, the gas tight casing 7 melts in the area of the discharge opening 2, so that the steel melt can flow into the subjacent vessel The gas is pumped off the discharge nozzle, so that a vacuum is created.

Claims

1. Discharge nozzle for an arrangement inside or at the base of a metallurgic vessel with an upper end, preferably for the connection to a metallurgic vessel or to a sliding valve of a metallurgic vessel, and a lower end, whereat a flow through channel with at least one discharge opening at its lower end is arranged between the two ends, whereat the radially to the outside pointing wall of the floA-through channel is surrounded by a gas-proof case, characterized by the fact that the case surrounds the lower end with at least one discharge opening in a gas proof manner.

2, Discharge nozzle according to claim I, characterized by the fact that the case features multiple case parts that are connected in a gas proof manner and preferably arranged above each other

3. Discharge nozzle according to claim 1 or 2, characterized by the fact that the case is made of metal, like steel, or another material which is appropriate to be gas proof and temperature-resistant like copper, nickel or stainless steel

4. Discharge nozzle according to claim 2, characterized by the fact that the case features a lower case part made out of steel which surrounds at least the lower end with the at least one discharge opening in a gas-proof manner and that above that a gas-proof case part which is designed as an integral part of the wall is arranged. RFP101312-WO Refractory intellectual Property GmbH & Co KG 13

5. Discharge nozzle according to claim 2, characterized by the fact that the case features a lower case part made of steel which is implemented in a gas-proof manner into the lower end with the at least one discharge opening and that a gas-proof case part as an integral part of the wall is arranged above, so that the discharge opening is closed by a plug, whereby the outer circumference of the discharge nozzle features a gas-proof surface as a part of the case.

6. Discharge nozzle according to daims I to 5, characterized by the fact that within the case a getter materials arranged, preferably made of at least one metal of the group silicon, calcium, titanium, aluminium, magnesium or zirconium.

7. Discharge nozzle according to claims 1 to 6, characterized by the fact that a heating is arranged inside the wall of the flow-through channel.

8, Discharge nozzle according to claims 1 to 7, characterized by the fact that a layer of a dividing material, like paper is arranged around the outer surface of the discharge nozzle.

9. Discharge nozzle according to claims 1 to 8, characterized by the fact that the outer surface of the wall is surrounded by an insulating cement seal at its upper end, below the gas-proof casewhereby the cement seal preferably contains a pourable heat-proof cement preferably with at least one of the group alumina, aluminium-silicate, magnesia,

10, Discharge nozzle according to claims 1 to 9, characterized by the fact that that the outer circumference of the wall is surrounded by an isolating material at its RFP101312-WO Refractory Intellectual Property GmbH & Co KG 14 lower end, below the gas-proof case, especially a ceramic paper or a woven fabric made of ceramic fibres,

11. Discharge nozzle according to claims 9 to 10, characterized by the fact that the insulating material can be arranged directly below the cement seal.

12, Discharge nozzle according to claims I to 11, characterized by the fact that below the gas-proof case, especially between the gas-proof case and the walt gas channels are arranged in the lengthwise direction of the nozzle.

13, Sliiding valve for use with a discharge nozzle, which siding valve includes a gas proof outer case, characterized by the fact that the gas proof case features at least one gas inlet and at least one gas outlet,

14. Method for the operation of a discharge nozzle, characterized by the fact that the discharge nozzle is arranged at a sliding gate valve or a stopper rod closure of a metallurgic vessel and that before the opening of the sliding gate valve or the stopper rod closure either a vacuum is created or a noble gas flushing with a subsequent creation of a noble gas excess or high pressure takes place in the discharge nozzle and that the sliding gate valve or the stopper rod closure is opened afterwards.

15, Method according to claim 7, characterized by the fact that after the opening of the sliding gate valve or the stopper rod closure either c) a noble gas high pressure is created, if a low pressure was present before the opening or RFP101312AO Refractory Inteecdua Property GmbH & Co KG 15 d) a low pressure is createdif a high pressure was present before the opening. 1. Method accorcbnq to daim 7 or S, characteri2ed by the fact that the low pressure is 1 to 1013 mobar and the high pressure is above atmosphere pressure,