AU2011294884C1 - Detergent composition comprising manganese-oxalate - Google Patents
Detergent composition comprising manganese-oxalate Download PDFInfo
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- AU2011294884C1 AU2011294884C1 AU2011294884A AU2011294884A AU2011294884C1 AU 2011294884 C1 AU2011294884 C1 AU 2011294884C1 AU 2011294884 A AU2011294884 A AU 2011294884A AU 2011294884 A AU2011294884 A AU 2011294884A AU 2011294884 C1 AU2011294884 C1 AU 2011294884C1
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- detergent composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 124
- 239000003599 detergent Substances 0.000 title claims abstract description 63
- RGVLTEMOWXGQOS-UHFFFAOYSA-L manganese(2+);oxalate Chemical compound [Mn+2].[O-]C(=O)C([O-])=O RGVLTEMOWXGQOS-UHFFFAOYSA-L 0.000 title claims description 24
- 239000007844 bleaching agent Substances 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 101100345345 Arabidopsis thaliana MGD1 gene Proteins 0.000 claims abstract 2
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 claims abstract 2
- 239000003826 tablet Substances 0.000 claims description 30
- 239000002775 capsule Substances 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 22
- 102000004190 Enzymes Human genes 0.000 claims description 15
- 108090000790 Enzymes Proteins 0.000 claims description 15
- 229940088598 enzyme Drugs 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 102000013142 Amylases Human genes 0.000 claims description 11
- 108010065511 Amylases Proteins 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 11
- 108091005804 Peptidases Proteins 0.000 claims description 10
- 239000004365 Protease Substances 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 10
- 235000019418 amylase Nutrition 0.000 claims description 10
- 238000005260 corrosion Methods 0.000 claims description 10
- 239000000499 gel Substances 0.000 claims description 9
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical group [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 230000007797 corrosion Effects 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 3
- 102000035195 Peptidases Human genes 0.000 claims description 3
- 229940025131 amylases Drugs 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000006072 paste Substances 0.000 claims description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
- 238000004851 dishwashing Methods 0.000 abstract description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 18
- 239000002736 nonionic surfactant Substances 0.000 description 15
- 150000002191 fatty alcohols Chemical class 0.000 description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 13
- 238000004061 bleaching Methods 0.000 description 13
- -1 alkali metal salts Chemical class 0.000 description 12
- 239000008118 PEG 6000 Substances 0.000 description 11
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 229920002535 Polyethylene Glycol 1500 Polymers 0.000 description 9
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical group CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- VUYXVWGKCKTUMF-UHFFFAOYSA-N tetratriacontaethylene glycol monomethyl ether Chemical compound COCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VUYXVWGKCKTUMF-UHFFFAOYSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 8
- 239000004382 Amylase Substances 0.000 description 7
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 7
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 239000012964 benzotriazole Substances 0.000 description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229940045872 sodium percarbonate Drugs 0.000 description 4
- 235000019832 sodium triphosphate Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000004967 organic peroxy acids Chemical class 0.000 description 3
- GTXVUMKMNLRHKO-UHFFFAOYSA-N 2-[carboxymethyl(2-sulfoethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCS(O)(=O)=O GTXVUMKMNLRHKO-UHFFFAOYSA-N 0.000 description 2
- XWSGEVNYFYKXCP-UHFFFAOYSA-N 2-[carboxymethyl(methyl)amino]acetic acid Chemical compound OC(=O)CN(C)CC(O)=O XWSGEVNYFYKXCP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000004966 inorganic peroxy acids Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- UWRLZJRHSWQCQV-YFKPBYRVSA-N (2s)-2-(2-sulfoethylamino)pentanedioic acid Chemical compound OC(=O)CC[C@@H](C(O)=O)NCCS(O)(=O)=O UWRLZJRHSWQCQV-YFKPBYRVSA-N 0.000 description 1
- HWXFTWCFFAXRMQ-JTQLQIEISA-N (2s)-2-[bis(carboxymethyl)amino]-3-phenylpropanoic acid Chemical compound OC(=O)CN(CC(O)=O)[C@H](C(O)=O)CC1=CC=CC=C1 HWXFTWCFFAXRMQ-JTQLQIEISA-N 0.000 description 1
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 description 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- LFFYIPJMKIXOIV-UHFFFAOYSA-N 1-hydroxy-3-prop-2-enoxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)C(O)CCOCC=C LFFYIPJMKIXOIV-UHFFFAOYSA-N 0.000 description 1
- CLHYKAZPWIRRRD-UHFFFAOYSA-N 1-hydroxypropane-1-sulfonic acid Chemical compound CCC(O)S(O)(=O)=O CLHYKAZPWIRRRD-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- JPGSFSFMINKKJZ-UHFFFAOYSA-N 2-[1,2-dicarboxyethyl(hydroxy)amino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)N(O)C(CC(O)=O)C(O)=O JPGSFSFMINKKJZ-UHFFFAOYSA-N 0.000 description 1
- YDJFNSJFJXJHBG-UHFFFAOYSA-N 2-carbamoylprop-2-ene-1-sulfonic acid Chemical compound NC(=O)C(=C)CS(O)(=O)=O YDJFNSJFJXJHBG-UHFFFAOYSA-N 0.000 description 1
- DMSRIHVZKOZKRV-UHFFFAOYSA-N 2-methyl-1-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C(C)=C DMSRIHVZKOZKRV-UHFFFAOYSA-N 0.000 description 1
- 125000004398 2-methyl-2-butyl group Chemical group CC(C)(CC)* 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- XMSFZHWBBUOKRY-UHFFFAOYSA-N 2-octylbutanediperoxoic acid Chemical compound CCCCCCCCC(C(=O)OO)CC(=O)OO XMSFZHWBBUOKRY-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- ODAKQJVOEZMLOD-UHFFFAOYSA-N 3-[bis(carboxymethyl)amino]-2-hydroxypropanoic acid Chemical compound OC(=O)C(O)CN(CC(O)=O)CC(O)=O ODAKQJVOEZMLOD-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229940125758 compound 15 Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 108010093305 exopolygalacturonase Proteins 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- PGOMUAXHEQEHJB-UHFFFAOYSA-N manganese;octadecanoic acid Chemical compound [Mn].CCCCCCCCCCCCCCCCCC(O)=O PGOMUAXHEQEHJB-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DTXLBRAVKYTGFE-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)-3-hydroxybutanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)C(O)C(C([O-])=O)NC(C([O-])=O)CC([O-])=O DTXLBRAVKYTGFE-UHFFFAOYSA-J 0.000 description 1
- GYBINGQBXROMRS-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)NC(C([O-])=O)CC([O-])=O GYBINGQBXROMRS-UHFFFAOYSA-J 0.000 description 1
- NGWOVIOEEGSBCX-UHFFFAOYSA-J tetrasodium;2-[1,2-dicarboxylatoethyl(hydroxy)amino]butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)N(O)C(CC([O-])=O)C([O-])=O NGWOVIOEEGSBCX-UHFFFAOYSA-J 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/391—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/0018—Controlling processes, i.e. processes to control the operation of the machine characterised by the purpose or target of the control
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1014328.7A GB201014328D0 (en) | 2010-08-27 | 2010-08-27 | Detergent composition comprising manganese-oxalate |
| GB1014328.7 | 2010-08-27 | ||
| PCT/GB2011/051556 WO2012025740A1 (en) | 2010-08-27 | 2011-08-18 | Detergent composition comprising manganese-oxalate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| AU2011294884A1 AU2011294884A1 (en) | 2013-03-07 |
| AU2011294884B2 AU2011294884B2 (en) | 2015-07-09 |
| AU2011294884C1 true AU2011294884C1 (en) | 2015-12-03 |
Family
ID=43013357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2011294884A Ceased AU2011294884C1 (en) | 2010-08-27 | 2011-08-18 | Detergent composition comprising manganese-oxalate |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20130199569A1 (https=) |
| EP (1) | EP2609188A1 (https=) |
| JP (1) | JP2013538268A (https=) |
| CN (1) | CN103180426B (https=) |
| AU (1) | AU2011294884C1 (https=) |
| BR (1) | BR112013004567A2 (https=) |
| CA (1) | CA2809551A1 (https=) |
| GB (1) | GB201014328D0 (https=) |
| RU (1) | RU2013113564A (https=) |
| WO (1) | WO2012025740A1 (https=) |
| ZA (1) | ZA201301317B (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8951956B2 (en) | 2008-01-04 | 2015-02-10 | Ecolab USA, Inc. | Solid tablet unit dose oven cleaner |
| US9574163B2 (en) | 2012-10-26 | 2017-02-21 | Ecolab Usa Inc. | Caustic free low temperature ware wash detergent for reducing scale build-up |
| US9394508B2 (en) | 2012-10-26 | 2016-07-19 | Ecolab Usa Inc. | Phosphorus free low temperature ware wash detergent for reducing scale build-up |
| US9605236B2 (en) | 2012-10-26 | 2017-03-28 | Ecolab Usa Inc. | Low alkaline low temperature ware wash detergent for protein removal and reducing scale build-up |
| DE102012022566A1 (de) * | 2012-11-17 | 2014-05-22 | Clariant International Ltd. | Waschmittelzusammensetzung enthaltend Manganoxalat und Carboxymethyloxybernsteinsäure (CMOS) und/oder deren Salze |
| CN105102602B (zh) * | 2013-04-02 | 2018-05-25 | 巴斯夫欧洲公司 | 配制剂、其作为或用于制品器皿洗涤清净剂的用途及其制备 |
| JP6140365B2 (ja) * | 2013-05-02 | 2017-05-31 | エコラボ ユーエスエー インコーポレイティド | 物品洗浄用途における澱粉の改善された除去のための濃縮した洗浄剤組成物 |
| CN105722768B (zh) * | 2013-10-07 | 2019-02-19 | 蒙诺苏尔有限公司 | 水溶性延迟释放胶囊、相关方法和相关制品 |
| US9670440B2 (en) * | 2013-10-07 | 2017-06-06 | Monosol, Llc | Water-soluble delayed release capsules, related methods, and related articles |
| MX395198B (es) | 2013-10-24 | 2025-03-25 | Ecolab Usa Inc | Composiciones y metodos para eliminar suciedades de las superficies. |
| US9267096B2 (en) | 2013-10-29 | 2016-02-23 | Ecolab USA, Inc. | Use of amino carboxylate for enhancing metal protection in alkaline detergents |
| US9139799B1 (en) | 2014-07-11 | 2015-09-22 | Diversey, Inc. | Scale-inhibition compositions and methods of making and using the same |
| US9920288B2 (en) | 2014-07-11 | 2018-03-20 | Diversey, Inc. | Tablet dishwashing detergent and methods for making and using the same |
| DE102014011023A1 (de) | 2014-07-24 | 2016-01-28 | Weylchem Wiesbaden Gmbh | Wasch- und Reinigungsmittel enthaltend Manganoxalat, Geschirrspülverfahren und deren Verwendung |
| RU2689387C2 (ru) * | 2014-10-17 | 2019-05-28 | Басф Се | Контейнер, включающий композицию моющего средства, содержащую mgda |
| US9765286B2 (en) | 2014-12-22 | 2017-09-19 | Ecolab Usa Inc. | Warewashing composition containing alkanol amine phosphonate and methods of use |
| EP3050952A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Method of dishwashing |
| EP3050954A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | New use of sulfonated polymers |
| EP3050951A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Method of dishwashing |
| EP3050953B1 (en) * | 2015-02-02 | 2018-12-26 | The Procter and Gamble Company | Detergent composition |
| EP3050947A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Detergent pack |
| EP3050955B2 (en) | 2015-02-02 | 2023-11-08 | The Procter & Gamble Company | Detergent pack |
| EP3053997B2 (en) | 2015-02-05 | 2021-01-13 | Dalli-Werke GmbH & Co. KG | Cleaning composition comprising a bleach catalyst and carboxymethylcellulose |
| CA3000989C (en) | 2015-04-29 | 2023-05-09 | Shutterfly, Inc | Image product creation based on face images grouped using image product statistics |
| JP6695103B2 (ja) * | 2015-06-25 | 2020-05-20 | 株式会社ニイタカ | カートリッジ洗浄剤 |
| MX2017016883A (es) | 2015-07-06 | 2018-09-18 | Ecolab Usa Inc | Remocion de mancha a traves de oxidante novedoso y combinacion de quelante. |
| DE102015213938A1 (de) * | 2015-07-23 | 2017-01-26 | Henkel Ag & Co. Kgaa | Einsatz einer Kombination aus Komplexbildner und Tensid zur Verbesserung der Klarspülleistung |
| DE102015213940A1 (de) * | 2015-07-23 | 2017-01-26 | Henkel Ag & Co. Kgaa | Maschinelles Geschirrspülmittel enthaltend Bleichmittel, Builder und Enzyme |
| PL3124587T3 (pl) | 2015-07-29 | 2019-08-30 | The Procter And Gamble Company | Wielofazowy produkt czyszczący w postaci dawki jednostkowej |
| EP3124586A1 (en) * | 2015-07-29 | 2017-02-01 | The Procter and Gamble Company | Process for reducing malodour in a pack |
| EP3241890B1 (en) * | 2016-05-03 | 2019-06-26 | The Procter and Gamble Company | Automatic dishwashing detergent composition |
| EP3746535A1 (en) | 2018-01-30 | 2020-12-09 | Eastman Chemical Company | Compositions comprising aminocarboxylate chelating agents |
| CN111819274B (zh) | 2018-03-08 | 2022-06-21 | 埃科莱布美国股份有限公司 | 固体酶洗涤剂组合物和其使用和制造方法 |
| GB201814188D0 (en) * | 2018-08-31 | 2018-10-17 | Reckitt Benckiser Finish Bv | Automatic dishwashing product |
| EP4097209A1 (en) * | 2020-01-31 | 2022-12-07 | Ecolab USA Inc. | Amylase synergy with oxygen bleach in warewash application |
| EP4232541B1 (de) * | 2020-10-23 | 2024-11-27 | Chemische Fabrik Dr. Weigert GmbH & Co. KG | Flüssiges reinigungsmittelkonzentrat, gebrauchsfertige anwendungslösung, deren verwendungen und reinigungsverfahren |
| EP4008765A1 (en) * | 2020-12-07 | 2022-06-08 | WeylChem Performance Products GmbH | Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2009040544A1 (en) * | 2007-09-28 | 2009-04-02 | Reckitt Benckiser N.V. | Detergent composition |
| WO2009092699A1 (en) * | 2008-01-24 | 2009-07-30 | Unilever Nv | Machine dishwash detergent compositions |
| DE102008045215A1 (de) * | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Verwendung von Mangan-Oxalatenn als Bleichkatalysatoren |
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| US5308532A (en) | 1992-03-10 | 1994-05-03 | Rohm And Haas Company | Aminoacryloyl-containing terpolymers |
| PL177936B1 (pl) | 1993-05-08 | 2000-01-31 | Henkel Kgaa | Niskoalkaliczny środek do maszynowego zmywania naczyń |
| CA2162459A1 (en) | 1993-05-08 | 1994-11-24 | Juergen Haerer | Corrosion inhibitors for silver (ii) |
| WO1995001416A1 (en) | 1993-07-01 | 1995-01-12 | The Procter & Gamble Company | Machine dishwashing composition containing oxygen bleach and paraffin oil and benzotriazole compound silver tarnishing inhibitors |
| DE19528059A1 (de) | 1995-07-31 | 1997-02-06 | Bayer Ag | Wasch- und Reinigungsmittel mit Iminodisuccinaten |
| EP0783034B1 (en) | 1995-12-22 | 2010-08-18 | Mitsubishi Rayon Co., Ltd. | Chelating agent and detergent comprising the same |
| US20050202995A1 (en) | 2004-03-15 | 2005-09-15 | The Procter & Gamble Company | Methods of treating surfaces using surface-treating compositions containing sulfonated/carboxylated polymers |
| GB0616444D0 (en) * | 2006-08-18 | 2006-09-27 | Reckitt Benckiser Nv | Detergent composition |
| GB0818804D0 (en) * | 2008-10-14 | 2008-11-19 | Reckitt Benckiser Nv | Compositions |
-
2010
- 2010-08-27 GB GBGB1014328.7A patent/GB201014328D0/en not_active Ceased
-
2011
- 2011-08-18 EP EP11748707.4A patent/EP2609188A1/en not_active Ceased
- 2011-08-18 US US13/818,468 patent/US20130199569A1/en not_active Abandoned
- 2011-08-18 BR BR112013004567A patent/BR112013004567A2/pt not_active IP Right Cessation
- 2011-08-18 WO PCT/GB2011/051556 patent/WO2012025740A1/en not_active Ceased
- 2011-08-18 AU AU2011294884A patent/AU2011294884C1/en not_active Ceased
- 2011-08-18 RU RU2013113564/04A patent/RU2013113564A/ru not_active Application Discontinuation
- 2011-08-18 CA CA2809551A patent/CA2809551A1/en not_active Abandoned
- 2011-08-18 JP JP2013525358A patent/JP2013538268A/ja active Pending
- 2011-08-18 CN CN201180041818.2A patent/CN103180426B/zh not_active Expired - Fee Related
-
2013
- 2013-02-20 ZA ZA2013/01317A patent/ZA201301317B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009040544A1 (en) * | 2007-09-28 | 2009-04-02 | Reckitt Benckiser N.V. | Detergent composition |
| WO2009092699A1 (en) * | 2008-01-24 | 2009-07-30 | Unilever Nv | Machine dishwash detergent compositions |
| DE102008045215A1 (de) * | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Verwendung von Mangan-Oxalatenn als Bleichkatalysatoren |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2013113564A (ru) | 2015-04-10 |
| US20130199569A1 (en) | 2013-08-08 |
| WO2012025740A1 (en) | 2012-03-01 |
| AU2011294884B2 (en) | 2015-07-09 |
| CN103180426A (zh) | 2013-06-26 |
| BR112013004567A2 (pt) | 2016-09-06 |
| EP2609188A1 (en) | 2013-07-03 |
| CN103180426B (zh) | 2016-03-02 |
| CA2809551A1 (en) | 2012-03-01 |
| JP2013538268A (ja) | 2013-10-10 |
| AU2011294884A1 (en) | 2013-03-07 |
| GB201014328D0 (en) | 2010-10-13 |
| ZA201301317B (en) | 2014-04-30 |
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