AU2011244683A1

AU2011244683A1 - Use of water-based lubricants for textile machines

Info

Publication number: AU2011244683A1
Application number: AU2011244683A
Authority: AU
Inventors: Thomas Kilthau; Martin Schweigkofler
Original assignee: Klueber Lubrication Muenchen SE and Co KG
Current assignee: Klueber Lubrication Muenchen GmbH and Co KG
Priority date: 2010-04-21
Filing date: 2011-04-18
Publication date: 2012-11-01
Also published as: WO2011131331A1; DE102010015757A1; DE102011016818A1; US20130035267A1; CN102884164A; MX2012011224A; CA2794779C; CA2794779A1; EP2561048A1; BR112012027006A2; ZA201207544B

Abstract

The present invention relates to the use of water-based lubricants for textile machines, especially to the use as needle oil and/or lifter oil.

Description

WO 2011/131331 PCT/EP2011/001961 Use of Water-Based Lubricants for Textile Machines Specification 5 This invention relates to the use of water-based lubricants for textile machines, in particular the use as needle oils and/or sinker oils in textile knitting machines. Lubricants that must meet high requirements are used for lubricating textile knitting machines. The compositions of a needle oil or sinker oil should have a constant viscosity at different machine speeds and temperatures. In this case, the operating viscosity of the 10 lubricant should lie in the range of ISO VG 15 - ISO VG 100. The compositions of the needle or sinker oils, moreover, should be resistant to aging. The lubricants are to be present in the form of as colorless and clear a solution as possible. These colorless lubricants are to have a good-to-excellent scourability, i.e. washing out ability; in particular, it should be possible to scour the lubricants at low temperatures. 15 When a lubricant can be scoured only incompletely, it results in problems in the subsequent treatments of knit fabrics. In particular, a uniform dyeing of the knit goods is no longer possible, and irreversible color defects are the result. In addition, the lubricants are also to have a long shelf life even at low temperatures without the formation of precipitates. The formation of precipitates can result in the clogging 20 of the oil supply systems of the knitting machines. The lubricant also must not have a tendency toward phase separation over the overall service temperature range of 0*C to 80'C. The phase separation of the lubricant can result in a deficient lubrication of the machine parts and thus can result in unevenness of the knit fabric, which also can result in defects in the knitwear in the subsequent color treatment. 25 In addition to good protection against wear and tear and corrosion, the lubricant must also have the lowest possible level of friction. This results in a considerable energy savings and in reducing the noise level, which in turn results in improving work conditions. In addition, the lubricant has to be slightly biodegradable, since the lubricant can get into the waste water via the scouring process and correspondingly has to be treated and 30 decomposed via the clarification process.

WO 2011/131331 PCT/EP2011/001961 2 The textile oils that are used over time, which are present in the form of an emulsion, in most cases consist of more than 80% mineral oil, to which the usual wear- and corrosion reducing additives are added. In addition, emulsifiers are added to improve the scourability. In this connection, both anionic emulsifiers (e.g., sulfonates) and nonionic emulsifiers (e.g., 5 fatty alcohol ethoxylates or else NPE), as well as cationic emulsifiers (e.g., quaternary ammonium compounds) can be used. At times, small amounts of water (less than 1%) have to be added to emulsifier-containing textile oils to stabilize them or reduce their tendency toward precipitation. Higher concentrations of water result in unacceptably high cloudiness by forming an emulsion, which results in phase separation, or can produce hydrolysis of the 10 additives that are used. In addition, it is known to apply lubricating agent to textile yarns by a roller, which runs over the corresponding yam, being immersed in a lubricating agent emulsion to facilitate the processibility of the yarns. To this end, a composition that contains 50 to 80 parts by weight of poly(oxyethylene-oxy-l,2-propylene)glycol, 10 to 40 parts by weight of emulsifier, 15 and 10 to 40 parts by weight of an ester is described in US 3 338 830 A. This mixture is present as a concentrate and is diluted with water, so that I to 25% by weight of non-aqueous components is present and is used in the form of an aqueous emulsion. From DE 30 08 500 C2, a water-soluble metal-working fluid that contains diethanol disulfide and one or more water-soluble polyoxyalkylene glycols are known. This liquid is used for working metals, 20 whereby maximum pressure and anti-friction properties are ensured by preparing a sufficient amount of liquid. The object of this invention is to prepare a liquid water-based lubricant for textile machines, with which the above-mentioned drawbacks, which develop when a mineral oil is used, are overcome, and which is present in the form of a solution. 25 So that the lubricant can be used in textile machines, it should be biodegradable, and it should be scourable at the lowest possible temperatures as well as used in an overall service temperature range without phase separation, should offer good protection against wear and tear and corrosion, and should have as low a friction level as possible. According to the invention, a water-based lubricant for textile knitting machines, 30 which contains 5 to 50% by weight of water-soluble polymer and/or 5 to 50% by weight of emulsifier add water up to 100% by weight, is therefore used.

WO 2011/131331 PCT/EP20 11/001961 3 In addition, the lubricant can also contain 0 to 15% by weight, in particular 2 to 5% by weight, of corrosion- reducing and protecting, respectively agent; 0 to 10% by weight, in particular 0.2 to 5% by weight, of wear- reducing and protecting, respectively agent; 0 to 1% by weight, in particular 0.01 to 0.75% by weight, of biocide; and 0 to 50% by weight, in 5 particular 2 to 25% by weight, of an anti-icing agent. The water-soluble polymer that is contained in the lubricant is selected from the group that consists of polyalkylene glycols, in particular polyethylene glycol with molar masses of 1,000 to 35,000, water-soluble esters, polyacrylates, polymethacrylates, polyvinyl pyrrolidones, polyacrylamides, carboxymethyl cellulose, polyanionic cellulose, hydroxy 10 cellulose, and hydroxyethyl cellulose. The emulsifier that is contained in the lubricant is selected from the group that consists of nonionic, anionic and cationic emulsifiers, in particular alkylene oxide polymers, sulfonates, carboxylic acid and dicarboxylic acid derivatives with a chain length of 6 to 16 carbon atoms, phosphate esters, and quaternary ammonium compounds. 15 The corrosion- and wear-reducing agent that is contained in the lubricant is selected from the group that consists of water-soluble phosphorus and/or sulfur compounds, and nitrogen compounds, the biocide is benzoic acid, and the anti-icing agent is selected from the group that consists of low-molecular glycols, in particular ethylene glycol, propylene glycol, trimethylene glycol, glycerol, salts or ionic liquids. 20 The lubricant according to the invention can also be used in the form of a concentrate. In this case, primarily the reduced goods traffic is advantageous, since the finished formulation can be produced directly by customers by dilution with water. Moreover, the storage space that is required at the user site is reduced. Besides, the user can adjust the lubricant directly to the desired viscosity for its application. 25 To ensure that the lubricant is biodegradable, can be scoured, i.e. washed out at the lowest possible temperatures, can be used in the overall service temperature range without phase separation, offers good protection against wear and tear and corrosion, and has as low a friction level as possible, water is used as a carrier liquid. Special water-soluble additives, such as polyalkylene glycol and/or water-soluble esters, are added to this carrier liquid, and 30 then the corresponding operating viscosity is set between ISO VG 15 -ISO VG 100.

WO 201 1/131331 PCT/EP20 11/001961 4 In this connection, it is pointed out expressly that the examples below do not involve any emulsions, but rather true clear aqueous solutions. The application is exclusively the lubrication of machines or machine parts and not the lubrication/finishing of yarns. The advantageous properties of the lubricant according to the invention are shown 5 based on the subsequent examples and the comparison example. Examples Example I The lubricant has the following composition: Distilled water 68.0% by weight 10 Water-soluble polymer, polyglycol 8000 S, Clariant Co. 22.0% by weight Alcohol polyalkylene glycol ether, Marlowet 5056, Sasol Co. 5.0% by weight Boric acid ester and alkanolamines, Hostacor Bi, Clariant Co. 2.0% by weight 15 Sulfurized fatty acid, LUBIO EP 1, Schafer Additive Systems GmbH 3.0% by weight Table I shows the results of the studies of the properties of the lubricating agent according to the invention in accordance with the invention compared to that of a known mineral-oil-based lubricating agent. 20 Table 1 Comparison Example Based Example I on Mineral Oil (Kluber Oil Tex 1-22 N) Appearance, Colorless Clear, Hazen < 50 Colorless Clear, Hazen < 50 Hazen Color Unit Corrosion Protection on Very Good Very Good Knitting Needles, KLM Test Scourability at 65 0 C with Very Good Very Good Washing Agent DIN EN ISO 105-AOl Scourability at 30 0 C Poor Very Good without Washing Agent DIN EN ISO 105-AOl Kin. Viscosity at 40 0 C 22 cst 22 cst WO 2011/131331 PCT/EP2011/001961 5 Protection Against Wear Very Good Very Good and Tear (SRV) DIN 51834-1; DIN 51834-2 Friction Coefficient (SRV) 0.10 0.06 Biodegradability --- Very Good The KLM test is performed as follows: In a Petri dish (diameter 80 mm), an acetone-purified knitting needle (length 44 mm) is placed on a round filter (filter paper with a diameter of 55 mm, Whatman) and covered 5 with 10 ml of aqueous textile oil. After 48 hours of storage at room temperature, the needle (black spots) and the filter paper (yellow-red coloring) are checked for corrosion. The study results shown in Table 1 can be summarized as follows. The lubricant that is produced according to the invention is a virtually colorless, limpid solution. The complete scourability is itself added without washing agents at low temperatures, which makes 10 possible a considerable savings in energy. The friction level that is drastically reduced in comparison to the conventional needle oils allows one to expect a clearly improved energy efficiency as well as a lower noise level and extended holding times during operation. By the exchange of mineral oil or a basic oil corresponding to the latter by water, a greater focus is placed on durability with the lubricant of this invention. 15 Example 2 Distilled water 68.0% by weight Water-soluble polymer, polyglycol 20000 S, Clariant Co. 22.0% by weight Alcohol polyalkylene glycol ether, Marlowet 5056, Sasol Co. 5.0% by weight 20 Boric acid ester and alkanolamines, Hostacor Bl, Clariant Co. 2.0% by weight Sulfurized fatty acid, LUBIO EP 1, Schafer Additive Systems GmbH 3.0% by weight Example 3 25 Distilled water 68.0% by weight Water-soluble polymer, polyglycol 8000 S, Clariant Co. 22.0% by weight Alcohol polyalkylene glycol ether, Marlowet 5056, WO 2011/131331 PCT/EP2011/001961 6 Sasol Co. 5.0% by weight Tolyl triazole, Rheinchemie Co. 2.0% by weight Sulfurized fatty acid, V 345, Schafer Additive Systems GmbH 3.0% by weight 5 In Table 2, the properties of the formulations of Example 2 and 3 are listed. Table 2 Example 2 Example 3 Appearance, Colorless Clear, Hazen < 50 Colorless Clear, Hazen < 50 Hazen Color Unit Corrosion Protection on Very Good Very Good Knitting Needles, KLM Test Scourability at 65'C with Very Good Very Good Washing Agent DIN EN ISO 105-AO1 Scourability at 30 0 C Very Good Very Good without Washing Agent DIN EN ISO 105-AO1 Kin. Viscosity at 40 0 C 46 cst 22 cst Protection Against Wear Very Good Very Good and Tear (SRV) DIN 51834-1; DIN 51834-2 Friction Coefficient (SRV) 0.07 0.06 Also here, the comparison with the comparison example shows the excellent properties of the use according to the invention of a water-based lubricant according to 10 Examples 2 and 3. Example 4 Distilled water 60.0% by weight Water-soluble dicarboxylic acid ethoxylate 35.0% by weight Sulfurized fatty acid 3.0% by weight 15 Boric acid ester and alkanolamines 2.0% by weight Example 5 Distilled water 60.0% by weight Water-soluble dicarboxylic acid ethoxylate 17.0% by weight Water-soluble polyethylene glycol 18.0% by weight WO 2011/131331 PCT/EP201 1/001961 Sulfurized fatty acid 3.0% by weight Boric acid ester and alkanolamines 2.0% by weight In Table 3, the properties of the formulations of Examples 5 and 6 are listed. Table 3 Example 5 Example 6 Appearance, Colorless Clear, Hazen < 50 Colorless Clear, Hazen < 50 Hazen Color Unit Corrosion Protection on Very Good Very Good Knitting Needles, KLM Test Scourability at 65 0 C with Very Good Very Good Washing Agent DIN EN ISO 105-AO_ Scourability at 30 0 C Very Good Very Good without . Washing Agent DIN EN ISO 105-AO1 Kin. Viscosity at 40*C 22 cst 22 cst Protection Against Wear Very Good Very Good and Tear (SRV) DIN 51834-1; DIN 51834-2 Friction Coefficient (SRV) 0.11 0.10 5 Advantageously, the water that is used can be used both in the distilled/ demineralized form and as tap water, which simplifies a possible application in the form of a concentrate. To achieve the required operating viscosity of ISO VG 15 - ISO VG 100, it may be 10 necessary to adjust the aqueous lubricant to a lower viscosity. By evaporating a portion of the water at the friction site, the target viscosity is then achieved. The emulsifiers that are optionally contained in the lubricant comprise all non-ionic, anionic and cationic systems from the cleaning agent industry and the metal-working industry. 15 Examples of the nonionic emulsifiers that are used are alkylene oxide polymers, such as alcohol ethoxylates that consist of, e.g., ethylene oxide and/or propylene oxide with alkylene oxide units of 5 - 50 and linear or branched alkyl radicals with a chain length of CIa to C 20

.

WO 2011/131331 PCT/EP2011/001961 8 Examples of anionic emulsifiers are sulfonates, carboxylic acid and dicarboxylic acid derivatives with a chain length of 6 to 16 carbon atoms, as well as phosphate esters. Examples of cationic emulsifiers are quaternary ammonium compounds. Water-soluble polymers comprise polyalkylene glycols, whereby polyethylene glycols 5 with molar masses of 1,000 to 35,000 are preferred. Moreover, water-soluble esters, such as, for example, polyacrylates or polymethacrylates, can be used, as well as polyvinyl pyrrolidones or polyacrylamide, cellulose or sugar derivatives, in particular carboxymethyl cellulose, polyanionic cellulose, hydroxycellulose, and hydroxyethyl cellulose. The desired viscosities can be set by different molecular weights of the polymers. 10 Typical usable corrosion- and wear-reducing additives originate from the (cool)lubricant industry and comprise phosphorus- and/or sulfur-containing water-soluble compounds as well as boron compounds, such as boric acid derivatives, or nitrogen compounds, such as, e.g., triazole derivatives or VCIs (volatile corrosion inhibitors, e.g., secondary amines). 15 To avoid bacterial growth in the aqueous solution accompanied by sludge formation, bactericides can be added, e.g., benzoic acid. To improve the low-temperature behavior, anti icing agents, such as low-molecular glycols, in particular ethylene glycol, propylene glycol, trimethylene glycol, glycerol, salts or ionic liquids, can be used. The advantages of the lubricant according to the invention can be listed as follows: 20 They can be scoured, i.e. washed out with tap water at room temperature without washing agents, thus energy is saved in the washing process, Water pollution is significantly reduced by the elimination of mineral oil and washing agent; a clarifying step can be eliminated.

Claims

1. Use of a water-based lubricant that contains 5 to 50% by weight of water-soluble polymer and/or 5 5 to 50% by weight of emulsifier add water up to 100% by weight of-watef as needle oil and/or sinker oil in textile knitting machines, in particular in circular and flat knitting machines.

2. Use of a water-based lubricant according to Claim 1, wherein the lubricant in 10 addition contains 0 to 5% by weight, in particular 2 to 5% by weight, of a corrosion-reducing agent, 0 to 5% by weight, in particular 0.2 to 5% by weight, of a wear-reducing agent, 15 0 to 1% by weight, in particular 0.0 1 to 0.75% by weight, of biocide, 0 to 50% by weight, in particular 2 to 25% by weight, of an anti-icing agent.

3. Use of a water-based lubricant according to Claim I or 2, whereby the water soluble polymer that is contained in the lubricant is selected from the group that consists of polyalkylene glycols, in particular polyethylene glycol with molar masses of 1,000 to 35,000, 20 water-soluble esters, polyacrylates, polymethacrylates, polyvinyl pyrrolidones, polyacrylamides, carboxymethyl cellulose, polyanionic cellulose, hydroxy cellulose, and hydroxyethyl cellulose.

4. Use of a water-based lubricant according to Claim I or 2, whereby the emulsifier that is contained in the lubricant is selected from the group that consists of nonionic, anionic, 25 and cationic emulsifiers, in particular alkylene oxide polymers, sulfonates, carboxylic acid and dicarboxylic acid derivatives with a chain length of 6 to 16 carbon atoms, phosphate esters, and quaternary ammonium compounds.

5. Use of a water-based lubricant according to Claim I or 2, whereby the corrosion and wear-reducing agent that is contained in the lubricant is selected from the group that 30 consists of water-soluble phosphorus and/or sulfur compounds, nitrogen compounds, the biocide is benzoic acid, and the anti-icing agent is selected from the group that consists of WO 2011/131331 PCT/EP2011/001961 10 low-molecular glycols, in particular ethylene glycol, propylene glycol, trimethylene glycol, glycerol, salts or ionic liquids.

6. Use of the lubricant according to one of Claims 1 to 5 in the form of a concentrate.