AU2008277656B2 - Method and apparatus for recovering and fractionating a mixed hydrocarbon feed stream - Google Patents
Method and apparatus for recovering and fractionating a mixed hydrocarbon feed stream Download PDFInfo
- Publication number
- AU2008277656B2 AU2008277656B2 AU2008277656A AU2008277656A AU2008277656B2 AU 2008277656 B2 AU2008277656 B2 AU 2008277656B2 AU 2008277656 A AU2008277656 A AU 2008277656A AU 2008277656 A AU2008277656 A AU 2008277656A AU 2008277656 B2 AU2008277656 B2 AU 2008277656B2
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- stream
- feed stream
- gas
- overhead
- gaseous
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- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 110
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 109
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 87
- 238000000034 method Methods 0.000 title claims abstract description 55
- 239000007788 liquid Substances 0.000 claims abstract description 108
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 98
- 239000007789 gas Substances 0.000 claims description 79
- 238000001816 cooling Methods 0.000 claims description 47
- 238000004821 distillation Methods 0.000 claims description 38
- 239000003345 natural gas Substances 0.000 claims description 25
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 16
- 239000003507 refrigerant Substances 0.000 claims description 15
- 238000005057 refrigeration Methods 0.000 claims description 14
- 230000010354 integration Effects 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 8
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 24
- 241000196324 Embryophyta Species 0.000 description 16
- 239000003949 liquefied natural gas Substances 0.000 description 15
- 239000000047 product Substances 0.000 description 12
- 239000001294 propane Substances 0.000 description 12
- 238000000926 separation method Methods 0.000 description 9
- 235000013844 butane Nutrition 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 7
- 238000005194 fractionation Methods 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- 238000000605 extraction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 description 2
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 244000256297 Euphorbia tirucalli Species 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/09—Purification; Separation; Use of additives by fractional condensation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J1/0057—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream after expansion of the liquid refrigerant stream with extraction of work
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
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- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
- F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
- F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
- F25J1/0235—Heat exchange integration
- F25J1/0237—Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
- F25J1/0239—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
- F25J1/0241—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling wherein the overhead cooling comprises providing reflux for a fractionation step
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- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0209—Natural gas or substitute natural gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/72—Refluxing the column with at least a part of the totally condensed overhead gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/62—Ethane or ethylene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/64—Propane or propylene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/66—Butane or mixed butanes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/02—Internal refrigeration with liquid vaporising loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/12—External refrigeration with liquid vaporising loop
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- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
A condensed mixed hydrocarbon feed stream (10), recovered from an initial feed stream (8), is fractionated into one ore more fractionated streams. In this process, the condensed mixed hydrocarbon feed stream (10) is separated into at least a first part-feed stream (20) and a second part-feed stream (30). The first part- feed stream (20) is passed into a first gas/liquid separator (14), to provide at least a first fractionated stream in the form of a first gaseous overhead stream (40). A first bottom liquid stream (50) provided by the first gas/liquid separator (14) is passed into a second gas/liquid separator (22) to provide at least a second fractionated stream in the form of a second gaseous overhead stream (70), which is cooled by heat exchange (26) against the second part-feed stream (30).
Description
WO 2009/010558 PCT/EP2008/059383 METHOD AND APPARATUS FOR RECOVERING AND FRACTIONATING A MIXED HYDROCARBON FEED STREAM The present invention relates to a method and apparatus for recovering a mixed hydrocarbon stream from an initial feed stream, such as a natural gas stream, and fractionating the mixed hydrocarbon feed stream into one 5 or more fractionated streams. Natural gas is a useful fuel source, as well as a source of various hydrocarbon compounds. It may be produced for distribution in a pipeline grid at or near the source. Sometimes the natural gas is first liquefied 10 in a liquefied natural gas (LNG) plant at or near the source of a natural gas stream for a number of reasons. As an example, natural gas can be stored and transported over long distances more readily as a liquid than in gaseous form because it occupies a small volume and does 15 not need to be stored at high pressure. Usually, natural gas, comprising predominantly methane, enters an LNG plant at elevated pressures and is pre-treated to produce a purified feed stream suitable for its intended purpose. In case of subsequent 20 liquefaction, the purified feed stream should be suitable for liquefaction at cryogenic temperatures. The purified gas is processed through a plurality of cooling stages using heat exchangers to progressively reduce its temperature until liquefaction is achieved. The liquid 25 natural gas is then further cooled and expanded to final atmospheric pressure suitable for storage and transportation.
WO 2009/010558 PCT/EP2008/059383 -2 In addition to methane, natural gas usually includes some heavier hydrocarbons and impurities, including but not limited to carbon dioxide, sulphur, hydrogen sulphide and other sulphur compounds, nitrogen, helium, water and 5 other non-hydrocarbon acid gases, ethane, propane, butanes, C 5 + hydrocarbons and aromatic hydrocarbons. These and any other common or known heavier hydrocarbons and impurities either prevent or hinder the usual known methods of liquefying the methane, especially the most 10 efficient methods of liquefying methane. Most if not all known or proposed methods of liquefying hydrocarbons, especially liquefying natural gas, are based on reducing as far as necessary the levels of at least most of the heavier hydrocarbons and impurities prior to the 15 liquefying process. Hydrocarbons heavier than methane and usually ethane are typically typically removed from the initial feed stream by partly condensing the initial feed stream thereby forming a condensed mixed hydrocarbon feed stream 20 that is subsequently separated from the initial feed stream. In case of the feed stream being formed of natural gas, the condensed mixed hydrocarbon feed stream is recovered as so-called natural gas liquids (NGL). The mixed hydrocarbon feed stream containing the NGLs 25 is often fractionated to yield valuable hydrocarbon products, either as product steams per se or for use in a process. For example, if the process is liquefaction, the hydrocarbon products may be used as a component of a refrigerant. 30 Fractionation typically involves separating one or more C 2 + hydrocarbon streams from a mixed hydrocarbon stream, in particular as or as part of a multi-column WO 2009/010558 PCT/EP2008/059383 -3 natural gas liquids (NGL) recovery system and arrangement. The use of two or more gas/liquid separators in series is commonly used in NGL recovery known to those 5 skilled in the art. In one example, an NGL extraction unit provides a single heavier hydrocarbon rich stream, which is subsequently used either per se, or is further divided into particular heavier hydrocarbon rich streams in a separate location or unit. The fractionation of a 10 heavier hydrocarbon rich stream can be carried out by one or more further gas/liquid separators known in the art, such as a fractionator. A fractionator using one or more columns could provide individual streams of certain heavier 15 hydrocarbons. For example, with multiple columns, each column could be designed to provide an individual hydrocarbon stream, such as an ethane-rich stream, a propane-rich stream, a butane-rich stream, and a C5-+ rich stream, the latter sometimes also termed a 'light 20 condensate stream'. Propane, butane, C 5 + hydrocarbons (and optionally ethane) are sometimes collectively termed "natural gas liquids" (NGL), and have known uses. An example of a fractionation tower as a conventional distillation column for NGL extraction is shown in US 25 2004/0079107 Al. In another example, an NGL extraction unit can include a fractionator, which integrally provides individual streams of certain heavier hydrocarbons such as those listed hereinbefore. 30 NGL recovery thus generally involves cooling, condensation and fractionation steps that require significant amounts of refrigeration and other power consumption. It is desirable to recover NGLs from a 4 natural gas stream with the most efficient or minimal refrigeration power consumption. US Patent 7,051,553 describes a typical gas separation process, in which a feed gas stream is cooled and liquids condensing from the cooled gas are then expanded and fractionated in a distillation column to separate residual components from desired heavier 5 components. US Pat. 7,051,553 also describes a two-column NGL recovery plant having an absorber and a distillation column, with the absorber receiving a second reflux stream comprising the cooled overhead gas of the distillation column. Cooling of the overhead gas from the distillation column is provided by a separate cooler, requiring separate power consumption. 10 US Patent 6,116,050 discloses methods for separating and recovering propane, propylene, and the C 3 + hydrocarbons from a feed gas, to produce pipeline gas and a liquid product. The methods employ sequentially configured first and second distillation columns, and a self-refrigeration system which is said to improve the separation efficiency in the first column. The cooled feed gas is separated in a feed separator, and is both the vapours and the liquids from the feed separator are fed into the first column. Part of the liquids conducted directly through a line into the first column, while the remaining portion is heated against a vapour overhead stream from the second column prior to introduction into the first column via the same line. It is the object of the present invention to substantially overcome or at least 20 ameliorate one or more of the above disadvantages or to provide a useful alternative.
5 According to a first aspect of the present invention there is disclosed herein a method of providing a liquefied hydrocarbon stream, and recovering a mixed hydrocarbon feed stream from an initial feed stream, and fractionating the mixed hydrocarbon feed stream into one or more fractionated streams, the method at least 5 comprising the step of: (a) providing an initial feed stream; (b) partly condensing the initial feed stream, thereby forming a partly condensed initial feed stream; (c) separating the partly condensed initial feed stream into an initial gaseous 10 overhead stream and a condensed mixed hydrocarbon feed stream; (ii) liquefying at least part of the initial gaseous overhead stream to provide a liquefied hydrocarbon stream; (d) dividing the condensed mixed hydrocarbon feed stream into at least a first part-feed stream and a second part-feed stream; 15 (e) passing the first part-feed stream into a first gas/liquid separator, via a first inlet into the first gas/liquid separator, to provide at least a first fractionated stream in the form of a first gaseous overhead stream and a first bottom liquid stream; (f) passing the first bottom liquid stream into a second gas/liquid separator to provide at least a second fractionated stream in the form of a second gaseous overhead 20 stream and a second bottom liquid stream; and (g) cooling the second overhead gaseous stream by heat exchange against the second part-feed stream, resulting in a warmer second part-feed stream, without integration with a refrigeration circuit associated with a liquefaction process; (h) passing the warmer second part-feed stream into the first gas/liquid separator 25 at a level gravitationally below the first inlet. According to a second aspect of the present invention there is disclosed herein an apparatus for providing a liquefied hydrocarbon stream, and recovering a mixed hydrocarbon feed stream from an initial feed stream and fractioning the mixed hydrocarbon feed stream into one or more fractioned streams, the apparatus at least 30 comprising: a pre-cooling heat exchanger arranged to cool the initial feed stream to provide a partly condensed initial feed stream; an initial gas/liquid separator arranged to separate the partly condensed initial feed stream into an initial gaseous overhead stream and a condensed mixed hydrocarbon 35 stream; 6 one or more heat exchangers, comprising a main cryogenic heat exchanger, wherein the initial gaseous overhead stream is allowed to exchange heat against one or more refrigerants being cycled in one or more refrigerant circuits to liquefy at least part of the initial gaseous overhead stream; 5 a stream splitter to divide the condensed mixed hydrocarbon feed stream into at least a first part-feed stream and a second part-feed stream; a first gas/liquid separator arranged to receive the first part-feed stream via first inlet into the first gas/liquid separator, and to provide at least a first fractionated stream in the form of a first overhead gaseous stream and a first bottom liquid stream; 10 a second gas/liquid separator arranged to receive the first bottom liquid stream, and to provide at least a second fractioned stream in the form of a second overhead gaseous stream and a second bottom liquid stream; a heat exchanger arranged to receive the second part-feed stream and the second overhead gaseous stream, and to provide a cooled second overhead gaseous stream and a 15 warmer second part-feed stream, without integration with a refrigeration circuit associated with a liquefaction process; and a second inlet into the first gas/liquid separator arranged to allow entry of the warmer second part-feed stream into the first gas/liquid separator, the second inlet being at a level gravitationally below the first inlet. 20 Embodiments and examples of the present invention will now be described by way of example and with WO 2009/010558 PCT/EP2008/059383 -7 reference to the accompanying non-limited drawings in which; Figure 1 is a diagrammatic scheme for a method of C 2 + separation; and 5 Figure 2 shows the integration of the method shown in Figure 1 within a diagrammatic LNG plant. For the purpose of this description, a single reference number will be assigned to a line as well as a stream carried in that line. 10 In the embodiments disclosed herein, cooling of the second overhead gaseous stream from the second gas/liquid separator is provided by use of a portion of the cold energy in the condensed mixed hydrocarbon feed stream, rather than requiring any separate refrigeration or 15 cooler involving separate power consumption, or rather than integration with a refrigeration system or circuit associated with a liquefaction process. Thus, cold energy from another source, such as (pre-) cooling of a hydrocarbon stream such as natural gas by a 20 separate refrigerant, refrigeration system or circuit, need not be diverted to be involved in recovery and fractionation of the mixed hydrocarbon stream, such as in NGL recovery, thereby increasing the efficiency of other processes or sections of a liquefaction plant such as an 25 LNG plant. The cooling of the second overhead gaseous stream provides a warmer second part-feed stream, which can still be passed into the first gas/liquid separator or used otherwise. The introduction of a fraction of the 30 mixed hydrocarbon feed stream into the first gas/liquid separator at a warmer temperature, (following use of some of its cold energy to cool the second overhead gaseous stream from the second gas/liquid separator), reduces the WO 2009/010558 PCT/EP2008/059383 -8 energy input required from a heat source such as a reboiler to operate the first gas/liquid separator. It has further been found that an improvement of the separation efficiency and a further decrease of any 5 heating duty from an external source can be achieved by passing the warmer second part-feed stream into the first gas/liquid separator at a height along the separator below where the first part-feed stream is passed into the first gas/liquid separator. 10 Usually the initial feed stream is comprised substantially of methane. Preferably the feed stream comprises at least 60 mol% methane, more preferably at least 80 mol% methane. The term "mixed hydrocarbon feed stream" as used 15 herein relates to a feed stream comprising methane and one or more hydrocarbons selected from the group comprising: ethane, propane, butanes, pentanes, and C 6 + hydrocarbons. The mixed hydrocarbon feed stream may be provided 20 from any suitable source. Preferably, the mixed hydrocarbon feed stream is provided from an initial feed stream. The initial feed stream may be any suitable hydrocarbon stream such as, but not limited to, a hydrocarbon-containing gas stream to be cooled. One 25 example is a natural gas stream obtained from a natural gas or petroleum reservoir. As an alternative the initial feed stream may also be obtained from another source, such as a refinery and/or including a synthetic source such as a Fischer-Tropsch process. 30 The term "C 2 +" as used herein relates to one or more components selected from the group comprising: ethane, propane, butanes, pentanes, and C 6 + hydrocarbons.
9 Similarly, the term "C 3 *" as used herein relates to one or more components selected from the group comprising: propane, butanes, pentanes, and C6+ hydrocarbons. The terms "C 4 *", etc. are similarly defined starting with "butanes", etc. Each gas/liquid separator of preferred embodiments of the present invention may 5 involve one or more columns, and one or each of such columns could provide individual liquid streams of certain heavier hydrocarbons such as ethane, propane, etc. Any fractionated, or individual stream of C 2 +, C 3 *, C 4 *, etc., may still comprise a minor (<10 mol%) amount of methane; each such stream is preferably >80 mol%, more preferably >95 mol%, of its one or more components as defined above. 10 The division of a stream such as a feed stream into two or more part streams may be carried out using any suitable stream splitter or divider, which may be a distinct unit, or a simpler division of a line such as a T-piece. Although the method according to preferred embodiments of the present invention is applicable to various initial hydrocarbon-containing feed streams, it is is particularly suitable for natural gas streams to be liquefied. As the person skilled readily understands how to liquefy a hydrocarbon stream, this will herein only be discussed at a basic level of detail. Figure 1 shows a simplified and general scheme I of a method for separating one or more C 2 ' hydrocarbon streams from a mixed hydrocarbon feed stream recovered from 20 an initial feed stream, such as natural gas. The scheme of WO 2009/010558 PCT/EP2008/059383 - 10 Figure 1 can be part of a liquefied natural gas plant 2 shown in Figure 2. Figure 1 illustrates a method and apparatus for separating one or more C 2 + hydrocarbon streams from an 5 initial feed stream such as natural gas. The apparatus comprises: means to separate a mixed hydrocarbon feed stream 10 from the initial feed stream 8; a stream splitter 36 to divide the mixed hydrocarbon 10 feed stream 10 into at least a first part-feed stream 20 and a second part-feed stream 30; a first gas/liquid separator 14 to receive the first part-feed stream 20, and to provide at least a first overhead gaseous stream 40 and a first bottom liquid 15 stream 50; a second gas/liquid separator 22 to receive the first bottom liquid stream 50, and to provide at least a second overhead gaseous stream 70 and a second bottom liquid stream 80; and 20 a heat exchanger 26 to receive the second part-feed stream 30 and the second overhead gaseous stream 70, and to provide a cooled second overhead gaseous stream 70a and a warmer second part-feed stream 30b. The method as illustrated in Figure 1 at least 25 comprises the steps of: providing a mixed hydrocarbon feed stream 10 from an initial feed stream 8; dividing the mixed hydrocarbon feed stream 10 into at least a first part-feed stream 20 and a second part-feed 30 stream 30; passing the first part-feed stream into a first gas/liquid separator 14 to provide at least a first WO 2009/010558 PCT/EP2008/059383 - 11 gaseous overhead stream 40 and a first bottom liquid stream 50; passing the first bottom liquid stream 50 into a second gas/liquid separator 22 to provide at least a 5 second gaseous overhead stream 70 and a second bottom liquid stream 80; and cooling the second overhead gaseous stream 70 by heat exchange against the second part-feed stream 30. The first and second gas/liquid separators may be any 10 form of separator such as a distillation column adapted to provide at least one gaseous stream, usually being enriched in one or more lighter hydrocarbons, and at least one liquid stream, usually being enriched in one or more heavier hydrocarbons. An example of such a 15 separator is a "de-methanizer" designed to provide a methane-enriched overhead stream, and one or more C2+ enriched liquid steams at or near the bottom. Similarly, there are "de-ethanizers" and "de-propanizers", etc., known in the art. 20 Thus, where the first gas/liquid separator is a de methanizer, the first bottom liquid stream will be a C2+ hydrocarbon stream. Where the second gas/liquid separator is a de-ethanizer, the second bottom liquid stream will be a C 3 + hydrocarbon stream, and the second 25 overhead gaseous stream is preferably >60 mol% ethane, more preferably >85 and even more preferably >90 mol% ethane. In more detail, Figure 1 shows an initial feed stream 8 containing natural gas, which is cooled by a pre 30 cooling heat exchanger 32 to provide a cooled and partly condensed initial stream 8a. The pre-cooling heat exchanger 32 may comprise one or more heat exchangers either in parallel, series or both, in a manner known in 12 the art. Cooling is provided by a first refrigerant stream 100, which is warmed in the pre cooling heat exchanger 32 to create a warmed refrigerant stream I 00a. This cooling of the initial feed stream 8 may be part of a liquefaction process, such as a pre-cooling stage involving a propane refrigerant circuit as described hereinafter 5 in relation to Figure 2, or a separate process. Cooling of the initial feed stream 8 may involve reducing the temperature of the initial feed stream 8 to below -0*C, for example, in the range -10*C to -40*C. The cooled initial stream 8a is passed into an initial gas/liquid separator such as a scrub column 34, operating at an above ambient pressure in the manner known in the art. 10 The scrub column 34 provides a condensed mixed hydrocarbon feed stream 10, and an initial gaseous overhead steam 110. The initial gaseous overhead stream 110 usually comprises greater than 80 mol% methane. It is typically a methane-enriched stream compared to the cooled initial stream 8a. The mixed hydrocarbon feed stream 10 comprises methane and one or more C2+ Is hydrocarbons. Typically, the proportion of methane in the mixed hydrocarbon feed stream is 30-50 mol%, with a significant fraction of ethane and propane, such as 5-10 mol% each. Commonly, it is desired to recover any methane in a mixed hydrocarbon stream (for use as a fuel or so that it can be liquefied in the LNG plant 2 and provided as 20 additional LNG), and to provide one or more of a C 2 stream, a C 2 * stream, a C 3 + stream, a
C
4 + stream, etc., or a combination of same. The method of preferred embodiments of the present invention is applicable to separation of any WO 2009/010558 PCT/EP2008/059383 - 13 one or more of the C 2 + streams, either as pure streams or as combined component streams. In Figure 1, the mixed hydrocarbon feed stream 10 is divided by a steam splitter 36 into a first part-feed 5 stream 20 and a second part-feed stream 30. The division of the mixed hydrocarbon feed stream 10 could be based on any ratio of mass and/or volume and/or flow rate. The ratio may be based on the size or capacity of the subsequent parts, systems or units, or the size, capacity 10 or cold energy for the second part-feed stream 30 and duty of the heat exchanger 26 (discussed hereinafter). Generally, the first part-feed stream 20 will be between 20 to 70 mass%, preferably 30 to 50 mass% and more preferably 40 vol%, of the mixed hydrocarbon feed stream 15 10. The first part-feed stream 20 passes through a valve 12 to provide a reduced pressure first part-feed stream 20a, which then enters a first gas/liquid separator such as a first distillation column 14 through a first inlet 20 at or near the top of the first distillation column 14. The reduced pressure first part-feed stream 20a is typically a mixed phase stream, and the first distillation column 14 is adapted to separate the gaseous and vapour phases, so as to provide a first overhead 25 gaseous stream 40 and a first bottom liquid stream 50. The nature of the streams provided by the first distillation column 14 can be varied according to the size and type of distillation column, and its operating conditions and parameters, in a manner known in the art. 30 For the arrangement shown in Figure 1, it is desired for the first overhead gaseous stream 40 to be methane enriched, preferably to be >90 mol% methane. This methane-enriched stream 40 could be added into other WO 2009/010558 PCT/EP2008/059383 - 14 parts of a liquefaction plant to provide for example further LNG, or it could be used as fuel. The first distillation column 14 also includes a first reboiler 17 and a bottom return stream 60, 5 typically in the form of a reboiler vapour return stream, in a manner known in the art. The first bottom liquid stream 50 will predominantly be C 2 + hydrocarbons, such as >90 or >95 mol% of ethane and heavier hydrocarbons. The first bottom liquid stream 10 50 is cooled by one or more ambient coolers, such as a water and/or air cooler 16, followed by a passage through a valve 18 to provide a reduced pressure first bottom stream 50a, which enters through inlet 42 into a second gas/liquid separator such as a second distillation column 15 22. Again, the type, size and capacity of the second distillation column 22, as well as its operating conditions and parameters, will control the nature of the streams provided by the second distillation column 22. In the arrangement shown in Figure 1, the second 20 distillation column 22 provides a second overhead gaseous stream 70 being predominantly ethane, preferably >85 or >90 mol% ethane, and a second bottom liquid stream 80, generally being >98% propane and heavier hydrocarbons. The second distillation column 22 also includes a 25 reboiler 27 and a reboiler vapour return stream 90. The cooling of the second overhead gaseous stream 70 preferably results in condensation of at least part, preferably all, of the second overhead gaseous stream. Particularly a condensed fraction may be used as a reflux 30 stream 70b for the second gas/liquid separator 22. In one embodiment of the present invention, the method thus further provides the steps of: WO 2009/010558 PCT/EP2008/059383 - 15 (i) dividing a cooled second gaseous overhead stream 70a provided by step (g) into two or more fractions (70b,70c) ; and (j) passing at least one of said fractions (70b) back 5 into the second gas/liquid separator 22, preferably as a reflux stream. Where the second gas/liquid separator is a distillation column, for instance a de-ethanizer, the fraction of the second overhead gaseous stream in step 10 (i) can be used to provide reflux to the distillation column. Conventionally, the second overhead gaseous stream 70 is cooled by a separate or external cooler as shown in US 7,051,553 B2, or by the pre-cooling heat exchanger 32. 15 Using the former requires the involvement of a separate energy source and use, whilst using the latter takes away some of the cooling power of the pre-cooling heat exchanger 32 from cooling of the initial feed stream 8. Both of these situations reduce the efficiency of an LNG 20 plant. Both also create complicated integration between the fractionation arrangement and the remainder of a liquefaction plant. The second part-feed stream 30 (from the mixed hydrocarbon feed stream 10), after passing through a 25 valve 24 to provide a reduced pressure second part stream 30a, preferably has a temperature that is low enough, such as between 0 0 C and -50 0 C, to provide cooling in a heat exchanger 26 to the second overhead gaseous stream 70. The heat exchanger 26 may be one or more heat 30 exchangers in parallel, series or both. In embodiments, heat exchanger 26 may be referred to as a reflux heat exchanger.
WO 2009/010558 PCT/EP2008/059383 - 16 The cold energy of the reduced pressure second part feed stream 30a withdraws warmth from the second overhead gaseous stream 70 to at least partially condense, preferably fully condense, the second overhead gaseous 5 stream 70 in the heat exchanger 26, and provide an at least partly condensed second stream 70a. Thus, cooling of the second overhead gas stream 70 is achieved without the need for a separate source of cooling, making the arrangement for NGL recovery shown in Figure 1 10 independent of any refrigeration system. The at least partly condensed second stream 70a can be divided by a stream splitter 44 into a reflux stream 70b, and a product stream 70c. The product stream 70c could be provided as a separate product stream for use 15 outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art. The heat exchange of the second overhead gaseous stream 70 and the second part-feed stream 30a also 20 provides a warmer second part-feed stream 30b, which can be passed into the first distillation column 14, preferably between the inlet 38 for the first part-feed stream 20a and the bottom return stream 60, e.g. via an inlet 39 into the first distillation column 14, located 25 gravitationally lower than inlet 38. The bottom return stream 60 may be fed back into the first distillation column 14 via return stream inlet 41. The arrangement shown in Figure 1 is for the separation of C 1 and C 2 streams 40, 70 from a mixed 30 hydrocarbon feed stream 10, resulting in a remaining C 3 + stream 80. However, this arrangement is equally applicable to provide, for example, a C 1 stream and a mixed C 2
/
3 stream, with the remainder being a C 4 + stream, 17 or to provide separate C 1 , C 2 and C 3 streams, with a remaining C 4 + stream. All such configurations and arrangements are known to the person skilled in the art in relation to NGL recovery. Thus, the method according to preferred embodiments of the present invention is 5 equally applicable to use with two other gas/liquid separators using a mixed hydrocarbon feed stream and adapted to provide different product streams. Equally, the method of preferred embodiments of the present invention is applicable to an arrangement involving more than two gas/liquid separators, where more than three product streams such as separate C 3 , C 4 and C 5 streams are provided. 10 Additionally, the second part-feed streams 30 could be divided into two or more fractions for cooling other overhead gaseous streams (such as from a de-propanizer, etc.), thus further reducing or eliminating the requirement for separate coolers or heat exchangers for each overhead stream. In the embodiment as shown in Figure 1, the mixed hydrocarbon feed stream 10 is is provided from the initial feed stream 8 by separating the initial feed stream 8 into the mixed hydrocarbon feed stream 10 and the initial gaseous overhead stream 110. The latter may in practical situations often be a methane-enriched stream. The initial gaseous overhead stream 110 may be fed into a gas grid to distribute the methane-enriched stream as gas to market. Before feeding into a grid, the initial 20 gaseous overhead stream 110 may, however, be subjected to other processing steps such as further treating to change the composition and/or cooling, preferably liquefying, to provide a cooled hydrocarbon stream, preferably LNG. Thus, preferred embodiments of the present invention further provides a method of cooling an initial feed stream such as a hydrocarbon WO 2009/010558 PCT/EP2008/059383 - 18 stream such as natural gas comprising at least the steps of: (i) passing the initial feed stream through an initial separator to provide an, methane-enriched, 5 initial gaseous overhead stream and a condensed mixed hydrocarbon feed stream; (ii) cooling, preferably liquefying, the initial gaseous overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream; and 10 (iii) separating one or more C 2 + hydrocarbons from the condensed mixed hydrocarbon stream by a method as herein defined. The initial gaseous overhead stream is preferably cooled without passing it through the first gas/liquid 15 separator. It may be cooled by passing the initial gaseous overhead stream to one or more heat exchangers where it is allowed to exchange heat against one or more refrigerants being cycled in one or more refrigerant cycles. 20 Figure 2 shows a LNG plant 2 incorporating the C 2 + separation arrangement 1 shown in Figure 1. Figure 2 shows an initial feed stream 8 being cooled by three pre-cooling heat exchangers 46 (similar or equivalent to the pre-cooling heat exchanger 32 in Figure 25 1) to provide a cooled initial stream 8a, which is divided by a divider 29 into a first stream 9 which passes directly into a scrub column 34, and a second stream 9a which passes into a main cryogenic heat exchanger 23 to provide a cooler initial feed stream 9b, 30 which also passes into the scrub column 34 at a higher level than the first stream 9. The scrub column 34 provides a condensed mixed hydrocarbon feed stream 10. This mixed stream 10 is WO 2009/010558 PCT/EP2008/059383 - 19 divided by a stream splitter 36 into a first part-feed stream 20 and second part-feed stream 30, whose passage is as hereinbefore described with relation to Figure 1. In this way, the first part-feed stream 20 passes 5 through a valve to provide a reduced pressure first part feed stream 20a, which then enters a first distillation column 14. The distillation column 14 provides a first overhead gaseous stream 40 generally being methane and labelled "Cl" in Figure 2, and a first bottom liquid 10 stream 50 which passes after cooling and expansion into a second distillation column 22. The second distillation column 22 provides a second overhead gaseous stream 70 which is cooled in the heat exchanger 26 against the reduced pressure second part 15 stream 30a to provide a cooled second overhead stream in the form of an at least partly, preferably fully, condensed second stream 70a, which is divided into a reflux stream 70b and a product stream 70c, which is predominantly ethane and labelled "C2" in Figure 2. 20 The second distillation column 22 also provides a second bottom liquid stream 80 being a C 3 + stream, which, after expansion, can be passed into a further gas/liquid separator such as a third distillation column 52, optionally also being a de-propanizer. The third 25 distillation column 52 can provide a third overhead stream 140 (which after cooling can provide a "C3" product stream comprising for example >95 mol%, preferably 99 mol%, propane), and a third bottom liquid stream 130 being a C 4 + stream. The third bottom stream 30 130 can pass into a fourth gas/liquid separator being a fourth distillation column 54, which provides a fourth gaseous overhead stream 160 (which after cooling can create a "C4" product stream comprising for example >95 20 mol%, preferably 99 mol%, butanes), and a fourth bottom stream 150 which can be a
"C
5 +" stream, (sometimes also termed a "light condensate" stream). Figure 2 shows a C 2 * separation scheme involving a number of separators to provide CI, C 2 , C 3 , C 4 and C 5 streams, which can be provided as direct product streams, 5 or otherwise used in ways known to the person skilled in the art. Meanwhile, the initial gaseous overhead stream 1 10 from the scrub column 34 can pass into a main cryogenic heat exchanger 23 to provide further cooling. Commonly, the cooling provided by the pre-cooling heat exchangers 46 can be considered as a 'pre cooling stage', and the cooling provided by the main cryogenic heat exchanger 23 can be io considered as a 'main or second cooling stage'. The main cryogenic heat exchanger 23 is typically able to reduce the temperature of the initial gaseous overhead stream 110 to below -90*C or -100*C, preferably to liquefy the initial gaseous overhead stream I 10. Such cooling can be provided in a number of ways known to the person skilled in the art. One example way is use of a is refrigerant circuit 25 in a manner known in the art. The main cryogenic heat exchanger 23 provides an overhead stream 120, preferably being fully liquid. Where the initial feed stream 8 is natural gas, the overhead gaseous stream 120 will generally be LNG. In particular, preferred embodiments of the present invention can improve the efficiency of the overall LNG plant 2 by reducing the 20 complexity of integration of cooling required of at least one overhead stream with other heat exchangers (such as the pre-cooling heat exchanger 32, 46), or other heat exchanger arrangements.
WO 2009/010558 PCT/EP2008/059383 - 21 Table 1 below gives an overview of estimated compositions, phases, pressures and temperatures of some of the streams at various parts of an example process of Figure 2. In the calculations, it has been assumed that 5 the warmer second part-feed stream 30b has been fed into the first distillation column 14 at the 9 th tray of 12 trays while the first part-feed stream 20a has been fed into the first distillation column 14 at the first tray (at the top). The C 1 purity of the first gaseous overhead 10 stream 40 is calculated to be about 94 % for the given mixed hydrocarbon feed stream 10 with a first reboiler duty of first reboiler 17 of 2.6 MW. Table 2 below gives results of a similar calculation as the one for Table 1, with the exception that the 15 warmer second part-feed stream 30b has been fed into the first distillation column 14 at the first tray, the same level as the first part-feed stream 20a. Compared to Table 1, the C 1 purity of the first gaseous overhead stream 40 has decreased to about 90 % for an increase of 20 the first reboiler duty of first reboiler 17 to 2.8 MW. Hence, feeding the warmer second part-feed stream 30b into the distillation column 14 at a level below the inlet 38 for the first part-feed stream 20a improves the separation efficiency of the first distillation column 14 25 while reducing reboiler duty of the first distillation column 14.
WO 2009/010558 PCT/EP2008/059383 22 +~O MD M>DC DC u ~ ~ ~ ~ ~ ~ ~ ( (N C C C D N N N N C n N (N (N N -1 1-1 00 00 00 00 (N CD u C* * * * * * * * 1-1 1-1 1 (9 * * * * * * * * 1- 1- * 1 on oD oD Ln i o Co CD~o > (9~~~~~C aD aD aCD D OD O D a~H - Lfl 00 CD CD CD CDo o D (N 0 ( (N ( (N (N (N CD CD CD C D CD C D C (9 co - a~ (N 0 00 - - -1 - - - CD - - CD CD Cd U U) CDH CDH CDH (N o~ m I-- aD a aD CD a a r CD 04 0n *n m oD * r - r- an LH 1-: a a a4 M * an L m m m m m (N (N m ~ ~ -H~-H CD ~- 1 m- CDH aCD a a a a) u D ~ D ~ C C C 0) N) N) 0) -i (N m L (N 0) a4 I I> > > (1) (9-1N N~ (N CD CD CD CD CD (N CD CD (ND F-H 00 CoH m m I I 1 1 1 I I Y I (N) 1 v-H Ln v- I- WO 2009/010558 PCT/EP2008/059383 23 + ~ ~~ ~ MD M D DCAC L) CD 0 1 0 A C Ln ) CIA~~~~ ~ ~ ~ CA CAC d0 0 0c oC (N (N (N (N CD H CD H OD D OD 00 CO LCD ad1 11 C CDa a CD CD CD CD CD CD I-- 1-- )H CD (N ~ ~ ~ ~ ~ ~ ~ 0 (N (N[-- r ~ ~) O) O) ~ ( Qu CD COD C D CD CO (CO (DO LDOD* o') Go GoG (9~~~~~C CD CD (DO D O O D~H~H - LC C C A CD) CD CD OD CD CD CD (9 O =) N~ O0 ~) ) 0) M~ CD CD CD MO CDH CDH M O (NI (N (N (N:: (N (NQ0 (9 -1 Q0 -1 - D C Cd CA M - M- CD v-I . v-H)00 0 a4H > > > > O > (a) -1 D D~ ~ NC LC D LC D CD CD CD CD CD (N (N co (1) ( O (N O o - v-H -1 CA v-H () 1, L) Ln (o - 24 Suitable process control of embodiments of the present invention may include a level controller on the initial gas/liquid separator 34, which manipulates the flow of the first part-feed stream 20 into the first gas/liquid separator 14, for instance via manipulating the setting of valve 12. Valve 24 may be manipulated using a flow 5 controller, of which the set point is determined by a pressure controller for the second gas/liquid separator. Equivalently, its set point may be determined by a level controller on an optional vessel 21 arranged to receive and discharge the cooled second overhead stream. This is equivalent to pressure control, since the level in the vessel is determined by the duty of the condenser condensation yielding stream 70a. 1o Preferred embodiments of the present invention can avoid complicated integration of a NGL removal process with the refrigeration systems of any associated LNG plant or facility. The person skilled in the art will understand that the present invention can be carried out in many various ways without departing from the scope of the appended 15 claims. For instance, instead of natural gas, the initial feed stream may be formed of other types of gas, including refinery or petroleum plant gas.
Claims (21)
1. A method of providing a liquefied hydrocarbon stream, and recovering a mixed hydrocarbon feed stream from an initial feed stream, and fractionating the mixed 5 hydrocarbon feed stream into one or more fractionated streams, the method at least comprising the step of: (a) providing an initial feed stream; (b) partly condensing the initial feed stream, thereby forming a partly condensed initial feed stream; 10 (c) separating the partly condensed initial feed stream into an initial gaseous overhead stream and a condensed mixed hydrocarbon feed stream; (ii) liquefying at least part of the initial gaseous overhead stream to provide a liquefied hydrocarbon stream; (d) dividing the condensed mixed hydrocarbon feed stream into at least a first part is feed stream and a second part-feed stream; (e) passing the first part-feed stream into a first gas/liquid separator, via a first inlet into the first gas/liquid separator, to provide at least a first fraction stream in the form of a first gaseous overhead stream and a first bottom liquid stream; (f) passing the first bottom liquid stream into a second gas/liquid separator to provide 20 at least a second fractioned stream in the form of a second gaseous overhead stream and a second bottom liquid stream; and (g) cooling the second overhead gaseous stream by heat exchange against the second part-feed stream, resulting in a warmer second part-feed stream, without integration with a refrigeration circuit associated with a liquefaction process; 25 (h) passing the warmer second part-feed stream into the first gas/liquid separator at a level gravitationally below the first inlet.
2. A method as claimed in claim 1, wherein at least part of the initial gaseous overhead stream is liquefied without passing the at least part of the initial gaseous overhead stream through the first gas/liquid separator. 30
3. The method as claimed in claim 1 or claim 2, wherein the initial gaseous overhead stream is a methane-enriched stream.
4. A method as claimed in any one of the preceding claims, further comprising the steps of: (i) dividing the cooled second gaseous overhead stream provided by the cooling 35 of the second gaseous overhead stream in step (g) into two or more fractions; and 26 () passing at least one of said fractions back into the second gas/liquid separator.
5. A method as claimed in claim 4, wherein said cooling of the second overhead gaseous stream in step (g) results in condensation of at least part of the second overhead gaseous stream, and wherein the at least one of said fractions in step (j) is a condensed s fraction being passed back into the second gas/liquid separator as a reflux stream.
6. A method as claimed in any one of the preceding claims, wherein the second part-feed stream is reduced in pressure prior to its heat exchanging against the second overhead gaseous stream in step (g).
7. A method as claimed in any one of the preceding claims, wherein the first 1o gas/liquid separator and the second gas/liquid separator are distillation columns.
8. A method as claimed in any one of the preceding claims, wherein said passing of the warmer second part-feed stream into the first gas/liquid separator at the level gravitationally below the first inlet comprises passing the warmer second part-feed stream into the first gas/liquid separator at a height along the separator between the first inlet and 15 the bottom of the separator.
9. A method as claimed in any one of the preceding claims, further comprising a step of drawing a reboiler stream from the first gas/liquid separator, heating the reboiler stream to produce a bottom return stream, and feeding the bottom return stream back to the first gas/liquid separator, wherein said passing of the warmer second part-feed stream 20 into the first gas/liquid separator at the level gravitationally below the first inlet comprises passing the warmer second part-feed stream into the first gas/liquid separator between the first inlet and the bottom return stream.
10. A method as claimed in any one of the preceding claims, wherein the second overhead gaseous stream comprises >60 mol% ethane. 25
11. A method as claimed in any one of the preceding claims, wherein the second overhead gaseous stream comprises >90 mol% ethane.
12. A method as claimed in any one of the preceding claims, wherein the first bottom liquid stream is a C2+ hydrocarbon stream.
13. A method as claimed in any one of the preceding claims, wherein the second 30 bottom liquid stream is a C3+ hydrocarbon stream.
14. A method as claimed in any one of the preceding claims, wherein no separate refrigeration involving separate power consumption is employed for providing said cooled second overhead gaseous stream from the second overhead gaseous stream.
15. A method as claimed in any one of the preceding claims, wherein the initial 35 feed stream is a natural gas stream. 27
16. Apparatus for providing a liquefied hydrocarbon stream, and recovering a mixed hydrocarbon feed stream from an initial feed stream and fractionating the mixed hydrocarbon feed stream into one or more fractionated streams, the apparatus at least comprising: 5 a pre-cooling heat exchanger arranged to cool the initial feed stream to provide a partly condensed initial feed stream; an initial gas/liquid separator arranged to separate the partly condensed initial feed stream into an initial gaseous overhead stream and a condensed mixed hydrocarbon stream; 10 one or more heat exchangers, comprising a main cryogenic heat exchanger, wherein the initial gaseous overhead stream is allowed to exchange heat against one or more refrigerants being cycled in one or more refrigerant circuits to liquefy at least part of the initial gaseous overhead stream; a stream splitter to divide the condensed mixed hydrocarbon feed stream into at is least a first part-feed stream and a second part-feed stream; a first gas/liquid separator arranged to receive the first part-feed stream via a first inlet into the first gas/liquid separator, and to provide at least a first fractionated stream in the form of a first overhead gaseous stream and a first bottom liquid stream; a second gas/liquid separator arranged to receive the first bottom liquid stream, 20 and to provide at least a second fractionated stream in the form of a second overhead gaseous stream and a second bottom liquid stream; a heat exchanger arranged to receive the second part-feed stream and the second overhead gaseous stream, and to provide a cooled second overhead gaseous stream and a warmer second part-feed stream, without integration with a refrigeration circuit associated 25 with a liquefaction process; and a second inlet into the first gas/liquid separator arranged to allow entry of the warmer second part-feed stream into the first gas/liquid separator, the second inlet being at a level gravitationally below the first inlet.
17. The apparatus as claimed in claim 16, wherein the main cryogenic heat 30 exchanger is arranged to receive the initial gaseous overhead stream via a path that does not pass through the first gas/liquid separator, and to provide further cooling to the initial gaseous overhead stream.
18. The apparatus as claimed in claim 16 or claim 17, further comprising a pressure reduction valve in the second part feed stream between the stream splitter and 35 the heat exchanger arranged to receive the second part-feed stream and the second overhead gaseous stream. 28
19. The apparatus as claimed in any one of claims 16 to 18, wherein no separate refrigeration involving separate power consumption is employed for providing said cooled second overhead gaseous stream from the second overhead gaseous stream.
20. A method of providing a liquefied hydrocarbon stream and recovering a 5 mixed hydrocarbon feed strain from an initial feed stream, and fractioning the mixed hydrocarbon feed stream into one or more fractioned streams, the method being substantially as hereinbefore described with reference toe the accompanying drawings.
21. Apparatus for providing a liquefied hydrocarbon stream, and recovering a mixed hydrocarbon feed stream from an initial feed stream and fractioning the mixed to hydrocarbon feed stream into one or more fractioned streams, the apparatus being substantially as hereinbefore described with reference to the accompanying drawings. Dated 15 June, 2011 Shell Internationale Research Maatschappij B.V. is Patent Attorneys for the Applicant/Nominated Person SPRUSON & FERGUSON
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EP07112760.9 | 2007-07-19 | ||
PCT/EP2008/059383 WO2009010558A2 (en) | 2007-07-19 | 2008-07-17 | Method and apparatus for recovering and fractionating a mixed hydrocarbon feed stream |
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AU2008277656B2 true AU2008277656B2 (en) | 2011-11-03 |
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AU (1) | AU2008277656B2 (en) |
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US9021832B2 (en) | 2010-01-14 | 2015-05-05 | Ortloff Engineers, Ltd. | Hydrocarbon gas processing |
RU2446854C1 (en) * | 2010-11-15 | 2012-04-10 | Открытое акционерное общество "НОВАТЭК" | Method of de-ethanising of unstable gas condensate and plant to this end |
CA2847475A1 (en) * | 2011-09-01 | 2013-03-07 | Gtlpetrol Llc | Integration of ft system and syn-gas generation |
US9683776B2 (en) * | 2012-02-16 | 2017-06-20 | Kellogg Brown & Root Llc | Systems and methods for separating hydrocarbons using one or more dividing wall columns |
RU2493898C1 (en) * | 2012-06-18 | 2013-09-27 | Открытое акционерное общество "НОВАТЭК" | Method of field processing of gas condensate deposit products using unstable gas condensate as coolant and plant to this end |
US9637696B2 (en) * | 2013-03-15 | 2017-05-02 | General Electric Company | Solids supply system and method for supplying solids |
EP3115721A1 (en) | 2015-07-10 | 2017-01-11 | Shell Internationale Research Maatschappij B.V. | Method and system for cooling and separating a hydrocarbon stream |
US10551119B2 (en) | 2016-08-26 | 2020-02-04 | Ortloff Engineers, Ltd. | Hydrocarbon gas processing |
US10533794B2 (en) | 2016-08-26 | 2020-01-14 | Ortloff Engineers, Ltd. | Hydrocarbon gas processing |
US10551118B2 (en) | 2016-08-26 | 2020-02-04 | Ortloff Engineers, Ltd. | Hydrocarbon gas processing |
RU2640969C1 (en) * | 2017-03-16 | 2018-01-12 | Публичное акционерное общество "Газпром" | Method for extraction of liquefied hydrocarbon gases from natural gas of main gas pipelines and plant for its implementation |
US11543180B2 (en) | 2017-06-01 | 2023-01-03 | Uop Llc | Hydrocarbon gas processing |
US11428465B2 (en) | 2017-06-01 | 2022-08-30 | Uop Llc | Hydrocarbon gas processing |
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- 2008-07-17 EA EA201000224A patent/EA016149B1/en not_active IP Right Cessation
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- 2008-07-17 GB GB0922540A patent/GB2463202B/en not_active Expired - Fee Related
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US20110036120A1 (en) | 2011-02-17 |
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WO2009010558A3 (en) | 2009-11-05 |
GB2463202A (en) | 2010-03-10 |
EA201000224A1 (en) | 2010-06-30 |
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AU2008277656A1 (en) | 2009-01-22 |
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