AU2006303413A1

AU2006303413A1 - Apparatus and method for mixing liquid colour and method for colouring plastics with liquid colour

Info

Publication number: AU2006303413A1
Application number: AU2006303413A
Authority: AU
Inventors: Simon Becht; Andreas Kluge; Maurice Weelen; Martin Welp
Original assignee: Evonik Degussa GmbH
Current assignee: Evonik Operations GmbH
Priority date: 2005-10-17
Filing date: 2006-09-08
Publication date: 2007-04-26
Anticipated expiration: 2026-09-08
Also published as: ATE470496T1; EP1943009B1; RU2008119278A; DE102005049926A1; CA2626294A1; KR20080046280A; CA2626294C; TWI306429B; CN100560193C; RU2389538C2; KR101027287B1; AU2006303413B2; WO2007045529A1; TW200728056A; JP4928555B2; JP2009511269A; ZA200803380B; CN101043935A; DE502006007195D1; EP1943009A1

Abstract

A mixer with a mixing tube (1), a mixing rotor (3) with a back-mixing effect and a feed (4, 5) for feeding the liquid colours through the wall of the mixing tube in the region of the mixing rotor makes it possible for liquid colours of different viscosities to be mixed uniformly even when the liquid colours are fed intermittently. The mixing of liquid colours with this mixer makes it possible when the liquid colours that are used are metered volumetrically for the mixed liquid colour to be metered directly into a plastics-processing machine.

Description

IN THE MATTER OF an Australian Application corresponding to PCT Application PCT/EP2006/066194 RWS Group Ltd, of Europa House, Marsham Way, Gerrards Cross, Buckinghamshire, England, hereby solemnly and sincerely declares that, to the best of its knowledge and belief, the following document, prepared by one of its translators competent in the art and conversant with the English and German languages, is a true and correct translation of the PCT Application filed under No. PCT/EP2006/066194. Date: 22 February 2008 N. T. SIMPKIN Deputy Managing Director - UK Translation Division For and on behalf of RWS Group Ltd WO 2007/045529 1 PCT/EP2006/066194 APPARATUS AND METHOD FOR MIXING LIQUID COLOUR AND METHOD FOR COLOURING PLASTICS WITH LIQUID COLOUR The present invention relates to a mixer for liquid 5 colorants and a method for mixing liquid colorants performed using this mixer, which is suitable for on-demand dosing of liquid colorants in plastic processing machines. In the processing of plastics via plastic melts, the 10 plastic is typically colored by masterbatches. Masterbatches are plastic granulates having a high content of coloring agent, which are added to the plastic during the processing via the melt in order to color the plastic. The use of masterbatches has the disadvantage that a 15 separate masterbatch must be manufactured for every type of plastic and every color and must be stored ready for the plastic processing. Rapid changes to new colors or changes of the color tone are not possible, since a new masterbatch must be produced in each case. 20 Instead of masterbatches, liquid colorants may also be used for coloring plastics, the liquid colorant either being supplied with the noncolored plastic granulate to the machine which processes the plastic or being mixed with the 25 already melted plastic in the machine. In this method, a liquid colorant mixed for the desired color tone is used, so that a corresponding liquid colorant must be produced and stored for every desired color. Rapid changes to new colors or a change of the color tone are also not possible 30 here, since a new liquid colorant must be manufactured in each case.

WO 2007/045529 2 PCT/EP2006/066194 Supplying multiple liquid colorants separately to a plastic processing machine and manufacturing plastics having different color tones via recipe-controlled dosing of the quantities of the individual liquid colorants has been 5 suggested in WO 02/087849. This method has the disadvantage, however, that in the event of recipes having greatly differing mixing ratios of the individual liquid colorants, the mixing of the liquid colorants with the plastic is not sufficiently homogeneous on many plastic 10 processing machines, so that unevenly colored products are obtained. Therefore, there is a need for a mixer and a mixing method, by which homogeneously mixed liquid colorants for coloring 15 plastics may be manufactured from individual liquid colorants according to a recipe, even with greatly differing proportions of the individual liquid colorants, the manufacture of the mixture being performed directly before the processing of the plastic in accordance with the 20 demand of the plastic processing machine. The mixer must be capable of reliably mixing even thixotropic liquid colorants, which only flow at a specific shear load. WO 99/34905 discloses a mixer for manufacturing paints, in 25 which individual liquid colorants and one or more lacquer base materials are dosed into a shared chamber of the mixer and mixed in a downstream turbine mixer, before the mixture leaves the mixer. However, this mixer is less suitable for mixing liquid colorants of differing viscosity and density 30 without adding larger quantities of a lacquer base material, as is necessary for coloring plastics, since the mixing of the liquid colorants then remains incomplete.

WO 2007/045529 3 PCT/EP2006/066194 US 3,664,638 discloses static mixers for mixing liquids, in which multiple helical mixing elements, each having an alternating rotational direction, are positioned in a pipe one after another. Static mixers of this construction are 5 known to those skilled in the art under the names helical mixers or Kenics mixers and are typically used for mixing reactive components during the manufacture of two-component plastics or two-component adhesives. 10 Dynamic mixers, in which the mixing elements known from the helical mixers rotate in a mixing pipe, are also used for manufacturing two-component plastics. In these mixers, the two components are axially supplied to the mixing pipe at one end as in the static mixers. 15 The known static helical mixers and the mixers having rotating helical mixing elements using axial supply of the components are not suitable for mixing liquid colorants having different flow behaviors, however, as are used for 20 coloring plastics, in the event of greatly differing mixing conditions. In the event of different viscosities of the liquid colorants to be mixed, there is uneven mixing of the more viscous components, for example, so that mixtures having varying color tone are obtained. Similar problems 25 also arise if the liquid colorants have different densities or one or more of the liquid colorants has thixotropic flow behavior. JP-A 3-60727 discloses a static mixer in the construction 30 of helical mixers, in which nozzles are positioned in the wall of the mixing pipe in order to mix a fluid with a fluid flowing through the pipe. The mixer is reported to have a high mixing action if small quantities of a fluid WO 2007/045529 4 PCT/EP2006/066194 are mixed, via the nozzles in the wall of the mixing pipe, into a large fluid stream which flows through the mixing pipe. 5 EP-A 0 090 257 discloses a mixer for multiple component plastics, which has a mixing chamber having a piston rotating in the mixing chamber, a shear gap forming between the piston and the mixing chamber. The individual components are dosed radially into the shear gap and leave 10 the mixer via an outlet opening opposite the piston. The mixer causes laminar flow in the shear gap and has no devices which move the content of the shear gap in the direction opposite to the outlet opening. 15 The object of uniform mixing of liquid colorants, even in the event of greatly differing proportions of the individual liquid colorants and different flow behaviors of the liquid colorants, may be achieved by the mixer according to the present invention and the method for 20 mixing liquid colorants performed using the mixer. The subject matter of the present invention is a mixer for liquid colorants, comprising a mixing pipe having an outlet opening at the end of the mixing pipe, a mixing unit, 25 positioned in the mixing pipe so it is rotatable around the longitudinal axis of the mixing pipe, having at least two mixing elements, a portion of the mixing elements moving the contents of the mixer in the direction of the outlet opening and a portion of the mixing elements moving the 30 contents of the mixer in the opposite direction in the event of identical rotational direction of the mixing unit, and at least two inlet openings for liquid colorants, which WO 2007/045529 5 PCT/EP2006/066194 are positioned in the wall of the mixing pipe between the ends of the mixing pipe in the area of the mixing unit. Furthermore, the subject matter of the present invention is 5 a method for mixing liquid colorants, in which at least two liquid colorants are mixed in the mixer according to the present invention, the liquid colorants being supplied to the mixer via the inlet openings for liquid colorants, while the mixing unit is moved around the longitudinal axis 10 of the mixing pipe and the mixed liquid colorant leaves the mixer via the outlet opening at the end of the mixing pipe. In addition, the subject matter of the present invention is a method for coloring plastics, in which at least two 15 liquid colorants are mixed using the method according to the present invention for mixing liquid colorants with volumetric dosing and the mixed liquid colorant is supplied directly to a plastic processing machine. 20 Liquid colorants as defined in the present invention are compositions capable of flowing which contain one or more pigments in dispersed form and/or one or more dyes in dissolved form. The liquid colorants may be liquid or pasty and may even comprise thixotropic compositions, which only 25 flow when a shear force which is higher than their yield point acts on them. The liquid colorants preferably contain up to 10 wt-%, particularly up to 5 wt-% pigments. The mixer according to the present invention has a mixing 30 pipe, at whose end an outlet opening for the mixed liquid colorant is located. The mixing pipe is preferably WO 2007/045529 6 PCT/EP2006/066194 implemented so it may be closed during the mixing procedure at the end opposite the outlet opening, so that the liquid colorant mixed in the mixing pipe may only leave the mixing pipe through the outlet opening. A pressure retention valve 5 may possibly also be positioned on the outlet opening in order to ensure that no mixed liquid colorant exits from the outlet opening as long as no liquid colorants are supplied to the mixer. The mixing pipe preferably has a circular cross-section and may have a cylindrical or 10 conical shape, a cylindrical shape being especially preferred. A mixing unit is positioned in the mixing pipe so that it is rotatable around the longitudinal axis of the mixing 15 pipe. The mixing unit thereby has at least two mixing elements, a portion of the mixing elements moving the contents of the mixer in the direction of the outlet opening and a portion of the mixing elements moving the contents of the mixer in the opposite direction with 20 identical rotational direction of the mixing unit. Through this differing effect of the mixing elements on the contents of the mixer, back-mixing of the contents is caused via vortex formation in the mixer. The mixing elements are preferably dimensioned so that during one 25 rotation of the mixing unit, the mixing elements are moved through at least 80 % of the cross-sectional area, especially preferably at least 90 % of the cross-sectional area of the mixing pipe. Through such dimensioning, mixing is caused over the entire cross-section of the mixing pipe. 30 The mixing unit is preferably implemented so that it is replaceable, particularly so that it may be pulled out of the mixing pipe still assembled.

WO 2007/045529 7 PCT/EP2006/066194 The mixing elements of the mixing unit preferably have the form of helical coils having alternating opposite rotational directions, as are known to those skilled in the art from the mixing elements of the helical mixers. 5 However, other forms of mixing elements may also be used, such as stirrers having stirring blades with opposing pitch. The mixing unit preferably has at least 5, especially preferably at least 9 mixing elements, each having a different action on the contents of the mixer. 10 The actuation of the mixing unit, which sets the mixing unit in motion, may be produced arbitrarily. Preferably, the mixing unit is driven via a motor. The mixing unit is especially preferably driven from the end of the mixing 15 pipe opposite the outlet opening via a shaft lying in the longitudinal axis of the mixing pipe. The mixing unit may be set into an oscillating or rotating movement by the drive, a rotating movement being preferred. If multiple mixing elements extend up to near the wall of the mixing 20 pipe, in the event of a drive via a shaft lying in the longitudinal axis of the mixing pipe, no additional mounting of the mixing element in the mixing pipe is necessary. 25 The mixer according to the present invention additionally has at least two inlet openings for liquid colorants, which are positioned in the wall of the mixing pipe lying between the ends of the mixing pipe in the area of the mixing unit. The liquid colorants are accordingly supplied to the mixing 30 pipe radially through the wall of the mixing pipe and not axially at the end of the mixing pipe. The inlet openings for liquid colorants are thereby preferably positioned so that at least 60 % and especially preferably more than 80 % of the length of the mixing unit lies between the inlet WO 2007/045529 8 PCT/EP2006/066194 openings and the outlet opening at the end of the mixing pipe. The inlet openings for liquid colorants preferably lie in one to three planes and especially preferably in only one plane transverse to the longitudinal axis of the 5 mixing pipe. The inlet openings may additionally be provided with shutoff valves or non-return valves, in order to prevent mixed liquid colorant from flowing back from the mixer into the lines leading to the inlet openings. 10 The inlet openings for liquid colorants and the mixing unit are preferably positioned so that during the movement of the mixing unit, at least one mixing element of the mixing unit is moved past each of the inlet openings at a small distance, preferably less than 1 mm distance, particularly 15 preferably less than 0.5 mm distance. A high shear force is thus attained at the inlet openings for liquid colorants and improved mixing is achieved. The mixer according to the present invention may 20 additionally have one or more additional inlet openings for flushing liquid and/or compressed air, preferably both for flushing liquid and for compressed air, in order to be able to empty and clean the mixer in the event of a color change. In addition, the mixer may also have one or more 25 outlet openings which allow emptying independently from the outlet opening at the end of the mixing pipe. The inlet openings for flushing liquid and/or compressed air and possibly additional outlet openings are preferably positioned radially near one end of the mixing pipe or 30 axially at one end of the mixing pipe. The method according to the present invention for mixing liquid colorants is performed in the mixer according to the WO 2007/045529 9 PCT/EP2006/066194 present invention. Thereby, the liquid colorants are supplied to the mixer via the inlet openings for liquid colorants, while the mixing unit is moved around the longitudinal axis of the mixing pipe and the mixed liquid 5 colorant leaves the mixer via the outlet opening at the end of the mixing pipe. Preferably, all openings besides the inlet openings for liquid colorants and the outlet opening at the end of the mixing pipe remain closed during the mixing procedure, so that the liquid colorants supplied via 10 the inlet openings may only leave the mixing pipe via the outlet opening at the end of the mixing pipe after the mixing. In particular, the end of the mixing pipe opposite the outlet opening remains closed during the mixing. 15 The movement of the mixing unit during the supply of the liquid colorants may be oscillating or rotating, a rotating movement being preferred. A rotating movement at essentially constant speed is especially preferred. The velocity of the movement of the mixing unit may be selected 20 by those skilled in the art within wide limits in accordance with the properties of the liquid colorants to be mixed. The velocity of the movement is selected so that it is at least sufficiently high for uniform mixing to be achieved. The velocity of the movement has an upward limit 25 only by the occurrence of cavitation at the mixing elements. As long as gas, such as air, is still contained in the mixer, the velocity of the movement is preferably selected low, in order to avoid mixing in gas bubbles and to obtain a bubble-free mixture. 30 The method according to the present invention for mixing liquid colorants is preferably performed continuously or intermittently. If it is performed continuously, the liquid colorants are supplied in predefined volume ratios, so that WO 2007/045529 10 PCT/EP2006/066194 a continuous flow of the mixed liquid colorant leaves the mixer. If the method is performed intermittently, the liquid colorants are supplied in predefined volume ratios alternately in each case in a first time interval, while, 5 in a following second time interval, the liquid colorants are not supplied. In intermittent operation, mixed liquid colorant only leaves the mixer during the first time interval, but not during the second time interval. 10 The liquid colorants are preferably supplied to the inlet openings for liquid colorants by volumetric dosing. In this case, the liquid colorants are supplied using predefined volume flows in predefined volume ratios, which result from the recipe for the desired color. The volumetric dosing is 15 preferably performed through forced-delivery pumps, in which the delivered volume results inevitably from the mechanical movement of the pump. Suitable forced-delivery pumps are, for example, piston pumps, rotary piston pumps, and gear pumps. Double-piston pumps are preferably used for 20 dosing the liquid colorants, in which liquid colorant is dosed alternately by one of two pistons, while the other piston is filled, so that a constant volume flow is dosed. Through volumetric dosing using forced-delivery pumps, a uniform composition of the mixed liquid colorant may be 25 achieved reproducibly, without variations in the control of the dosing resulting in color variations. In addition, through the volumetric dosing, the quantity flow of mixed liquid colorant which leaves the mixer may be set precisely, so that using the method according to the 30 present invention, the liquid colorant may be dosed directly into a plastic processing machine. In this case, the dosing may be performed continuously into a continuously operating plastic processing machine, for example, into an extruder. Similarly, dosing may also be 35 performed intermittently into a discontinuously operating WO 2007/045529 11 PCT/EP2006/066194 plastic processing machine, such as an injection molding machine. The volumetric dosing of the liquid colorants into the 5 mixer according to the present invention is preferably controlled by the plastic processing machine, so that dosing may be performed directly into the plastic processing machine without an intermediate container. The control of the dosing of the liquid colorants into the 10 mixer according to the present invention by the plastic processing machine is especially advantageously used for dosing into discontinuously operating plastic processing machines, such as injection molding machines. 15 The direct dosing from the method according to the present invention into a plastic processing machine allows rapid color change or an alteration of the color tone during the plastic processing, without a colorant mixture having to be prepared beforehand for this purpose or a colorant 20 container having to be changed on the plastic processing machine. Forced-delivery pumps which are driven by stepping motors are especially preferably used for dosing the liquid 25 colorants. These pumps have the advantage of a significantly broader range of precisely and uniformly adjustable dosing rates compared to continuously driven pumps having variable-speed drive. While with variable speed drive, the range from minimum to maximum dosing rate 30 is typically not more than 1:100, by using a drive having stepping motors, ranges of more than 1:1000 may be implemented. Therefore, a larger range of mixing ratios may be set without replacing pumps and therefore a larger WO 2007/045529 12 PCT/EP2006/066194 number of color tones may be produced. Motorized piston burettes which are driven by stepping motors are especially suitable for dosing the liquid colorants. 5 In the method according to the present invention the supply of the liquid colorants to the inlet openings for liquid colorants may be performed continuously or in fixed cycles in each case. Through the back-mixing occurring in the mixing pipe, even with fixed-cycle supply of one or more 10 liquid colorants, uniform mixing without variations of the composition over time may be achieved using the mixer according to the present invention if the ratio between the average hold-up time of the mixed liquid colorant and the duration of a fixed cycle in the mixer is more than 5:1, 15 preferably more than 10:1. The duration of a fixed cycle according to the present invention is the sum of the duration of an individual step of the colorant supply into the mixer and the duration of a pause between two such steps of the colorant supply. Through the possibility of 20 fixed-cycle supply, even mixtures having greatly differing ratios of the liquid colorants used may be manufactured reproducibly without color variations using the method according to the present invention. 25 In the method according to the present invention, the mixing procedure is preferably interrupted for a color change and the mixer is cleaned using a flushing liquid in order to obtain a mixed liquid colorant having altered and uniform composition as rapidly as possible and keep the 30 quantities of waste arising from a color change low. For this purpose, the supply of the liquid colorants is first interrupted and the mixing pipe is emptied by supplying compressed air. Subsequently, the mixing pipe is filled at least once with flushing liquid and the mixing unit is WO 2007/045529 13 PCT/EP2006/066194 moved in order to remove the liquid colorant adhering to the mixing pipe and to the mixing unit with the flushing liquid. The mixing pipe is then emptied once again by supplying compressed air and subsequently the supply of the 5 liquid colorants is continued in another ratio. If, in the method according to the present invention, the liquid colorant is dosed directly into a plastic processing machine, the contents of the mixing pipe emptied using compressed air and a first part of the liquid colorant 10 mixed using an altered ratio are expediently conveyed to a separate collection container during the cleaning procedure, before the direct dosing into the plastic processing machine is continued. In principle, any liquid which is capable of dissolving or dispersing the components 15 of the liquid colorant is suitable as the flushing liquid. The flushing procedure is preferably performed so that at the end of the flushing procedure, all lines connected to the mixing pipe are filled with liquid. By avoiding gas 20 cushions in supply lines, a more uniform flow of the mixed liquid colorant out of the mixer may be obtained during the following mixing procedure. If an inlet opening is not needed for manufacturing the 25 currently needed mixture of liquid colorants, the supply line for liquid colorant leading to this inlet opening is preferably at least partially filled with mixed liquid colorant from the mixing pipe after beginning the supply of the liquid colorants. This is preferably performed by 30 briefly operating a pump used for supplying the liquid colorant in the reverse delivery direction. By at least partially filling the supply line with already mixed liquid colorant, contamination of the currently mixed liquid colorant by an undesired liquid colorant from a currently WO 2007/045529 14 PCT/EP2006/066194 unneeded inlet opening may be avoided. In an alternative embodiment, the supply lines to unneeded inlet openings may also be at least partially filled with flushing liquid during the flushing procedure. 5 In the method according to the present invention for mixing liquid colorants, in addition to the at leasttwo liquid colorants, still further free-flowing components or compositions may also be supplied via the inlet openings 10 positioned in the wall of the mixing pipe. During the manufacturing of liquid colorants for coloring plastics, for example, UV stabilizers, antioxidants, flame retardants, plasticizers, or additives which improve the impact strength may also be admixed in order to add them to 15 the plastic with the mixed liquid colorant. Figure 1 shows a preferred embodiment of the mixer according to the present invention having mixing elements in the form of helical coils, additional inlet openings for 20 flushing liquid and compressed air, and dosing of the liquid colorants by volumetrically dosing double-piston pumps. Figure 2 shows the flow of liquid colorants plotted against 25 time t for continuous operation of the mixer with continuous dosing of the first liquid colorant at a flow rate FI and fixed-cycle dosing of the second liquid colorant at a flow rate F 2 and a duration of a fixed cycle of t 1 . 30 WO 2007/045529 15 PCT/EP2006/066194 Figure 3 shows the flow of liquid colorants plotted against time t for intermittent operation of the mixer with continuous dosing of the first liquid colorant at a flow rate F, and fixed-cycle dosing of the second liquid 5 colorant at a flow rate F 2 . During the intermittent operation, both liquid colorants are each dosed for a first time interval t 2 and the dosing of both liquid colorants is interrupted for a second time interval t 3 . 10 Figure 4 shows a preferred embodiment of the mixer according to the present invention having two mixing pipes. In the embodiment of Figure 1, the mixer comprises a cylindrical mixing pipe (1) having an outlet opening (2) at 15 the lower end of the mixing pipe (1). In the mixing pipe (1), a mixing unit (3), which is driven by a motor via a shaft (8), is positioned so it is rotatable around the longitudinal axis of the mixing pipe (1). The mixing unit (3) has a total of 5 mixing elements (3a, 3b) in the form 20 of helical coils having alternating opposite rotational directions, which are moved through more than 80 % of the cross-sectional area of the mixing pipe (1) during a rotation of the mixing unit (3). With identical rotational direction of the mixing unit (3), a first portion of the 25 mixing elements (3a) moves the contents of the mixer in the direction of the outlet opening and a second portion of the mixing elements (3b) moves the contents of the mixer in the opposite direction. The mixer additionally has two inlet openings (4, 5) for liquid colorants (6, 7), which are 30 positioned in the wall of the mixing pipe lying between the ends of the mixing pipe (1) in the area of the mixing unit (3) in a plane transverse to the longitudinal axis of the mixing pipe (1), so that more than 60 % of the length of the mixing unit (3) lies between the inlet openings (4, 5) WO 2007/045529 16 PCT/EP2006/066194 and the outlet opening (2) at the end of the mixing pipe (1). The inlet openings (4, 5) for liquid colorants (6, 7) and the mixing unit (3) are positioned in this case so that during the movement of the mixing unit, a mixing element 5 (3b) is moved past the inlet openings (4, 5) at less than 0.5 mm distance. The mixer also has an additional inlet opening (9) for flushing liquid (10) and compressed air (11). 10 In an especially preferred embodiment of the method according to the present invention, two liquid colorants (6, 7) are supplied by double-piston pumps (13, 14) to the mixing pipe (1) via the inlet openings (4, 5) for liquid colorants (6, 7), while the mixing unit (3) rotates around 15 the longitudinal axis of the mixing pipe (1). The end of the mixing pipe (1) opposite the outlet opening (2) and the additional inlet opening (9) remain closed in this case, so that all of the quantity of liquid colorants (6, 7) supplied via the inlet openings (4, 5) leaves the mixer as 20 mixed liquid colorant (12) via the outlet opening (2) and a valve (15). The double-piston pumps (13, 14) are driven via stepping motors in this case, so that the liquid colorants (6, 7) may be supplied to the mixer in fixed cycles, the ratio between the duration of a cycle and the average hold 25 up time of the mixed liquid colorant in the mixer being selected as less than 1:10. The mixed liquid colorant (12) is supplied directly to a plastic processing machine, the volumetric dosing of the liquid colorants (6, 7) being activated by the plastic processing machine. 30 For a color change, the mixer shown in Figure 1 is especially preferably cleaned by first stopping the dosing of the liquid colorants (6, 7) and closing the valve (15) via which the mixed liquid colorant (12) is supplied to a WO 2007/045529 17 PCT/EP2006/066194 plastic processing machine. Subsequently, compressed air (11) is supplied via the additional inlet opening (9) and the contents of the mixing pipe (1) are emptied as a waste stream (16) into a collection container via the valve (15). 5 The mixing pipe (1) is then filled completely with a flushing liquid (10) via the additional inlet opening (9) with valve (15) closed, the mixing unit (3) rotating and the mixing pipe (1) being ventilated via a ventilation opening (not shown) at the upper end of the mixing pipe 10 (1). After approximately 30 seconds, during which the mixing unit (3) rotates further, compressed air (11) is supplied via the additional inlet opening (9) and the contents of the mixing pipe (1) are emptied as a waste stream (16) into a collection container via the valve (15). 15 This flushing procedure is subsequently repeated again twice. The speed of the mixing unit (3) is then reduced and the liquid colorants (6, 7) are dosed at the new ratio, the valve (15) initially remaining open so that the mixed liquid colorant is supplied to a collection container as a 20 waste stream (16). After a quantity of liquid colorants (6, 7) corresponding to the volume of the mixing pipe (1) has been dosed and the air has thus been displaced out of the mixing pipe (1), the speed of the mixing unit (3) is increased back to the original value. After a quantity of 25 liquid colorants (6, 7) which corresponds to two to three times the volume of the mixing pipe (1) has been dosed, the valve (15) is switched so that the mixed liquid colorant (12) is again supplied to the plastic processing machine. 30 In the embodiment of Figure 4, the mixer comprises two mixing pipes (1), each comprising an outlet opening (2), a mixing unit (3) and inlet openings (4, 5). Liquid colorants (6, 7) are supplied to the inlet openings (4, 5) by double piston pumps (13, 14), whereby in each of the double-piston 35 pumps the pistons may be actuated independently of each WO 2007/045529 18 PCT/EP2006/066194 other and liquid colorant can be dosed from either of the two pistons independently of each other into either of the two mixing pipes via appropriately arranged valves. The two mixing pipes are connected by a valve (15) designed as a 5 four-way valve in such a manner, that alternatively one of the mixing pipes is connected via a line with the device into which the mixed liquid colorant (12) is dosed, while at the same time the other mixing pipe is connected with a collection container for the waste stream (16). In addition 10 to inlet openings (9) for flushing liquid (10) the mixer preferably also comprises valves (17), whereby flushing liquid (10) or compressed air (11) can also be passed via the outlet opening (2) into the mixing pipe (3), as well as additional outlet openings (18) for waste streams (19) at 15 the end of the mixing pipe (3) opposite to the outlet opening (2). The additional valves (17) and outlet openings (18) allow flushing of the mixing pipe in both directions and thereby more effective cleaning of the mixing pipe for a color change. 20 The preferred embodiment of the mixer according to Figure 4 allows a liquid colorant with a new, altered mixing ratio to be prepared in a second mixing pipe for a color change, while still dosing from a first mixing pipe at the old 25 mixing ratio. This shortens the down time for a color change, since only the line for mixed liquid colorant (12) leading from valve (15) to the consuming device has to be flushed or exchanged for the color change, while the cleaning of the mixing pipe can occur without interruption 30 of the dosing of liquid colorant. The second mixing pipe is flushed and emptied with flushing liquid (10) and compressed air (11) as described above, while liquid colorants (6, 7) are still dosed into the first mixing pipe at the old mixing ratio and a mixed liquid colorant is 35 obtained at the old mixing ratio via valve (15). Besides WO 2007/045529 19 PCT/EP2006/066194 the supply of flushing liquid and compressed air via inlet opening (9) and emptying via valve (15), there is preferably additional flushing in the opposite direction by the supply of flushing liquid and compressed air via valve 5 (17) and emptying via outlet opening (18). Subsequently, the second mixing pipe is filled with liquid colorants (6, 7) in the new mixing ratio as described above, while the dosing of liquid colorants into the first mixing pipe is continued at the old mixing ratio. For that purpose, the 10 two pistons of a double-piston pump (13, 14) are operated in such a manner as to dose from one of the pump pistons into the first mixing pipe according to the old mixing ratio, while dosing from the other pump piston into the second mixing pipe according to the new mixing ratio. If 15 one of the pump pistons dosing into the first mixing pipe has to be filled during this procedure, the filling of the second mixing pipe is interrupted, the ongoing dosing is switched to the second, still filled pump piston, the first pump piston is filled and thereafter filling of the second 20 mixing pipe is continued, so that the ongoing dosing into the first mixing pipe is not interrupted. Preferably, with each of the double-piston pumps the pump piston not actually needed for dosing into the first mixing pipe is filled before the second mixing pipe being filled, then all 25 pumps are switched to dosing into the first mixing pipe from the filled piston, thereafter the second pump piston not currently needed for dosing into the first mixing pipe is likewise filled and then filling of the second mixing pipe is started. With this procedure, the filling of the 30 second mixing pipe can normally be completed before a switch between the pistons of a double-piston pump becomes necessary for the dosing into the first mixing pipe.

WO 2007/045529 20 PCT/EP2006/066194 Examples The experiments were performed in a mixer corresponding to Figure 1 with a mixing pipe (1) having 8.3 mm internal 5 diameter and 10 cm length. The mixing pipe had two inlet openings (4, 5), each 1.5 mm in diameter, at 8 cm distance to the outlet opening (2). A helical mixer MR 08-12 having 8 mm diameter and 93 mm length from Mixpac, which has 12 mixing elements in the form of helical coils with opposing 10 directions, was used as the mixing unit (3). The mixing unit was set in rotation by a motor at 1500 rpm. Motorized burettes model PSD/8 from Hamilton were used as piston pumps (13, 14) for dosing the liquid colorants. 15 Example 1 A red and a white Polytrend 700 liquid colorant from Colortrend were supplied intermittently to the mixer radially via two different inlet openings (4, 5) in the volume ratio 10:9, resulting in a total volume flow of 20 1.8 ml/min. The time interval for supplying the liquid colorants and the time interval for interrupting the supply were each 10 seconds. To judge the mixing quality, individual droplets of mixed liquid colorant obtained at the outlet opening (2) were drawn out thinly on a 25 microscope slide and visually evaluated. No inhomogeneities or variations of the color tone could be observed in the mixed liquid colorant. Example 2 (Comparative Example) 30 Example 1 was repeated, but the two liquid colorants were not supplied radially via the inlet openings (4, 5), but WO 2007/045529 21 PCT/EP2006/066194 axially via inlet openings in the end of the mixing pipe opposite to the outlet opening (2). The mixed liquid colorant had clearly recognizable variations in the color tone.

Claims

1. A mixer for liquid colorants, comprising a) a mixing pipe (1) having an outlet opening (2) at the end of the mixing pipe, 5 b) a mixing unit (3), positioned in the mixing pipe so it is rotatable around the longitudinal axis of the mixing pipe, having at least two mixing elements (3a, 3b), a portion of the mixing elements moving the contents of the mixer in the direction of the outlet 10 opening and a portion of the mixing elements moving the contents of the mixer in the opposite direction with identical rotational direction of the mixing unit, and c) at least two inlet openings (4, 5) for liquid 15 colorants (6, 7), which are positioned in the wall of the mixing pipe between the ends of the mixing pipe in the area of the mixing unit.

2. The mixer according to Claim 1, 20 characterized in that the mixing pipe (1) has a cylindrical shape.

3. The mixer according to Claim 1 or 2, characterized in that the mixing elements (3a, 3b) of 25 the mixing unit (3) have the form of helical coils having alternating opposite rotational directions.

4. The mixer according to one of the preceding claims, characterized in that the mixing elements (3a, 3b) of 30 the mixing unit (3) move through at least 80 % of the cross-sectional area of the mixing pipe (1) during one rotation of the mixing unit. WO 2007/045529 23 PCT/EP2006/066194

5. The mixer according to one of the preceding claims, characterized in that the inlet openings (4, 5) for liquid colorants (6, 7) are positioned so that at least 60 % of the length of the mixing unit (3) lies between 5 the inlet openings and the outlet opening (2) at the end of the mixing pipe (1).

6. The mixer according to one of the preceding claims, characterized in that the inlet openings (4, 5) for 10 liquid colorants (6, 7) and the mixing unit (3) are positioned so that during the movement of the mixing unit, at least one mixing element (3a, 3b) of the mixing unit is moved past each of the inlet openings at less than 1 mm distance, preferably less than 0.5 mm 15 distance.

7. The mixer according to one of the preceding claims, characterized in that the inlet openings (4, 5) for liquid colorants (6, 7) lie in one plane transverse to 20 the longitudinal axis of the mixing pipe (1).

8. The mixer according to one of the preceding claims, characterized in that the mixing unit (3) is driven from the end of the mixing pipe opposite the outlet opening 25 (2) via a shaft (8) lying in the longitudinal axis of the mixing pipe (1).

9. The mixer according to one of the preceding claims, characterized in that it has one or more additional 30 inlet openings (9) for flushing liquid (10) and compressed air (11). WO 2007/045529 24 PCT/EP2006/066194

10.The mixer according to one of the preceding claims, characterized in that it comprises two mixing pipes (1), whose outlet openings (2) are connected via a valve (15) with a common line for mixed liquid colorant 5 (12). ll.The mixer according to Claim 10, characterized in that it comprises at least two double piston pumps (13, 14), and liquid colorant can be dosed 10 from both pistons of a double-piston pump independently of each other into either of the two mixing pipes.

12.A method for mixing liquid colorants, characterized in that at least two liquid colorants 15 (6, 7) are mixed in a mixer according to one of Claims 1 through 11, the liquid colorants being supplied to the mixer via the inlet openings (4, 5) for liquid colorants, while the mixing unit (3) is moved around the longitudinal axis of the mixing pipe (1) and the 20 mixed liquid colorant (12) leav the mixer via the outlet opening (2) at the end of the mixing pipe.

13.The method according to Claim 12, characterized in that the mixing unit (3) rotates 25 around the longitudinal axis of the mixing pipe (1).

14.The method according to Claim 12 or 13, characterized in that the end of the mixing pipe (1) opposite the outlet opening (2) remains closed during 30 the mixing.

15.The method according to one of Claims 12 through 14, characterized in that at least one of the liquid WO 2007/045529 25 PCT/EP2006/066194 colorants (6, 7) is supplied to the mixer in fixed cycles, the ratio between the average hold-up time of the mixed liquid colorant in the mixer and the duration of a fixed cycle being more than 5:1, preferably more 5 than 10:1.

16.The method according to Claim 15, characterized in that at least one of the liquid colorants (6, 7) is supplied to the mixer using a pump 10 which is driven by a stepping motor.

17.The method according to one of Claims 12 through 16, characterized in that the liquid colorants (6, 7) are supplied to the mixer volumetrically dosed. 15

18.The method according to Claim 17, characterized in that the volumetric dosing of the liquid colorants (6, 7) is performed by forced delivery, preferably by double-piston pumps (13, 14). 20

19.The method according to one of Claims 12 through 18, characterized in that no liquid colorant is supplied via at least one inlet opening (5) and the supply line leading to this inlet opening (5) is at least partially 25 filled with mixed liquid colorant from the mixing pipe after beginning the supply of liquid colorants.

20.The method according to one of Claims 12 through 19, characterized in that, 30 for a color change, a) the supply of the liquid colorants (6, 7) is interrupted, WO 2007/045529 26 PCT/EP2006/066194 b)the mixing pipe (1) is emptied by supplying compressed air (11), c) the mixing pipe is filled with flushing liquid (10) and the mixing unit (3) is moved, 5 d) the mixing pipe (1) is emptied by supplying compressed air (11), and e) the supply of the liquid colorants (6, 7) is continued in another ratio. 10 21.The method according to one of Claims 12 through 19, characterized in that a mixer with two mixing pipes (1) is used and at least two liquid colorants (6, 7) are supplied to one of the mixing pipes, while in the other mixing pipe for a color change, 15 a) the mixing pipe is emptied by supplying compressed air (11), b) the mixing pipe is filled with flushing liquid (10) and the mixing unit (3) is moved, and c) the mixing pipe is emptied by supplying compressed air 20 (11).

22.A method for coloring plastics, characterized in that at least two liquid colorants (6, 7) are mixed according to a method according to one 25 of Claims 17 through 21 and the mixed liquid colorant (12) is supplied directly to a plastic processing machine.

23.The method according to Claim 22, 30 characterized in that the volumetric dosing of the liquid colorants (6, 7) is controlled by the plastic processing machine.