AU2003269786B2 - Method of preparing iron-based components by compaction with elevated pressures - Google Patents
Method of preparing iron-based components by compaction with elevated pressures Download PDFInfo
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- AU2003269786B2 AU2003269786B2 AU2003269786A AU2003269786A AU2003269786B2 AU 2003269786 B2 AU2003269786 B2 AU 2003269786B2 AU 2003269786 A AU2003269786 A AU 2003269786A AU 2003269786 A AU2003269786 A AU 2003269786A AU 2003269786 B2 AU2003269786 B2 AU 2003269786B2
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0264—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements the maximum content of each alloying element not exceeding 5%
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/052—Metallic powder characterised by the size or surface area of the particles characterised by a mixture of particles of different sizes or by the particle size distribution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F2003/023—Lubricant mixed with the metal powder
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F2003/026—Mold wall lubrication or article surface lubrication
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Iron (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention concerns a process for the preparation of high density green compacts comprising the steps of providing an iron-based powder essentially free from fine particles; optionally mixing said powder with graphite and other additives; uniaxially compacting the powder in a die at a compaction pressure of at least about 800 MPa and ejecting the green body. The invention also concerns the powder used in the method.
Description
WO 2004/037468 PCTSE2003/001633 Method of preparing iron-based components by compaction with elevated pressures.
FIELD OF THE INVENTION The present invention relates to metal powder compositions useful within the powder metallurgical industry. More specifically the invention concerns a method for the preparation of components having high density by using these compositions.
There are several advantages by using powder metallurgical methods for producing structural parts compared with conventional matching processes of full dense steel. Thus, the energy consumption is much lower and the material utilisation is much higher. Another important factor in favour of the powder metallurgical route is that components with net shape or near net shape can be produced directly after the sintering process without costly shaping processes such as turning, milling, boring or grinding. However, normally a full dense steel material has superior mechanical properties compared with PM components. This is mainly due to the occurrence of porosity in the PM components. Therefore, the strive has been to increase the density of PM components in order to reach values as close as possible to the density value of a full dense steel.
Among the methods used in order to reach higher density of PM components the powder forging process has the advantage that full dense components may be obtained. The process is however costly and is utilised mainly for mass production of heavier components, such as connection rods. Full dense materials can also be obtained by elevated pressures at high temperatures, such as in hot isostatic pressing, HIP, but also this method is costly.
By using warm compaction, a process where the compaction is performed at an elevated temperature, typically at 120 to 250 the density can be increased with about 0,2 g/cm 3 which results in a considerable improvement of the mechanical properties. A disadvantage is however that the warm compaction method involves additional investment and processing. Other processes, such as double pressing, double sintering, sintering at elevated temperatures etc, may further increase the density. Also these methods will add further production costs hence reducing the overall cost effectiveness.
NOV. 200 15:38 PHILLIPS ORMONDE FITZPATRICK NO. 0925 P. 9/13 I 2 0 SIn order to expand the market for powder metallurgical components and utilise the advantages with the powder metallurgical technique there is thus a need for a simple, O less expensive method of achieving high density compacts with improved static and Z dynamic mechanical strength.
0 SUMMARY OF THE INVENTION It has now been found that high density components can be obtained by using high 00 compaction pressures in combination with coarse powders. In view of the general knowledge, that conventionally used powders, i.e. powders including fine particles, NO 10 cannot be compacted to high densities without problems with e.g. damaged or C deteriorated surfaces of the compacts this finding is quite unexpected. Specifically, the Smethod according to the present invention includes the steps of providing an ironl based powder essentially free from fine particles; optionally mixing said powder with graphite and other additives; uniaxially compacting the powder in a die at high pressure and ejecting the green body, which may subsequently be sintered.
According to one aspect of the present invention, there is provided a process for the preparation of high density green compacts including the following steps: providing an iron or iron-based powder wherein less than about 5% of the ironbased powder particles have a size below 45 prm; optionally mixing said powder with graphite and other additives; uniaxially compacting the powder in a die at a compaction pressure of at least about 800 MPa and ejecting the green body from the die; wherein the iron-based powder is combined with a lubricant in an amount between 0.05 and 0.6% by weight before compaction, the lubricant being selected from the group consisting of stearates, waxes, fatty acids and derivatives thereof, oligomers, polymers and other organic substances with lubricating effect.
According to another aspect of the present invention, there is provided a powder composition including an iron or iron-based powder wherein less than about 5% of the powder particles have a size below 45 pm; 0.1-1.0% by weight of graphite, and 0.05- 0.6% by weight of a lubricant selected from the group consisting of stearates, waxes, fatty acids and derivatives thereof, oligomers, polymers and other organic substances with lubricating effect.
P;A\ nBAindBEH'.737O2ipcd 30-1 -O7.oC COMS ID No: ARCS-170748 Received by IP Australia: Time 16:40 Date 2007-11-30 30 NOV. 2007-15:39
O.,
PHILLIPS ORMONDE FITZPATRICK NO. 0925 P. 10/13 2a DETAILED DESCRIPTION OF THE INVENTION The term "high density" is intended to mean compacts having a density of about at least 7.3 g/cm 3 Components having lower densities can of course also be produced but are believed to be of less interest.
The iron-based powder according to the present invention includes pure iron powder such as atomised iron powder, sponge iron powder, reduced iron powder; partially diffusion-alloyed steel powder; and completely alloyed steel powder. The partially diffusion-alloyed steel powder is preferably a steel powder alloyed partially with one or more of Cu, Ni, and Mo. The completely alloyed steel powder is preferably a steel powder alloyed with Mn, Cu, Ni, Cr, Mo, V, Co, W, Nb, Ti, Al, P, S and B. Also stainless steel powders are of interest.
As regards the particle shape it is preferred that the particles have an irregular form as is obtained by water atomisation. Also sponge iron powders having irregularly shaped particles may be of interest, A critical feature of the invention is that the powder used has coarse particles, i.e. the powder is essentially without fine particles. The term "essentially without fine particles" is intended to P:WJtB EMwl lL73731 \S c 30.11-OToAmo COMS ID No: ARCS-170748 Received by IP Australia: Time 16:40 Date 2007-11-30 WO 2004/037468 PCT/SE2003/001633 mean that less than about 5 of the powder particles have a size below 45 gm as measured by the method described in SS-EN 24 497. So far the most interesting results have been achieved with powders essentially consisting of particles above about 106 Rm and particularly above about 212 gm. The term "essentially consists" is intended to mean that at least 50 preferably at least 60 and most preferably at least 70 of the particles have a particle size above 106 and 212 jm, respectively. The maximum particle size may be about 2 mm. The particle size distribution for iron-based powders used at PM manufacturing is normally distributed with a gaussian distribution with a average particle diameter in the region of 30 to 100 4m and about 10-30 less than 45 jim. Iron based powders essentially free from fine particles may be obtained by removing the finer fractions of the powder or by manufacturing a powder having the desired particle size distribution.
The influence of particle size distribution and the influence of particle shape on the compaction properties and properties of the compacted body have been subjected to intense studies.
Thus the US patent 5,594,186 reveals a method of producing PM components with a density higher than 95 of theoretical density by utilising substantially linear, acicular metal particles having a triangular cross section. Such particles are suitably produced by a machining or milling process.
Powders having coarse particles are also used for the manufacture of soft magnetic components. Thus the US patent 6 309 748 discloses a ferromagnetic powder, the particles of which have a diameter size between 40 and 600 gm. In contrast to iron based powder particles according to the present invention, these powder particles are provided with a coating.
In the US patent 4,190,441 a powder composition for production of sintered soft magnetic components is disclosed. In this patent the iron powder includes particles with less than 5 exceeding 417 pm, and less than about 20 of the powder particles have a size less than 147 gm. This patent teaches that, because of the very low content of particles less than 147 jm, the mechanical properties of components manufactured from this coarse, highly pure powder are very low. Furthermore the patent teaches that if higher strength is desired, it is not possible to increase the content of particles having a size less than 147 Pm without simultaneously deteriorating the soft magnetic properties. Therefore this powder is mixed with specific amounts of ferrophosphorus. Graphite which may be used in the compositions according to 2007 15:39 PHILLIPS ORMONDE FITZPATRICK N0. 0925 P, 11/13- 4 c the present invention is not mentioned in this patent and besides the presence of >graphite would deteriorate the magnetic properties.
SPowder mixtures including coarse particles are also disclosed in the US patent 5225459 c 5 (EP 554 009) which also concerns powder mixtures for the preparation of soft magnetic components. Nor do these powder mixtures include graphite.
Va 00 Within the field of powder forging it is furthermore known that pro-alloyed iron-based \0 powders with coarse particles can be used. The US patent 3 901 661 discloses such (c 10 powders. This patent discloses that a lubricant may be included and specifically that the amount of lubricant should be 1 by weight (example If the powders according to the present invention were mixed with such a high amount of lubricant it would however not be possible to achieve the high densities.
In order to obtain compacts having satisfactory mechanical sintered properties of the sintered part according to the present invention it is necessary to add certain amounts of graphite to the powder mixture to be compacted. Thus graphite in amounts between 0.1- 1, preferably 0,2-1. 0 and most preferably 0,2-0.8 by weight of the total mixture to be compacted could be added before the compaction.
Other additives may be added to the iron-based powder before compaction, such as alloying elements comprising Mn, Cu, Ni, Cr, Mo, V, Co, W, Nb, Ti,AI, P, S, and B. These alloying elements may be added in amounts up to 10 by weight. Further additives are machinability enhancing compounds, hard phase material and flow agents.
2 The iron-base powder is combined with a lubricant before it is transferred to the die (internal lubrication). The lubricant is added to minimize friction between the metal powder particles and between the particles and the die during a compaction, or pressing, step.
The lubricant is selected from the group consisting of stearates, waxes, fatty acids and derivatives thereof, oligomers, polymers and other organic substances with lubricating effect. The lubricants are preferably added in the form of particles but may also be bonded and/or coated to the particles. According to the present invention the amount of lubricant added to the iron-based powder varies between 0.05 and 0.6 and more preferably between 0.1-0.5 by weight of the mixture.
P'iUw htelIdraM7a7u31igDfo 30117.dcC COMS ID No: ARCS-170748 Received by IP Australia: Time 16:40 Date 2007-11-30 WO 2004/037468 PCT/SE2003/001633 The method according to the invention may also be performed with the use of external lubrication (die wall lubrication) where the walls of the die are provided with a lubricant before the compaction is performed. A combination of external and internal lubrication may also be used.
The term "at high compaction pressure" is intended to mean at pressures of about at least 800 MPa. More interesting results are obtained with higher pressures such as pressures above 900, preferably above 1000, more preferably above 1100 MPa.
Conventional compaction at high pressures, i.e. pressures above about 800 MPa with conventionally used powders including finer particles, in admixture with low amounts of lubricants (less than 0.6 by weight) are generally considered unsuitable due to the high forces re- quired in order to eject the compacts from the die, the accompanying high wear of the die and the fact that the surfaces of the components tend to be less shiny or deteriorated. By using the powders according to the present invention it has unexpectedly been found that the ejection force is reduced at high pressures, about 1000 MPa, and that components having acceptable or even perfect surfaces may be obtained also when die wall lubrication is not used.
The compaction may be performed with standard equipment, which means that the new method may be performed without expensive investments. The compaction is performed uniaxially in a single step at ambient or elevated temperature. Alternatively the compaction may be performed with the aid of a percussion machine (Model HYP 35-4 from Hydropulsor) as described in patent publication WO 02/38315.
The sintering may be performed at temperatures normally used within the PM field, e.g. at standard temperature between 1080 and 1160C'C or at higher temperatures above 1160'C and in conventionally used atmospheres.
Other treatments of the green or sintered component may as well be applied, such as machining, case hardening, surface densification or other methods used in PM technology.
In brief the advantages obtained by using the method according to the present invention are that high density green compacts can be cost effectively produced. The new method also WO 2004/037468 PCT/SE2003/001633 permits production of higher components which are difficult to produce by using the conventional technique. Additionally standard compaction equipment can be used for producing high density compacts having acceptable or even perfect surface finish.
Examples of products which suitably can be manufactured by the new method are connecting rods, gears and other structural parts subjected to high loads. By using stainless steel powders flanges are of special interest.
The invention is further illustrated by the following examples.
Example 1 Two different iron-based powder compositions according to the present invention were compared with a standard iron-based powder composition. All three compositions were produced with Astaloy Mo available from H6ganis AB, Sweden. 0.2 by weight of graphite and 0.4 by weight of a lubricant (KenolubeTM) were added to the compositions. In one of the ironbased powder compositions according to the invention, particles of the Astaloy Mo with a diameter less than 45 pm were removed and in the other composition according to the invention particles ofAstaloy Mo less than 212 [tm were removed. The compaction was performed at ambient temperature and in standard equipment. As can be seen from figure 1-1 a clear density increase at all compaction pressures is obtained with the powder having a particle size above 212jtm.
Figure 1-2 shows that in order to obtain components without deteriorated surfaces the most important factor is the reduction or elimination of the smallest particles, i.e. particles below gim. Furthermore from this figure it can be seen that the force needed for ejection of the compacts produced by the iron based powder composition without particles less than 212[tm was considerably reduced compared with the ejection force needed for compacts produced from the standard iron-based powder composition having about 20 of the particles less than 45gm. The ejection force needed for compacts produced from the iron-based powder composition according to the invention without particles less than 45 tm is also reduced in comparison with the standard powder.
O A noticeable phenomenon is that the ejection force for compacts produced according to r the present invention decreases with the increasing ejection pressure whereas the opposite is valid for the standard composition.
It was also observed that the compacts obtained when the standard powder was compacted at a pressure above 700 MPa had deteriorated surfaces and were 00 accordingly not acceptable. The compacts, which were obtained when the powder essentially without particles less than 45 pm was compacted at a pressure above 700 NC MPa, had a less shiny surface which at least under certain circumstances is
(N
S 10 acceptable.
Example 2 Example 1 was repeated but as lubricant 0.5% of EBS (ethylene bisstearamide) was used and the compaction was performed with the aid of a percussion machine (Model HYP 35-4 from Hydropulsor, Sweden) From figure 2-1 and 2-2, respectively, it can be noticed that higher green densities and lower ejection forces were obtained with the powder composition according to the invention compared with the powder composition with the standard powder. It can also be noticed that components produced from the standard powder had deteriorated surfaces at all compaction pressures.
The discussion above of the background to the invention is included to explain the context of the invention. This is not to be taken as an admission that any of the material referred to was published, known or part of the common general knowledge in the art as at the priority date of each claim of the present application.
P:\SandraDear2003269786 Speci 6 July
Claims (8)
- 2. Process according to claim 1 wherein the compaction is performed in a single step.
- 3. Process according to claim 1 or 2, wherein at least 50%, preferably at least and most preferably at least 70% of the iron-based powder consists of particles having a particle size above about 106 pm.
- 4. Process according to any one of the claims 1-3, wherein at least preferably at least 60% and most preferably at least 70% of the iron-based powder consists of particles having a particle size above about 212 pm. Process according to claim 4, wherein the maximum particle size is about 2mm.
- 6. Process according to any of claims 2-5, wherein the graphite is present In an amount of 0.1-1.0%.
- 7. Process according to any of claims 1-6, wherein the compaction is performed in a lubricated die.
- 8. Process according to claim 7, wherein the compaction is performed by using a combination of internal and external lubrication.
- 9. Process according to any of claims 1-8 wherein the additives are selected from the group consisting of alloying elements such as Mn, Cu, Ni, Cr, Mo, V, Co, W, Nb, TI, Al, P, S and B machinability enhancing agents, hard phase materials and flow agents. P:'Ja4iU r hedb\flBEClf Z d 1 it-$t.tc COMS ID No: ARCS-170748 Received by IP Australia: Time 16:40 Date 2007-11-30
- 30.NOV.2007 15:39 PHILLIPS ORMONDE FITZPATRICK -NO.0925- P. 13/13 0 9 o 10. Process according to any one of claims 1-9, wherein the compaction is performed at a pressure of at least 900 MPa, more preferably at least 1000 O and most preferably above 1100 MPa. Z 11. Process according to any of claims 1-10, wherein the compaction is r 5 performed at ambient temperature. 12. Process according to any of claims 1-10, wherein the compaction is IO performed at elevated temperature. 00 13. Process according to any of claims 1-12 for preparing sintered products said process further including a single sintering step at a temperature N 10 above 1100°C. o 14. Powder composition including an iron or iron-based powder wherein less 0 than about 5% of the powder particles have a size below 45 pm; 0.1-1.0% by weight of graphite, and 0.05-0.6% by weight of a lubricant selected from the group consisting of stearates, waxes, fatty acids and derivatives thereof, oligomers, polymers and other organic substances with lubricating effect. Composition according to claim 14, wherein at least 50%, preferably at least 60% and most preferably at least 70% of the iron-based powder have a particle size above about 106 pm. 16. Composition according to claim 15, wherein at least 50% of the iron-based powder particles have a particle size above about 212 pm. 17. Composition according to any one of the claims 14-16 further including additives selected from the group consisting of alloying elements such as Mn, Cu, Ni, Cr, Mo, V, Co, W, Nb, Ti, Al, P, S and B machinability enhancing agents, hard phase materials and flow agents. 18. A process for the preparation of high density green compacts substantially as herein described with reference to any one of the examples. 19. A powder composition substantially as herein described with reference to any one of the examples. P'U \Beainda\l\6E770,Sk e Ol11.Do.da COMS ID No: ARCS-170748 Received by IP Australia: Time 16:40 Date 2007-11-30
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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SE0203134A SE0203134D0 (en) | 2002-10-22 | 2002-10-22 | Method of preparing iron-based components |
SE0203134-2 | 2002-10-22 | ||
PCT/SE2003/001633 WO2004037468A1 (en) | 2002-10-22 | 2003-10-22 | Method of preparing iron-based components by compaction with elevated pressures |
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AU2003269786A1 AU2003269786A1 (en) | 2004-05-13 |
AU2003269786B2 true AU2003269786B2 (en) | 2007-12-13 |
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AU2003269786A Ceased AU2003269786B2 (en) | 2002-10-22 | 2003-10-22 | Method of preparing iron-based components by compaction with elevated pressures |
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EP (1) | EP1554071B1 (en) |
JP (2) | JP4909514B2 (en) |
KR (2) | KR101179725B1 (en) |
CN (1) | CN1705533B (en) |
AT (1) | ATE490830T1 (en) |
AU (1) | AU2003269786B2 (en) |
BR (1) | BR0314079B1 (en) |
CA (1) | CA2495697C (en) |
DE (1) | DE60335280D1 (en) |
ES (1) | ES2357741T3 (en) |
MX (1) | MXPA05004256A (en) |
PL (1) | PL208668B1 (en) |
RU (1) | RU2333075C2 (en) |
SE (1) | SE0203134D0 (en) |
TW (2) | TW201127521A (en) |
WO (1) | WO2004037468A1 (en) |
ZA (1) | ZA200501296B (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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US8075710B2 (en) | 2005-06-15 | 2011-12-13 | Höganäs Ab | Soft magnetic composite materials |
KR100978901B1 (en) * | 2008-03-21 | 2010-08-31 | 가야에이엠에이 주식회사 | MANUFACTURING METHOD OF Fe-BASED SINTERED BODY WITH HIGH TENSILE STRENGTH AND HIGH HARDNESS |
CN102947028B (en) * | 2010-05-19 | 2015-09-02 | 赫格纳斯公司 | In iron powder metallurgical application for improvement of the composition of size Control and method |
WO2013122873A1 (en) * | 2012-02-15 | 2013-08-22 | Gkn Sinter Metals, Llc | Powder metal with solid lubricant and powder metal scroll compressor made therefrom |
JP5903738B2 (en) * | 2012-03-29 | 2016-04-13 | 住友電工焼結合金株式会社 | Method for producing ferrous sintered alloy |
EP2743361A1 (en) * | 2012-12-14 | 2014-06-18 | Höganäs AB (publ) | New product and use thereof |
RU2588979C1 (en) * | 2015-03-16 | 2016-07-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный технологический университет" (ФГБОУ ВПО "КубГТУ") | Method of producing high-density powder chromium containing material based on iron |
AT526261B1 (en) * | 2022-07-05 | 2024-03-15 | Miba Sinter Austria Gmbh | Method for producing a component from a sinter powder |
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US5225459A (en) * | 1992-01-31 | 1993-07-06 | Hoeganaes Corporation | Method of making an iron/polymer powder composition |
US5594186A (en) * | 1995-07-12 | 1997-01-14 | Magnetics International, Inc. | High density metal components manufactured by powder metallurgy |
GB2315115A (en) * | 1996-07-10 | 1998-01-21 | Hitachi Powdered Metals | Sintered valve guide |
US5892164A (en) * | 1997-03-19 | 1999-04-06 | Air Products And Chemicals, Inc. | Carbon steel powders and method of manufacturing powder metal components therefrom |
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WO2002038315A1 (en) * | 2000-11-09 | 2002-05-16 | Höganäs Ab | High density products and method for the preparation thereof |
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Also Published As
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ES2357741T3 (en) | 2011-04-29 |
EP1554071B1 (en) | 2010-12-08 |
TW200417433A (en) | 2004-09-16 |
SE0203134D0 (en) | 2002-10-22 |
ZA200501296B (en) | 2006-10-25 |
JP4909514B2 (en) | 2012-04-04 |
BR0314079A (en) | 2005-07-05 |
JP2010189769A (en) | 2010-09-02 |
CA2495697A1 (en) | 2004-05-06 |
KR101179725B1 (en) | 2012-09-04 |
RU2005115474A (en) | 2005-10-27 |
DE60335280D1 (en) | 2011-01-20 |
BR0314079B1 (en) | 2011-10-04 |
ATE490830T1 (en) | 2010-12-15 |
MXPA05004256A (en) | 2005-07-05 |
CN1705533B (en) | 2010-08-11 |
PL208668B1 (en) | 2011-05-31 |
CA2495697C (en) | 2011-12-13 |
CN1705533A (en) | 2005-12-07 |
TWI415698B (en) | 2013-11-21 |
JP2006503983A (en) | 2006-02-02 |
TW201127521A (en) | 2011-08-16 |
EP1554071A1 (en) | 2005-07-20 |
AU2003269786A1 (en) | 2004-05-13 |
WO2004037468A1 (en) | 2004-05-06 |
KR20110114689A (en) | 2011-10-19 |
RU2333075C2 (en) | 2008-09-10 |
PL375094A1 (en) | 2005-11-14 |
KR20050059285A (en) | 2005-06-17 |
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