AU2002217974A1 - Electrochemical polymer electrolyte membrane cell stacks - Google Patents
Electrochemical polymer electrolyte membrane cell stacksInfo
- Publication number
- AU2002217974A1 AU2002217974A1 AU2002217974A AU1797402A AU2002217974A1 AU 2002217974 A1 AU2002217974 A1 AU 2002217974A1 AU 2002217974 A AU2002217974 A AU 2002217974A AU 1797402 A AU1797402 A AU 1797402A AU 2002217974 A1 AU2002217974 A1 AU 2002217974A1
- Authority
- AU
- Australia
- Prior art keywords
- fuel cell
- polymer electrolyte
- cassette
- electrolyte membrane
- manifold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/028—Sealing means characterised by their material
- H01M8/0284—Organic resins; Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0286—Processes for forming seals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/242—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes comprising framed electrodes or intermediary frame-like gaskets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/2475—Enclosures, casings or containers of fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/248—Means for compression of the fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/249—Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
An improved electrochemical polymer electrolyte membrane cell stack is provided that includes one or more individual fuel cell cassettes, each fuel cell cassette having at least one membrane electrode assembly, fuel flow field and oxidant flow field. Within each fuel cell cassette, each membrane electrode assembly has at least one manifold opening for the passage of reactant manifolds through the cassette, all of which are bonded about the perimeter by a sealant, and each flow field has at least one manifold opening and any manifold openings on the flow fields which do not correspond to a manifold providing reactant for distribution to such flow field is bonded about its perimeter by a sealant. Each fuel cell cassette may also contain other typical components of a electrochemical polymer electrolyte membrane cell stack, such as separator plates or coolant flow fields, which also have manifold openings which may or may not be bonded about the perimeter. The membrane electrode assembly, flow fields, and other components are encapsulated along the peripheral edges by a resin such that the entire periphery of the fuel cell cassette is encapsulated by the resin.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25319900P | 2000-11-27 | 2000-11-27 | |
US60253199 | 2000-11-27 | ||
US09908359 | 2001-07-18 | ||
US09/908,359 US6946210B2 (en) | 2000-11-27 | 2001-07-18 | Electrochemical polymer electrolyte membrane cell stacks and manufacturing methods thereof |
PCT/US2001/044880 WO2002043173A1 (en) | 2000-11-27 | 2001-11-27 | Electrochemical polymer electrolyte membrane cell stacks |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2002217974A1 true AU2002217974A1 (en) | 2002-06-03 |
Family
ID=26943016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2002217974A Abandoned AU2002217974A1 (en) | 2000-11-27 | 2001-11-27 | Electrochemical polymer electrolyte membrane cell stacks |
Country Status (8)
Country | Link |
---|---|
US (2) | US6946210B2 (en) |
EP (1) | EP1356532B1 (en) |
JP (1) | JP4346905B2 (en) |
AT (1) | ATE426252T1 (en) |
AU (1) | AU2002217974A1 (en) |
CA (1) | CA2430083C (en) |
DE (1) | DE60138045D1 (en) |
WO (1) | WO2002043173A1 (en) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6946210B2 (en) * | 2000-11-27 | 2005-09-20 | Protonex Technology Corporation | Electrochemical polymer electrolyte membrane cell stacks and manufacturing methods thereof |
US20050095492A1 (en) * | 2001-05-15 | 2005-05-05 | Hydrogenics Corporation | Fuel cell stack |
US6852439B2 (en) | 2001-05-15 | 2005-02-08 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
US6821666B2 (en) * | 2001-09-28 | 2004-11-23 | The Regents Of The Univerosity Of California | Method of forming a package for mems-based fuel cell |
WO2003036747A1 (en) | 2001-10-22 | 2003-05-01 | Protonex Technology Corporation | One-shot fabrication of membrane-based electrochemical cell stacks |
US6805990B2 (en) * | 2001-10-24 | 2004-10-19 | Fuelcell Energy, Ltd. | Flat plate fuel cell stack |
DE10160905B4 (en) * | 2001-12-12 | 2007-07-19 | Carl Freudenberg Kg | Sealing arrangement for fuel cells, method for producing and using such a sealing arrangement |
US7687181B2 (en) * | 2002-04-23 | 2010-03-30 | Protonex Technology Corporation | Channel-based electrochemical cassettes |
WO2004047210A2 (en) * | 2002-11-18 | 2004-06-03 | Protonex Technology Corporation | Membrane based electrochemical cell stacks |
EP1573846A2 (en) * | 2002-09-23 | 2005-09-14 | Protonex Technology Corporation | Liquid electrochemical cell stacks and manufacturing methods for same |
JP4067371B2 (en) | 2002-09-25 | 2008-03-26 | 本田技研工業株式会社 | Fuel cell |
WO2004051766A2 (en) * | 2002-12-04 | 2004-06-17 | Lynntech Power Systems, Ltd | Adhesively bonded electrochemical cell stacks |
CN1754279B (en) * | 2003-02-27 | 2010-09-29 | 布罗托尼克斯技术公司 | Externally manifolded membrane based electrochemical cell stacks |
US20050048349A1 (en) * | 2003-08-28 | 2005-03-03 | Fannon Megan A. | Method of manufacturing a fuel cell array and a related array |
US7297269B2 (en) * | 2003-10-31 | 2007-11-20 | Protonex Technology Corporation | Cross-flow filtration cassettes and methods for fabrication of same |
US8758958B2 (en) | 2004-12-29 | 2014-06-24 | Clearedge Power, Llc | Fuel cell separator plate assembly |
EP1836738B1 (en) * | 2004-12-29 | 2011-10-05 | UTC Power Corporation | Fuel cell separator plate assembly |
US20070212587A1 (en) * | 2005-04-01 | 2007-09-13 | Nick Fragiadakis | Apparatus for and method of forming seals in an electrochemical cell assembly |
NO20053220D0 (en) * | 2005-06-29 | 2005-06-29 | Norsk Hydro As | Compression of a PEM cell stack in a pressure tank. |
US7914943B2 (en) * | 2005-08-19 | 2011-03-29 | Daimler Ag | Integrated seal for fuel cell assembly and fuel cell stack |
US20070048580A1 (en) * | 2005-08-30 | 2007-03-01 | Cheng-Hsin Chen | Fuel cell |
EP1760808B1 (en) * | 2005-09-06 | 2008-07-23 | Sgl Carbon Ag | Electrodes for a fuel cell |
EP2266682A3 (en) * | 2005-09-09 | 2014-08-20 | Tangenx Technology Corporation | Laminated cassette device and method for making same |
FR2891950B1 (en) * | 2005-10-11 | 2014-05-30 | Commissariat Energie Atomique | FUEL CELL SEALED STACK |
CA2633349A1 (en) * | 2005-12-20 | 2007-07-05 | Tangenx Technology Corporation | Filtration assembly and methods for making and using same |
US7879507B2 (en) * | 2006-04-10 | 2011-02-01 | Protonex Technology Corporation | Insert-molded, externally manifolded, one-shot sealed membrane based electrochemical cell stacks |
KR100821033B1 (en) | 2007-04-12 | 2008-04-08 | 삼성에스디아이 주식회사 | Fuel cell stack and manufacturing method thereof |
US8580457B2 (en) * | 2007-06-28 | 2013-11-12 | Protonex Technology Corporation | Fuel cell stack sealed with encapsulating material and method of making the same |
US8124292B2 (en) * | 2007-06-28 | 2012-02-28 | Protonex Technology Corporation | Fuel cell stacks and methods |
US20090123784A1 (en) * | 2007-09-13 | 2009-05-14 | Pavlik Thomas J | Fuel cell module |
KR101274893B1 (en) * | 2008-08-05 | 2013-06-14 | 주식회사 엘지화학 | Stack and folding-typed electrode assembly and electrochemical cell comprising the Same |
US8236067B2 (en) * | 2008-08-11 | 2012-08-07 | GM Global Technology Operations LLC | Method and apparatus for fuel cell stack assembly |
US20110171562A1 (en) * | 2010-01-08 | 2011-07-14 | Gm Global Technology Operations, Inc. | Process for forming a membrane-subgasket assembly using vacuum sealing |
US20110229790A1 (en) * | 2010-03-19 | 2011-09-22 | Kenji Sato | Fuel cell module and fuel cell stack |
CN101826620B (en) * | 2010-03-30 | 2014-08-13 | 上海恒劲动力科技有限公司 | Bipolar plate for fuel cells |
KR20120105331A (en) * | 2011-03-15 | 2012-09-25 | 현대자동차주식회사 | Fuel cell stack with improved corrosion-resistance |
JP2013004352A (en) * | 2011-06-17 | 2013-01-07 | Toyota Motor Corp | Fuel cell system |
CN103915631B (en) * | 2012-12-31 | 2018-04-24 | 上海恒劲动力科技有限公司 | A kind of air-cooled integrated bipolar plates of fuel cell |
US10096844B2 (en) | 2013-10-03 | 2018-10-09 | Hamilton Sundstrand Corporation | Manifold for plural fuel cell stacks |
US20170331092A1 (en) | 2016-05-13 | 2017-11-16 | Quantumscape Corporation | Solid electrolyte separator bonding agent |
DE102016221998A1 (en) * | 2016-11-09 | 2018-05-09 | Bayerische Motoren Werke Aktiengesellschaft | Method for producing a fuel cell stack |
US20180212259A1 (en) | 2017-01-23 | 2018-07-26 | GM Global Technology Operations LLC | Fuel cell microseal and a method of manufacture thereof |
AU2018229330B2 (en) | 2017-03-01 | 2023-07-27 | Axine Water Technologies Inc. | Stack of electrochemical cells for wastewater treatment with isolated electrodes |
US20200395584A1 (en) * | 2017-11-28 | 2020-12-17 | Quantumscape Corporation | Catholyte management for a solid-state separator |
EP4207395A1 (en) * | 2018-01-17 | 2023-07-05 | Nuvera Fuel Cells, LLC | Electrochemical cells with improved fluid flow design |
IL259978B (en) * | 2018-06-12 | 2020-07-30 | Pocell Tech Ltd | Alkaline membrane fuel cell assembly comprising a thin membrane and method of making same |
DE102018212715A1 (en) * | 2018-07-31 | 2020-02-06 | Robert Bosch Gmbh | Fuel cell stack and method for producing a fuel cell stack |
DE102018213912A1 (en) * | 2018-08-17 | 2020-02-20 | Audi Ag | Fuel cell device and method for monitoring and structural adaptation of a fuel cell device |
FR3102308B1 (en) * | 2019-10-18 | 2022-06-03 | Air Liquide | Fuel cell bipolar plate |
KR20210049339A (en) * | 2019-10-25 | 2021-05-06 | 현대자동차주식회사 | Fuel cell |
WO2023049507A2 (en) | 2021-09-27 | 2023-03-30 | Quantumscape Battery, Inc. | Electrochemical stack and method of assembly thereof |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
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DE1902392C3 (en) | 1969-01-18 | 1975-07-03 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Process for the production of fuel elements cast with plastic |
US4397917A (en) | 1982-01-11 | 1983-08-09 | Energy Research Corporation | Fuel cell pack with internal connection of fuel cells |
US4505992A (en) | 1983-04-11 | 1985-03-19 | Engelhard Corporation | Integral gas seal for fuel cell gas distribution assemblies and method of fabrication |
US4604331A (en) * | 1984-05-29 | 1986-08-05 | The United States Of America As Represented By The United States Department Of Energy | Fuel cell separator plate with bellows-type sealing flanges |
JPH0260063A (en) * | 1988-08-24 | 1990-02-28 | Meidensha Corp | Stacked fuel cell |
US5176966A (en) | 1990-11-19 | 1993-01-05 | Ballard Power Systems Inc. | Fuel cell membrane electrode and seal assembly |
US5110691A (en) | 1991-01-16 | 1992-05-05 | International Fuel Cells Corporation | Fuel cell component sealant |
WO1993013566A1 (en) | 1991-12-26 | 1993-07-08 | International Fuel Cells, Inc. | Plate-shaped fuel cell component and a method of making the same |
US5264299A (en) | 1991-12-26 | 1993-11-23 | International Fuel Cells Corporation | Proton exchange membrane fuel cell support plate and an assembly including the same |
US5453331A (en) | 1994-08-12 | 1995-09-26 | University Of Chicago | Compliant sealants for solid oxide fuel cells and other ceramics |
EP0833400B1 (en) * | 1995-05-25 | 2005-08-03 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell and method for its control |
DE19703214C2 (en) * | 1997-01-29 | 2003-10-30 | Proton Motor Fuel Cell Gmbh | Membrane electrode unit with integrated sealing edge and process for its manufacture |
US5858569A (en) * | 1997-03-21 | 1999-01-12 | Plug Power L.L.C. | Low cost fuel cell stack design |
DE19713250C2 (en) | 1997-03-29 | 2002-04-18 | Ballard Power Systems | Electrochemical energy converter with polymer electrolyte membrane |
US6190793B1 (en) * | 1997-07-16 | 2001-02-20 | Ballard Power Systems Inc. | Electrochemical fuel cell stack with an improved compression assembly |
CN1122322C (en) * | 1998-04-17 | 2003-09-24 | 松下电器产业株式会社 | Solid polymer electrolyte fuel cell and method for producing the same |
US6165634A (en) | 1998-10-21 | 2000-12-26 | International Fuel Cells Llc | Fuel cell with improved sealing between individual membrane assemblies and plate assemblies |
US6159628A (en) | 1998-10-21 | 2000-12-12 | International Fuel Cells Llc | Use of thermoplastic films to create seals and bond PEM cell components |
US6399234B2 (en) | 1998-12-23 | 2002-06-04 | Utc Fuel Cells, Llc | Fuel cell stack assembly with edge seal |
US6372372B1 (en) * | 2000-02-11 | 2002-04-16 | Plug Power Inc. | Clamping system for a fuel cell stack |
US6596427B1 (en) * | 2000-11-06 | 2003-07-22 | Ballard Power Systems Inc. | Encapsulating seals for electrochemical cell stacks and methods of sealing electrochemical cell stacks |
US6946210B2 (en) * | 2000-11-27 | 2005-09-20 | Protonex Technology Corporation | Electrochemical polymer electrolyte membrane cell stacks and manufacturing methods thereof |
US6852439B2 (en) | 2001-05-15 | 2005-02-08 | Hydrogenics Corporation | Apparatus for and method of forming seals in fuel cells and fuel cell stacks |
US20020172852A1 (en) | 2001-05-15 | 2002-11-21 | David Frank | Flow field plate for a fuel cell and fuel cell assembly incorporating the flow field plate |
WO2003036747A1 (en) * | 2001-10-22 | 2003-05-01 | Protonex Technology Corporation | One-shot fabrication of membrane-based electrochemical cell stacks |
-
2001
- 2001-07-18 US US09/908,359 patent/US6946210B2/en not_active Expired - Lifetime
- 2001-11-27 AT AT01997859T patent/ATE426252T1/en not_active IP Right Cessation
- 2001-11-27 DE DE60138045T patent/DE60138045D1/en not_active Expired - Lifetime
- 2001-11-27 JP JP2002544801A patent/JP4346905B2/en not_active Expired - Lifetime
- 2001-11-27 AU AU2002217974A patent/AU2002217974A1/en not_active Abandoned
- 2001-11-27 CA CA2430083A patent/CA2430083C/en not_active Expired - Lifetime
- 2001-11-27 EP EP01997859A patent/EP1356532B1/en not_active Expired - Lifetime
- 2001-11-27 WO PCT/US2001/044880 patent/WO2002043173A1/en active Application Filing
-
2005
- 2005-09-16 US US11/229,087 patent/US7482086B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1356532A4 (en) | 2007-02-21 |
US20060024545A1 (en) | 2006-02-02 |
ATE426252T1 (en) | 2009-04-15 |
US20020068212A1 (en) | 2002-06-06 |
JP2004534350A (en) | 2004-11-11 |
EP1356532A1 (en) | 2003-10-29 |
EP1356532B1 (en) | 2009-03-18 |
US6946210B2 (en) | 2005-09-20 |
WO2002043173A1 (en) | 2002-05-30 |
JP4346905B2 (en) | 2009-10-21 |
CA2430083A1 (en) | 2002-05-30 |
DE60138045D1 (en) | 2009-04-30 |
US7482086B2 (en) | 2009-01-27 |
CA2430083C (en) | 2010-11-09 |
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