AU2001289934B2 - Cooling element for shaft furnaces - Google Patents

Cooling element for shaft furnaces Download PDF

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Publication number
AU2001289934B2
AU2001289934B2 AU2001289934A AU2001289934A AU2001289934B2 AU 2001289934 B2 AU2001289934 B2 AU 2001289934B2 AU 2001289934 A AU2001289934 A AU 2001289934A AU 2001289934 A AU2001289934 A AU 2001289934A AU 2001289934 B2 AU2001289934 B2 AU 2001289934B2
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AU
Australia
Prior art keywords
cooling
coolant
cooling element
channel
base body
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Expired - Fee Related
Application number
AU2001289934A
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AU2001289934A2 (en
AU2001289934A1 (en
Inventor
Peter Heinrich
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SMS Siemag AG
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SMS Demag AG
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Publication date
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Publication of AU2001289934A1 publication Critical patent/AU2001289934A1/en
Publication of AU2001289934A2 publication Critical patent/AU2001289934A2/en
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Publication of AU2001289934B2 publication Critical patent/AU2001289934B2/en
Anticipated expiration legal-status Critical
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/12Casings; Linings; Walls; Roofs incorporating cooling arrangements
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/10Cooling; Devices therefor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/24Cooling arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • F27D2009/0002Cooling of furnaces
    • F27D2009/0045Cooling of furnaces the cooling medium passing a block, e.g. metallic
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • F27D2009/0002Cooling of furnaces
    • F27D2009/0051Cooling of furnaces comprising use of studs to transfer heat or retain the liner
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Blast Furnaces (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Heat Treatment Of Articles (AREA)
  • Manufacture Of Iron (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Details (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Electric Stoves And Ranges (AREA)

Abstract

A cooling element for shaft furnaces includes an area through which coolant flows as a result of the arrangement of at least one internal coolant-carrying channel, which leads to coolant feed and discharge pipes connected to the cooling element. At the end of the element where coolant enters and/or exits, the coolant-carrying channel extends beyond the opening of the pipe and into an edge area of the cooling element. The coolant carrying channel has a cross-section which is larger than the cross-section of the internal channel, wherein the coolant section is provided with a guide element which divides the channel lengthwise in the flow direction so that the coolant is guided to the edge area of the cooling element and then back again in the opposite direction.

Description

i TRANSLATION (HM-517): WO 02/31,211 Al PCT/EP01/11,221 COOLING ELEMENT FOR SHAFT FURNACES The invention pertains to a cooling element for shaft furnaces, especially blast furnaces, with an area through which a coolant, preferably water, flows as the result of the arrangement of at least one internal coolant-carrying channel, which leads to coolant feed and discharge pipes connected to the cooling element, the cooling element also having edge areas.
Cooling elements of this type, also known as "staves", serve to cool the walls of blast furnaces. They are usually installed between the steel furnace jacket and the furnace lining and are provided with refractory material on the side facing the interior of the furnace.
Cooling elements are known in which the cooling channels are formed by pipes, usually made of steel, which are cast into a matrix of cast iron. The cooling channels passing through the cooling element are usually arranged vertically with respect to the longitudinal axis of the base body. These plates can also consist of cast copper instead of cast iron. In addition, forged or rolled cooling plates of copper or low-alloy copper are also known, the cooling channels of which are vertically oriented blind bores, which are introduced by deep mechanical drilling or milling. Finally, it is also known that a cooling element can be produced from one or more extruded or rolled profiled sections, the interiors of which are provided with coolant channels.
A feature essentially common to all of the known staves is that they have an area through which a coolant flows as the result of the arrangement of cooling channels, which lead to coolant feed and discharge pipes passing through the wall of the blast furnace, the staves also having edge areas, which extend essentially beyond the pipes. These edge areas are not cooled as intensively, of course, as the area of the staves through which the cooling channels pass. The reason for the less intensive cooling of the edge areas is the disproportionately large distance between the coolant-carrying area and the corners or edges of the staves, that is, the end areas. The heat which accumulates there must be transported by conduction to the cross section through which the coolant flows. This leads to higher temperatures at the corners and edges than in the other areas of the stave and thus to thermal stresses, to overheating, and to premature wear. Staves of cast iron in particular suffer losses of material especially at the corners and edges, as a result of which ultimately the adjacent areas of the steel jacket around the blast furnace are no longer adequately protected. It thus becomes necessary to replace the staves in question. In the case of copper staves, the same basic problems also occur, but because of the much higher thermal conductivity of copper, they occur later and to a less pronounced degree.
For geometric and manufacturing reasons, the cooling pipes cannot be moved as far as one might wish into the edge areas of 2 the staves to improve the cooling effect. So-called "compensators", furthermore, are installed on the outside surface of the steel jacket of the furnace, which have the job of allowing the cooling pipes to pass in a gas-tight manner through the steel jacket. Because of their geometric dimensions, these compensators require that the centers of the cooling pipes must be maintained at certain vertical and horizontal distances from each other. These distances must also be maintained so that the steel jacket of the furnace is not weakened too much, which could be the case if the holes were too closely spaced in their rows.
In the case of staves with cast-in pipes, furthermore, the outside diameter and wall thickness of the pipes limit the degree to which they can be bent, which means that it is impossible to bend them into a shape which could allow them to pass through the edge area.
The problem of inadequate cooling at the corners and edges of the cooling elements is solved by the cooling plate described in EP 94 115 821, in that its edge areas are provided with bores, the cross section of which is smaller than that of the cooling channels proper. Considered overall, an independent cooling system with its own coolant inlets and outlets is proposed, this system being obtained by the use of vertical and horizontal bores in the edge area. Also provided are the required pipe connectors, which extend through the blast furnace wall.
3a DE 33 13 998 Al discloses a cooling plate for metallurgical furnaces and a method of producing it. This cooling plate consists of a cast material, in which the coolant channels are formed by steel pipes. To provide a cooling element with an unjacketed steel pipe with satisfactory heat transfer, a bore extending from a surface on the narrow side of the casting into the interior of the casting is provided, such that a steel pipe in press connection with the wall of the bore is inserted in the bore. Since it is difficult to insert a pipe with a curved elbow section into a vertical bore, and the relatively large openings at the head and end region of the plates must be sealed with refractory material, it is proposed that the feed and discharge of the coolant be combined on one side of the cooling plate. The steel pipe is constructed as a double-jacket pipe, which is closed by a base at its lower end. The coolant flows through the outer annular region into the cooling element and back through the inner pipe.
The invention is based on the task of creating a cooling element of the basic type in question which offers improved IND 4
\O
O cooling in the end areas, that is, at the edges.
STo accomplish this task, according to the present Sinvention there is provided a cooling element for shaft 00 furnaces, with a channel, which is internally arranged in 5 the cooling element, for coolant flowing in only one direction, leading to which channel at opposite edge Sregions of the cooling element from outside are pipe lengths, which are connected with the cooling element for 00 the feed and discharge of the coolant, characterised in that the channel in a region, which reaches beyond the pipe length and/or the pipe lengthup to the edge of the cooling element, goes over into a U-shaped channel section for coolant flowing forward and back along a guide element.
In contrast to the state of the art, the proposed cooling system is not an independent cooling system with its own pipe connectors which weaken the wall of the blast furnace but rather a modification of the coolant feed system according to which thecooling channels passing through the base body are extended all the way to the edge areas, including the corner areas, if desired.
In the area where the coolant leaves the stave, the cross section of the channel extending through the edge area is comparatively larger and is provided with a (coolant) guide element, so that the coolant, coming from the base body, flows into the edge area, reverses direction, and flows back essentially in the opposite direction to the opening of the pipe. At the end where the coolant enters the stave, the coolant is guided first to the edge area and flows from there into the base body through the cooling channel. It is advantageous here for the cross section of the cooling section to be doubled, so that the actual cross sections of the two parts of the channel in the cooling section which carry the coolant in opposite directions will be the same as that of the main cooling channel in the base body. As a result of this measure, a homogeneous flow velocity is obtained within the cooling N:\Melbourne\Cases\Patent\48OO-4S999\P48975 AU\Specis\P48975.AU Specificaion 2006-12-27doc 28/12/06 IND- 4asystem.
The cooling effect on the edge and corner areas of the stave 00 00 N \Melboume\Cases\Patent\480O-48999\P48975 AU\Specis\P48975 AU Specificaion 2006-I 2-27.doc 28/1 2/06 several profiled sections, the number of endpieces could correspond to the number of profiled sections.
A preferred embodiment of the cooling element according to the invention is described in the following: Figure 1 shows a side view of parts of two cooling elements with endpieces as proposed according to the invention, one element being installed above the other; Figure 2 shows a view of the cooling elements according to Figure 1 from the perspective of the steel jacket around the furnace; Figure 3 shows a side view of parts of two cooling elements according to the state of the art, one installed above the other; and Figure 4 shows a view of the cooling elements according to Figure 3 from the perspective of the steel jacket of the furnace.
Figure 1 shows parts of two staves i, 2. A pipe 3 for the discharge of coolant is connected to the top end of the lower stave i, whereas a pipe 4 for supplying coolant is connected to the bottom end of the upper stave 2. The pipes 3, 4 themselves pass through openings 6, 7 in the furnace wall Each of the staves i, 2 comprises a base body 8 with vertical cooling channels 9. The staves consist of copper or of a low-alloy copper. On the side facing the interior of the furnace, the staves i, 2 are provided with webs and grooves 11 to accept refractory material. An endpiece 12 as proposed by 6
I'
the invention is welded to the top end of the base body 8 of the stave 1. This endpiece has a channel section 13 forming an extension of the associated vertical cooling channel 9 or several channel sections forming extensions of the several cooling channels in the base body, only one of which can be seen in the cross-sectional view shown. The cross section of the channel section 13 is larger than that of the vertical cooling channel 9 and is divided over part of its length by a guide element 14. In the embodiment shown, the guide element 14 forms a direct extension of the side 15 of the channel which can be seen in the base body, the side facing the steel jacket of the furnace.
When castings are used, an appropriate bore is introduced into the separate endpiece at the level of the pipe 3, so that the endpieces can be connected to the pipes passing through the blast furnace wall. When a welded construction is used, the endpiece can be made of several parts, which are then welded together.
The way in which the water flows through the lower stave 1 and its top part 12 is described below and illustrated with the help of arrows. The cooling water is guided through the proposed endpiece 13 in such a way that it first flows up all the way to the very edge of the cooling element. Then, after reversing direction by 1800, it flows a short distance in the direction opposite its original flow direction and then is redirected again, this time by 900, into the pipe 3 and thus passes through the pipe 3 and an elbow (not shown, merely suggested by a broken line) to the pipe 4 of the stave 2 located on top. After the cooling water has flowed through the uppermost stave, it is sent into the coolant circuit of the blast furnace.
The pipes 3, 4 themselves are surrounded by compensators 16, 17, which are necessary to ensure a gas-tight seal of the pipes.
It is evident that optimal cooling of the edge areas of the cooling elements is achieved in spite of the spacing of the pipes 3, 4 necessitated by the compensators 15, 17.
The endpieces are preferably provided with the pipes 3 before said endpieces are installed.
It is not absolutely necessary for both the top and bottom ends of each stave to be replaced with an endpiece according to the invention with its modified water channel. Even if the modified water channel is provided at only one end (as shown here), the cooling capacity is increased in the edge areas of both adjoining staves. It is advantageous for a stave to be provided with a separate endpiece at only one end. Although such an endpiece will be longer than would be the case if two endpieces were used, that is, one at the top and one at the bottom, it offers economic advantages in terms of manufacturing.
Figure 2 shows how the staves are installed on the furnace wall when the staves in question have endpieces only at their top ends. The staves i, 2 shown here are assembled from extruded or rolled sections, which are welded together at the webs extending along their long edges (see the dashed line). As indicated by the dash-dot line of the weld 19, each section is welded at the top end to an endpiece 12 with the water flow system according to the invention. The distance between the water feed pipes and the seam 18 between the two stacked staves 1, 2 is different from that between the water discharge pipes and the seam. The seam is thus not equidistant between the pipes (see Figure 4).
The distances A and A' in Figure 2 are intended to show how, as a result of the water-cooled endpiece 12 with its flow-guiding element 14, the distance between the area through which cooling water flows and the outer edges of the staves is reduced, resulting in an improved cooling action in the corners and edges.
It should be mentioned that an endpiece attached to the top end offers the advantage of providing a fixed point by which the cooling element can be hung in place. Attaching the endpiece to the bottom end of the cooling element, however, offers the advantage of reducing the danger of the formation of air or vapor spaces, the insulating effect of which could interfere with good cooling.
For comparison, Figure 3 shows the water flow system of the previously known staves. The parts of these cooling elements which are the same as those in Figure 1 have been given the same reference numbers. The staves 20, 21 shown here are provided with cast-in pipes 22, 23 as cooling channels, which are guided by means of suitable shield pipes 24, 25 through appropriate openings 6, 7 in the furnace wall 5. The flow of cooling water between the two staves is again indicated by a broken line. It is evident that, in comparison with the cooling elements proposed IND 10 Sin accordance with the invention, much larger edge areas S26, 27 are not cooled, which are therefore subject to Sgreater wear. For comparison with Figure 2, Figure 4 00 shows a view of stacked cooling elements 20, 21 with C 5 vertical cooling channels 22, 23 according to the state of the art. In this previously conventional stave Sarrangement, the seam between two staves arranged vertically one above the other along the furnace wall is 00 basically the same distance away from the two sets of 10 cooling channels and is therefore in the center between Sthe associated edge areas.
It is to be understood that, if any prior art publication is referred to herein, such reference does not constitute an admission that the publication forms a part of the common general knowledge in the art, in Australia or any other country.
N.AMelboume\Cases\Patcnt\48D00-48999\P4897S AU\Specis\P4897SAU Speciication 2006-I2-27doc 28/12/06

Claims (5)

  1. 2. The cooling element according to claim i, characterised in that the edge region inclusive of the respective cooling section with guide element is constructed as at least one separate end member which is fastened to the base body guiding the internal cooling channels.
  2. 3. The cooling element according to claim 2, characterised in that the separate end member is constructed as a cast part or as a welded construction and is welded to the base body.
  3. 4. The cooling element according to one of claims 1 to 3, characterised in that the cross sectional dimension of the channel section in relation to the dimensions of the cooling channel in the base body is twice as large and that the guide element is so arranged that it subdivides the channel section into two cooling channels with corresponding dimensions.
  4. 5. The cooling element according to claim 2 or 3, characterised in that the separate end member is provided on the side of the furnace steel jacket at least with a N:\MclboumeCses\Patent\48OOO-48999\P48975ALJSpecis\P4897SAU Specification 2006-I 2-27doc 28/12106 ND 12 \O bore in which the opening region of the respective pipe o length for the coolant inflow or outflow is introduced and Swelded. 00 c 5 6. The cooling element according to claim 2 or 3, characterised in that it comprises a base body consisting of at least two welded-together, extruded or rolled profile sections, which are each penetrated by at least 00 one cooling channel, as well as a number which corresponds with the number of profile sections, of end members, which are welded at the head end or foot end to the profile members.
  5. 7. A cooling element substantially as herein described with reference to the accompanying drawings. N \MelboumekCases\Patent\48000-4899\P48975.AtASpcis\P4S975AU Specification 2006-12-27.doc 28/12/06
AU2001289934A 2000-10-07 2001-09-28 Cooling element for shaft furnaces Expired - Fee Related AU2001289934B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10049707A DE10049707A1 (en) 2000-10-07 2000-10-07 Cooling element used in blast furnaces comprises a region through which the coolant passes with an arrangement of internal coolant-conveying channels extending via a mouth region of tubular pieces into the edge region of the cooling element
DE10049707.1 2000-10-07
PCT/EP2001/011221 WO2002031211A1 (en) 2000-10-07 2001-09-28 Cooling element for shaft furnaces

Publications (3)

Publication Number Publication Date
AU2001289934A1 AU2001289934A1 (en) 2002-06-27
AU2001289934A2 AU2001289934A2 (en) 2003-06-26
AU2001289934B2 true AU2001289934B2 (en) 2007-02-15

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ID=7659000

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AU8993401A Pending AU8993401A (en) 2000-10-07 2001-09-28 Cooling element for shaft furnaces
AU2001289934A Expired - Fee Related AU2001289934B2 (en) 2000-10-07 2001-09-28 Cooling element for shaft furnaces

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AU8993401A Pending AU8993401A (en) 2000-10-07 2001-09-28 Cooling element for shaft furnaces

Country Status (16)

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US (2) US20040046292A1 (en)
EP (1) EP1322790B1 (en)
JP (1) JP2004511745A (en)
KR (1) KR20030033088A (en)
CN (1) CN1203192C (en)
AT (1) ATE299951T1 (en)
AU (2) AU8993401A (en)
BR (1) BR0114306A (en)
CA (1) CA2423877A1 (en)
DE (2) DE10049707A1 (en)
MX (1) MXPA03003017A (en)
PL (1) PL360691A1 (en)
RU (1) RU2264590C2 (en)
UA (1) UA76433C2 (en)
WO (1) WO2002031211A1 (en)
ZA (1) ZA200302304B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10049707A1 (en) * 2000-10-07 2002-04-11 Sms Demag Ag Cooling element used in blast furnaces comprises a region through which the coolant passes with an arrangement of internal coolant-conveying channels extending via a mouth region of tubular pieces into the edge region of the cooling element
EP1391521A1 (en) * 2002-08-20 2004-02-25 Voest-Alpine Industrieanlagenbau GmbH & Co. Cooling plate for metallurgical furnace
KR100902826B1 (en) * 2002-11-08 2009-06-12 주식회사 포스코 Coolant impression method of blast furnace lower part
EP1469085A1 (en) * 2003-04-14 2004-10-20 Paul Wurth S.A. Cooling plate for a metallurgical vessel
LU91494B1 (en) * 2008-11-04 2010-05-05 Wurth Paul Sa Cooling plate for a metallurgical furnace and its method of manufacturing
KR20130065648A (en) * 2010-03-30 2013-06-19 베리 메탈 컴패니 Apparatus and method for gas tight secondary stave support
DE102012013494A1 (en) * 2012-07-09 2014-01-09 Kme Germany Gmbh & Co. Kg Cooling element for a melting furnace
CN105769830B (en) * 2016-03-30 2019-03-26 陕西科技大学 A kind of cooling emulsion and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2252606A (en) * 1941-05-27 1941-08-12 Falcon Bronze Company Cooling plate for blast furnace inwalls and mantles
US2252605A (en) * 1938-03-02 1941-08-12 Falcon Bronze Company Cooling plate for blast furnace inwalls and mantles
GB2073387A (en) * 1980-04-02 1981-10-14 Touze F Flat cooling plates or boxes for blast furnace walls
DE3313998A1 (en) * 1982-05-25 1983-12-08 Voest-Alpine AG, 4010 Linz Cooling plate for metallurgical furnaces and method for the manufacture thereof
JPH0247211A (en) * 1988-08-10 1990-02-16 Kawasaki Steel Corp Protecting wall of furnace body in blast furnace
US4938456A (en) * 1988-12-12 1990-07-03 Richards Raymond E Metallurgical panel structure

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1564294A (en) * 1978-01-25 1980-04-02 Vni I Proek I Ochistke Tekhnol Plate cooler for shaft furnace
DE3249343C2 (en) * 1982-02-02 1984-09-27 Institut problem lit'ja Akademii Nauk Ukrainskoj SSR, Kiev Process for the production of cooling plates for hut mills and a cooling plate
DE19503912C2 (en) * 1995-02-07 1997-02-06 Gutehoffnungshuette Man Cooling plate for shaft furnaces, especially blast furnaces
DE10049707A1 (en) * 2000-10-07 2002-04-11 Sms Demag Ag Cooling element used in blast furnaces comprises a region through which the coolant passes with an arrangement of internal coolant-conveying channels extending via a mouth region of tubular pieces into the edge region of the cooling element

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2252605A (en) * 1938-03-02 1941-08-12 Falcon Bronze Company Cooling plate for blast furnace inwalls and mantles
US2252606A (en) * 1941-05-27 1941-08-12 Falcon Bronze Company Cooling plate for blast furnace inwalls and mantles
GB2073387A (en) * 1980-04-02 1981-10-14 Touze F Flat cooling plates or boxes for blast furnace walls
DE3313998A1 (en) * 1982-05-25 1983-12-08 Voest-Alpine AG, 4010 Linz Cooling plate for metallurgical furnaces and method for the manufacture thereof
JPH0247211A (en) * 1988-08-10 1990-02-16 Kawasaki Steel Corp Protecting wall of furnace body in blast furnace
US4938456A (en) * 1988-12-12 1990-07-03 Richards Raymond E Metallurgical panel structure

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BR0114306A (en) 2003-10-28
JP2004511745A (en) 2004-04-15
AU8993401A (en) 2002-04-22
PL360691A1 (en) 2004-09-20
ATE299951T1 (en) 2005-08-15
ZA200302304B (en) 2003-08-14
EP1322790A1 (en) 2003-07-02
UA76433C2 (en) 2006-08-15
DE10049707A1 (en) 2002-04-11
MXPA03003017A (en) 2004-01-29
WO2002031211A1 (en) 2002-04-18
CA2423877A1 (en) 2003-03-27
DE50106812D1 (en) 2005-08-25
CN1203192C (en) 2005-05-25
US20070013113A1 (en) 2007-01-18
US20040046292A1 (en) 2004-03-11
RU2264590C2 (en) 2005-11-20
KR20030033088A (en) 2003-04-26
EP1322790B1 (en) 2005-07-20
CN1468318A (en) 2004-01-14

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