AU2001288901A1 - A methanol, olefin, and hydrocarbon synthesis process - Google Patents

A methanol, olefin, and hydrocarbon synthesis process

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Publication number
AU2001288901A1
AU2001288901A1 AU2001288901A AU8890101A AU2001288901A1 AU 2001288901 A1 AU2001288901 A1 AU 2001288901A1 AU 2001288901 A AU2001288901 A AU 2001288901A AU 8890101 A AU8890101 A AU 8890101A AU 2001288901 A1 AU2001288901 A1 AU 2001288901A1
Authority
AU
Australia
Prior art keywords
methanol
hydrocarbon synthesis
synthesis unit
olefin
integrates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001288901A
Other languages
English (en)
Inventor
Gary F Janda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of AU2001288901A1 publication Critical patent/AU2001288901A1/en
Abandoned legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516Multisteps
    • C07C29/1518Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
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    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
AU2001288901A 2000-09-28 2001-09-06 A methanol, olefin, and hydrocarbon synthesis process Abandoned AU2001288901A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/672,470 US6444712B1 (en) 2000-09-28 2000-09-28 Methanol, olefin, and hydrocarbon synthesis process
US09/672,470 2000-09-28
PCT/US2001/028106 WO2002026677A2 (en) 2000-09-28 2001-09-06 A methanol, olefin, and hydrocarbon synthesis process

Publications (1)

Publication Number Publication Date
AU2001288901A1 true AU2001288901A1 (en) 2002-04-08

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AU2001288901A Abandoned AU2001288901A1 (en) 2000-09-28 2001-09-06 A methanol, olefin, and hydrocarbon synthesis process

Country Status (10)

Country Link
US (1) US6444712B1 (zh)
EP (1) EP1328497B1 (zh)
CN (2) CN101028997B (zh)
AT (1) ATE327213T1 (zh)
AU (1) AU2001288901A1 (zh)
CA (1) CA2422844A1 (zh)
DE (1) DE60119954D1 (zh)
MX (1) MXPA03002744A (zh)
NO (1) NO20031381L (zh)
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Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6495609B1 (en) * 2000-11-03 2002-12-17 Exxonmobil Chemical Patents Inc. Carbon dioxide recovery in an ethylene to ethylene oxide production process
DE60336444D1 (de) 2002-09-26 2011-05-05 Haldor Topsoe As Verfahren zur Herstellung von Synthesegas
EP1403217A1 (en) * 2002-09-26 2004-03-31 Haldor Topsoe A/S Process and apparatus for the preparation of synthesis gas
ES2405587T3 (es) * 2002-09-26 2013-05-31 Haldor Topsoe A/S Procedimiento y aparato para la preparación de gas de síntesis
EP1413547A1 (en) * 2002-09-26 2004-04-28 Haldor Topsoe A/S Process for the production of synthesis gas
US7102048B2 (en) * 2002-12-17 2006-09-05 Exxonmobil Chemical Patents Inc. Methanol feed for producing olefin streams
WO2004056731A2 (en) * 2002-12-21 2004-07-08 Haldor Topsøe A/S Process for synthesis of methanol
US7161051B2 (en) * 2002-12-30 2007-01-09 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
US7151198B2 (en) * 2002-12-30 2006-12-19 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
US7144565B2 (en) 2003-07-29 2006-12-05 Headwaters Nanokinetix, Inc. Process for direct catalytic hydrogen peroxide production
US8394863B2 (en) * 2003-08-21 2013-03-12 Pearson Technologies, Inc. Process and apparatus for the production of useful products from carbonaceous feedstock
TW200519073A (en) * 2003-08-21 2005-06-16 Pearson Technologies Inc Process and apparatus for the production of useful products from carbonaceous feedstock
US6846951B1 (en) 2003-10-09 2005-01-25 Acetex (Cyprus) Limited Integrated process for acetic acid and methanol
KR20100131528A (ko) * 2004-01-22 2010-12-15 에이스텍스 (사이프러스) 리미티드 아세트산 및 메탄올을 위한 통합 방법
US7192987B2 (en) * 2004-03-05 2007-03-20 Exxonmobil Chemical Patents Inc. Processes for making methanol streams and uses for the streams
WO2006117499A1 (en) * 2005-05-03 2006-11-09 Quartey-Papafio Alexander H Synthesis gas production process
US7485767B2 (en) * 2005-06-29 2009-02-03 Exxonmobil Chemical Patents Inc. Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids
US7396972B2 (en) * 2005-08-25 2008-07-08 Exxonmobil Chemical Patents Inc. Methanol feed for producing olefin streams
US20070155999A1 (en) * 2005-12-30 2007-07-05 Pujado Peter R Olefin production via oxygenate conversion
US7781490B2 (en) * 2006-05-05 2010-08-24 Exxonmobil Chemical Patents Inc. Process for the production of mixed alcohols
DE102006023248C5 (de) * 2006-05-18 2018-01-25 Air Liquide Global E&C Solutions Germany Gmbh Verfahren und Anlage zur Herstellung von Synthesegas
US7829751B2 (en) * 2006-10-27 2010-11-09 Exxonmobil Chemical Patents, Inc. Processes for converting oxygenates to olefins using aluminosilicate catalysts
EP2121873A2 (en) 2006-12-13 2009-11-25 Haldor Topsoe A/S Process for the synthesis of hydrocarbon constituents of gasoline
US20080260631A1 (en) * 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US20090093555A1 (en) * 2007-07-09 2009-04-09 Range Fuels, Inc. Methods and apparatus for producing syngas
US20090014689A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
US8153027B2 (en) * 2007-07-09 2012-04-10 Range Fuels, Inc. Methods for producing syngas
US8142530B2 (en) * 2007-07-09 2012-03-27 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
US9227895B2 (en) * 2007-07-09 2016-01-05 Albemarle Corporation Methods and apparatus for producing alcohols from syngas
US20090018371A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing alcohols from syngas
WO2009009243A1 (en) * 2007-07-12 2009-01-15 Exxonmobil Chemical Patents Inc. Method for determining a carbon source of a product
US8058497B2 (en) * 2008-03-13 2011-11-15 Exxonmobil Chemical Patents Inc. Reducing deleterious effects of aldehydes in oxygenates to olefins reactions with catalysts containing basic metal oxides
EP2116295A1 (en) * 2008-04-16 2009-11-11 Methanol Casale S.A. Process for producing methanol from steam reforming
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
EP2406545B1 (en) 2008-09-26 2019-05-29 The Ohio State University Conversion of carbonaceous fuels into carbon free energy carriers
CN101550052B (zh) * 2008-11-19 2013-04-03 新奥新能(北京)科技有限公司 含甲烷合成气生产甲醇联产甲烷工艺
WO2010143980A1 (en) * 2009-06-08 2010-12-16 Ignite Energy Resources Nz Limited A process for integration of a methanol plant and an oil hydroprocessing plant
WO2011018233A1 (en) 2009-08-14 2011-02-17 Saudi Basic Industries Corporation (Sabic) Combined reforming process for methanol production
WO2011031752A2 (en) 2009-09-08 2011-03-17 The Ohio State University Research Foundation Synthetic fuels and chemicals production with in-situ co2 capture
EP2499219A2 (en) * 2009-11-10 2012-09-19 Shell Internationale Research Maatschappij B.V. Process for producing olefins
CN103354763B (zh) 2010-11-08 2016-01-13 俄亥俄州立大学 具有反应器之间的气体密封和移动床下导管的循环流化床
US8686206B2 (en) 2010-11-09 2014-04-01 Primus Green Energy Inc. Single loop multistage fuel production
WO2012155054A1 (en) 2011-05-11 2012-11-15 The Ohio State University Systems for converting fuel
EP2707583B1 (en) 2011-05-11 2019-07-10 Ohio State Innovation Foundation Oxygen carrying materials
WO2013013895A1 (en) 2011-07-25 2013-01-31 Haldor Topsøe A/S Process for production of synthesis gas
EP2953892B1 (en) 2013-02-05 2023-04-05 Ohio State Innovation Foundation Methods for fuel conversion
US20150238915A1 (en) 2014-02-27 2015-08-27 Ohio State Innovation Foundation Systems and methods for partial or complete oxidation of fuels
DE102014209635A1 (de) 2014-05-21 2015-11-26 Thyssenkrupp Ag Herstellung von Synthesegas mit zwei autothermen Reformern
JP2017534624A (ja) * 2014-10-27 2017-11-24 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ 水蒸気改質と乾式改質とによるシンガス生成の統合
DE102014016704A1 (de) 2014-11-12 2016-05-12 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung eines oder mehrerer Reaktionsprodukte
US9637433B2 (en) 2014-11-28 2017-05-02 Pioneer Energy, Inc. Systems and methods for manufacture of methanol from natural gas and flare gas feedstock
US9670416B2 (en) 2014-12-10 2017-06-06 Primus Green Energy Inc. Configuration in single-loop synfuel generation
WO2016181265A1 (en) * 2015-05-08 2016-11-17 Sabic Global Technologies B.V. Systems and methods related to olefin production
WO2016181266A1 (en) 2015-05-08 2016-11-17 Sabic Global Technologies B.V. Systems and methods related to syngas to olefin production
US11111143B2 (en) 2016-04-12 2021-09-07 Ohio State Innovation Foundation Chemical looping syngas production from carbonaceous fuels
AR110362A1 (es) * 2016-12-22 2019-03-20 Dow Global Technologies Llc Proceso para convertir gas de síntesis en olefinas usando un catalizador bifuncional de óxido de cromozinc - sapo-34
IL271938B2 (en) 2017-07-25 2024-04-01 Haldor Topsoe As A method for making synthesis gas
WO2019027972A1 (en) 2017-07-31 2019-02-07 Ohio State Innovation Foundation REACTOR SYSTEM WITH UNEQUAL OPERATING PRESSURE OF REACTOR ASSEMBLY
AR113267A1 (es) * 2017-10-10 2020-03-11 Dow Global Technologies Llc Procesos para mejorar la eficiencia en la producción de hidrocarburos
US20190113223A1 (en) * 2017-10-18 2019-04-18 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude METHOD FOR MINIMIZING NOx EMISSIONS DURING POX BASED SYNGAS PLANT STARTUP
US10549236B2 (en) 2018-01-29 2020-02-04 Ohio State Innovation Foundation Systems, methods and materials for NOx decomposition with metal oxide materials
WO2020033500A1 (en) 2018-08-09 2020-02-13 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
AU2020271068A1 (en) 2019-04-09 2021-09-30 Ohio State Innovation Foundation Alkene generation using metal sulfide particles
JP2023549531A (ja) * 2020-11-14 2023-11-27 ゾーンフロー リアクター テクノロジーズ リミテッド ライアビリティ カンパニー グリーンメタノールの製造
US11578016B1 (en) 2021-08-12 2023-02-14 Saudi Arabian Oil Company Olefin production via dry reforming and olefin synthesis in a vessel
US11718575B2 (en) 2021-08-12 2023-08-08 Saudi Arabian Oil Company Methanol production via dry reforming and methanol synthesis in a vessel
US11787759B2 (en) 2021-08-12 2023-10-17 Saudi Arabian Oil Company Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel
US11617981B1 (en) 2022-01-03 2023-04-04 Saudi Arabian Oil Company Method for capturing CO2 with assisted vapor compression

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076698A (en) 1956-03-01 1978-02-28 E. I. Du Pont De Nemours And Company Hydrocarbon interpolymer compositions
NZ126521A (zh) 1959-06-06
US3305538A (en) 1961-11-22 1967-02-21 Montedison Spa Polymerization process
US3364190A (en) 1964-04-27 1968-01-16 Standard Oil Co Process for polymerizing propylene to syndiotactic polypropylene
US3450777A (en) 1964-09-29 1969-06-17 Tokuyama Soda Kk Process for preparing alcohols by hydration of olefins
US3452106A (en) 1965-05-27 1969-06-24 Japan Gasoline Process for manufacturing alcohol by direct catalytic hydration of olefins
CA849081A (en) 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
JPS4936203B1 (zh) 1969-05-08 1974-09-28
US3888896A (en) 1973-05-29 1975-06-10 Chem Systems Methanol production
CA1086426A (en) 1975-10-13 1980-09-23 Shunji Minami Analog voltage memory device
US4031123A (en) 1975-11-21 1977-06-21 Chem Systems Inc. Methanol production in a paraffinic medium
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4243691A (en) 1979-05-18 1981-01-06 The Procter & Gamble Company Sodium-free salt substitute
DE3160327D1 (en) 1980-02-12 1983-07-07 Chem Systems Method for making methanol
US4310440A (en) 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
NL8006751A (nl) 1980-12-12 1982-07-01 Shell Int Research Werkwijze voor de bereiding van zuurstofhoudende organische verbindingen en paraffinische koolwaterstoffen.
US4833171A (en) * 1981-01-27 1989-05-23 Sweeney Maxwell P Synthesis gas system
EP0096996B1 (en) 1982-06-15 1988-06-22 Mobil Oil Corporation Process for the conversion of alcohols into petrochemicals
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4499327A (en) 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
US4677243A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4677242A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
DE3521304A1 (de) * 1985-06-13 1986-12-18 Linde Ag, 6200 Wiesbaden Verfahren zur erzeugung eines synthesegases
US4659685A (en) 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
US4752651A (en) 1986-06-16 1988-06-21 Union Carbide Corporation Production of light olefins
US4861938A (en) 1987-07-07 1989-08-29 Uop Chemical conversion process
US4861743A (en) 1987-11-25 1989-08-29 Uop Process for the production of molecular sieves
FR2645141B1 (fr) 1989-03-31 1992-05-29 Elf France Procede de synthese de precurseurs de tamis moleculaires du type silicoaluminophosphate, precurseurs obtenus et leur application a l'obtention desdits tamis moleculaires
US5177114A (en) 1990-04-11 1993-01-05 Starchem Inc. Process for recovering natural gas in the form of a normally liquid carbon containing compound
US5095163A (en) 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5191141A (en) 1991-11-13 1993-03-02 Uop Process for converting methanol to olefins using an improved metal aluminophosphate catalyst
US5126308A (en) 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
EP0642485B1 (en) 1992-05-27 1996-08-14 Exxon Chemical Patents Inc. Production of high purity olefins
JP2724420B2 (ja) * 1992-05-27 1998-03-09 エクソン・ケミカル・パテンツ・インク 酸素化物の転化における酸抽出されたモレキュラーシーブ触媒の使用
IT1272532B (it) * 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
US5714662A (en) 1995-08-10 1998-02-03 Uop Process for producing light olefins from crude methanol
US5990369A (en) * 1995-08-10 1999-11-23 Uop Llc Process for producing light olefins
US5952538A (en) 1996-12-31 1999-09-14 Exxon Chemical Patents Inc. Use of short contact time in oxygenate conversion
US5907076A (en) 1996-12-31 1999-05-25 Exxon Chemical Patents Inc. Process for selectively separating hydrogen, or both hydrogen and carbon monoxide from olefinic hydrocarbons
US6069288A (en) 1996-12-31 2000-05-30 Exxon Chemical Patents Inc. Process for selectively separating hydrogen, or both hydrogen and carbon monoxide from olefinic hydrocarbons
US5904880A (en) 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)
US5927063A (en) 1997-08-19 1999-07-27 Exxon Chemical Patents Inc. High efficiency reformed methanol gas turbine power plants
US5892079A (en) 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6147126A (en) 1998-02-10 2000-11-14 Exxon Research And Engineering Company Gas conversion using hydrogen from syngas gas and hydroconversion tail gas
US6156809A (en) * 1999-04-21 2000-12-05 Reema International Corp. Multiple reactor system and method for fischer-tropsch synthesis

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CA2422844A1 (en) 2002-04-04
EP1328497B1 (en) 2006-05-24
NO20031381L (no) 2003-05-16
MXPA03002744A (es) 2004-01-26
US6444712B1 (en) 2002-09-03
DE60119954D1 (de) 2006-06-29
EP1328497A2 (en) 2003-07-23
ATE327213T1 (de) 2006-06-15
CN1561320A (zh) 2005-01-05
CN101028997A (zh) 2007-09-05
NO20031381D0 (no) 2003-03-26
CN101028997B (zh) 2010-12-15
CN1250500C (zh) 2006-04-12

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