ATE470461T1 - Verfahren zum schmieren von injektionsnadeln mit strahlenhärtbarem silikonmaterial - Google Patents
Verfahren zum schmieren von injektionsnadeln mit strahlenhärtbarem silikonmaterialInfo
- Publication number
- ATE470461T1 ATE470461T1 AT03766000T AT03766000T ATE470461T1 AT E470461 T1 ATE470461 T1 AT E470461T1 AT 03766000 T AT03766000 T AT 03766000T AT 03766000 T AT03766000 T AT 03766000T AT E470461 T1 ATE470461 T1 AT E470461T1
- Authority
- AT
- Austria
- Prior art keywords
- cure
- lubrication
- lubricants
- silicone material
- prior
- Prior art date
Links
- 229920001296 polysiloxane Polymers 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000002347 injection Methods 0.000 title 1
- 239000007924 injection Substances 0.000 title 1
- 238000005461 lubrication Methods 0.000 title 1
- 230000005855 radiation Effects 0.000 title 1
- 239000000314 lubricant Substances 0.000 abstract 5
- 239000004593 Epoxy Substances 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000010894 electron beam technology Methods 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/10—Macromolecular materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/04—Surgical instruments, devices or methods, e.g. tourniquets for suturing wounds; Holders or packages for needles or suture materials
- A61B17/06—Needles ; Sutures; Needle-suture combinations; Holders or packages for needles or suture materials
- A61B17/06066—Needles, e.g. needle tip configurations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/32—Surgical cutting instruments
- A61B17/3209—Incision instruments
- A61B17/3211—Surgical scalpels, knives; Accessories therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Heart & Thoracic Surgery (AREA)
- Animal Behavior & Ethology (AREA)
- Vascular Medicine (AREA)
- Epidemiology (AREA)
- Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Anesthesiology (AREA)
- Biomedical Technology (AREA)
- Hematology (AREA)
- Materials For Medical Uses (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Lubricants (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39818602P | 2002-07-24 | 2002-07-24 | |
PCT/US2003/023136 WO2004009146A1 (en) | 2002-07-24 | 2003-07-24 | Medical device lubricant comprising radiation curable silicon material |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE470461T1 true ATE470461T1 (de) | 2010-06-15 |
Family
ID=30771197
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT03766000T ATE470461T1 (de) | 2002-07-24 | 2003-07-24 | Verfahren zum schmieren von injektionsnadeln mit strahlenhärtbarem silikonmaterial |
Country Status (10)
Country | Link |
---|---|
US (1) | US7354628B2 (de) |
EP (1) | EP1553992B1 (de) |
JP (1) | JP4947898B2 (de) |
KR (1) | KR101057921B1 (de) |
CN (1) | CN100337697C (de) |
AT (1) | ATE470461T1 (de) |
AU (1) | AU2003256746B2 (de) |
CA (1) | CA2493813C (de) |
DE (1) | DE60332949D1 (de) |
WO (1) | WO2004009146A1 (de) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070060952A1 (en) * | 2005-09-02 | 2007-03-15 | Roby Mark S | Surgical stapling device with coated knife blade |
US7332227B2 (en) * | 2003-03-14 | 2008-02-19 | Becton, Dickinson And Company | Non-volatile lubricant system for medical devices |
GB0402838D0 (en) * | 2004-02-10 | 2004-03-17 | Univ Belfast | Method |
US20060153892A1 (en) * | 2005-01-10 | 2006-07-13 | Porter David S | Protein-resistant articles |
US20100184940A1 (en) * | 2005-03-02 | 2010-07-22 | Eastman Chemical Company | Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof |
US7951900B2 (en) | 2005-06-17 | 2011-05-31 | Eastman Chemical Company | Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
US7704605B2 (en) | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
US20110144266A1 (en) * | 2005-06-17 | 2011-06-16 | Eastman Chemical Company | Thermoplastic Articles Comprising Cyclobutanediol Having a Decorative Material Embedded Therein |
US8586701B2 (en) * | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
CA2625842A1 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
US8193302B2 (en) | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
US20070100122A1 (en) * | 2005-10-28 | 2007-05-03 | Crawford Emmett D | Polyester compositions containing cyclobutanediol and articles made therefrom |
US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
US7737246B2 (en) | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
US20070142511A1 (en) * | 2005-12-15 | 2007-06-21 | Crawford Emmett D | Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
US7914841B2 (en) * | 2006-02-09 | 2011-03-29 | Cook Medical Technologies Llc | Inline application of coatings |
US20100300918A1 (en) * | 2006-03-28 | 2010-12-02 | Eastman Chemical Company | Bottles comprising polyester compositions which comprise cyclobutanediol |
US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
US7943242B2 (en) | 2006-03-30 | 2011-05-17 | Becton, Dickinson And Company | Sealing members, articles using the same and methods of reducing sticktion |
US8075995B2 (en) | 2006-03-30 | 2011-12-13 | Becton, Dickinson And Company | Coating system, articles and assembly using the same and methods of reducing sticktion |
US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
KR101790591B1 (ko) | 2007-11-21 | 2017-10-26 | 이스트만 케미칼 컴파니 | 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법 |
US20110076712A1 (en) * | 2008-06-13 | 2011-03-31 | Xy, Llc. | Lubricious microfludic flow path system |
US8198371B2 (en) | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
US20100099828A1 (en) * | 2008-10-21 | 2010-04-22 | Eastman Chemical Company | Clear Binary Blends of Aliphatic Polyesters and Aliphatic-Aromatic Polyesters |
US8895654B2 (en) | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
US20100159176A1 (en) * | 2008-12-18 | 2010-06-24 | Eastman Chemical Company | Miscible blends of terephthalate polyesters containing 1,4-cyclohexanedimethanol and 2,2,4,4-tetramethylcyclobutane-1,3-diol |
US9221075B2 (en) * | 2009-11-09 | 2015-12-29 | Ethicon, Inc. | Surgical needle coatings and methods |
US9332982B2 (en) * | 2009-11-09 | 2016-05-10 | Ethicon, Llc | Surgical needle coatings and methods |
US9259219B2 (en) | 2009-11-09 | 2016-02-16 | Ethicon, Llc | Surgical needle coatings and methods |
US8802603B2 (en) | 2010-06-17 | 2014-08-12 | Becton, Dickinson And Company | Medical components having coated surfaces exhibiting low friction and low reactivity |
US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8757087B2 (en) | 2011-05-24 | 2014-06-24 | Nordson Corporation | Device and method for coating elongate objects |
US9434857B2 (en) | 2011-11-15 | 2016-09-06 | Ethicon, Inc. | Rapid cure silicone lubricious coatings |
US20130217830A1 (en) | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
KR20150003395A (ko) | 2012-05-07 | 2015-01-08 | 벡톤 디킨슨 프랑스 | 의료 용기용 윤활제 코팅 |
JP6195413B2 (ja) * | 2014-03-05 | 2017-09-13 | 信越化学工業株式会社 | 放射線硬化性シリコーン組成物 |
US10308771B2 (en) | 2016-08-31 | 2019-06-04 | Ppg Industries Ohio, Inc. | Coating compositions and coatings for adjusting friction |
US10465094B2 (en) * | 2016-12-08 | 2019-11-05 | Ethicon, Inc. | Method of applying rapid cure silicone lubricious coatings |
US11197666B2 (en) | 2017-09-15 | 2021-12-14 | Cilag Gmbh International | Surgical coated needles |
CN108853607A (zh) * | 2018-09-28 | 2018-11-23 | 广州市爱创医疗科技有限公司 | 一种胰岛素针表面硅化处理剂 |
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US3975350A (en) * | 1972-08-02 | 1976-08-17 | Princeton Polymer Laboratories, Incorporated | Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles |
CS169274B1 (de) * | 1974-03-29 | 1976-07-29 | ||
US3939049A (en) * | 1974-04-10 | 1976-02-17 | The United States Of America As Represented By The United States Energy Research And Development Administration | Process for radiation grafting hydrogels onto organic polymeric substrates |
US4100309A (en) * | 1977-08-08 | 1978-07-11 | Biosearch Medical Products, Inc. | Coated substrate having a low coefficient of friction hydrophilic coating and a method of making the same |
US4119094A (en) * | 1977-08-08 | 1978-10-10 | Biosearch Medical Products Inc. | Coated substrate having a low coefficient of friction hydrophilic coating and a method of making the same |
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US4467073A (en) * | 1982-10-20 | 1984-08-21 | Hydromer, Inc. | Transparent anti-fog coating compositions |
US4720521A (en) * | 1985-12-03 | 1988-01-19 | Becton, Dickinson And Company | Film-forming silicone compositions having lubricating properties |
US4806430A (en) * | 1985-12-03 | 1989-02-21 | Becton, Dickinson And Company | Film-forming silicone compositions having lubricating properties |
US5091205A (en) * | 1989-01-17 | 1992-02-25 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrophilic lubricious coatings |
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CA2055861A1 (en) * | 1991-01-07 | 1992-07-08 | Richard N. Granger | Siliconized surgical needle and method for its manufacture |
US5260348A (en) * | 1992-01-31 | 1993-11-09 | General Electric Company | Silicone compositions which exhibit enhanced cure characteristics |
TW268969B (de) * | 1992-10-02 | 1996-01-21 | Minnesota Mining & Mfg | |
EP0627474B1 (de) * | 1993-05-13 | 2000-10-25 | American Cyanamid Company | Wässrige Siloxan-Beschichtungs-Zusammensetzung |
JP3339946B2 (ja) * | 1993-12-24 | 2002-10-28 | ジーイー東芝シリコーン株式会社 | 注射針 |
US5650453A (en) * | 1995-04-28 | 1997-07-22 | General Electric Company | UV curable epoxysilicone blend compositions |
JP3303288B2 (ja) * | 1997-05-12 | 2002-07-15 | ニプロ株式会社 | 穿刺針 |
DE19722880C1 (de) * | 1997-05-24 | 1998-11-19 | Ethicon Gmbh | Verfahren zum Beschichten von chirurgischen Nadeln |
US5911711A (en) * | 1998-06-29 | 1999-06-15 | Becton, Dickinson And Company | Lubricant system for hypodermic needles and method for its application |
DE19832026A1 (de) * | 1998-07-16 | 2000-01-27 | Wacker Chemie Gmbh | Strahlungshärtende, Copolymere enthaltende Zusammensetzungen |
US6022050A (en) * | 1998-09-02 | 2000-02-08 | Monarch Marking Systems, Inc. | Silicone release coating composition |
EP1004612A1 (de) | 1998-11-25 | 2000-05-31 | Dow Corning Corporation | Vinylether-funktionelle Organopolysiloxane und ihre Verwendung in strahlenhärtbaren Siliconzusammensetzungen |
GB9902823D0 (en) * | 1998-12-23 | 1999-03-31 | Dow Corning Sa | Biocompatible coatings |
US6344520B1 (en) * | 1999-06-24 | 2002-02-05 | Wacker Silicones Corporation | Addition-crosslinkable epoxy-functional organopolysiloxane polymer and coating compositions |
US6187834B1 (en) | 1999-09-08 | 2001-02-13 | Dow Corning Corporation | Radiation curable silicone compositions |
JP4144019B2 (ja) * | 2000-01-07 | 2008-09-03 | ニプロ株式会社 | 穿刺針 |
US6486267B1 (en) * | 2000-08-03 | 2002-11-26 | Avery Dennison Corporation | Release composition |
FR2816951B1 (fr) * | 2000-11-21 | 2003-01-10 | Rhodia Chimie Sa | Compositions a base de silicones fonctionnalisees durcissables sous irradiation et revetements anti-adherents obtenus a partir de ces compositions |
US6787490B2 (en) * | 2001-12-26 | 2004-09-07 | Kimberly-Clark Worldwide, Inc. | Glove donning delivery system |
US7332227B2 (en) * | 2003-03-14 | 2008-02-19 | Becton, Dickinson And Company | Non-volatile lubricant system for medical devices |
-
2003
- 2003-07-24 AU AU2003256746A patent/AU2003256746B2/en not_active Expired
- 2003-07-24 DE DE60332949T patent/DE60332949D1/de not_active Expired - Lifetime
- 2003-07-24 KR KR1020057001323A patent/KR101057921B1/ko active IP Right Grant
- 2003-07-24 AT AT03766000T patent/ATE470461T1/de not_active IP Right Cessation
- 2003-07-24 CN CNB038228246A patent/CN100337697C/zh not_active Expired - Lifetime
- 2003-07-24 JP JP2004523377A patent/JP4947898B2/ja not_active Expired - Fee Related
- 2003-07-24 EP EP03766000A patent/EP1553992B1/de not_active Expired - Lifetime
- 2003-07-24 WO PCT/US2003/023136 patent/WO2004009146A1/en active Application Filing
- 2003-07-24 US US10/521,937 patent/US7354628B2/en not_active Expired - Lifetime
- 2003-07-24 CA CA2493813A patent/CA2493813C/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN100337697C (zh) | 2007-09-19 |
KR20050062515A (ko) | 2005-06-23 |
CN1684726A (zh) | 2005-10-19 |
CA2493813A1 (en) | 2004-01-29 |
EP1553992A1 (de) | 2005-07-20 |
AU2003256746B2 (en) | 2008-08-14 |
US7354628B2 (en) | 2008-04-08 |
JP4947898B2 (ja) | 2012-06-06 |
EP1553992B1 (de) | 2010-06-09 |
US20050203201A1 (en) | 2005-09-15 |
DE60332949D1 (de) | 2010-07-22 |
AU2003256746A1 (en) | 2004-02-09 |
JP2005533569A (ja) | 2005-11-10 |
KR101057921B1 (ko) | 2011-08-19 |
WO2004009146A1 (en) | 2004-01-29 |
CA2493813C (en) | 2010-11-23 |
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