ATE366240T1 - Imidazolidinonen-saureadditionssalze als reaktionskatalysatoren - Google Patents

Imidazolidinonen-saureadditionssalze als reaktionskatalysatoren

Info

Publication number
ATE366240T1
ATE366240T1 AT01942621T AT01942621T ATE366240T1 AT E366240 T1 ATE366240 T1 AT E366240T1 AT 01942621 T AT01942621 T AT 01942621T AT 01942621 T AT01942621 T AT 01942621T AT E366240 T1 ATE366240 T1 AT E366240T1
Authority
AT
Austria
Prior art keywords
acid addition
addition salts
beta
alpha
chiral
Prior art date
Application number
AT01942621T
Other languages
English (en)
Inventor
David Macmillan
Kateri Ahrendt
Original Assignee
Univ California
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/484,082 external-priority patent/US6369243B1/en
Application filed by Univ California filed Critical Univ California
Application granted granted Critical
Publication of ATE366240T1 publication Critical patent/ATE366240T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B01J31/0247—Imides, amides or imidates (R-C=NR(OR))
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/10—Cyclisation
    • C07B37/12—Diels-Alder reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/69—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/326—Diels-Alder or other [4+2] cycloadditions, e.g. hetero-analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/44—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing eight carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
AT01942621T 2000-01-18 2001-01-18 Imidazolidinonen-saureadditionssalze als reaktionskatalysatoren ATE366240T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/484,082 US6369243B1 (en) 2000-01-18 2000-01-18 Chemical transformation of substrates using nonmetallic, organic catalyst compositions
US09/547,958 US6307057B1 (en) 2000-01-18 2000-04-12 Acid addition salts of imidazolidinones as reaction catalysts

Publications (1)

Publication Number Publication Date
ATE366240T1 true ATE366240T1 (de) 2007-07-15

Family

ID=27047852

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01942621T ATE366240T1 (de) 2000-01-18 2001-01-18 Imidazolidinonen-saureadditionssalze als reaktionskatalysatoren

Country Status (8)

Country Link
US (2) US6534434B2 (de)
EP (1) EP1263735B1 (de)
JP (1) JP2003520274A (de)
AT (1) ATE366240T1 (de)
AU (2) AU2001229670B2 (de)
CA (1) CA2397644A1 (de)
DE (1) DE60129211T2 (de)
WO (1) WO2001053269A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6770074B2 (en) * 1988-06-13 2004-08-03 Gary Karlin Michelson Apparatus for use in inserting spinal implants
NL1021362C2 (nl) * 2001-08-31 2003-08-05 Inst Francais Du Petrole Katalysator- en oplosmiddelsamenstelling en katalysewerkwijzen waarbij deze samenstelling wordt toegepast.
AU2003289000A1 (en) * 2002-12-19 2004-07-14 Semiconductor Energy Laboratory Co., Ltd. Organometal complex, electroluminescent element containing the organometal complex and luminescent device including the electroluminescent element
ITMI20041211A1 (it) * 2004-06-16 2004-09-16 Endura Spa Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo
US7323604B2 (en) * 2004-11-19 2008-01-29 California Institute Of Technology Hydride reduction of α,β-unsaturated carbonyl compounds using chiral organic catalysts
US7265249B2 (en) * 2005-01-18 2007-09-04 California Institute Of Technology Enantioselective alpha-fluorination of aldehydes using chiral organic catalysts
WO2007084075A1 (en) * 2006-01-19 2007-07-26 Agency For Science, Technology And Research Heterogeneous chiral catalyst
EP2179080A4 (de) * 2007-07-24 2015-04-15 Univ Princeton Organokaskadenkatalysatoren: eintopfherstellung von chemischen bibliotheken
US8187468B2 (en) * 2008-09-17 2012-05-29 University Of Texas At El Paso Preparation and use of chiral zeolites for liquid chromatography

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2437211A1 (fr) * 1978-08-31 1980-04-25 Bristol Myers Co Application pharmacologique d'un adduct de l'acetone et de l'ester methoxymethylique de l'amoxicilline
JPS574930A (en) 1980-05-02 1982-01-11 Nippon Soda Co Ltd Synthesis of alpha,beta-unsaturated ketone
US4324884A (en) 1980-09-25 1982-04-13 General Electric Company Organic amine catalyzed method for making polyetherimide
IT1222367B (it) * 1985-06-21 1990-09-05 Isf Spa Amminoacil derivati di 4(5)-imidazolodinoni adattivita' nootropica:loro preparazione ed uso farmaceutico
JPH0769609B2 (ja) 1987-02-09 1995-07-31 日本電信電話株式会社 感光性樹脂組成物
DE3821197A1 (de) 1988-06-23 1989-12-28 Basf Ag Verfahren zur herstellung von (alpha),(beta)-ungesaettigten ketonen
NL9001786A (nl) 1990-08-08 1992-03-02 Stamicarbon Werkwijze voor de bereiding van gesubstitueerde pyridines via 1-aza-1,3-butadienen en de tussenprodukten 1-aza-1,3-butadienen.
FR2757850B1 (fr) * 1996-12-27 1999-04-16 Inst Francais Du Petrole Procede ameliore pour la condensation dienique dite reaction de diels-alder
WO1999002510A1 (en) * 1997-07-10 1999-01-21 Pharmacia & Upjohn S.P.A. Matrix metalloproteinase inhibitors
GB9805107D0 (en) 1998-03-10 1998-05-06 Bp Chem Int Ltd Catalyst and use therof

Also Published As

Publication number Publication date
EP1263735B1 (de) 2007-07-04
WO2001053269A1 (en) 2001-07-26
EP1263735A1 (de) 2002-12-11
US20020016473A1 (en) 2002-02-07
DE60129211T2 (de) 2008-04-03
US6534434B2 (en) 2003-03-18
DE60129211D1 (de) 2007-08-16
US20020013475A1 (en) 2002-01-31
AU2001229670B2 (en) 2005-04-07
CA2397644A1 (en) 2001-07-26
JP2003520274A (ja) 2003-07-02
AU2967001A (en) 2001-07-31
US6515137B2 (en) 2003-02-04

Similar Documents

Publication Publication Date Title
Zhang et al. Enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by Ti (BINOL) complex
North et al. Lewis acid catalyzed asymmetric cyanohydrin synthesis
Gröger The development of new monometallic bifunctional catalysts with Lewis acid and Lewis base properties, and their application in asymmetric cyanation reactions
Sigman et al. The renaissance of palladium (II)-catalyzed oxidation chemistry
Tsogoeva Recent advances in asymmetric organocatalytic 1, 4‐conjugate additions
Zhang et al. Enantioselective epoxidation of allylic alcohols by a chiral complex of vanadium: an effective controller system and a rational mechanistic model
Ahmed et al. Frontiers in catalytic nitrile hydration: Nitrile and cyanohydrin hydration catalyzed by homogeneous organometallic complexes
Ishikawa et al. Modified guanidines as chiral superbases: application to asymmetric Michael reaction of glycine imine with acrylate or its related compounds
Sundén et al. Novel organic catalysts for the direct enantioselective α-oxidation of carbonyl compounds
Liu et al. Highly efficient and recyclable heterogeneous asymmetric transfer hydrogenation of ketones in water
ATE366240T1 (de) Imidazolidinonen-saureadditionssalze als reaktionskatalysatoren
DE60116295D1 (de) Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren
DK1165580T3 (da) Katalytisk fremgangsmåde til modifikation af carbohydrater, alkoholer, aldehyder eller polyhydroxyforbindelser
Tomooka et al. Enantioselective [1, 2] Wittig rearrangement using an external chiral ligand
CN101116828B (zh) 手性吡啶双噁唑啉催化剂及制备方法和应用
Groth et al. Diastereoselective Ce (OiPr) 3‐Catalyzed Pinacol Couplings of Aldehydes
ATE146790T1 (de) Enantioselektive katalysatoren aus oxazaborolidin
Kavanagh et al. Urea derivatives are highly active catalysts for the base-mediated generation of terminal epoxides from aldehydes and trimethylsulfonium iodide
TWI396678B (zh) 二級醇製備方法
Bang et al. Sonochemical Reformatsky reaction using indium
CN101748160B (zh) 地衣芽孢杆菌碱性蛋白酶作为不对称直接Aldol反应催化剂的应用
Bolm et al. Hyperbranched chiral catalysts for the asymmetric reduction of ketones with borane
Baird et al. Asymmetric synthesis of epoxides using chiral sulfimides
Daghmoum et al. Merging Au (I)-Catalysis and Biocatalysis: Practical and Scalable Synthesis of Chiral Amino Building Blocks from Alkynes
CN102584511A (zh) 二级醇制备方法

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties