ATE321791T1 - Verfahren zur verabreichung von katalysatoren für popylenpolymerisation - Google Patents

Verfahren zur verabreichung von katalysatoren für popylenpolymerisation

Info

Publication number
ATE321791T1
ATE321791T1 AT03752514T AT03752514T ATE321791T1 AT E321791 T1 ATE321791 T1 AT E321791T1 AT 03752514 T AT03752514 T AT 03752514T AT 03752514 T AT03752514 T AT 03752514T AT E321791 T1 ATE321791 T1 AT E321791T1
Authority
AT
Austria
Prior art keywords
polymerization
catalyst
popylene
catalysts
administration
Prior art date
Application number
AT03752514T
Other languages
English (en)
Inventor
Lawrence C Smith
James C Vizzini
Ted A Powell
Terry J Burkhardt
Anthony N Speca
Shiaw Ju
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32093991&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE321791(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE321791T1 publication Critical patent/ATE321791T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/0035—Periodical feeding or evacuation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/919—Catalyst injection technique in addition polymerization processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT03752514T 2002-10-09 2003-09-22 Verfahren zur verabreichung von katalysatoren für popylenpolymerisation ATE321791T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41725402P 2002-10-09 2002-10-09

Publications (1)

Publication Number Publication Date
ATE321791T1 true ATE321791T1 (de) 2006-04-15

Family

ID=32093991

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03752514T ATE321791T1 (de) 2002-10-09 2003-09-22 Verfahren zur verabreichung von katalysatoren für popylenpolymerisation

Country Status (6)

Country Link
US (2) US7232868B2 (de)
EP (1) EP1556422B1 (de)
AT (1) ATE321791T1 (de)
AU (1) AU2003270801A1 (de)
DE (1) DE60304342T2 (de)
WO (1) WO2004033506A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2749835C (en) 2011-08-23 2018-08-21 Nova Chemicals Corporation Feeding highly active phosphinimine catalysts to a gas phase reactor
DE102011112862A1 (de) 2011-09-07 2013-03-07 Volkswagen Aktiengesellschaft Brennkraftmaschine, Maskierungsmodul und Strömungskörper
US10544246B2 (en) 2016-08-10 2020-01-28 Exxonmobil Chemical Patents Inc. Methods for supplying solid catalysts to a solution polymerization reactor
SG10202102810RA (en) * 2016-08-10 2021-05-28 Exxonmobil Chemical Patents Inc Methods for supplying solid catalysts to a solution polymerization reactor

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2508744A (en) * 1947-12-30 1950-05-23 Standard Oil Dev Co Propylene polymerization
US2852501A (en) * 1954-10-05 1958-09-16 Monsanto Chemicals Polymerization of ethylene
BE552401A (de) * 1955-11-08
US2917465A (en) * 1956-04-27 1959-12-15 Phillips Petroleum Co Polymerization catalyst feed control
US2956995A (en) * 1956-06-28 1960-10-18 Nat Distillers Chem Corp Continuous process for the production of aliphatic monoolefin polymers
US3004086A (en) * 1956-08-27 1961-10-10 Phillips Petroleum Co Method and apparatus for providing a solids slurry
US3257363A (en) * 1961-05-22 1966-06-21 Phillips Petroleum Co Control of the composition of a reaction mixture
AT255852B (de) 1963-01-11 1967-07-25 Julius Dopslaff Einstellventil
US3440238A (en) * 1965-09-08 1969-04-22 Mobil Oil Corp Polymerization of olefins in a gravitating bed
US3687920A (en) * 1971-01-25 1972-08-29 Union Carbide Corp Polymerization of olefins with silane modified catalyst system
US3726845A (en) * 1971-03-22 1973-04-10 Exxon Research Engineering Co Supplying catalyst to a reaction zone
US3779712A (en) * 1971-11-26 1973-12-18 Union Carbide Corp Particulate solids injector apparatus
US4011383A (en) * 1974-05-20 1977-03-08 E. I. Du Pont De Nemours And Company Tetra(neophyl) zirconium and its use in process for the polymerization of olefins
US4123601A (en) * 1977-04-20 1978-10-31 Gulf Oil Corporation Catalyst feeding apparatus
US4232138A (en) * 1977-12-19 1980-11-04 Standard Oil Company (Indiana) Olefin polymerization catalyst
US4268017A (en) * 1979-12-28 1981-05-19 Exxon Research & Engineering Co. Reactor with extractable feed nozzle
US5326855A (en) * 1983-10-06 1994-07-05 Henry Kahn Process for the manufacture of elastomers in particulate form
US4610574A (en) * 1984-05-30 1986-09-09 Amoco Corporation Catalyst feeding system
US4585644A (en) * 1984-06-04 1986-04-29 Phillips Petroleum Company Changing oil tubes in a carbon black reactor
WO1989000584A1 (en) * 1987-07-10 1989-01-26 Quantum Chemical Corporation Propylene polymerization catalyst and method
GB9103527D0 (en) * 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
GB2274110B (en) 1992-11-30 1996-12-18 Sumitomo Chemical Co Polymerization apparatus and powder catalyst supply therein
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
US5643846A (en) 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
NZ264288A (en) 1993-09-30 1996-08-27 Boc Group Inc Preparation of ethylene and propylene polymers from mixtures of ethylene/ethane and propylene/propane, respectively, with either pre-polymerisation or post-polmerisation adsorption of the unsaturated component and recycling of at least part of the unreacted monomer
US6239058B1 (en) * 1995-07-18 2001-05-29 Fina Technology, Inc. Process for activating a metallocene catalyst supported on silica
FR2741549B1 (fr) 1995-11-29 1998-01-02 Bp Chemicals Snc Procede d'introduction d'un catalyseur dans un reacteur de polymerisation d'olefine en phase gazeuse
US6583227B2 (en) * 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US5968864A (en) 1996-12-20 1999-10-19 Fina Technology, Inc. Catalyst efficiency for supported metallocene catalyst
US6245868B1 (en) * 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US6051631A (en) * 1998-06-10 2000-04-18 Phillips Petroleum Company Process for treating fluid streams
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
CA2338603C (en) * 1998-08-26 2008-11-18 Exxon Chemical Patents, Inc. Highly active supported catalyst compositions
US6346584B1 (en) * 1999-09-09 2002-02-12 Univation Technologies, Llc Catalyst modifiers and their use in the polymerization of olefins(s)
US6150478A (en) * 1999-06-04 2000-11-21 Union Carbide Chemicals & Plastics Technology Corporation Ultrasonic catalyst feed for fluid bed olefin polymerization
US6617405B1 (en) 1999-07-14 2003-09-09 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of polyethylene
US6319995B2 (en) * 1999-08-30 2001-11-20 Equistar Chemicals, Lp Method of feeding dry catalyst to a polymerization reactor
US6426394B1 (en) * 1999-12-10 2002-07-30 Union Carbide Chemicals & Plastics Technology Corporation Method of polymerizing olefins using unsupported catalyst compositions
US6660812B2 (en) 2000-07-13 2003-12-09 Exxonmobil Chemical Patents Inc. Production of olefin derivatives
IL156172A0 (en) 2000-12-04 2003-12-23 Univation Tech Llc Polymerization process

Also Published As

Publication number Publication date
DE60304342D1 (de) 2006-05-18
DE60304342T2 (de) 2006-11-09
WO2004033506A1 (en) 2004-04-22
US20040097667A1 (en) 2004-05-20
EP1556422B1 (de) 2006-03-29
EP1556422A1 (de) 2005-07-27
AU2003270801A1 (en) 2004-05-04
US7494626B2 (en) 2009-02-24
US7232868B2 (en) 2007-06-19
US20060257294A1 (en) 2006-11-16

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