ATE245483T1 - Verfahren zur abtrennung eines rhodiumphosphitligandkomplexes und freien phosphitligandes aus hydroformylierungsmischungen - Google Patents

Verfahren zur abtrennung eines rhodiumphosphitligandkomplexes und freien phosphitligandes aus hydroformylierungsmischungen

Info

Publication number
ATE245483T1
ATE245483T1 AT00974489T AT00974489T ATE245483T1 AT E245483 T1 ATE245483 T1 AT E245483T1 AT 00974489 T AT00974489 T AT 00974489T AT 00974489 T AT00974489 T AT 00974489T AT E245483 T1 ATE245483 T1 AT E245483T1
Authority
AT
Austria
Prior art keywords
phosphite ligand
mixture
rhodium
separating
free
Prior art date
Application number
AT00974489T
Other languages
German (de)
English (en)
Inventor
Onko Jan Gelling
Peter Cornelis Borman
Hubertus Adrianus Smits
Veerle Cauwenberg
Franciscus Hendrik P Vergossen
Original Assignee
Dsm Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8240899&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE245483(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dsm Nv filed Critical Dsm Nv
Application granted granted Critical
Publication of ATE245483T1 publication Critical patent/ATE245483T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT00974489T 1999-11-23 2000-10-27 Verfahren zur abtrennung eines rhodiumphosphitligandkomplexes und freien phosphitligandes aus hydroformylierungsmischungen ATE245483T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99203927A EP1103303A1 (en) 1999-11-23 1999-11-23 Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture
PCT/EP2000/010699 WO2001037993A1 (en) 1999-11-23 2000-10-27 Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture

Publications (1)

Publication Number Publication Date
ATE245483T1 true ATE245483T1 (de) 2003-08-15

Family

ID=8240899

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00974489T ATE245483T1 (de) 1999-11-23 2000-10-27 Verfahren zur abtrennung eines rhodiumphosphitligandkomplexes und freien phosphitligandes aus hydroformylierungsmischungen

Country Status (11)

Country Link
US (1) US20030018210A1 (OSRAM)
EP (2) EP1103303A1 (OSRAM)
JP (1) JP2003514877A (OSRAM)
KR (1) KR100697916B1 (OSRAM)
CN (1) CN1164365C (OSRAM)
AT (1) ATE245483T1 (OSRAM)
AU (1) AU1277601A (OSRAM)
CA (1) CA2392195A1 (OSRAM)
DE (1) DE60004088T2 (OSRAM)
TW (1) TW527217B (OSRAM)
WO (1) WO2001037993A1 (OSRAM)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR0313866A (pt) 2002-08-31 2005-07-05 Oxeno Olefinchemie Gmbh Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos
DE10328715A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur kontinuierlichen Herstellung einer Verbindung, die mindestens zwei funktionelle Gruppen trägt
DE102005046250B4 (de) * 2005-09-27 2020-10-08 Evonik Operations Gmbh Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren
DE102006003618A1 (de) * 2006-01-26 2007-08-02 Oxeno Olefinchemie Gmbh Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen
DE102009001230A1 (de) * 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
DE102009016652A1 (de) * 2009-04-07 2010-10-14 Oxea Gmbh Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
US9555374B2 (en) 2009-04-29 2017-01-31 Basf Se Method for conditioning catalysts by means of membrane filtration
DE102012202779A1 (de) * 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
RU2585285C1 (ru) * 2015-04-20 2016-05-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ непрерывного гидроформилирования олефинов c2-c8
WO2019017490A1 (ja) * 2017-07-21 2019-01-24 宇部興産株式会社 ペンテン酸エステル誘導体の製造方法
JP7269238B2 (ja) 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
CN112479841B (zh) * 2020-11-26 2022-09-20 万华化学集团股份有限公司 一种丙烯氢甲酰化合成丁醛的工艺
WO2024123510A1 (en) 2022-12-06 2024-06-13 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1312076A (en) * 1970-05-15 1973-04-04 Bp Chem Int Ltd Hydroformylation process
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
CA2204676A1 (en) * 1996-05-15 1997-11-15 Helmut Bahrmann Process for preparing aldehydes
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound

Also Published As

Publication number Publication date
AU1277601A (en) 2001-06-04
TW527217B (en) 2003-04-11
KR20020052214A (ko) 2002-07-02
CN1164365C (zh) 2004-09-01
KR100697916B1 (ko) 2007-03-20
JP2003514877A (ja) 2003-04-22
WO2001037993A1 (en) 2001-05-31
DE60004088D1 (de) 2003-08-28
US20030018210A1 (en) 2003-01-23
CA2392195A1 (en) 2001-05-31
DE60004088T2 (de) 2004-04-22
EP1103303A1 (en) 2001-05-30
EP1232008B1 (en) 2003-07-23
EP1232008A1 (en) 2002-08-21
CN1424939A (zh) 2003-06-18

Similar Documents

Publication Publication Date Title
DE60004088D1 (de) Verfahren zur abtrennung eines rhodiumphosphitligandkomplexes und freien phosphitligandes aus hydroformylierungsmischungen
Sinn Proposals for structure and effect of methylalumoxane based on mass balances and phase separation experiments
ATE173266T1 (de) Sulfonierte 2,2'-bis(diphenylphosphinomethyl)- 1,1'-binaphthaline, verfahren zu ihrer herstellung und ihre verwendung in einem verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen
EP0933415A3 (de) Additive zur Inhibierung der Gashydratbildung
GB9507441D0 (en) Mixtures of hexahydrotriazines useful as h2s scavengers
DE3480845D1 (de) Verfahren zur herstellung von polyketonen.
FI872297A0 (fi) Menetelmä polymeerin valmistamiseksi hiilimonoksidista ja olefiinisesti tyydyttämättömästä orgaanisesta yhdisteestä (yhdisteistä)
ATE147398T1 (de) 3,4-dimethyl-2,5-6-tris(p-sulfonatophenyl)-1- phosphanorbornadien, verfahren zu seiner herstellung und verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen
BR9907091A (pt) Polipropileno modificado, e, processos para modificação de um (co)polìmero de polipropileno, para produzir um polipropileno modificado e, para modificação de um polìmero <244>-olefìnico
EP1279658A3 (de) Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator
EP0479462A1 (en) Method for inhibiting scale formation
EP0068773B1 (en) Polyethylene compositions
CA1051854A (en) Process for recovering catalyst systems from raw hydroformylation products
ATE292613T1 (de) Stabilisierte o- iodoxybenzoesäurezusammensetzungen und verfahren zu ihrer herstellung
Ayers et al. Solvent extraction of boron with 2-ethyl-1, 3-hexanediol and 2-chloro-4-(1, 1, 3, 3-tetramethylbutyl)-6-methylol-phenol
KR20130139828A (ko) 조절제 분자
RU2141543C1 (ru) Ингибитор сероводородной и/или углекислотной коррозии
KR970042691A (ko) 규소 함유 수용성 고분자 화합물 및 이의 제조방법 및 용도
KR20180127425A (ko) 가성 탑 내의 오염을 예방하기 위한 방법 및 조성물
CA1229621A (en) Metal ion control agents based on dicyclopentadiene derivatives
CA2057424A1 (en) Catalyst compositions and process for the preparation of polymers
EP1138675A3 (de) Verfahren zur Herstellung von 2-Methyl-4-amino-5-aminomethylpyrimidin
DE502005006117D1 (de) Verbindungen enthaltend 3,4-Methylendioxythiopen-Einheiten
EP1262227A3 (de) Emulgatorgemisch für die Emulsionspolymerisation
MX2007014906A (es) Esteres de acido aminocarboxilico con polimeros de bloque oe/op/obu y su empleo como desemulsionantes.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties