ATE229051T1 - Linear, optisch aktives polymer, verwendbar als ligand in der herstellung von asymmetrischen metallkomplexkatalysatoren - Google Patents

Linear, optisch aktives polymer, verwendbar als ligand in der herstellung von asymmetrischen metallkomplexkatalysatoren

Info

Publication number
ATE229051T1
ATE229051T1 AT00900590T AT00900590T ATE229051T1 AT E229051 T1 ATE229051 T1 AT E229051T1 AT 00900590 T AT00900590 T AT 00900590T AT 00900590 T AT00900590 T AT 00900590T AT E229051 T1 ATE229051 T1 AT E229051T1
Authority
AT
Austria
Prior art keywords
optically active
ligand
linear
production
metal complex
Prior art date
Application number
AT00900590T
Other languages
English (en)
Inventor
Marc Lemaire
Halle Rob Ter
Emmanuelle Schulz
Benoit Colasson
Michel Spagnol
Christine Saluzzo
Thierry Lamouille
Original Assignee
Rhodia Chimie Sa
Centre Nat Rech Scient
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa, Centre Nat Rech Scient filed Critical Rhodia Chimie Sa
Application granted granted Critical
Publication of ATE229051T1 publication Critical patent/ATE229051T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/06Phosphorus linked to carbon only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J5/00Devices or arrangements for controlling character selection
    • B41J5/08Character or syllable selected by means of keys or keyboards of the typewriter type
    • B41J5/10Arrangements of keyboards, e.g. key button disposition
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00Preparation of carboxylic acid amides
    • C07C231/16Preparation of optical isomers
    • C07C231/18Preparation of optical isomers by stereospecific synthesis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/5027Polyphosphines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07Optical isomers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
  • Polyurethanes Or Polyureas (AREA)
AT00900590T 1999-03-01 2000-01-14 Linear, optisch aktives polymer, verwendbar als ligand in der herstellung von asymmetrischen metallkomplexkatalysatoren ATE229051T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9902510A FR2790477B1 (fr) 1999-03-01 1999-03-01 Polymere lineaire optiquement actif utilisable comme ligand dans la preparation de complexes metalliques destines a la catalyse asymetrique
PCT/FR2000/000082 WO2000052081A1 (fr) 1999-03-01 2000-01-14 Polymere lineaire optiquement actif utilisable comme ligand dans la preparation de complexes metalliques destines a la catalyse asymetrique

Publications (1)

Publication Number Publication Date
ATE229051T1 true ATE229051T1 (de) 2002-12-15

Family

ID=9542657

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00900590T ATE229051T1 (de) 1999-03-01 2000-01-14 Linear, optisch aktives polymer, verwendbar als ligand in der herstellung von asymmetrischen metallkomplexkatalysatoren

Country Status (9)

Country Link
US (1) US6646106B1 (de)
EP (1) EP1161481B1 (de)
JP (1) JP4607337B2 (de)
AT (1) ATE229051T1 (de)
AU (1) AU3055000A (de)
DE (1) DE60000920T2 (de)
ES (1) ES2188499T3 (de)
FR (1) FR2790477B1 (de)
WO (1) WO2000052081A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2789992B1 (fr) * 1999-02-19 2001-05-25 Rhodia Chimie Sa Procede de preparation de diphosphines chirales utiles comme ligands dans la synthese de complexes destines a la catalyse asymetrique
US20030135014A1 (en) * 2001-11-26 2003-07-17 Radu Nora S. Polymeric, phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
US20070010695A1 (en) * 2002-12-18 2007-01-11 Marc Lemaire Diphosphines, preparation and uses thereof
FR2854405B1 (fr) * 2003-04-29 2008-02-29 Rhodia Chimie Sa Diphosphines chirales sous forme insoluble; leur preparation et leurs utilisations comme ligands dans la synthese de complexes destines a la catalyse asymetrique.
FR2854401A1 (fr) * 2003-04-29 2004-11-05 Rhodia Chimie Sa Diphosphines chirales sous forme insoluble, leur preparation et leurs utilisations comme ligands dans la synthese de complexes destines a la catalyse asymetrique.
US7402262B2 (en) * 2003-10-24 2008-07-22 Bar-Ilan University Electroconductive polymers
US7785496B1 (en) 2007-01-26 2010-08-31 Clemson University Research Foundation Electrochromic inks including conducting polymer colloidal nanocomposites, devices including the electrochromic inks and methods of forming same
CN106622376B (zh) * 2016-12-08 2019-10-11 武汉凯特立斯科技有限公司 一种内烯烃的异构化与氢甲酰化反应方法和催化剂
CN113817157B (zh) * 2021-09-28 2022-08-16 四川大学 一种半芳香族聚酰胺缩聚催化剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0728768B1 (de) * 1995-02-24 2002-08-28 Syngenta Participations AG An Seitenketten von Polymeren gebundene Diphosphine und deren Metall-Komplexe
JP3526956B2 (ja) * 1995-03-13 2004-05-17 高砂香料工業株式会社 光学活性ポリケトンの製造方法
HRP960295A2 (en) * 1995-07-06 1997-08-31 Ciba Geigy Ag Process for the hydrogenation of imines in the presence of immobilized iridium-diphosphine catalysts
GB9619684D0 (en) * 1996-09-20 1996-11-06 Oxford Asymmetry Ltd Phosphine ligands

Also Published As

Publication number Publication date
US6646106B1 (en) 2003-11-11
ES2188499T3 (es) 2003-07-01
EP1161481B1 (de) 2002-12-04
JP4607337B2 (ja) 2011-01-05
DE60000920D1 (de) 2003-01-16
WO2000052081A1 (fr) 2000-09-08
FR2790477B1 (fr) 2001-05-25
JP2002538249A (ja) 2002-11-12
AU3055000A (en) 2000-09-21
DE60000920T2 (de) 2003-12-04
FR2790477A1 (fr) 2000-09-08
EP1161481A1 (de) 2001-12-12

Similar Documents

Publication Publication Date Title
ATE213748T1 (de) Ethylenpolymerisation mit spezifischen eisen- oder kobaltkomplexen, neue pyridinbis(imine) und neue komplexe von pyridinbis(iminen) mit eisen und kobalt
ATE273329T1 (de) Polymerisation von olefinen
ATE229026T1 (de) Verbrückte nicht-aromatische anionische dienylgruppen enthaltende metallkomplexe und darauf basierte polymerisatonskatalysatoren
EA200100189A1 (ru) Полимеризация олефинов
ATE283295T1 (de) Polymerisation von ethylen
ATE229051T1 (de) Linear, optisch aktives polymer, verwendbar als ligand in der herstellung von asymmetrischen metallkomplexkatalysatoren
EA200000262A1 (ru) Полимеризация олефинов
ATE243719T1 (de) Verfahren zur herstellung von norbornensulfonamidpolymeren
DE69912599D1 (de) Copolymerisation von olefine
BR9804520A (pt) Polimerização catalitica e processos para a mesma
ATE282666T1 (de) Harze verwendbar als nassfestigkeitsmittel und krepphilfsmittel, ihre herstellung und ihre verwendung
PL375955A1 (en) Monocyclopentadienyl complexes
DE60020108D1 (de) Polymerisation von ethylen
DE50005290D1 (de) Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung
DE69940743D1 (de) Kunststoff-geträgerte phosphorliganden verwendbar in der katalyse
WO2004020479A3 (en) Monocyclopentadienyl complexes
EA200700682A1 (ru) Полимеры, подобные пэнп, с лигандами на основе бисинденила с различными циклами
DK1368403T3 (da) Polymerer
DE60211168D1 (de) Dianionische, chelatierende liganden enthaltende olefinpolymerisationkatalysatoren
EP1127897A3 (de) Eisen- oder Kobalt-Komplexe enthaltende Katalysatorzusammensetzung und Verfahren zur Ethylenoligomerisation oder Ethylenpolymerisation unter Verwendung derselben
ATE407960T1 (de) Absorbierendes polymerharz mit hoher konsistenz

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties