ATE113865T1 - Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung. - Google Patents

Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung.

Info

Publication number
ATE113865T1
ATE113865T1 AT91901538T AT91901538T ATE113865T1 AT E113865 T1 ATE113865 T1 AT E113865T1 AT 91901538 T AT91901538 T AT 91901538T AT 91901538 T AT91901538 T AT 91901538T AT E113865 T1 ATE113865 T1 AT E113865T1
Authority
AT
Austria
Prior art keywords
catalyst
hydrogenation
dehydrosilation
hydrosilation
acetylenes
Prior art date
Application number
AT91901538T
Other languages
English (en)
Inventor
Takamasa Fuchikami
Yumiko Ubukata
Yasutaka Tanaka
Original Assignee
Sagami Chem Res
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1335207A external-priority patent/JP2509718B2/ja
Priority claimed from JP2206879A external-priority patent/JPH0490856A/ja
Priority claimed from JP2206881A external-priority patent/JPH0490855A/ja
Priority claimed from JP2206880A external-priority patent/JPH0490857A/ja
Application filed by Sagami Chem Res filed Critical Sagami Chem Res
Application granted granted Critical
Publication of ATE113865T1 publication Critical patent/ATE113865T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0801—General processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827—Syntheses with formation of a Si-C bond
    • C07F7/0829—Hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0896—Compounds with a Si-H linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/188—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-O linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20—Carbonyls

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT91901538T 1989-12-26 1990-12-26 Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung. ATE113865T1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1335207A JP2509718B2 (ja) 1989-12-26 1989-12-26 水素化用触媒
JP2206879A JPH0490856A (ja) 1990-08-06 1990-08-06 ケトン類の脱水素シリル化用触媒及びシリルエノールエーテル類の製造方法
JP2206881A JPH0490855A (ja) 1990-08-06 1990-08-06 アセチレン類のヒドロシリル化用触媒及びビニルシラン類の製造方法
JP2206880A JPH0490857A (ja) 1990-08-06 1990-08-06 ジエン類のヒドロシリル化用触媒及びアリルシラン類の製造方法

Publications (1)

Publication Number Publication Date
ATE113865T1 true ATE113865T1 (de) 1994-11-15

Family

ID=27476326

Family Applications (1)

Application Number Title Priority Date Filing Date
AT91901538T ATE113865T1 (de) 1989-12-26 1990-12-26 Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung.

Country Status (5)

Country Link
US (1) US5182246A (de)
EP (1) EP0460240B1 (de)
AT (1) ATE113865T1 (de)
DE (1) DE69014101T2 (de)
WO (1) WO1991009674A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5508460A (en) * 1994-08-15 1996-04-16 Trustees Of The University Of Pennsylvania Method of synthesizing arylsilanes
US6613923B1 (en) 1999-01-22 2003-09-02 Brookhaven Science Associates, Llc Catalytic ionic hydrogenation of ketones using tungsten or molybdenum catalysts with increased lifetimes
US6124509A (en) * 1999-01-22 2000-09-26 Brookhaven Science Associates Catalytic ionic hydrogenation of ketones using tungsten or molybdenum organometallic species
US6392077B1 (en) * 2000-11-01 2002-05-21 Korea Institute Of Science And Technology Process for preparing organochlorosilanes by dehydrohalogenative coupling reaction of alkyl halides with chlorosilanes
US6737531B1 (en) 2002-12-17 2004-05-18 Brookhaven Science Associates, Llc Catalysts for hydrogenation and hydrosilylation, methods of making and using the same
CN114605462A (zh) * 2020-12-09 2022-06-10 中国科学院大连化学物理研究所 一种钴催化制备烯丙基硅衍生物的方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849513A (en) * 1969-10-01 1974-11-19 Exxon Research Engineering Co Disproportionation process
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3832403A (en) * 1971-03-01 1974-08-27 Univ Akron Method for reacting organic halides
FR2225401B1 (de) * 1973-04-12 1976-05-21 Aquitaine Petrole
US4190609A (en) * 1976-10-04 1980-02-26 Hooker Chemicals & Plastics Corp. Process for the directed chlorination of xylenes
DE2727245C3 (de) * 1977-06-16 1980-06-26 Brintzinger, Hans, Prof. Dr., 7750 Konstanz Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US4331811A (en) * 1981-03-12 1982-05-25 The Dow Chemical Company Preparation of 2,3-dichloro-5-trichloromethylpyridine
US4514380A (en) * 1984-01-09 1985-04-30 The Dow Chemical Company Method of preparing tetrarhodium dodecacarbonyl
JPS6178734A (ja) * 1984-09-25 1986-04-22 Sagami Chem Res Center α，β−不飽和カルボニル化合物の還元方法
FR2575085B1 (fr) * 1984-12-20 1987-02-20 Rhone Poulenc Spec Chim Complexe platine-triene comme catalyseur de reaction d'hydrosilylation et son procede de preparation
JPS61171450A (ja) * 1986-01-11 1986-08-02 T Hasegawa Co Ltd シス‐ジヤスモンの製法

Also Published As

Publication number Publication date
WO1991009674A1 (en) 1991-07-11
DE69014101T2 (de) 1995-03-23
US5182246A (en) 1993-01-26
EP0460240A4 (en) 1992-05-20
DE69014101D1 (de) 1994-12-15
EP0460240A1 (de) 1991-12-11
EP0460240B1 (de) 1994-11-09

Similar Documents

Publication Publication Date Title
Quatieri et al. Shape invariant time-scale and pitch modification of speech
ATE113865T1 (de) Katalysator zur hydrierung, dehydrosilylierung oder hydrosilylierung und dessen verwendung.
ATE32876T1 (de) Verfahren zur herstellung von mitteldestillaten.
DE69020730D1 (de) Verfahren zur herstellung eines beheizbaren und abkühlbaren elementes für ein system zur behandlung geringer stoffmengen von flüssigkeit und danach hergestelltes element.
DE69628912D1 (de) Herstellungb und verwendung eines spezifischen gaba-aalpha5 rezeptorligands zur behandlung der erkrankung von alzheimer
DE3772196D1 (de) Bauelemente von gasturbinen und verfahren zur herstellung von schutzschichten auf segmenten.
DE69502028D1 (de) Katalytische zusammensetzung und verfahren zur olefinpolymerisation
ATE143286T1 (de) Verfahren zur entfernung von hcn aus gasgemischen und katalysator zur zersetzung von hcn
AT365453B (de) Verfahren zur gewinnung des antihaemophilen faktors viii aus blut, blutplasma oder blutplasma- -fraktionen
DE69606353D1 (de) Übergangsmetallkomplexe enthaltende neue katalytische Zusammensetzung und Verfahren für die Hydrierung von ungesättigten Verbindungen
YU242190A (sh) Kompomente katalizatora za polimerizaciju olefina
DE69024791D1 (de) Kontinuierliches verfahren zur telomerisation von konjugierten dienen
DE3177306D1 (de) Verfahren und Verbindungen zur Herstellung von H-ARG-X-Z-Y-TYR-R.
DE69522580D1 (de) Carboxylierte aminoguanidine zur behandlung von insulin-unabhängigem diabetes mellitus
DE69721762D1 (de) Verfahren zur herstellung von siliconölen durch hydrosilylierung von polyorganohydrogensiloxanen und sauerstoff- enthaltenden cylischen verbindungen in anwesenheit eines heterogenes katalysator
ATE189146T1 (de) Verfahren zur herstellung von pulvern für hartmaterialien aus kobaltsalzen und löslichen wolframatsalzen
DE69610169D1 (de) Neue katalytische Zusammenstellung zur Zwei-Phasen-Katalyse, insbesondere auf Grund von Nickelkomplexen, und Verfahren zur Oligomerisierung von Olefinen
ATE204173T1 (de) Verwendung von 1-beta-d-ribofuranosyl-1,2,4- triazol-3-carboxamid (ribavirin) zur herstellung eines medikaments für die behandlung von arboviren
Jang et al. Using time-frequency analysis technique in the classification of surface EMG signals
FI925506A0 (fi) Menetelmä jätevesien puhdistamiseksi
DE69623325T2 (de) 4-hydroxycoumarin-3-carboxamide für die behandlung von nicht-insulin-abhängigen diabetes mellitus
ATE200414T1 (de) Verwendung eines mittels zur haarbehandlung
ATE177121T1 (de) Verfahren zum polymerisieren von cyclischen olefinen und photopolymerisierbare zusammensetzung
Wexler et al. Wigner-space synthesis of discrete-time periodic signals
DE68906700D1 (de) Verwendung eines polypeptids zur herstellung einer zusammensetzung zur behandlung von pankreatitis.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties